Radiation-curing binders and a process for their preparation
    64.
    发明授权
    Radiation-curing binders and a process for their preparation 有权
    辐射固化粘合剂及其制备方法

    公开(公告)号:US07666970B2

    公开(公告)日:2010-02-23

    申请号:US11217728

    申请日:2005-09-01

    摘要: The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ≦130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ≧2, in the presence of D) a catalyst containing one or more ammonium salts or phosphonium salts of aliphatic or cycloaliphatic carboxylic acids, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.

    摘要翻译: 本发明涉及一种制备粘合剂的方法,其包含1)脲基甲酸酯基团,2)与烯键式不饱和化合物反应的基团与暴露于光化辐射(辐射固化基团)和3)任选的NCO-反应性基团反应的基团, A)一种或多种含有脲二酮基团的NCO-官能化合物,B)一种或多种含有异氰酸酯反应性基团的化合物和与烯键式不饱和化合物反应而与光化辐射(辐射 - 固化基团),然后C)与除了B)之外的一种或多种饱和的含羟基化合物,在D的存在下,在具有OH官能度≥2的这些化合物中的至少一种的化合物中含有一种或多种铵 脂肪族或脂环族羧酸的盐或鏻盐,与化合物C)的反应至少与脲基甲酸酯基团的形成成比例地发生。 本发明还涉及通过本发明的方法获得的粘合剂。

    DEFORMABLE FILM WITH RADIATION-CURING COATING AND SHAPED ARTICLES PRODUCED THEREFROM
    66.
    发明申请
    DEFORMABLE FILM WITH RADIATION-CURING COATING AND SHAPED ARTICLES PRODUCED THEREFROM 审中-公开
    具有辐射固化涂层和形成的形状的可变形膜

    公开(公告)号:US20090269568A1

    公开(公告)日:2009-10-29

    申请号:US12430359

    申请日:2009-04-27

    IPC分类号: B32B5/16 B05D3/02 B29C39/00

    摘要: The present invention relates to a film, further comprising a radiation-curing coating, wherein the coating comprises a polyurethane polymer which contains (meth)acrylate groups and which is obtainable from the reaction of a reaction mixture comprising (a) polyisocyanates and (b1) compounds which comprise (meth)acrylate groups and are reactive towards isocyanates and wherein the coating further comprises inorganic nanoparticles with an average particle size of ≧1 nm to ≦200 nm. It also relates to a process for the production of such coated films, the use of such films for the production of shaped articles, a process for the production of shaped articles with a radiation-cured coating and shaped articles which can be produced by this process.

    摘要翻译: 本发明涉及一种薄膜,其还包括辐射固化涂层,其中该涂层包含含有(甲基)丙烯酸酯基团的聚氨酯聚合物,其可通过包含(a)多异氰酸酯和(b1)的反应混合物的反应获得, 包含(甲基)丙烯酸酯基团并且对异氰酸酯具有反应性的化合物,并且其中该涂层还包含平均粒径> = 1nm至<= 200nm的无机纳米颗粒。 它还涉及生产这种涂膜的方法,这种膜用于生产成型制品的方法,用辐射固化涂层生产成形制品的方法和可以通过该方法生产的成型制品 。

    Low-viscosity allophanates containing actinically curable groups
    70.
    发明授权
    Low-viscosity allophanates containing actinically curable groups 有权
    含有光化固化基团的低粘度脲基甲酸酯

    公开(公告)号:US07361723B2

    公开(公告)日:2008-04-22

    申请号:US11080706

    申请日:2005-03-14

    摘要: A process for preparing binders containing allophanate groups which contain, at the oxygen atom of the allophanate group that is bonded via two single bonds, organic radicals with activated groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation; the process includes reacting A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and C) optionally further NCO-reactive compounds, and D) in the presence of one or more compounds containing phenoxide groups, as catalysts. The binders can be used in preparing coatings, coating materials, coating compositions, adhesives, printing inks, casting resins, dental compounds, sizes, photoresists, stereolithography systems, resins for composite materials and sealants.

    摘要翻译: 一种制备含有脲基甲酸酯基团的粘合剂的方法,其在通过两个单键键合的脲基甲酸酯基的氧原子上含有具有活化基团的活性基团,所述活性基团在与光化辐射接触时可与烯属不饱和化合物进行聚合反应; 该方法包括使A)一种或多种含有脲二酮基团的化合物与B)一种或多种OH官能化合物,其含有能够在暴露于光化辐射下与烯键式不饱和化合物进行聚合反应的基团,和C)任选地进一步的NCO- 活性化合物和D)在一种或多种含有酚氧化物的化合物的存在下作为催化剂。 粘合剂可用于制备涂料,涂料,涂料组合物,粘合剂,印刷油墨,浇铸树脂,牙科化合物,尺寸,光致抗蚀剂,立体光刻系统,复合材料和密封剂的树脂。