Abstract:
There is described a method of determining the UV fluence received by a fluid. The method comprises the steps of: (a) irradiating the fluid at an unknown UV fluence; (b) measuring the fluorescence of a test sample of the fluid after irradiation in Step (a) to produce a test signal proportional to the concentration of a prescribed fluorescent composition of matter comprised in the test sample; and (c) determining the value of the unknown UV fluence by comparing the test signal to a calibration curve of a control signal proportional to concentration of the prescribed fluorescent composition of matter in the fluid as a function of applied UV fluence. There is also described a system for determining the UV fluence received by a fluid being treated in UV fluid treatment system comprising at least one UV source. The system comprises: (a) a radiation-transparent vessel for receiving a test sample of the fluid after irradiation of the fluid at an unknown UV fluence; (b) a fluorometer for measuring the fluorescence of the test sample received in the radiation-transparent vessel to produce a test signal proportional to the concentration of a prescribed fluorescent composition of matter comprised in the test sample; and (c) a controller configured to determine the value of the unknown UV fluence by comparing the test signal to a calibration curve of a control signal proportional to concentration of the prescribed fluorescent composition of matter in the fluid as a function of applied UV fluence.
Abstract:
There is described a process for treatment of a fluid comprising an oxidizable contaminant. The process comprises the step of contacting the wastewater with a combination of: (i) a sulfide, (ii) a complex of Fe(III) and a chelating agent, and (iii) an oxidant. It has been discovered that of treatment of a fluid containing an oxidizable contaminant employing iron(III)-chelates as the Fenton catalyst may be significantly improved by including a sulfide in the reaction scheme. As described herein, by employing sulfide ion, the present inventors have been able to: (i) increase the rate of iron recycling from minutes or hours to a few seconds, and (ii) destroy benzene in an oil and gas refinery (OGR) wastewater in less than one minute. It is believed that these findings in OGR wastewater can be extended to other fluids containing other oxidizable contaminants.
Abstract:
The is described a process for determining a validated Reduction Equivalent Dose for reducing the concentration of a target contaminant contained in a fluid in a radiation fluid treatment system. In one embodiment, the process comprises the steps of: (a) determining a short wavelength Reduction Equivalent Dose for the target contaminant or a challenge contaminant in a first region of the electromagnetic spectrum having a wavelength of less than or equal to about 240 nm; (b) determining a long wavelength Reduction Equivalent Dose for the target contaminant or a challenge contaminant in a second region of the electromagnetic spectrum having a wavelength of greater than about 240 nm; and (c) summing the short wavelength Reduction Equivalent Dose and the long wavelength Reduction Equivalent Dose to produce the validated Reduction Equivalent Dose for the target contaminant. In a preferred embodiment, the present invention provides a useful approach for determining the relevant Reduction Equivalent Dose (RED) for Cryptosporidium disinfection and accomplishes this by using the discovered relation between the short wavelength sensor signal and the short wavelength RED, and subtracting the short wavelength RED from the RED determined using a challenge microbe with synthetic lamp sleeves, to obtain the long wavelength RED applicable to Cryptosporidium disinfection. In a bioassay, one would only need the short wavelength sensor reading and the challenge microbe RED using synthetic lamp sleeves to determine the applicable RED, once the relationship between the short wavelength sensor reading and the short wavelength RED was established.
Abstract:
A fluid treatment system having an inlet, an outlet, and a fluid treatment zone therebetween. The zone has an array of rows of radiation source assemblies. Each radiation source assembly has a longitudinal axis disposed at an oblique angle with respect to a direction of fluid flow. Each row has a plurality of radiation source assemblies in spaced relation in a direction transverse to the direction of fluid flow, to define a gap through which fluid may flow between an adjacent pair of assemblies. Preferably, all rows in the array are staggered with respect to one another in a direction orthogonal to the direction of fluid flow, such that the gap between an adjacent pair of radiation source assemblies in an upstream row of assemblies is partially or completely obstructed in the direction of fluid flow by a serially disposed radiation source assembly in at least one downstream row.
Abstract:
There is described an on-line device for predicting at least one fluid flow parameter in a process. In embodiment, the process in question comprises a flow domain having disposed therein a pre-determined portion in which a fluid flows and the device comprises a computer having: (i) a memory for receiving a database, the database comprising relative information in respect of a plurality of nodes or a plurality of particle pathways in the pre-determined portion; (ii) means to receive input data from the process, and (iii) means to calculate the at least one fluid flow parameter from the database and the input data. In another embodiment the process in question comprises a bounded flow domain having disposed therein a pre-determined matrix and the device comprises a computer having: (i) a memory for receiving a database, the database comprising location information for a plurality of nodes or particle pathways in the matrix, (ii) means to receive input data from the process, and (iii) means to calculate the at least one fluid flow parameter from the database and the input data. The device is particularly advantageously employed as a UV dosimeter.
Abstract:
A fluid treatment device, preferably for the treatment of water, is described. The device comprises a closed housing having a fluid inlet, a fluid outlet and a fluid treatment zone disposed between the fluid inlet and the fluid outlet. The fluid treatment zone comprises a first irradiation zone and a second irradiation zone. At least one fluid mixing element is interposed between the first irradiation zone and the second irradiation zone.
Abstract:
A radiation source module comprising a support member, a radiation source assembly connected to the support member and a seal disposed on a first surface of the module, the seal operable to provide a substantially fluid tight seal between the first surface and a second surface which is adjacent to the first surface.