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公开(公告)号：US5286691A
公开(公告)日：1994-02-15
申请号：US966475
申请日：1992-10-26
CPC分类号： C10G11/182 , B01J29/90 , B01J38/30 , Y10S502/516
摘要： A process for demetallizing metals contaminated FCC catalyst in an FCC regenerator. A metals getter additive, with higher settling velocity, is added to the regenerator, to remove metals from FCC catalyst by solid-solid interaction. The FCC catalyst forms a light, discrete, dense phase fluidized bed on top of a fluidized bed of additive. FCC catalyst is recycled to the cracking reactor from the top fluidized bed, while additive can be withdrawn from the lower fluidized bed for disposal or for metals recovery and recycle. Additive can be optimized for metals removal and will not dilute the cracking catalyst in the FCC reactor.
摘要翻译： 在FCC再生器中使金属污染的FCC催化剂脱金属的方法。 将一种具有较高沉降速度的金属吸附剂添加到再生器中，以通过固体 - 固体相互作用从FCC催化剂中除去金属。 FCC催化剂在添加剂流化床的顶部形成轻质，离散的致密相流化床。 FCC催化剂从顶部流化床再循环到裂化反应器中，而添加剂可从下流化床中排出以进行处理或用于金属回收和回收。 添加剂可以优化金属去除，不会稀释FCC反应器中的裂化催化剂。
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公开(公告)号：US5260493A
公开(公告)日：1993-11-09
申请号：US907909
申请日：1992-07-02
申请人： Mohsen N. Harandi , Hartley Owen
发明人： Mohsen N. Harandi , Hartley Owen
CPC分类号： C07C41/06 , C10L1/023 , C10G2300/1092
摘要： A continuous process for converting lower aliphatic alkanol and light olefinic hydrocarbon feedstock rich in tertiary olefins, such as isobutylene and other C.sub.4 isomeric hydrocarbons, to alkyl tertiary-alkyl ethers and C.sub.5 + gasoline boiling range hydrocarbons. An improved process and reactor system includes means for: washing the olefinic hydrocarbon feedstock with an aqueous liquid stream in a contactor unit to recover water-soluble impurities therefrom in a washwater stream recovered from the contactor unit; contacting the lower aliphatic alkanol and a washed light olefinic hydrocarbon stream from the contactor unit under iso-olefin etherification conditions in at least one etherification reaction zone containing acid etherification catalyst; separating etherification effluent to recover a light primary effluent stream comprising unreacted alkanol and light olefinic hydrocarbon and a liquid product stream containing alkyl tertiary-butyl ether; contacting at least one effluent stream containing unreacted alkanol and light olefinic hydrocarbon with a substantially fresh water liquid extractant stream to recover unreacted alkanol therein. In a preferred embodiment, at least a portion of the alkanol-containing liquid extract stream is passed to the washing step for treatment of hydrocarbon feedstock.
摘要翻译： 将富含叔烯烃（如异丁烯和其他C4异构烃）的低级脂族链烷醇和轻质烯烃原料转化为烷基叔烷基醚和C5 +汽油沸程烃的连续方法。 改进的方法和反应器系统包括用于在接触器单元中用含水液体流洗涤烯烃原料以在从接触器单元回收的洗涤水流中回收水溶性杂质的装置; 在含有酸醚化催化剂的至少一个醚化反应区中，在异烯烃醚化条件下使来自接触器单元的低级脂族链烷醇和洗涤的轻质烯烃物流接触; 分离醚化流出物以回收包含未反应的链烷醇和轻烯烃的轻的初级流出物流和含有烷基叔丁基醚的液体产物流; 将含有未反应的链烷醇和轻质烯烃的至少一种流出物流与基本上为淡水的液体萃取剂流接触以在其中回收未反应的链烷醇。 在优选的实施方案中，将至少一部分含链烷醇的液体提取物料流送至用于处理烃原料的洗涤步骤。
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公开(公告)号：US5233101A
公开(公告)日：1993-08-03
申请号：US958829
申请日：1992-10-09
申请人： Mohsen N. Harandi
发明人： Mohsen N. Harandi
摘要： An improvement in iso-olefin hydration is obtained in an integrated process combining a fluidized catalytic cracking reaction and a fluidized catalyst hydration reaction wherein zeolite catalyst particles are withdrawn in partially deactivated form from the alkanol reaction stage and added as part of the catalyst in the FCC reaction.
摘要翻译： 在结合流化催化裂化反应和流化催化剂水合反应的一体化方法中获得异烯烃水合的改进，其中沸石催化剂颗粒以部分失活的形式从烷醇反应阶段取出并作为FCC中的催化剂的一部分加入 反应。
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64.发明授权
公开(公告)号：US5146032A
公开(公告)日：1992-09-08
申请号：US806780
申请日：1991-12-12
申请人： Mohsen N. Harandi
发明人： Mohsen N. Harandi
CPC分类号： C07C2/12 , C07C1/20 , C10G3/49 , C10G50/00 , C10L1/023 , B01J29/40 , C07C2529/06 , C07C2529/40 , C10G2300/1088 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/20 , C10G2400/22 , Y02P20/125 , Y02P20/52 , Y02P30/20
摘要： An integrated process comprising the steps of pressurizing a C.sub.3.sup.+ olefin hydrocarbon stream and a methanol feed and contacting the C.sub.3.sup.+ hydrocarbon stream and methanol feed in a first reaction zone with a medium-pore shape selective oligomerization zeolite catalyst at elevated pressure and moderate temperature to convert at least a portion of the C.sub.3.sup.+ hydrocarbons and methanol feed to heavier liquid hydrocarbon product stream comprising olefinic gasoline and distillate range liquids. An ethene stream and a stream containing unreacted methanol and water are recovered from the first reaction zone effluent and the methanol is separated from the water.The ethene and the separated unreacted methanol are contacted with a medium-pore shape selective zeolite catalyst in a second reaction zone at elevated temperature and moderate pressure to convert the methanol feed to hydrocarbons comprising C.sub.3.sup.+ olefins and cooling effluent from the second reaction zone to recover a C.sub.3.sup.+ olefin hydrocarbon stream and a C.sub.2.sup.- light gas stream. The C.sub.3.sup.+ olefin hydrocarbon stream is fed to the first reaction zone with the methanol feed.
摘要翻译： 一种整合方法，其包括以下步骤：加压C3 +烯烃烃流和甲醇进料，并在第一反应区中将C3 +烃流和甲醇进料与中孔形选择性低聚沸石催化剂在升高的压力和适中的温度下接触以在 至少一部分C3 +烃和甲醇进料到包含烯烃汽油和馏出液范围液体的较重液体烃产物流中。 从第一反应区流出物回收乙烯流和含有未反应的甲醇和水的流，并将甲醇与水分离。 将乙烯和分离的未反应的甲醇在高温和中等压力下在第二反应区中与中孔形选择性沸石催化剂接触，以将甲醇进料转化成包含C3 +烯烃的烃和来自第二反应区的冷却流出物，以回收 C3 +烯烃烃流和C2轻质气流。 用甲醇进料将C3 +烯烃烃料流送入第一反应区。
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公开(公告)号：US5144086A
公开(公告)日：1992-09-01
申请号：US695843
申请日：1991-05-06
CPC分类号： C07C41/09 , C07C1/24 , C07C2529/70
摘要： A process for synthesizing di-isopropyl ether (DIPE) by etherification of isopropanol. A multi-stage process can employ propene in mixture with other feedstock materials, such as propane from refinery gas, in a primary hydration stage to produce isopropanol. The isopropanol is enriched between stages to remove water. In the second reaction stage the isopropanol is converted catalytically with large pore acidic zeolite to yield DIPE, which can be separated to recover pure propene.
摘要翻译： 通过异丙醇醚化合成二异丙醚（DIPE）的方法。 多级方法可以在初级水合阶段中使用丙烯与其它原料物质混合，例如来自精炼厂气体的丙烷，以产生异丙醇。 阶段之间富含异丙醇以除去水分。 在第二反应阶段，异丙醇用大孔酸性沸石催化转化，得到DIPE，可以分离回收纯丙烯。
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66.发明授权Integrated system for extraction of crude alcohol and co-conversion raffinate with olefin 失效用于萃取粗醇和烯烃共转化萃余液的综合系统
公开(公告)号：US5064623A
公开(公告)日：1991-11-12
申请号：US308237
申请日：1989-02-09
申请人： Mohsen N. Harandi , Hartley Owen
发明人： Mohsen N. Harandi , Hartley Owen
IPC分类号： C07C41/06
CPC分类号： C07C41/06 , Y10S203/06
摘要： An improved reactor system reacts crude aqueous methanol feedstock with iso-olefinic hydrocarbons to produce C.sub.5.sup.+ methyl t-alkyl ethers. The system includes an extractor for contacting the aqueous methanol feedstock with a liquid hydrocarbon extraction solvent rich in C.sub.4.sup.+ isoalkene. Both an organic extract phase and an aqueous methanol raffinate phase recovered from the extractor and fed to a primary reactor. This primary reactors reacts the methanol and C.sub.4.sup.+ isoalkene from the organic extract phase under catalytic conditions to produce an ether product. The ether product is fed to an etherification effluent fractionator to separate the ether product from unreacted methanol and C.sub.4.sup.+ isoalkene. A secondary reactor then converts methanol from the aqueous methanol raffinate phase with the unreacted methanol and C.sub.4.sup.+ isolakene to produce hydrocarbons.
摘要翻译： 改进的反应器系统使粗的含水甲醇原料与异烯烃反应生成C5 +甲基t-烷基醚。 该系统包括用于使含水甲醇原料与富含C 4 +异烯烃的液体烃萃取溶剂接触的萃取器。 从萃取器中回收有机提取相和含水甲醇萃余液相，并将其进料到初级反应器中。 该初级反应器在催化条件下从有机萃取相中使甲醇和C 4+异烯烃反应生成醚产物。 将醚产物进料至醚化流出物分馏器以将醚产物与未反应的甲醇和C 4+异烯烃分离。 然后，二级反应器将来自甲醇萃取相的甲醇与未反应的甲醇和C4 +异构体一起转化成烃。
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公开(公告)号：US5043499A
公开(公告)日：1991-08-27
申请号：US480697
申请日：1990-02-15
申请人： Mohsen N. Harandi , Hartley Owen
发明人： Mohsen N. Harandi , Hartley Owen
IPC分类号： C10G50/00
CPC分类号： C10G50/00
摘要： A continuous multistage process for converting normally gaseous olefins containing an amount of ethene to gasoline and/or distillate range hydrocarbons, the process employing at least two fluidized olefins oligomerization reaction zones operating in parallel with one reaction zone operating under high severity reaction conditions effective for converting ethene.
摘要翻译： 用于将含有一定量乙烯的常规气态烯烃转化成汽油和/或馏出物范围烃的连续多级方法，该方法使用至少两个流化烯烃低聚反应区，该反应区与在有效转化的高浓度反应条件下运行的一个反应区并行运行 乙烯。
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公开(公告)号：US5030783A
公开(公告)日：1991-07-09
申请号：US569309
申请日：1990-08-20
申请人： Mohsen N. Harandi , Hartley Owen
发明人： Mohsen N. Harandi , Hartley Owen
IPC分类号： C07C2/00 , C07C15/00 , C07C29/151
CPC分类号： C07C29/1518 , C07C15/00 , C07C2/00 , C07C2529/40 , C07C2529/65 , C07C2529/70
摘要： A process is disclosed for the conversion of an aliphatic feedstream in which an oxygen-deficient flue gas is used to directly transfer heat to the primary conversion reaction. Hydrogen, carbon monoxide and carbon dioxide from the primary conversion reactor effluent are converted to methanol or Fischer-Tropsch liquid and may be recycled to the primary conversion reactor. Preferred primary conversion reactions include dehydrogenation and aromatization of aliphatics.
摘要翻译： 公开了一种用于转化脂肪族原料流的方法，其中使用缺氧烟道气直接将热转移到初级转化反应。 来自初级转化反应器流出物的氢气，一氧化碳和二氧化碳被转化为甲醇或费 - 托液体，并且可以再循环到初级转化反应器。 优选的一级转化反应包括脱氢和芳族化合物的芳构化。
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公开(公告)号：US5030782A
公开(公告)日：1991-07-09
申请号：US347297
申请日：1989-05-04
申请人： Mohsen N. Harandi , Hartley Owen
发明人： Mohsen N. Harandi , Hartley Owen
CPC分类号： C07C4/06 , C07C15/00 , C07C2529/40 , C07C2529/65 , C07C2529/70
摘要： Aliphatics are aromatized in a two-stage catalytic upgrading process. In the first stage, aliphatic hydrocarbons are at least partially cracked and dehydrogenated to form an intermediate product stream. The extent and selectivity of the cracking and dehydrogenation reactions are preferably controlled to maintain heat balance in a second stage catalytic aromatization step.In a preferred embodiment, a first aliphatic feedstream is cracked and dehydrogenated to form an intermediate product stream. The intermediate product stream is then mixed with a second aliphatic feedstream and contacted with a zeolite aromatization catalyst. Cracking and dehydrogenation of the first aliphatic feedstream is controlled to provide heat balanced aromatization of the combined streams.
摘要翻译： 在两阶段催化升级过程中，脂肪族芳香化。 在第一阶段中，脂族烃至少部分地裂化并脱氢以形成中间产物流。 优选控制裂化和脱氢反应的程度和选择性以在第二阶段催化芳构化步骤中保持热平衡。 在优选的实施方案中，第一脂族原料流被裂化并脱氢以形成中间产物流。 然后将中间产物流与第二脂肪族原料流混合并与沸石芳构化催化剂接触。 控制第一脂肪族原料流的裂化和脱氢以提供组合物流的热平衡芳构化。
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公开(公告)号：US5030338A
公开(公告)日：1991-07-09
申请号：US269087
申请日：1988-11-09
申请人： Mohsen N. Harandi , Hartley Owen
发明人： Mohsen N. Harandi , Hartley Owen
IPC分类号： B01J29/90 , C10G35/095
CPC分类号： B01J29/90 , C10G35/095
摘要： A process and apparatus are disclosed for the catalytic conversion of hydrocarbons in a transport or sub-transport fluidized bed reaction zone. Inert particles are used to transfer heat to the reaction zone. The particles may be heated separately from the catalyst in a combustion zone or together with the catalyst in a regenerator. Fuel is fired to heat the inert particles or a mixture of catalyst and inert particles. Hydrogen deficient fuels such as charcoal or coke are preferred.
摘要翻译： 公开了用于在运输或副输送流化床反应区中的烃的催化转化的方法和装置。 惰性颗粒用于将热量传递到反应区。 颗粒可以在燃烧区中与催化剂分开加热，或者与再生器中的催化剂一起加热。 燃烧燃料以加热惰性颗粒或催化剂和惰性颗粒的混合物。 缺碳燃料如木炭或焦炭是优选的。
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