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61.发明申请公开(公告)号：US20140094576A1
公开(公告)日：2014-04-03
申请号：US14123794
申请日：2012-06-01
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F110/06 , C08F4/6492 , C08F2500/24
摘要： A pre-polymerized catalyst component for the polymerization of olefins CH2═CHR, wherein R is hydrogen or a C1-C12 hydrocarbon group, characterized by comprising a non-stereospecific solid catalyst component, comprising Ti, Mg and a halogen, said pre-polymerized catalyst component containing an amount of a (co)polymer of a monomer having formula CH2═CHA, where A is a C6 aliphatic or aromatic ring, optionally substituted, up to 5 g per g of said solid catalyst component. Said prepolymerized catalyst shows an excellent balance in terms of activity, morphological stability, reduced tendency to agglomeration and hydrogen response.
摘要翻译： 用于烯烃CH 2 = CHR聚合的预聚合催化剂组分，其中R是氢或C1-C12烃基，其特征在于包含非立体特异性固体催化剂组分，其包含Ti，Mg和卤素，所述预聚合 催化剂组分含有一定量的具有式CH 2 = CAB的单体（（共））聚合物，其中A是任选取代的C 6脂族或芳环，每克所述固体催化剂组分最多达5克。 所述预聚合催化剂在活性，形态稳定性，凝聚趋势和氢反应方面表现出极好的平衡。
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公开(公告)号：US20140046010A1
公开(公告)日：2014-02-13
申请号：US14111144
申请日：2012-03-29
申请人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T.M. Pater , Fabrizio Piemontesi , Diego Brita
发明人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T.M. Pater , Fabrizio Piemontesi , Diego Brita
IPC分类号： C08F4/16
CPC分类号： C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
摘要： A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.
摘要翻译： 一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于 事实上，ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或 等于0.60。
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63.发明申请Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom 失效二氯化镁 - 醇加合物和由其获得的催化剂组分公开(公告)号：US20120165483A1
公开(公告)日：2012-06-28
申请号：US13394042
申请日：2010-09-03
IPC分类号： C08F4/654 , C08F110/06
CPC分类号： C08F110/06 , C08F10/06 , C08F4/022 , C08F4/651 , C08F4/6545
摘要： Solid adducts comprising a MgCl2, ethanol and a compound (A), said compounds being present in molar ratios defined by the following formula MgCl2.(EtOH)n(A)p in which n is from 0.1 to 6, p ranges from 0.001 to 0.5 and A is a compound selected from cyclic hydrocarbon structures which are substituted with at least two hydroxy groups.
摘要翻译： 包含MgCl 2，乙醇和化合物（A）的固体加合物，所述化合物以下式MgCl 2（EtOH）n（A）p定义的摩尔比存在，其中n为0.1至6，p为0.001至 0.5和A是选自被至少两个羟基取代的环状烃结构的化合物。
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公开(公告)号：US20110082270A1
公开(公告)日：2011-04-07
申请号：US12587187
申请日：2009-10-02
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6555 , C08F4/6495 , C08F4/651 , C08F210/08 , C08F2500/12 , C08F2500/04 , C08F2500/21
摘要： A modified Ziegler-Natta catalyst system, a method for preparing the catalyst system, and a process for polymerizing an olefin in the presence of the catalyst system are disclosed. The catalyst system comprises a titanium or vanadium compound, an aluminum compound, and a pyridazine. Improved properties such as increased molecular weight and narrowed molecular weight distribution are obtained.
摘要翻译： 公开了改进的齐格勒 - 纳塔催化剂体系，制备催化剂体系的方法和在催化剂体系存在下使烯烃聚合的方法。 催化剂体系包括钛或钒化合物，铝化合物和哒嗪。 获得了改进的性能，例如分子量增加和分子量分布变窄。
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公开(公告)号：US20110082268A1
公开(公告)日：2011-04-07
申请号：US12587148
申请日：2009-10-02
CPC分类号： C08F10/00 , C08F210/16 , C08F4/651 , C08F4/6495 , C08F4/6555 , C08F210/08 , C08F2500/12 , C08F2500/04 , C08F2500/21
摘要： A modified Ziegler-Natta catalyst system, a method for preparing the catalyst system, and a process for polymerizing an olefin in the presence of the catalyst system are disclosed. The catalyst system comprises a titanium or vanadium compound, an aluminum compound, and an indazole. Improved comonomer incorporation and the ability to regulate molecular weight are achieved in the manufacture of polyolefins.
摘要翻译： 公开了改进的齐格勒 - 纳塔催化剂体系，制备催化剂体系的方法和在催化剂体系存在下使烯烃聚合的方法。 催化剂体系包括钛或钒化合物，铝化合物和吲唑。 在聚烯烃的制造中实现改进的共聚单体掺入和调节分子量的能力。
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公开(公告)号：US20090209714A1
公开(公告)日：2009-08-20
申请号：US11887528
申请日：2006-03-15
CPC分类号： C08F110/02 , C08F210/16 , C08F4/6565 , C08F4/6548 , C08F2500/12 , C08F210/08
摘要： Catalyst components for the(co)polymerization of ethylene comprising Ti, Mg, halogen, ORI groups, where RI is a C1-C12 hydrocarbon group optionally containing heteroatoms, having ORI/Ti molar ratio in the range 0.1-1.5, a Mg/Ti molar ratio of less than 8, an amount of titanium, with respect to the total weight of said solid catalyst component, higher than 4% by weight characterized by a specific SS-NMR pattern are particularly useful for preparing narrow MWD crystalline ethylene polymers.
摘要翻译： 含有Ti，Mg，卤素，ORI基团的乙烯（共）聚合的催化剂组分，其中RI是任选含有杂原子的C 1 -C 12烃基，ORI / Ti摩尔比在0.1-1.5范围内，Mg / Ti 摩尔比小于8，相对于所述固体催化剂组分的总重量，钛的量高于4重量％，其特征在于特定的SS-NMR图案，特别适用于制备窄MWD结晶乙烯聚合物。
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公开(公告)号：US20070282083A1
公开(公告)日：2007-12-06
申请号：US10581983
申请日：2004-11-24
申请人： Pietro Baita , Massimo Covezzi , Gabriele Mei , Giampiero Morini , Joachim Pater
发明人： Pietro Baita , Massimo Covezzi , Gabriele Mei , Giampiero Morini , Joachim Pater
CPC分类号： C08F10/00 , C08F10/02 , C08F210/16 , C08F4/6494 , C08F4/651 , C08F2/001 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F2500/07 , C08F210/08
摘要： A process for preparing a broad molecular weight polyethylene carried out in the presence of a catalyst system comprising (i) a solid catalyst component comprising Mg, Ti, halogen, and optionally an internal electron donor compound, and (ii) an Al-alkyl cocatalyst said process comprising at least two step of polymerization (a) and (b), in which: in a first step (a) ethylene is polymerized in the presence of a molecular weight regulator in order to produce a ethylene (co)polymer, and in a further step (b), which is carried out in the presence of an external electron donor compound added to this polymerization step as a fresh reactant, ethylene is copolymerized with an alpha olefin of formula CH2═CHR, in which R is a C1-C20 hydrocarbon group, to produce an ethylene copolymer having a molecular weight higher than that of the copolymer produced in step (b).
摘要翻译： 一种制备在催化剂体系存在下进行的宽分子量聚乙烯的方法，包括（i）包含Mg，Ti，卤素和任选的内电子给体化合物的固体催化剂组分，和（ii）Al-烷基助催化剂 所述方法包括至少两个聚合步骤（a）和（b）），其中：在第一步（a）中，在分子量调节剂存在下使乙烯聚合以产生乙烯（共）聚合物，和 在另外的步骤（b）中，其在作为新的反应物加入到该聚合步骤中的外部电子给体化合物的存在下进行，乙烯与式CH 2 -CHR的α-烯烃共聚，其中R是C1 -C 20烃基，得到分子量高于步骤（b）中制备的共聚物的乙烯共聚物。
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公开(公告)号：US07202314B2
公开(公告)日：2007-04-10
申请号：US10527298
申请日：2003-08-01
IPC分类号： C08F4/42
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651 , C08F4/6543 , C08F2500/08
摘要： The present invention relates to a solid catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbon radical with 1–12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from succinates, said catalyst component being obtainable by a process comprising the following steps: (a) dissolving a halide of magnesium in a solvent system comprising an organic epoxy compound or an organic phosphorus compound and optionally an inert diluent to form a solution; (b) mixing the obtained solution with a titanium compound to form a mixture; (c) precipitating a solid from the mixture obtained in step (b) in the presence of a succinate and/or an auxiliary precipitant; (d) if a succinate is not used in step (c), contacting the solid obtained in (c) with a succinate, and (e) treating the solid obtained in (c) or (d) with a titanium compound optionally in the presence of an inert diluent.
摘要翻译： 本发明涉及用于烯烃CH 2 -CHR的聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和电子 所述催化剂组分可通过包括以下步骤的方法获得：（a）将镁的卤化物溶解在包含有机环氧化合物或有机磷化合物和任选的惰性稀释剂的溶剂体系中以形成溶液; （b）将所得溶液与钛化合物混合以形成混合物; （c）在琥珀酸盐和/或辅助沉淀剂存在下从步骤（b）中获得的混合物中沉淀出固体; （d）如果在步骤（c）中不使用琥珀酸酯，则将（c）中获得的固体与琥珀酸酯接触，和（e）用钛化合物处理在（c）或（d）中获得的固体， 存在惰性稀释剂。
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69.发明授权1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers 失效1,3-二醚和用于烯烃聚合的组分和催化剂，其含有所述二醚公开(公告)号：US07049377B1
公开(公告)日：2006-05-23
申请号：US08603497
申请日：1996-02-20
IPC分类号： C08F4/44
CPC分类号： C08F10/00 , C07C41/16 , C07C43/162 , C07C2601/10 , C07C2602/08 , C07C2603/18 , C07C2603/24 , C07C2603/28 , C07D311/82 , C07F7/081 , C08F110/06 , C08F4/651 , C08F4/6494 , C08F2500/12 , C08F2500/17
摘要： Cyclopolyenic 1,3-diethers wherein the carbon atom in position 2 belongs to a particular cyclic or polycyclic structure containing two or three unsaturations, solid catalyst components and catalysts therefrom, the catalysts comprising the reaction product of: i. a solid catalyst component containing an internal donor; ii. an Al-alkyl compound, and optionally iii. an external donor; the internal donor and/or the external donor being cyclopolyenic 1,3-diethers. The catalysts are useful for the polymerization of alpha-olefins.
摘要翻译： 其中位置2的碳原子属于特定的含有两个或三个不饱和的环状或多环结构的环多烯1,3-二醚，固体催化剂组分和催化剂，所述催化剂包含以下反应产物： 含有内给体的固体催化剂组分; ii。 烷基铝化合物，和任选的iii。 外部供体; 内给体和/或外供体是环多取代1,3-二醚。 该催化剂可用于α-烯烃的聚合。
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公开(公告)号：US07033970B2
公开(公告)日：2006-04-25
申请号：US10486060
申请日：2003-02-28
CPC分类号： C08F4/651 , C08F110/06 , C08F2500/12
摘要： A process for preparing a diether-based catalyst component in which: a) a slurry is obtained by contacting a solid support comprising a magnesium halide or a precursor thereof, one or more 1,3-diethers and a liquid phase containing a titanium compound, and b) the obtained slurry is then subjected to a solid/liquid separation step in order to isolate a diether-based catalyst component; said separation step b) being characterized in that the ratio between the solid/liquid separation velocity and the final amount of separated solid must be higher than 0.5 liter/(min·Kg).
摘要翻译： 一种制备二醚类催化剂组分的方法，其中：a）通过使包含卤化镁或其前体的固体载体，一种或多种1,3-二醚和含有钛化合物的液相， 和b）然后对所获得的浆料进行固/液分离步骤以分离二醚类催化剂组分; 所述分离步骤b）的特征在于固/液分离速度与分离固体的最终量之间的比率必须高于0.5升/（分·克）。
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