公开(公告)号：US06284857B1

公开(公告)日：2001-09-04

申请号：US08351136

申请日：1994-11-30

申请人： Tetsunori Shinozaki ,  Kazumitsu Kawakita ,  Mamoru Kioka

发明人： Tetsunori Shinozaki ,  Kazumitsu Kawakita ,  Mamoru Kioka

IPC分类号： C08F1006

CPC分类号： C08F297/083 ,  C08F10/06 ,  C08F110/06 ,  C08F297/06 ,  C08F2500/15 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/26

摘要： Disclosed are a propylene polymer having a high crystallinity of a boiled heptane-insoluble component contained therein, a high stereoregularity and an extremely long mesochain (continuous propylene units wherein directions of &agr;-methyl carbons are the same as each other), and a process for preparing said polymer. Further disclosed is a propylene polymer composition comprising the above propylene polymer and at least one stabilizer selected from a phenol type stabilizer, an organophosphite type stabilizer, a thioether type stabilizer, a hindered amine type stabilizer and a metallic salt of higher aliphatic acid. The propylene polymer of the invention is excellent in rigidity, heat resistance and moisture resistance, and can be favorably used for sheet, film, filament, injection molded product, blow molded product, etc. The propylene polymer composition of the invention has excellent properties of the propylene polymer or the propylene block copolymer, and moreover is excellent in heat stability during the molding stage, long-term heat stability and weathering resistance. The propylene polymer composition can be favorably used for sheet, film, filament, injection molded product, blow molded product, etc.

摘要翻译： 公开了具有高沸点庚烷不溶性组分的高结晶度丙烯聚合物，高立构规整性和极长的分散信号（其中α-甲基碳的方向彼此相同的连续丙烯单元），以及 制备所述聚合物。 进一步公开的是包含上述丙烯聚合物和至少一种选自酚类稳定剂，有机亚磷酸酯类稳定剂，硫醚型稳定剂，受阻胺型稳定剂和高级脂肪酸的金属盐的稳定剂的丙烯聚合物组合物。 本发明的丙烯聚合物的刚性，耐热性和耐湿性优异，可有利地用于片材，薄膜，长丝，注塑产品，吹塑制品等。本发明的丙烯聚合物组合物具有优异的性能 丙烯聚合物或丙烯嵌段共聚物，并且在成型阶段的热稳定性，长期的热稳定性和耐候性也优异。 丙烯聚合物组合物可有利地用于片材，薄膜，长丝，注塑产品，吹塑产品等。

公开(公告)号：US06214939B1

公开(公告)日：2001-04-10

申请号：US09089116

申请日：1998-06-03

申请人： Tetsunori Shinozaki ,  Mamoru Kioka

发明人： Tetsunori Shinozaki ,  Mamoru Kioka

IPC分类号： C08F29708

CPC分类号： C08F297/083 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  Y02P20/52 ,  Y10S526/904 ,  C08F4/6492 ,  C08F4/6494 ,  C08F4/6465 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/18 ,  C08F210/16

摘要： The present invention provides olefin polymerization catalysts and processes for preparing a polypropylene and a propylene block copolymer using the olefin polymerization catalysts. The olefin polymerization catalyst (1) of the invention is formed from: (I-1) a contact product obtained by contacting: (A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (C) a specific organosilicon compound; (II-1) (D) a specific polyether compound; and optionally, (III) an organometallic compound catalyst component. The olefin polymerization catalyst (2) of the invention is formed from: (I-2) a contact product obtained by contacting: (A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (D) a specific polyether compound; (II-2) (C) a specific organosilicon compound; and optionally, (III) an organometallic compound catalyst component. The propylene is polymerized in the presence of the above-mentioned olefin polymerization catalysts to prepare highly isotactic polypropylene. The propylene block copolymer is prepared by the steps of polymerizing propylene to form a polypropylene component and copolymerizing ethylene and an &agr;-olefin of 3 to 20 carbon atoms to form an ethylene/&agr;-olefin copolymer component in the presence of the polymerization catalysts.

摘要翻译： 本发明提供烯烃聚合催化剂和使用烯烃聚合催化剂制备聚丙烯和丙烯嵌段共聚物的方法。 本发明的烯烃聚合催化剂（1）由以下物质形成：（I-1）通过使（A）固体钛催化剂成分，（B）有机金属化合物催化剂成分和（C） 有机硅化合物; （II-1）（D）特定的聚醚化合物; 和（III）有机金属化合物催化剂组分。 本发明的烯烃聚合催化剂（2）由以下物质形成：（I-2）通过使（A）固体钛催化剂成分（B）有机金属化合物催化剂成分与（D） 聚醚化合物; （II-2）（C）特定的有机硅化合物; 和（III）有机金属化合物催化剂组分。 丙烯在上述烯烃聚合催化剂的存在下聚合以制备高度全同立构的聚丙烯。 丙烯嵌段共聚物通过聚合丙烯以形成聚丙烯组分并使乙烯和3-20个碳原子的α-烯烃共聚以在聚合催化剂存在下形成乙烯/α-烯烃共聚物组分的步骤来制备。

公开(公告)号：US6080828A

公开(公告)日：2000-06-27

申请号：US310918

申请日：1999-05-13

申请人： Shin-ichi Kojoh ,  Mamoru Kioka

发明人： Shin-ichi Kojoh ,  Mamoru Kioka

IPC分类号： C08F4/658 ,  C08F4/651 ,  C08F4/655 ,  C08F8/00 ,  C08F10/02 ,  C08F110/02

CPC分类号： C08F10/02 ,  C08F110/02 ,  Y10S526/904

摘要： An ethylene polymer having small values of Mw/Mn and Mz/Mw, a small proportion of long-chain branches, a high melt tension and a high swell ratio, and a process for preparing the ethylene polymer are disclosed. A solid titanium catalyst component obtained by initially bringing a solid titanium composite which is obtained by the contact of a solid magnesium aluminum composite containing magnesium, halogen, aluminum, and an alkoxy group of 6 or more carbon atoms and/or alcohol of 6 or more carbon atoms with a tetravalent titanium compound into contact with an organometallic compound, and then bringing the resulting product into contact with oxygen is further disclosed. An ethylene polymerization catalyst comprising the above catalyst component and an organometallic compound catalyst component is furthermore disclosed. Therefore, the ethylene polymer is excellent in moldability, and a molded article obtained therefrom is excellent in rigidity and impact resistance and free from poor appearance.

摘要翻译： 公开了具有小的Mw / Mn值和Mz / Mw值，小分支长支链，高熔体张力和高溶胀比的乙烯聚合物，以及制备乙烯聚合物的方法。 一种固体钛催化剂组分，其通过首先将含有6个或更多个碳原子和/或6个或更多个碳原子的烷基的固体镁铝复合物与含有镁，卤素，铝的固体镁铝复合物接触而获得的固体钛复合物 碳原子与四价钛化合物与有机金属化合物接触，然后使所得产物与氧接触。 还公开了包含上述催化剂组分和有机金属化合物催化剂组分的乙烯聚合催化剂。 因此，乙烯聚合物的成型性优异，其得到的成型体的刚性和耐冲击性优异，外观不良。

公开(公告)号：US5939495A

公开(公告)日：1999-08-17

申请号：US809926

申请日：1997-04-10

申请人： Mamoru Kioka ,  Shinichi Kojo

发明人： Mamoru Kioka ,  Shinichi Kojo

IPC分类号： C08F4/656 ,  C08F4/60 ,  C08F8/00 ,  C08F10/00

CPC分类号： C08F8/00

摘要： The present invention relates to a process for producing a polyolefin having a functional group at its terminal and the object thereof is to provide a process in which the above polyolefin can be obtained with industrial advantages. This object can be attained by the process comprising step (A) producing a terminal-modified polyolefin of the formula P-AlR.sup.1 R.sup.2, wherein P is a polymer chain and each of R.sup.1 and R.sup.2 is, for example, a hydrocarbon group having 1 to 10 carbon atoms, in the presence of an olefin polymerization catalyst composed of a solid titanium catalyst component (a) and an organoaluminum compound catalyst component (b) optionally together with an organosilicon compound (c) and step (B) producing a polyoiefin of the formula P-X, wherein P is as defined above and X is a functional group, by conducting a substitution reaction between -AlR.sup.1 R.sup.2 group of the terminal-modified polyolefin obtained in the above step (A) and a compound having a functional group structure or by first conducting a substitution reaction between -AlR.sup.1 R.sup.2 group of the terminal-modified polyolefin obtained in the above step (A) and a compound having such a structure that a functional group is formed by solvolysis and thereafter conducting solvolysis. The polyolefin having a functional group at its terminal is advantageously used as, for example, a compatibilizer for a polymer blend or a starting material in molecular designing.

摘要翻译： PCT No.PCT / JP95 / 02081 Sec。 371日期1997年04月10日 102（e）日期1997年4月10日PCT提交1995年10月12日PCT公布。 出版物WO96 / 11958 日期：1996年04月25日本发明涉及一种在其末端具有官能团的聚烯烃的制造方法，其目的在于提供其工业上可以得到上述聚烯烃的方法。 该目的可以通过包括步骤（A）制备式P-AlR 1 R 2的末端改性聚烯烃的方法来实现，其中P是聚合物链，R 1和R 2各自是例如具有1至10个 在由固体钛催化剂组分（a）和有机铝化合物催化剂组分（b）组成的烯烃聚合催化剂的存在下，任选与有机硅化合物（c）和步骤（B）一起制备式（I）的聚烯烃， PX，其中P如上所定义，X是官能团，通过在上述步骤（A）中获得的末端改性聚烯烃的-AlR 1 R 2基团和具有官能团结构的化合物之间进行取代反应或通过首先导电 在上述步骤（A）中获得的末端改性聚烯烃的-AlR1R2基团与通过溶剂分解形成官能团的结构的化合物之后进行取代反应，然后导入 溶剂分解。 在其末端具有官能团的聚烯烃有利地用作例如聚合物共混物的增容剂或分子设计中的原料。

公开(公告)号：US5780378A

公开(公告)日：1998-07-14

申请号：US523946

申请日：1995-09-06

申请人： Tetsuya Toida ,  Tetsunori Shinozaki ,  Mamoru Kioka

发明人： Tetsuya Toida ,  Tetsunori Shinozaki ,  Mamoru Kioka

IPC分类号： C08F4/654 ,  C08F4/60 ,  C08F4/64 ,  C08F4/642 ,  C08F4/651 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

CPC分类号： C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  Y10S526/904

摘要： A solid titanium catalyst component comprising (a) magnesium, (b) titanium, (c) a halogen, (d) a polyether, (e) a hydrocarbon and (f) an electron donor other than the polyether (d) as essential components is provided. Also a process for preparing a solid titanium catalyst component for olefin polymerization, comprising the steps of contacting a halogenated magnesium compound with a compound selected from the group consisting of an alcohol, an ether and an ester in a hydrocarbon solvent to obtain a magnesium compound solution, contacting the magnesium compound solution with a polyether and contacting the resultant solution with a liquid titanium compound is provided. Further, a catalyst for olefin polymerization comprising the above-mentioned solid titanium catalyst component, an organoaluminum compound catalyst component and an electron donor, and a process for polymerizing an olefin using the catalyst for olefin polymerization are also disclosed. By the use of the catalyst for olefin polymerization, an olefin (co)polymer having uniform particle size, less dust quantity, high bulk density and high stereoregularity can be obtained with excellent polymerization activity.

公开(公告)号：US5618886A

公开(公告)日：1997-04-08

申请号：US690054

申请日：1996-07-31

申请人： Tetsunori Shinozaki ,  Mamoru Kioka

发明人： Tetsunori Shinozaki ,  Mamoru Kioka

IPC分类号： C08F4/02 ,  C08F4/649 ,  C08F4/651 ,  C08F4/654 ,  C08F4/658 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F297/08 ,  C08F8/00

CPC分类号： C08F297/083 ,  C08F10/06 ,  C08F210/06 ,  C08F110/06 ,  Y02P20/52 ,  Y10S526/904

摘要： The present invention provides olefin polymerization catalysts and processes for preparing a polypropylene and a propylene block copolymer using said olefin polymerization catalysts.The olefin polymerization catalyst (1) of the invention is formed from:[I-1] a contact product obtained by contacting:(A) a solid titanium catalyst component,(B) an organometallic compound catalyst component, and(C) a specific organosilicon compound;[II-1] (D) a specific polyether compound; and optionally,[III] an organometallic compound catalyst component.The olefin polymerization catalyst (2) of the invention is formed from:[I-2] a contact product obtained by contacting:(A) a solid titanium catalyst component,(B) an organometallic compound catalyst component, and(D) a specific polyether compound;[11-2] (C) a specific organosilicon compound.

摘要翻译： 本发明提供烯烃聚合催化剂和使用所述烯烃聚合催化剂制备聚丙烯和丙烯嵌段共聚物的方法。 本发明的烯烃聚合催化剂（1）由以下物质形成：[I-1]通过使（A）固体钛催化剂成分，（B）有机金属化合物催化剂成分和（C） 有机硅化合物; [II-1]（D）特定的聚醚化合物; 和[III]有机金属化合物催化剂组分。 本发明的烯烃聚合催化剂（2）由以下物质形成：[I-2]通过使（A）固体钛催化剂成分，（B）有机金属化合物催化剂成分和（D） 聚醚化合物; [11-2]（C）特定的有机硅化合物。

公开(公告)号：US5292811A

公开(公告)日：1994-03-08

申请号：US33432

申请日：1993-03-18

申请人： Kazuhiko Murata ,  Shizuo Shimizu ,  Mamoru Kioka ,  Akinori Toyota

发明人： Kazuhiko Murata ,  Shizuo Shimizu ,  Mamoru Kioka ,  Akinori Toyota

IPC分类号： C08F287/00 ,  C08L23/16 ,  C08L23/26 ,  C08L53/00

CPC分类号： C08F287/00 ,  C08L23/16 ,  C08L2207/04 ,  C08L2312/00 ,  Y10S526/943

摘要： Proposed herein is a process for preparing thermoplastic elastomers, which comprises dynamically heat treating polymer particles together with a crosslinking agent, each of the polymer particles being composed of a portion comprising a crystalline olefin polymer and portions comprising an amorphous olefin polymer, the polymer particles having an average particle diameter of at least 10 .mu.m and an apparent bulk density of at least 0.2 g/ml.

摘要翻译： 本文提出了一种制备热塑性弹性体的方法，其包括将交联剂与聚合物颗粒一起动态热处理，每个聚合物颗粒由包含结晶烯烃聚合物的部分和包含无定形烯烃聚合物的部分组成，聚合物颗粒具有 平均粒径为至少10（my）m，表观松密度为至少0.2g / ml。

公开(公告)号：US5266636A

公开(公告)日：1993-11-30

申请号：US928015

申请日：1992-08-11

申请人： Mamoru Kioka ,  Masaya Yamada ,  Masanobu Ishiyama ,  Masao Nakano ,  Akinori Toyota

发明人： Mamoru Kioka ,  Masaya Yamada ,  Masanobu Ishiyama ,  Masao Nakano ,  Akinori Toyota

IPC分类号： C08F10/06 ,  C08L23/10 ,  C08F297/08 ,  C08J5/18 ,  C08L23/20

CPC分类号： C08F10/06

摘要： A process for producing polypropylene, which comprises preliminarily polymerizing 3-methylbutene-1 in the presence of a catalyst system formed from[A] a solid titanium catalyst component containing magnesium, titanium, halogen and polycarboxylic acid esters as essential components,[B] an organoaluminum compound, and[C] an organosilicon compound represented by the general formula R.sub.n Si(OR').sub.4-n wherein R and R' represent a hydrocarbon group, and 0

摘要翻译： 一种生产聚丙烯的方法，其包括在由[A]含有镁，钛，卤素和多元羧酸酯作为必要组分的固体钛催化剂组分形成的催化剂体系的情况下预先聚合3-甲基丁烯[B] 有机铝化合物和[C]由通式RnSi（OR'）4-n表示的有机硅化合物，其中R和R'表示烃基，0

公开(公告)号：US06630559B2

公开(公告)日：2003-10-07

申请号：US09899135

申请日：2001-07-06

申请人： Tetsunori Shinozaki ,  Kazumitsu Kawakita ,  Mamoru Kioka

发明人： Tetsunori Shinozaki ,  Kazumitsu Kawakita ,  Mamoru Kioka

IPC分类号： C08F4642

CPC分类号： C08F297/083 ,  C08F10/06 ,  C08F110/06 ,  C08F297/06 ,  C08F2500/15 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/26

摘要： Disclosed are a propylene polymer having a high crystallinity of a boiled heptane-insoluble component contained therein, a high stereoregularity and an extremely long mesochain (continuous propylene units wherein directions of {acute over (&agr;)}-methyl carbons are the same as each other), and a process for preparing said polymer. Further disclosed is a propylene polymer composition comprising the above propylene polymer and at least one stabilizer selected from a phenol type stabilizer, an organophosphite type stabilizer, a thioether type stabilizer, a hindered amine type stabilizer a metallic salt of higher aliphatic acid. The propylene block polymer of the invention is well-balanced between rigidity, heat resistance and moisture resistance, and can be favorably used for sheet, filament, injection molded product, blow molded product, etc. The propylene polymer composition of the invention has excellent properties of the propylene polymer of or the propylene block copolymer, and moreover is excellent in heat stability during the molding stage, long-term heat stability and weathering resistance. The propylene polymer composition can be favorably used for sheet, film, filament, injection mold product, blow molded product, etc.

摘要翻译： 公开了具有高沸点庚烷不溶性组分的高结晶度丙烯聚合物，高立构规整性和极长的分散信号（其中α-甲基碳的方向彼此相同的连续丙烯单元），以及 制备所述聚合物。 还公开了包含上述丙烯聚合物和至少一种选自酚类稳定剂，有机亚磷酸酯型稳定剂，硫醚型稳定剂，受阻胺型稳定剂，高级脂肪酸金属盐的稳定剂的丙烯聚合物组合物。 本发明的丙烯嵌段聚合物在刚性，耐热性和耐湿性之间的平衡性良好，可有利地用于片材，长丝，注塑产品，吹塑产品等。本发明的丙烯聚合物组合物具有优异的性能 丙烯嵌段共聚物的丙烯聚合物，而且在成型阶段的热稳定性，长期的热稳定性和耐候性优异。 丙烯聚合物组合物可有利地用于片，膜，丝，注塑产品，吹塑产品等。

公开(公告)号：US06521560B1

公开(公告)日：2003-02-18

申请号：US09109908

申请日：1998-07-02

申请人： Shinichi Kojoh ,  Mamoru Kioka

发明人： Shinichi Kojoh ,  Mamoru Kioka

IPC分类号： C08F460

CPC分类号： C08F10/00 ,  C08F4/6543

摘要： This invention provides a solid titanium catalyst component which comprises magnesium, titanium, halogen and an electron donor, is free from elimination of titanium when washed with hexane at room temperature, and has a titanium content decrease ratio of less than 15 % by weight when washed with o-dichlorobenzene at 90° C. The catalyst component can be prepared by a process wherein solid titanium (i) which is free from elimination of titanium when washed with hexane at room temperature is contacted with a polar compound having a dipole moment of 0.50 to 4.00 Debye to decrease the titanium content by at least 25 % by weight, whereby a solid titanium catalyst component having a weight ratio of an electron donor to titanium of at least 6 is prepared. Olefin polymerization catalyst containing the solid titanium catalyst component can be used for (co)polymerization of olefins with high activity to obtain a polyolefin of high stereoregularity in decreased quantities of a low stereoregular polyolefin.

摘要翻译： 本发明提供了一种固体钛催化剂组分，其包含镁，钛，卤素和电子给体，在室温下用己烷洗涤时，不会除去钛，并且当洗涤时钛含量降低率小于15重量％ 与邻二氯苯在90℃下反应。催化剂组分可以通过其中在室温下用己烷洗涤时不消除钛的固体钛（i）的方法制备，其中偶极矩为0.50的极性化合物 至4.00德拜，以将钛含量降低至少25重量％，由此制备电子给体与钛的重量比至少为6的固体钛催化剂组分。 含有固体钛催化剂组分的烯烃聚合催化剂可以用于具有高活性的（共）聚合烯烃，以获得低立体规则聚烯烃的量减少的高立构规整性的聚烯烃。