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201 条记录 (耗时 0.047 秒)

    Process for preparing composites based on oriented mesogenic thermoset resins
    55.
    发明授权
    Process for preparing composites based on oriented mesogenic thermoset resins 失效
    基于定向介晶热固性树脂制备复合材料的方法

    公开(公告)号：US5248360A

    公开(公告)日：1993-09-28

    申请号：US830105

    申请日：1992-02-03

    申请人： Robert E. Jones, Jr. ,  Jimmy D. Earls ,  Robert E. Hefner, Jr.

    发明人： Robert E. Jones, Jr. ,  Jimmy D. Earls ,  Robert E. Hefner, Jr.

    IPC分类号： C08J5/04 ,  C07D303/24 ,  C08G59/22 ,  C08J5/24 ,  C09K19/38

    CPC分类号： C08J5/24 ,  C07D303/24 ,  C08G59/22 ,  Y10T428/1059 ,  Y10T428/1073

    摘要： Continuous fiber reinforced oriented mesogen-containing resin matrix composites are prepared by (A) saturating a continuous fiber substrate material with a curable composition comprising (1) at least one mesogen-containing resin which contains an average of more than one vicinal epoxide group, thiirane group, cyanate group or vinyl ester group per molecule; and, optionally, (2) a curing amount of at least one curing agent and/or curing catalyst therefor; (B) arranging one or more saturated continuous fiber substrate material(s) formed in step (A) into a desired configuration; (C) subjecting the arranged saturated continuous fiber substrate material(s) from step (B) to a temperature which causes the mesogen-containing resin to convert to a liquid crystalline state; (D) subjecting the heated arranged saturated continuous fiber substrate material(s) from step (C) to a pressure sufficient to cause flow induced shear in the interstices of said continuous fiber substrate; (E) subjecting the continuous fiber substrate material of step (D) to curing conditions either simultaneously with the application of pressure in step (D) and/or subsequent to said application of pressure; and (F) permitting the cured continuous fiber reinforced composite of step (E) to cool to room temperature; thereby forming a cured continuous fiber reinforced composite containing an oriented mesogen-containing resin matrix. These composites have improved properties as compared to composites which are not oriented.

    摘要翻译： 通过（A）使可固化组合物饱和连续纤维基材材料制备连续纤维增强取向的含介晶树脂基复合材料，所述可固化组合物包含（1）含有平均多于一个邻位环氧基团的至少一个含介晶树脂， 基团，氰酸酯基或乙烯基酯基; 和（2）至少一种固化剂和/或其固化催化剂的固化量; （B）将在步骤（A）中形成的一个或多个饱和连续纤维基材材料排列成所需的构型; （C）使来自步骤（B）的排列的饱和连续纤维基材材料经受使含含介晶的树脂转化为液晶状态的温度; （D）对来自步骤（C）的经加热排列的饱和连续纤维基材进行足以在所述连续纤维基材的间隙中引起流动诱导剪切的压力; （E）使步骤（D）的连续纤维基材材料在步骤（D）中施加压力和/或在施加压力之后同时进行固化条件; 和（F）使步骤（E）的固化的连续纤维增强复合材料冷却至室温; 从而形成含有定向含介晶树脂基体的固化的连续纤维增强复合材料。 与不定向的复合材料相比，这些复合材料具有改进的性能。

    Mesogenic cyanate functional maleimides and thermosets thereof
    57.
    发明授权
    Mesogenic cyanate functional maleimides and thermosets thereof 失效
    介晶氰酸酯官能马来酰亚胺及其热固性材料

    公开(公告)号：US5077380A

    公开(公告)日：1991-12-31

    申请号：US596138

    申请日：1990-10-11

    申请人： Robert E. Hefner, Jr. ,  Jimmy D. Earls

    发明人： Robert E. Hefner, Jr. ,  Jimmy D. Earls

    IPC分类号： C07D207/44 ,  C07D207/452 ,  C08G73/12 ,  C08L63/00 ,  C09K19/38

    CPC分类号： C07D207/452 ,  C08G73/12 ,  C08L63/00 ,  C09K19/3804

    摘要： Compounds containing at least one cyanate group, at least one maleimide group and at least one mesogenic or rodlike moiety are prepared by reacting one or more aminophenols containing one or more mesogenic or rodlike moieties with a stoichimetric quantity of a maleic anhydride per amine group of said aminophenol and then cyanating the resulting phenolic functional maleimide.

    摘要翻译： 含有至少一个氰酸酯基团，至少一个马来酰亚胺基团和至少一个介晶或棒状部分的化合物通过一种或多种含有一种或多种介晶或棒状部分的氨基苯酚与每种每个胺基团的偶联剂量的马来酸酐反应来制备 然后将所得酚官能的马来酰亚胺氰化。

    Hybrid epoxy resin adducts
    60.
    发明授权
    Hybrid epoxy resin adducts 有权
    混合环氧树脂加合物

    公开(公告)号：US09255177B2

    公开(公告)日：2016-02-09

    申请号：US14117907

    申请日：2012-06-14

    申请人： Robert E. Hefner, Jr.

    发明人： Robert E. Hefner, Jr.

    IPC分类号： C08G59/14 ,  C08G59/04 ,  C08G59/18 ,  C08G59/02 ,  C08L63/00

    CPC分类号： C08G59/1477 ,  C08G59/022 ,  C08G59/04 ,  C08G59/184 ,  C08L63/00

    摘要： A hybrid epoxy resin adduct comprising, consisting of, or consisting essentially of the reaction product of: (A) a material selected from the group consisting of a hybrid polyfunctional aliphatic epoxy resin, a hybrid cycloaliphatic epoxy resin, and combinations thereof; wherein (A) is formed by contacting: (a) a hydroxyl-containing material selected from the group consisting of an aliphatic hydroxyl-containing material, a cycloaliphatic hydroxyl-containing material, and combinations thereof; (b) a material selected from the group consisting of a monoglycidyl ether-containing material, a diglycidyl ether-containing material, and combinations thereof wherein (b) is prepared from a different precursor than (a); (c) an epihalohydrin; (d) a basic acting substance; (e) a non-Lewis acid catalyst; and (f) optionally, a solvent and (B) at least one epoxide reactive compound comprising one or more compounds having two or more epoxide-reactive hydrogen atoms per molecule, is disclosed.

    摘要翻译： 一种混合环氧树脂加合物，其包含由以下物质组成或由其组成：（A）选自杂化多官能脂族环氧树脂，杂化脂环族环氧树脂及其组合的材料; 其中（A）通过使（a）选自含脂肪族羟基的材料，含脂环族羟基的材料及其组合的含羟基材料接触而形成; （b）选自含有单缩水甘油醚的材料，含二缩水甘油醚的材料及其组合的材料，其中（b）由不同于（a）的前体制备; （c）表卤代醇; （d）基本作用物质; （e）非路易斯酸催化剂; 和（f）任选地，溶剂和（B）至少一种包含一种或多种每分子具有两个或更多个环氧化物反应性氢原子的化合物的环氧化物反应性化合物。