公开(公告)号：US06541129B1

公开(公告)日：2003-04-01

申请号：US09530597

申请日：2000-05-09

申请人： Hisayuki Kawamura ,  Chishio Hosokawa

发明人： Hisayuki Kawamura ,  Chishio Hosokawa

IPC分类号： H05B3314

CPC分类号： C07D239/26 ,  C07C211/54 ,  C07C211/58 ,  C07C211/61 ,  C07C217/92 ,  C07C2603/18 ,  C07C2603/24 ,  C09K11/06 ,  C09K2211/1022 ,  H01L51/005 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/0058 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0062 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0069 ,  H01L51/007 ,  H01L51/0071 ,  H01L51/0081 ,  H01L51/5012 ,  H01L51/5048 ,  H01L51/5088 ,  H01L2251/308 ,  H05B33/14 ,  H05B33/22 ,  Y10S428/917

摘要： The invention is to provide an organic EL device having a long life time that can reduce the driving voltage of the organic EL device, and to provide a material having a small ionization potential and exhibiting a large hole mobility by using as a layer or a zone. The organic electroluminescence device comprises a pair of electrodes and an organic light emitting layer sandwiched in the electrodes, characterized in that a hole transporting zone provided between the electrodes comprises the phenylenediamine derivative represented by the specific structural formulae, and the phenylenediamine derivative has a hole mobility of 10−4 cm2/V·s or more upon using as a layer or a zone, with the organic light emitting layer containing a charge injection auxiliary.

摘要翻译： 本发明提供一种寿命长的有机EL器件，其可以降低有机EL器件的驱动电压，并且通过使用层或区域来提供具有小的电离电位并显示出大的空穴迁移率的材料 。 有机电致发光元件包括夹在电极中的一对电极和有机发光层，其特征在于，设置在电极之间的空穴传输区域包含由具体结构式表示的苯二胺衍生物，并且苯二胺衍生物具有空穴迁移率 在作为层或区域使用时为10 -4 cm 2 / Vs以上，有机发光层含有电荷注入助剂。

公开(公告)号：US06379824B1

公开(公告)日：2002-04-30

申请号：US09424873

申请日：2000-01-27

申请人： Chishio Hosokawa

发明人： Chishio Hosokawa

IPC分类号： H05B1114

CPC分类号： H01L51/5088 ,  H01L51/0059 ,  H01L51/5048 ,  H01L51/5092 ,  Y10S428/917 ,  Y10T428/24942

摘要： The invention provides an organic EL device with improved luminous efficiency. The device has a structure comprising an inorganic non-degenerate semiconductor layer 12, an organic light-emitting layer 14 and a counter electrode 16 as formed in that order on a lower electrode 10, in which the inorganic non-degenerate semiconductor layer 12 is formed of an amorphous material of In—Zn—Al—O and its band gap energy is 2.9 eV.

摘要翻译： 本发明提供一种具有改善的发光效率的有机EL器件。 该器件具有如下结构：在形成无机非简并半导体层12的下电极10上依次形成无机非简并半导体层12，有机发光层14和对电极16 的In-Zn-Al-O的无定形材料，其带隙能为2.9eV。

公开(公告)号：US5458977A

公开(公告)日：1995-10-17

申请号：US300144

申请日：1994-09-02

申请人： Chishio Hosokawa ,  Tadashi Kusumoto

发明人： Chishio Hosokawa ,  Tadashi Kusumoto

IPC分类号： C23C14/06 ,  H01L51/52 ,  H05B33/10 ,  H05B33/26 ,  H05B33/14

CPC分类号： H05B33/26 ,  C23C14/06 ,  H01L51/5221 ,  H05B33/10 ,  Y10S428/917 ,  Y10T428/31504

摘要： A thin film electrode comprising an electron-injectable metal and an organic compound. Said thin film electrode has excellent uniformity and may be very thin and has a small volume resistivity. An electroluminescence device using said thin film electrode has high luminous efficiency, making it useful as a light-emitting material.

摘要翻译： 一种包含电子注入金属和有机化合物的薄膜电极。 所述薄膜电极具有优异的均匀性，并且可能非常薄并具有小体积电阻率。 使用所述薄膜电极的电致发光器件具有高的发光效率，使其成为发光材料。

公开(公告)号：US5142343A

公开(公告)日：1992-08-25

申请号：US667386

申请日：1991-03-21

申请人： Chishio Hosokawa ,  Tadashi Kusumoto ,  Hisahiro Higashi

发明人： Chishio Hosokawa ,  Tadashi Kusumoto ,  Hisahiro Higashi

IPC分类号： H01L51/00 ,  H01L51/30 ,  H01L51/50 ,  H05B33/14 ,  H05B33/22

CPC分类号： H05B33/22 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0068 ,  H01L51/5012 ,  H05B33/14 ,  H01L2251/308 ,  H01L51/005 ,  H01L51/0052 ,  H01L51/0053 ,  H01L51/0059 ,  H01L51/0067 ,  H01L51/007 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0073

摘要： An organic electroluminescence device having a high brightness of 50 cd/m.sup.2 or more and a luminous efficiency of 0.02 lm/W or more, wherein an organic semiconductor zone and an organic insulator zone are sandwiched between electrodes, the organic insulator zone contains an organic light emitting area, and the above organic semiconductor zone comprises electroconducting oligomer. The organic electroluminescence device is capable of emitting light in a plane, shows a stable emission of light, and further can be easily prepared.

摘要翻译： PCT No.PCT / JP90 / 01043 Sec。 371日期1991年3月21日 102（e）1991年3月21日PCT PCT 1990年8月16日PCT公布。 出版物WO91 / 03142 日期：1991年3月7日。具有50cd / m 2以上的高亮度和0.02lm / W以上的发光效率的有机电致发光元件，其中有机半导体区域和有机绝缘体区域夹在电极之间， 有机绝缘体区域包含有机发光区域，并且上述有机半导体区域包括导电低聚物。 有机电致发光元件能够在平面内发光，显示出稳定的发光，并且还可以容易地制备。

公开(公告)号：US5126214A

公开(公告)日：1992-06-30

申请号：US488702

申请日：1990-03-05

申请人： Hiroshi Tokailin ,  Chishio Hosokawa ,  Tadashi Kusomoto

发明人： Hiroshi Tokailin ,  Chishio Hosokawa ,  Tadashi Kusomoto

IPC分类号： C09K11/06 ,  G09F9/33 ,  H01L27/32 ,  H01L51/00 ,  H01L51/30 ,  H01L51/50 ,  H05B33/14

CPC分类号： H05B33/14 ,  C09K11/06 ,  G09F9/33 ,  H01L51/005 ,  H01L51/0052 ,  H01L51/5036 ,  H01L2251/308 ,  H01L27/322 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0053 ,  H01L51/0059 ,  H01L51/0067 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0073 ,  Y10S428/917 ,  Y10T428/24975

摘要： An electroluminescent element comprising an electroluminescent (EL) material part which emits a near ultraviolet ray of light and a fluorescent material part which absorbs the ultraviolet light emitted from the electroluminescent material and emits a fluorescence in a visible light range from blue to red. The electroluminescent element provides for emission of lights with a wide range of wavelength and three elementary colors of blue, green and red can be expressed by appropriate combinations of the organic EL material and the fluorescent material. Consequently, the electroluminescent element provides for a full color display.

公开(公告)号：US09120748B2

公开(公告)日：2015-09-01

申请号：US11932100

申请日：2007-10-31

申请人： Yoriyuki Takashima ,  Masakazu Funahashi ,  Kiyoshi Ikeda ,  Chishio Hosokawa

发明人： Yoriyuki Takashima ,  Masakazu Funahashi ,  Kiyoshi Ikeda ,  Chishio Hosokawa

IPC分类号： H01L51/50 ,  C07D209/86 ,  C07C13/62 ,  C07C13/72 ,  C07C22/08 ,  C07C25/22 ,  C07C43/267 ,  C07C49/784 ,  C07C205/12 ,  C07C211/54 ,  C07C211/58 ,  C07C211/60 ,  C07C255/50 ,  C07C255/52 ,  C07C321/30 ,  C07D307/91 ,  C07F7/08 ,  C09K11/06 ,  H01L51/00

CPC分类号： C07D209/86 ,  C07C13/62 ,  C07C13/72 ,  C07C22/08 ,  C07C25/22 ,  C07C43/267 ,  C07C49/784 ,  C07C205/12 ,  C07C211/54 ,  C07C211/58 ,  C07C211/60 ,  C07C255/50 ,  C07C255/52 ,  C07C321/30 ,  C07C2601/14 ,  C07C2603/18 ,  C07C2603/20 ,  C07C2603/24 ,  C07C2603/26 ,  C07C2603/48 ,  C07C2603/50 ,  C07C2603/52 ,  C07C2603/54 ,  C07C2603/94 ,  C07D307/91 ,  C07F7/0805 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1048 ,  C09K2211/1059 ,  C09K2211/1088 ,  H01L51/0055 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/0067 ,  H01L51/0094

摘要： A fluoranthene compound with a specified asymmetric structure; an organic EL device which is composed of one or more organic compound layers including at least one emitting layer sandwiched between a pair of electrodes, wherein at least one of the organic compound layers contains at least one kind of the fluoranthene compound; and a solution containing a material for the organic EL which is composed of the fluoranthene compound as the material for the organic EL and a solvent. An organic electroluminescence (EL) device having a superior luminance of light emission, an enhanced efficiency of light emission, and a prolonged lifetime and a compound realizing the device are provided.

摘要翻译： 具有规定不对称结构的荧蒽化合物; 一种有机EL器件，其由包含夹在一对电极之间的至少一个发光层的一个或多个有机化合物层组成，其中至少一个有机化合物层含有至少一种荧蒽化合物; 以及含有作为有机EL的材料的荧蒽化合物和溶剂的由有机EL材料构成的溶液。 提供了具有优异的发光亮度，增强的发光效率和延长的寿命的有机电致发光（EL）器件以及实现该器件的化合物。

公开(公告)号：US09112171B2

公开(公告)日：2015-08-18

申请号：US13124991

申请日：2008-10-23

申请人： Brian D'Andrade ,  Julia J. Brown ,  Michael S. Weaver ,  Kazuki Nishimura ,  Toshihiro Iwakuma ,  Chishio Hosokawa ,  Masahiro Kawamura ,  Mitsunori Ito

发明人： Brian D'Andrade ,  Julia J. Brown ,  Michael S. Weaver ,  Kazuki Nishimura ,  Toshihiro Iwakuma ,  Chishio Hosokawa ,  Masahiro Kawamura ,  Mitsunori Ito

IPC分类号： H01L51/54 ,  C09K11/06 ,  H01L51/50 ,  C07C15/30 ,  C07C15/28 ,  C07C15/38 ,  H01L51/00

CPC分类号： H01L51/5016 ,  C07C15/28 ,  C07C15/30 ,  C07C15/38 ,  C07C2603/26 ,  C07C2603/42 ,  C07C2603/48 ,  C07C2603/52 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/185 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/0055 ,  H01L51/0058 ,  H01L51/0085 ,  H01L51/0094

摘要： The present invention provides an OLED in which an organic thin film layer comprising a single layer or plural layers is provided between a cathode and an anode, where the organic thin film layer comprises at least one light emitting layer, and the at least one light emitting layer comprises (a) a host material represented by the following Formula (1): Ra—Ar1—Ar2—Rb (1) where Ar1, Ar2, Ra and Rb represent a substituted or unsubstituted benzene ring or a condensed aromatic hydrocarbon group selected from a substituted or unsubstituted naphthalene ring, chrysene ring, a substituted or unsubstituted fluoranthene ring, triphenylene ring, a substituted or unsubstituted phenanthrene ring, a substituted or unsubstituted benzophenanthrene ring, a substituted or unsubstituted dibenzophenanthrene ring, a substituted or unsubstituted benzotriphenylene ring, a substituted or unsubstituted benzochrysene ring, a substituted or unsubstituted picene ring and a substituted or unsubstituted benzofluoranthene ring; and (b) at least one phosphorescent material comprises a phosphorescent organometallic complex having a substituted chemical structure represented by one of the following partial chemical structures represented by the formulas: wherein each R is independently hydrogen or an alkyl substituent having 1-3 carbon atoms, and wherein at least one ring of the formula has one or more of said alkyl substituent.

摘要翻译： 本发明提供了一种OLED，其中在阴极和阳极之间设置包括单层或多层的有机薄膜层，其中有机薄膜层包括至少一个发光层，并且所述至少一个发光 层包含（a）由下式（1）表示的主体材料：Ra-Ar1-Ar2-Rb（1）其中Ar1，Ar2，Ra和Rb表示取代或未取代的苯环或稠合芳族烃基， 取代或未取代的萘环，环，取代或未取代的荧蒽环，三亚苯环，取代或未取代的菲环，取代或未取代的苯并菲环，取代或未取代的二苯并菲环，取代或未取代的苯并亚苯基环， 或未取代的苯并环，取代或未取代的吡啶环和取代或未取代的苯并环 香叶烯环 和（b）至少一种磷光材料包含具有由下式表示的以下部分化学结构之一表示的取代的化学结构的磷光有机金属络合物：其中每个R独立地是氢或具有1-3个碳原子的烷基取代基， 并且其中至少一个下式的环具有一个或多个所述烷基取代基。

公开(公告)号：US08927118B2

公开(公告)日：2015-01-06

申请号：US13349377

申请日：2012-01-12

申请人： Tomoki Kato ,  Masaki Numata ,  Kazuki Nishimura ,  Toshihiro Iwakuma ,  Chishio Hosokawa

发明人： Tomoki Kato ,  Masaki Numata ,  Kazuki Nishimura ,  Toshihiro Iwakuma ,  Chishio Hosokawa

IPC分类号： H05B33/14 ,  C07D495/04 ,  C07D307/91 ,  C07D487/04 ,  C07D493/04 ,  C07D519/00 ,  C09K11/06 ,  H01L51/00 ,  H01L51/50

CPC分类号： H01L51/0073 ,  C07D307/91 ,  C07D487/04 ,  C07D493/04 ,  C07D495/04 ,  C07D519/00 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1088 ,  C09K2211/185 ,  H01L51/0055 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5008 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5024 ,  H01L51/504 ,  H01L51/5048 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/5092 ,  H01L51/5206 ,  H01L51/5221 ,  H05B33/14

摘要： Provided are an organic electroluminescence device, which shows high luminous efficiency, is free of any pixel defect, and has a long lifetime, and a material for an organic electroluminescence device for realizing the device. The material for an organic electroluminescence device is a compound having a n-conjugated heteroacene skeleton crosslinked with a carbon atom, nitrogen atom, oxygen atom, or sulfur atom. The organic electroluminescence device has one or more organic thin film layers including a light emitting layer between a cathode and an anode, and at least one layer of the organic thin film layers contains the material for an organic electroluminescence device.

摘要翻译： 提供一种显示高发光效率，没有任何像素缺陷并且具有长寿命的有机电致发光器件，以及用于实现器件的有机电致发光器件的材料。 用于有机电致发光器件的材料是具有与碳原子，氮原子，氧原子或硫原子交联的正共轭异炔骨架的化合物。 有机电致发光元件具有包含阴极和阳极之间的发光层的一个或多个有机薄膜层，至少一层有机薄膜层含有有机电致发光元件用材料。

公开(公告)号：US08895154B2

公开(公告)日：2014-11-25

申请号：US10588773

申请日：2005-03-01

申请人： Toshihiro Iwakuma ,  Hiroya Yasuda ,  Kiyoshi Ikeda ,  Keiko Yamamichi ,  Takashi Arakane ,  Chishio Hosokawa

发明人： Toshihiro Iwakuma ,  Hiroya Yasuda ,  Kiyoshi Ikeda ,  Keiko Yamamichi ,  Takashi Arakane ,  Chishio Hosokawa

IPC分类号： H01L51/54 ,  H01L51/56 ,  C09K11/06 ,  H05B33/14 ,  H01L51/50 ,  H05B33/22

CPC分类号： C09K11/06 ,  C09K2211/1029 ,  C09K2211/1037 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/185 ,  H01L51/5016 ,  H05B33/14 ,  H05B33/22 ,  Y10S428/917 ,  Y10T428/265 ,  Y10T428/31504

摘要： Provided is an organic electroluminescent device in which an organic thin film layer comprising a single layer or plural layers comprising a phosphorescence light-emitting layer containing at least a host material and a phosphorescent organic metal complex is interposed between a cathode and an anode, wherein the total of the halogen element mass concentrations of bromine, iodine and chlorine which are contained as impurities in the host material constituting the light-emitting layer described above is 50 ppm or less. It has a high emission luminance, a high luminous efficiency and a long life.

摘要翻译： 本发明提供了一种有机电致发光器件，其中包括包含至少含有主体材料和磷光有机金属络合物的磷光发光层的单层或多层的有机薄膜层插入在阴极和阳极之间，其中， 在构成上述发光层的主体材料中作为杂质含有的溴，碘和氯的卤素元素质量浓度的总和为50ppm以下。 发光亮度高，发光效率高，寿命长。

公开(公告)号：US08759819B2

公开(公告)日：2014-06-24

申请号：US12744178

申请日：2008-11-21

申请人： Kazuki Nishimura ,  Toshihiro Iwakuma ,  Kenichi Fukuoka ,  Chishio Hosokawa ,  Jun Endo ,  Nobuhiro Yabunouchi ,  Hiroshi Yamamoto

发明人： Kazuki Nishimura ,  Toshihiro Iwakuma ,  Kenichi Fukuoka ,  Chishio Hosokawa ,  Jun Endo ,  Nobuhiro Yabunouchi ,  Hiroshi Yamamoto

IPC分类号： H01L29/08

CPC分类号： H01L51/0054 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1044 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0052 ,  H01L51/0055 ,  H01L51/0059 ,  H01L51/0067 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/5016 ,  H01L51/5048

摘要： An organic electroluminescence device includes an anode, a cathode, and an organic thin-film layer interposed between the anode and the cathode. The organic thin-film layer includes a phosphorescent-emitting layer containing a host and a phosphorescent dopant, and an electron transporting layer that is provided closer to the cathode than the phosphorescent-emitting layer. The host contains a substituted or unsubstituted polycyclic fused aromatic skeleton.

摘要翻译： 有机电致发光器件包括阳极，阴极和置于阳极和阴极之间的有机薄膜层。 有机薄膜层包括含有主体和磷光掺杂剂的磷光发光层以及比磷光发光层更靠近阴极的电子传输层。 宿主含有取代或未取代的多环稠合芳族骨架。