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公开(公告)号：US07582690B2
公开(公告)日：2009-09-01
申请号：US11171772
申请日：2005-06-30
IPC分类号： C08K5/3492 , C08K5/51
CPC分类号： C08K5/34 , C08G63/199 , C08K5/527 , C08L67/02
摘要： Disclosed are stabilized aliphatic polyester compositions comprising an aliphatic polyester, a HALS, and a tris-aryl-S-triazine UV absorber that show low embrittlement, haze formation, and discoloration during weathering. Also disclosed are aliphatic polyester compositions comprising aliphatic polyester, a hindered amine light stabilizer, a triazine UV absorber, and a phosphite that exhibit low color prior to weathering but retain good clarity, color, and excellent impact strength after exposure to weathering conditions. The aliphatic polyester compositions may be used prepare shaped articles such as, for example, films, sheets, bottles, tubes, profiles, fibers, and molded articles.
摘要翻译： 公开了包含脂族聚酯，HALS和三芳基-S-三嗪紫外线吸收剂的稳定的脂族聚酯组合物，其在耐候过程中显示低脆化性，雾度形成和变色。 还公开了包含脂族聚酯，受阻胺光稳定剂，三嗪紫外线吸收剂和亚磷酸酯的脂族聚酯组合物，其在风化之前显示低颜色，但在暴露于耐候条件之后保持良好的透明度，颜色和优异的冲击强度。 可以使用脂族聚酯组合物制备成形制品，例如薄膜，片材，瓶子，管，型材，纤维和模制品。
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62.发明授权公开(公告)号：US07491760B2
公开(公告)日：2009-02-17
申请号：US11204461
申请日：2005-08-16
IPC分类号： C08K5/3495
CPC分类号： C08K5/34 , C08K5/13 , C08K5/5205 , C08L67/02
摘要： This invention relates to a polymer composition comprising (A) at least one polyester prepared by the reaction of at least one diol with at least one dicarboxylic acid/or dialkyl ester thereof in the presence of a metallic catalyst; (B) a salt comprising at least one suitable phosphorus-containing acid and at least one suitable basic organic compound, such as a hindered amine light stabilizer; (C) at least one ultraviolet light absorbing compound and optionally at least one phenolic antioxidant. A second embodiment of the present invention pertains to a blend of (A) at least one polyester prepared by the reaction of at least one diol with at least one dicarboxylic acid/or dialkyl ester thereof in the presence of a metallic catalyst; (B) a salt comprising at least one suitable phosphorus-containing acid and at least one suitable basic organic compound; (C) at least one ultraviolet light absorbing compound and, optionally, at least one phenolic antioxidant; and (D) at least one polycarbonate.
摘要翻译： 本发明涉及一种聚合物组合物，其包含（A）至少一种通过至少一种二醇与至少一种二羧酸或其二烷基酯在金属催化剂存在下反应制备的聚酯; （B）含有至少一种合适的含磷酸和至少一种合适的碱性有机化合物如受阻胺光稳定剂的盐; （C）至少一种紫外光吸收化合物和任选的至少一种酚类抗氧化剂。 本发明的第二个实施方案涉及（A）至少一种通过至少一种二醇与至少一种二羧酸或其二烷基酯在金属催化剂存在下反应制备的聚酯的共混物; （B）包含至少一种合适的含磷酸和至少一种合适的碱性有机化合物的盐; （C）至少一种紫外光吸收化合物和任选的至少一种酚类抗氧化剂; 和（D）至少一种聚碳酸酯。
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63.发明授权Methods for slowing the degradation rate of biodegradable polymers and biodegradable polymer compositions and compositions thereof 失效降低可生物降解聚合物和生物可降解聚合物组合物的降解速率的方法及其组合物公开(公告)号：US06767972B1
公开(公告)日：2004-07-27
申请号：US09662965
申请日：2000-09-15
IPC分类号： C08L6702
CPC分类号： C08L67/02 , C08L25/18 , C08L65/00 , C08L67/04 , Y10S525/938 , C08L2666/02
摘要： The invention provides a biodegradable polymer composition comprising a biodegradable polymer and a phenol-containing compound mixed with the polymer. The phenol-containing compound is present in the biodegradable polymer at an amount sufficient to slow the degradation rate of the biodegradable polymer. The invention also pertains to a method for slowing the degradation rate of a biodegradable polymer.
摘要翻译： 本发明提供一种生物可降解聚合物组合物，其包含可生物降解聚合物和与该聚合物混合的含苯酚化合物。 含酚化合物以足以减缓生物可降解聚合物降解速率的量存在于可生物降解的聚合物中。 本发明还涉及一种减缓生物可降解聚合物降解速率的方法。
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公开(公告)号：US06565987B2
公开(公告)日：2003-05-20
申请号：US09438860
申请日：1999-11-12
申请人： Gether Irick, Jr.
发明人： Gether Irick, Jr.
IPC分类号： B32B2710
CPC分类号： G03C1/79 , C08K5/0041 , C08L23/04 , C08L23/10 , C08L23/20 , C08L25/04 , G03C1/815 , Y10T428/3188 , Y10T428/31895 , Y10T428/31899 , Y10T428/31902 , C08L2666/04
摘要： Optical brighteners are widely used for decreasing the apparent yellowness of polymeric materials. Polyethylene, as a coating film for photographic paper has presented unique problems because of its general lack of compatibility with conventional, large, fluorescent brightener molecules. The present invention provides a solution to this problem by incorporating into the polyethylene an optical brightener compatibilizing amount of a second polyolefin having alkyl groups pendant from the polymer backbone which serves to reduce the exudation of the optical brightener in articles or substrates comprised of or coated with such compositions.
摘要翻译： 荧光增白剂广泛用于降低聚合物材料的表观黄度。 聚乙烯作为相纸的涂膜呈现出独特的问题，因为它与普通的大型荧光增白剂分子通常缺乏相容性。 本发明通过将具有从聚合物主链悬挂的烷基的第二聚烯烃与荧光增白剂相容化量相结合的方式提供了这一问题的解决方案，该第二聚烯烃用于减少由包含或涂覆有聚合物的制品或基材中的荧光增白剂的渗出物 这样的组合物。
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公开(公告)号：US5245089A
公开(公告)日：1993-09-14
申请号：US965818
申请日：1992-10-23
CPC分类号： C07C37/16 , B01J21/063 , B01J23/08 , B01J35/1019 , B01J37/0201 , C07C37/11
摘要： Provided is a process for alkylating aromatic compounds in the presence of mixed oxides of titanium and gallium which have been found to be highly active catalysts for the alkylation of aromatics with alkyl esters, alcohols, olefins and ethers. When the alkyl acceptor is a phenol, the catalysts provide high reaction rates and high selectivity for ortho alkylated products.
摘要翻译： 提供了在钛和镓的混合氧化物的存在下烷基化芳族化合物的方法，已经被发现是用烷基酯，醇，烯烃和醚烷基化芳族化合物的高活性催化剂。 当烷基受体是苯酚时，催化剂对邻烷基化产物提供高反应速率和高选择性。
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66.发明授权Photoactive catalyst of barium phosphate or calcium phosphate supported on anatase titanium dioxide 失效负载在锐钛矿二氧化钛上的磷酸钡或磷酸钙的光催化剂
公开(公告)号：US5242880A
公开(公告)日：1993-09-07
申请号：US889326
申请日：1992-05-27
申请人： Gether Irick, Jr.
发明人： Gether Irick, Jr.
IPC分类号： B01J27/053 , B01J27/18 , C08B3/22
CPC分类号： B01J27/1806 , B01J27/053 , C08B3/22
摘要： Provided are novel titania comprising anatase titanium dioxide and sodium, potassium, calcium, magnesium, barium, zinc, or magnesium salts of sulfuric or phosphoric acid. The titania of this invention are useful in the pigmentation of oxidizable polymers, while at the same time providing a catalyst system for the photooxidation of said oxidizable polymers.
摘要翻译： 提供了包含锐钛矿二氧化钛和硫酸或磷酸的钠，钾，钙，镁，钡，锌或镁盐的新型二氧化钛。 本发明的二氧化钛可用于可氧化聚合物的着色，同时提供用于所述可氧化聚合物的光氧化的催化剂体系。
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67.发明授权Catalyst compositions and the use thereof in the hydrogenation of carboxylic acid esters 失效催化剂组合物及其在羧酸酯氢化中的用途
公开(公告)号：US4929777A
公开(公告)日：1990-05-29
申请号：US309641
申请日：1989-02-13
IPC分类号： B01J23/72 , B01J23/76 , C07C29/136 , C07C29/149
CPC分类号： B01J23/76 , B01J23/72 , C07C29/149 , C07C2101/14 , Y02P20/52
摘要： Disclosed are catalyst compositions comprised of chemically-mixed, copper-titanium oxides and the use of such catalyst compositions in the hydrogenation of certain esters to obtain the alcohol corresponding to the acid residue of the ester.
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68.发明授权
公开(公告)号：US4326065A
公开(公告)日：1982-04-20
申请号：US159090
申请日：1980-06-13
IPC分类号： C07D209/42 , C07D233/90 , C07D249/10 , C07D249/18 , C07D263/34 , C07D271/06 , C07D277/56 , C07D285/12 , C08K5/35 , C07D271/10
CPC分类号： C07D263/34 , C07D209/42 , C07D233/90 , C07D249/10 , C07D249/18 , C07D271/06 , C07D277/56 , C07D285/12 , C08K5/35
摘要： The invention relates to heterocyclic ester compounds which have been found to be extremely effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing an amount of a heterocyclic ester composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions such as polymers by adding to the polymer melt or dissolved in the polymer dope, coated on the exterior of the shaped or molded article, film or extruded fiber.
摘要翻译： 本发明涉及已被发现是非常有效的紫外线稳定剂的杂环酯化合物。 本发明还涉及含有一定量的用于防止这种降解的杂环酯组合物的紫外可降解有机组合物。 这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的，包括例如颜料，着色剂，填料，增强剂等。 这些紫外线稳定剂也可以通过添加到聚合物熔体中或溶解在聚合物涂料中而被包含在有机组合物如聚合物中，涂覆在成形或模制品的外部，膜或挤出纤维上。
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69.发明授权Bichromophoric benzotriazole-benzoxazole ultraviolet stabilizers and their use in organic compositions 失效双色谱苯并三唑 - 苯并恶唑紫外线稳定剂及其在有机组合物中的应用
公开(公告)号：US4271307A
公开(公告)日：1981-06-02
申请号：US30670
申请日：1979-04-16
IPC分类号： C07C243/38 , C07D263/56 , C07D263/57 , C07D271/10 , C07D271/107 , C08K5/35 , C07D413/10
CPC分类号： C07D263/57 , C07C243/38 , C07D271/107 , C08K5/35
摘要： The invention relates to bichromophoric benzotriazole-benzoxazole compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the bichromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
摘要翻译： 本发明涉及已被发现是有效的紫外线稳定剂的双色性苯并三唑 - 苯并恶唑化合物。 本发明还涉及含有稳定量的显色组合物以防止这种降解的紫外可降解有机组合物。 这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的，包括例如颜料，着色剂，填料，增强剂等。 这些紫外线稳定剂也可以掺入聚合物熔体中的有机组合物中或溶解在聚合物涂料中，涂覆在模塑制品，薄膜或挤出纤维的外部上。
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公开(公告)号：US4187229A
公开(公告)日：1980-02-05
申请号：US875029
申请日：1978-02-03
IPC分类号： C07D249/22 , C08K5/3475 , C07D249/20
CPC分类号： C07D249/22 , C08K5/3475
摘要： The invention relates to bis-benzotriazole compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the bis-benzotriazole compounds to prevent such degradation. These stabilizing compounds are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
摘要翻译： 本发明涉及已被发现是有效的紫外线稳定剂的双 - 苯并三唑化合物。 本发明还涉及含有稳定量的双 - 苯并三唑化合物以防止这种降解的紫外可降解有机组合物。 这些稳定化合物在聚合物组合物中通常使用的其它添加剂的存在下是有效的，包括例如颜料，着色剂，填料，增强剂等。 这些紫外线稳定剂也可以掺入聚合物熔体中的有机组合物中或溶解在聚合物涂料中，涂覆在模塑制品，薄膜或挤出纤维的外部上。
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