公开(公告)号：US07678949B2

公开(公告)日：2010-03-16

申请号：US11988983

申请日：2006-08-04

申请人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

发明人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

IPC分类号： C07C17/00

CPC分类号： C07C21/18 ,  B01J23/868 ,  B01J37/26 ,  C07C17/21 ,  C07C17/23 ,  C07C17/25 ,  C07C19/10

摘要： A process for the manufacture of CF3CH═CHF and/or CF3CF═CH2 is disclosed. The process involves (a) reacting HF and chlorine and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or Cl) to produce a product including both CF3CCI2CCIF2 and CF3CCIFCCI2F; (b) reacting CF3CCI2CCIF2 and CF3CCIFCCI2F produced in (a) with hydrogen to produce a product including both CF3CH2CHF2 and CF3CHFCH2F; (c) dehydrofluorinating CF3CH2CHF2 and CF3CHFCH2F produced in (b) to produce a product including both CF3CH═CHF and CF3CF═CH2; and (d) recovering CF3CH═CHF and/or CF3CF═CH2 from the product produced in (c). In (a), both CF3CCI2CCIF2 and CF3CCIFCCI2F are produced in the presence of a chlorofluorination catalyst consisting of (i) compositions comprising a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by copper, and (ii) compositions of (i) which have been treated with a fluorinating agent.

摘要翻译： 公开了制造CF 3 CH = CHF和/或CF 3 CF = CH 2的方法。 该方法包括（a）使HF和氯与至少一种式CX3CCI = CCIX的卤代丙烯（其中每个X独立地为F或Cl）反应以产生包含CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F的产物; （b）使（a）中制备的CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F与氢反应以产生包含CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F的产物; （c）在（b）中制备的CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F脱氟化氟化产生包括CF 3 CH = CHF和CF 3 CF = CH 2的产物; 和（d）从（c）中制备的产物中回收CF 3 CH = CHF和/或CF 3CF≡CH2。 在（a）中，CF3CCI2CCIF2和CF3CCIFCCI2F都是在氯氟化催化剂存在下制备的，所述氯氟化催化剂由（i）包含结晶α-氧化铬的组合物组成，其中至少0.05原子％的α-氧化铬晶格中的铬原子被替换 和（ii）已经用氟化剂处理的（i）的组合物。

公开(公告)号：US20100051853A1

公开(公告)日：2010-03-04

申请号：US12514348

申请日：2007-11-15

申请人： Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

发明人： Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

IPC分类号： C09K5/00 ,  C07C21/18

CPC分类号： C07C21/18 ,  C07C17/206 ,  C07C17/25 ,  C07C17/354 ,  Y02P20/582 ,  C07C19/08

摘要： A process is disclosed for making CF3CF═CHF or a mixture thereof with CF2═CFCHF2. The process involves (i) contacting CH2ClCF2CF3, and optionally CH2FCF2CClF2, in a reaction zone in the presence of a catalytically effective amount of dehydrofluorination catalyst to produce CHCl═CFCF3, and, if CH2FCF2CClF2 is present, CHF═CFCClF2; (ii) contacting CHCl═CFCF3, and CHF═CFCClF2, if any, formed in (i) with hydrogen fluoride (HF) in a reaction zone, optionally in the presence of a fluorination catalyst, to produce a product mixture comprising CHF═CFCF3, and, if CHF═CFCClF2 is present, CF2═CFCHF2; and (iii) recovering CF3CF═CHF, or a mixture thereof with CF2═CFCHF2, from the product mixture formed in (ii); and optionally (iv) separating at least a portion of any CF3CF═CHF in the product mixture formed in (ii) from the CF2═CFCHF2 in the product mixture formed in (ii). Also disclosed is an azeotropic composition involving CHCl═CFCF3, CHF═CFCClF2 and HF.

摘要翻译： 公开了制备CF 3 CF = CHF或其与CF 2 = CFCHF 2的混合物的方法。 该方法包括：（i）在催化有效量的脱氟化氢催化剂存在下，在反应区中使CH 2 ClCF 2 CF 3和任选的CH 2 CF 2 CClF 2接触，生成CHCl = CFCF 3，如果存在CH 2 CF 2 CClF 2，则CHF = CFCClF 2; （ii）任选在氟化催化剂的存在下，在反应区中，在（i）中与氟化氢（HF）形成CHCl = CFCF 3和CHF = CFCClF 2（如果有的话），以产生包含CHF = CFCF 3 ，如果存在CHF = CFCClF 2，则CF 2 = CFCHF 2; 和（iii）从（ii）中形成的产物混合物中回收CF 3 CF = CHF或其与CF 2 = CFCHF 2的混合物; 和任选地（iv）将（ii）中形成的产物混合物中的CF 3 CF = CHF中的至少一部分与在（ii）中形成的产物混合物中的CF 2 = CFCHF 2分离。 还公开了涉及CHCl = CFCF 3，CHF = CFCClF 2和HF的共沸组合物。

公开(公告)号：US20100051852A1

公开(公告)日：2010-03-04

申请号：US12444598

申请日：2007-11-15

申请人： Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

发明人： Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

IPC分类号： C09K5/00 ,  C07C17/23

CPC分类号： C07C21/18 ,  C07C17/206 ,  C07C17/23 ,  C07C17/25 ,  C07C17/354 ,  Y02P20/582 ,  C07C19/08

摘要： A process is disclosed for making CF3CF═CHF or mixtures thereof with CF2═CFCHF2. The process involves (i) contacting CHCl2CF2CF3, and optionally CHClFCF2CClF2, in a reaction zone in the presence of a catalytically effective amount of dehydrofluorination catalyst to produce CCl2═CFCF3, and, if CHClFCF2CClF2 is present, CClF═CFCClF2; (ii) contacting CCl2═CFCF3 and CClF═CFCClF2, if any, formed in (i) with hydrogen fluoride (HF) in a reaction zone, optionally in the presence of a fluorination catalyst, to produce CClF═CFCF3, and if CClF═CFCClF2 is present, CF2═CFCClF2; (iii) contacting CClF═CFCF3 and CF2═CFCClF2, if any, formed in (ii) in a reaction zone with H2 in the presence of a catalyst comprising a catalytically effective amount of palladium supported on a support of chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride, and/or fluorinated alumina to produce a product mixture comprising CF3CF═CHF, and if CF2═CFCClF2 is present, CF2═CFCHF2; and (iv) recovering CF3CF═CHF, or a mixture thereof with CF2═CFCHF2, from the product mixture formed in (iii); and optionally (v) separating at least a portion of any CF3CF═CHF in the product mixture formed in (iii) from the CF2═CFCHF2 in the product mixture formed in (iii).Also disclosed are azeotropic compositions involving CCl2═CFCF3 and HF; involving CCl2═CFCF3, CClF═CFCClF2 and HF; involving CClF═CFCF3 and HF; involving CClF═CFCF3, CF2═CFCClF2 and HF; or involving CF2═CFCHF2 and HF.

摘要翻译： 公开了制备CF 3 CF = CHF或其与CF 2 = CFCHF 2的混合物的方法。 该方法包括（i）在催化有效量的脱氟化氢催化剂存在下，在反应区中使CHCl 2 CF 2 CF 3和任选的CHClFCF 2 CClF 2接触以产生CCl 2 = CFCF 3，并且如果存在CHClFCF 2 CClF 2，则CClF = CFCClF 2; （ii）在反应区中任选地在（i）中与氟化氢（HF）形成的CCl 2 = CFCF 3和CClF = CFCClF 2（如果有的话）任选地在氟化催化剂的存在下接触，生成CClF = CFCF 3，并且如果CClF = 存在CFCClF 2，CF 2 = CFCClF 2; （iii）在包含催化有效量的负载在氧化铬载体上的载体的催化剂存在下，在与反应区中的（ii）反应区中形成的CClF = CFCF 3和CF 2 = CFCClF 2， ，氟化铬，氧化铝，氟化铝和/或氟化氧化铝，以产生包含CF 3CF≡CHF的产物混合物，如果存在CF 2 = CFCClF 2，CF 2 = CFCHF 2; 和（iv）从（iii）中形成的产物混合物中回收CF 3 CF = CHF或其与CF 2 = CFCHF 2的混合物; （iii）中形成的产物混合物中的CF 3 CF = CHF的至少一部分与（iii）中形成的产物混合物中的CF 2 = CFCHF 2分离。 还公开了涉及CCl 2 = CFCF 3和HF的共沸组合物; 涉及CCl 2 = CFCF 3，CClF = CFCClF 2和HF; 涉及CClF = CFCF3和HF; 涉及CClF = CFCF3，CF2 = CFCClF2和HF; 或涉及CF2 = CFCHF2和HF。

公开(公告)号：US07659435B2

公开(公告)日：2010-02-09

申请号：US11988200

申请日：2006-08-04

申请人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

发明人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

IPC分类号： C07C17/00 ,  C07C17/10

CPC分类号： B01J23/868 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/26 ,  C07C17/21 ,  C07C17/23 ,  C07C19/08 ,  C08J9/146 ,  C07C19/10

摘要： A process is disclosed for the manufacture of CF3CH2CHF2 and CF3CHFCH2F. The process involves (a) reacting hydrogen fluoride, chlorine, and at least one halopropene of the formula CX3CCl═CClX (where each X is independently F or Cl) to produce a product including both CF3CCl2CClF2 and CF3CClFCCl2F; (b) reacting CF3CCl2CClF2 and CF3CClFCCl2F produced in (a) with hydrogen to produce a product including both CF3CH2CHF2, and CF3CHFCH2F; and (c) recovering CF3CH2CHF2 and CF3CHFCH2F from the product produced in (b). In (a), the CF3CCl2CF3 and CF3CClFCClF2 are produced in the presence of a chlorofluorination catalyst including (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and/or (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.

摘要翻译： 公开了用于制造CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F的方法。 该方法包括（a）使氟化氢，氯和至少一种式CX3CCl-CClX（其中每个X独立地为F或Cl）的卤代丙烯反应以产生包含CF 3 CCl 2 CClF 2和CF 3 CClFCCl 2 F的产物; （b）使（a）中制备的CF 3 CCl 2 CClF 2和CF 3 CClFCCl 2 F与氢反应，生成包含CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F的产物; 和（c）从（b）中制备的产物中回收CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F。 在（a）中，CF 3 CCl 2 CF 3和CF 3 CClFCClF 2在氯氟化催化剂的存在下制备，包括（i）结晶α-氧化铬，其中至少0.05原子％的α-氧化铬晶格中的铬原子被二价铜 ，和/或（ⅱ）已经用氟化剂处理的（ⅰ）的含铬组合物。

公开(公告)号：US20090124836A1

公开(公告)日：2009-05-14

申请号：US11988200

申请日：2006-08-04

申请人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

发明人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

IPC分类号： C07C17/20 ,  C07C19/08

CPC分类号： B01J23/868 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/26 ,  C07C17/21 ,  C07C17/23 ,  C07C19/08 ,  C08J9/146 ,  C07C19/10

摘要： A process is disclosed for the manufacture of CF3CH2CHF2 and CF3CHFCH2F. The process involves (a) reacting hydrogen fluoride, chlorine, and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or CI) to produce a product including both CF3CCI2CCIF2 and CF3CCIFCCI2F; (b) reacting CF3CCI2CCIF2 and CF3CCIFCCI2F produced in (a) with hydrogen to produce a product including both CF3CH2CHF2, and CF3CHFCH2F; and (c) recovering CF3CH2CHF2 and CF3CHFCH2F from the product produced in (b). In (a), the CF3CCI2CF3 and CF3CCIFCCIF2 are produced in the presence of a chlorofluorination catalyst including (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and/or (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.

摘要翻译： 公开了用于制造CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F的方法。 该方法包括（a）使氟化氢，氯和至少一种式CX3CCI-CCIX（其中每个X独立地为F或Cl）的卤代丙烯反应以产生包含CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F的产物; （b）使（a）中制备的CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F与氢反应以产生包含CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F的产物; 和（c）从（b）中制备的产物中回收CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F。 在（a）中，CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2在氯氟化催化剂存在下制备，包括（i）α-氧化铬晶格中至少0.05原子％的铬原子被二价铜取代的结晶α-氧化铬 ，和/或（ⅱ）已经用氟化剂处理的（ⅰ）的含铬组合物。

公开(公告)号：US20090118554A1

公开(公告)日：2009-05-07

申请号：US11988983

申请日：2006-08-04

申请人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

发明人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

IPC分类号： C07C17/21

CPC分类号： C07C21/18 ,  B01J23/868 ,  B01J37/26 ,  C07C17/21 ,  C07C17/23 ,  C07C17/25 ,  C07C19/10

摘要： A process for the manufacture of CF3CH═CHF and/or CF3CF═CH2 is disclosed. The process involves (a) reacting HF and chlorine and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or Cl) to produce a product including both CF3CCI2CCIF2 and CF3CCIFCCI2F; (b) reacting CF3CCI2CCIF2 and CF3CCIFCCI2F produced in (a) with hydrogen to produce a product including both CF3CH2CHF2 and CF3CHFCH2F; (c) dehydrofluorinating CF3CH2CHF2 and CF3CHFCH2F produced in (b) to produce a product including both CF3CH═CHF and CF3CF═CH2; and (d) recovering CF3CH═CHF and/or CF3CF═CH2 from the product produced in (c). In (a), both CF3CCI2CCIF2 and CF3CCIFCCI2F are produced in the presence of a chlorofluorination catalyst consisting of (i) compositions comprising a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by copper, and (ii) compositions of (i) which have been treated with a fluorinating agent.

摘要翻译： 公开了制备CF 3 CH-CHF和/或CF 3 CF-CH 2的方法。 该方法包括（a）使HF和氯以及至少一种式CX3CCI-CCIX（其中每个X独立地为F或Cl）的卤代丙烯反应，以产生包含CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F的产物; （b）使（a）中制备的CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F与氢反应以产生包含CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F的产物; （c）在（b）中制备的CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F脱氟化氢，制得包含CF 3 CH-CHF和CF 3 CF-CH 2的产物; 和（d）从（c）中制备的产物中回收CF 3 CH-CHF和/或CF 3 CF-CH 2。 在（a）中，CF3CCI2CCIF2和CF3CCIFCCI2F都是在氯氟化催化剂存在下制备的，所述氯氟化催化剂由（i）包含α-氧化铬晶格中的至少0.05原子％的铬原子的结晶α-氧化铬的组合物组成 和（ii）已经用氟化剂处理的（i）的组合物。

公开(公告)号：US20090043138A1

公开(公告)日：2009-02-12

申请号：US11988259

申请日：2006-08-04

申请人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

发明人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

IPC分类号： C07C17/23

CPC分类号： B01J23/868 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/26 ,  C07C17/206 ,  C07C17/21 ,  C07C17/23 ,  C07C17/25 ,  C07C17/354 ,  C07C19/08 ,  C07C21/18 ,  C07C19/10

摘要： A process for the manufacture of CF3CH═CHF and/or CF3CH═CF2 is disclosed. The process involves involves (a) reacting HF and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or CI) to produce a product including both CF3CCI═CF2 and CF3CHCICF3; (b) reacting CF3CCI═CF2 and/or CF3CHCICF3 produced in (a) with hydrogen to produce a product including CF3CH2CHF2 and/or CF3CH2CF3; (c) dehydrofluorinating CF3CH2CHF2 and/or CF3CH2CF3 produced in (b) to produce a product comprising CF3CH═CHF and/or CF3CH═CF2; and (d) recovering CF3CH═CHF and/or CF3CH═CF2 from the product produced in (c). In (a), the CF3CCI═CF2 and CF3CHCICF3 are produced in the presence of a fluorination catalyst comprising at least one chromium-containing component selected from (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.

摘要翻译： 公开了制造CF 3 CH-CHF和/或CF 3 CH-CF 2的方法。 该方法涉及（a）使HF和至少一种式CX3CCI-CCIX的卤代丙烯（其中每个X独立地为F或Cl）反应以产生包含CF 3 CCl-CF 2和CF 3 CHCICF 3的产物; （b）使（a）中制备的CF 3 CCl-CF 2和/或CF 3 CHCICF 3与氢反应以产生包含CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3的产物; （c）在（b）中制备的CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3脱氟化氢以产生包含CF 3 CH-CHF和/或CF 3 CH-CF 2的产物; 和（d）从（c）中制备的产物中回收CF 3 CH-CHF和/或CF 3 CH-CF 2。 在（a）中，CF 3 CCl-CF 2和CF 3 CHCICF 3在含有至少一种含铬组分的氟​​化催化剂的存在下制备，所述含铬组分选自（i）结晶α-氧化铬，其中至少0.05原子％ 所述α-氧化铬晶格被二价铜取代，和（ii）已经用氟化剂处理的（i）的含铬组合物。

公开(公告)号：US20080207962A1

公开(公告)日：2008-08-28

申请号：US12070784

申请日：2008-02-21

申请人： Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

发明人： Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

IPC分类号： C07C17/23 ,  B01J23/26

CPC分类号： C07C19/08 ,  B01J23/6522 ,  B01J23/685 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/14 ,  B01J37/26 ,  C07C17/04 ,  C07C17/206 ,  C07C17/21 ,  C07C17/23 ,  C07C17/25 ,  C07C21/18 ,  C07C19/10

摘要： A catalyst composition is disclosed that includes chromium, oxygen, and at least two of gold, silver, and palladium as essential constituent elements. The amount of modifier metals (gold, silver, and/or palladium) in the composition is from about 0.05 atom % to about 10 atom % based on the total amount of chromium and modifier metals. Also disclosed is a process for changing the fluorine distribution (i.e., content and/or arrangement) in a hydrocarbon or halogenated hydrocarbon in the presence of the catalyst composition; and methods for preparing said catalyst composition. One preparation method involves (a) co-precipitating a solid by adding ammonium hydroxide (aqueous ammonia) to an aqueous solution of soluble salts of modifier metals and a soluble chromium salt that contains at least three moles of nitrate per mole of chromium in the solution and has a modifier metal content of from about 0.05 atom % to about 10 atom % of the total content of modifier metals and chromium in the solution to form an aqueous mixture containing co-precipitated solid; (b) drying the co-precipitated solid formed in (a); and (c) calcining the dried solid formed in (b) in an atmosphere containing at least 10% oxygen by volume. Another preparation method involves (a) impregnating solid chromium oxide with a solution of a soluble modifier metal salts; (b) drying the impregnated chromium oxide prepared in (a); and optionally; (c) calcining the dried solid. Yet another preparation method involves mixing multiple compositions, each comprising chromium, oxygen, and at least one modifier metal.

摘要翻译： 公开了一种催化剂组合物，其包括铬，氧和至少两种金，银和钯作为必需组成元素。 组合物中改性金属（金，银和/或钯）的量相对于铬和改性金属的总量为约0.05原子％至约10原子％。 还公开了在催化剂组合物存在下改变烃或卤代烃中的氟分布（即含量和/或排列）的方法; 以及制备所述催化剂组合物的方法。 一种制备方法包括（a）通过向改性剂金属的可溶性盐的水溶液中加入氢氧化铵（氨水）并在溶液中每摩尔铬含有至少三摩尔硝酸盐的可溶性铬盐共沉淀固体 并且具有改性剂金属含量为溶液中改性剂金属和铬的总含量的约0.05原子％至约10原子％，以形成含共沉淀固体的含水混合物; （b）干燥（a）中形成的共沉淀固体; 和（c）在（b）中形成的干燥固体在含有至少10体积％氧气的气氛中煅烧。 另一种制备方法包括（a）用可溶性修饰金属盐溶液浸渍固体氧化铬; （b）干燥（a）中制备的浸渍的氧化铬; 和可选地; （c）煅烧干燥的固体。 另一种制备方法包括混合多种组合物，每种组合物包含铬，氧和至少一种改性金属。

公开(公告)号：US09000241B2

公开(公告)日：2015-04-07

申请号：US13277268

申请日：2011-10-20

申请人： Mario Joseph Nappa ,  Ekaterina N. Swearingen ,  Allen Capron Sievert ,  Xuehui Sun

发明人： Mario Joseph Nappa ,  Ekaterina N. Swearingen ,  Allen Capron Sievert ,  Xuehui Sun

IPC分类号： C07C17/00 ,  C07C17/25 ,  C07C17/23

CPC分类号： C07C17/25 ,  C07C17/23 ,  C07C21/18

摘要： The disclosure describes a process for dehalogenation of chlorofluorocompounds. The process comprises contacting a saturated chlorofluorocompound with hydrogen in the presence of a catalyst at a temperature sufficient to remove chlorine and/or fluorine substituents to produce a fluorine containing terminal olefin.

摘要翻译： 本公开描述了氯氟化合物脱卤的方法。 该方法包括在足以除去氯和/或氟取代基以产生含氟末端烯烃的温度的催化剂存在下使饱和氯氟化合物与氢气接触。

公开(公告)号：US08633339B2

公开(公告)日：2014-01-21

申请号：US11591400

申请日：2006-11-01

申请人： Joseph Anthony Creazzo ,  Mario Joseph Nappa ,  Allen Capron Sievert ,  Ekaterina N. Swearingen

发明人： Joseph Anthony Creazzo ,  Mario Joseph Nappa ,  Allen Capron Sievert ,  Ekaterina N. Swearingen

IPC分类号： C07C21/18

CPC分类号： C08J9/146 ,  B01F17/0085 ,  C03C23/0075 ,  C07C21/18 ,  C08G18/4208 ,  C08G18/4883 ,  C08G2101/0025 ,  C08J9/0019 ,  C08J9/144 ,  C08J2205/05 ,  C08J2205/052 ,  C08J2325/06 ,  C08J2375/06 ,  C08J2375/08 ,  C10M105/52 ,  C10M107/38 ,  C10M147/04 ,  C10M169/04 ,  C10M169/041 ,  C10M177/00 ,  C10M2211/022 ,  C10M2211/06 ,  C10M2213/04 ,  C10M2213/06 ,  C10N2230/06 ,  C10N2230/22 ,  C10N2240/20 ,  C10N2240/204 ,  C10N2250/121 ,  C10N2270/00 ,  C11D3/245 ,  C11D3/43 ,  C11D7/5018 ,  C11D11/0023 ,  C11D11/0029 ,  C11D11/0035 ,  C11D11/0047 ,  C23G5/02803 ,  C23G5/02825 ,  G11B5/71 ,  G11B5/725 ,  G11B5/8408 ,  G11B23/505

摘要： Disclosed herein are blowing agents comprising fluorocarbons and/or hydrofluorocarbons useful in foamable compositions. Also disclosed are methods for forming a foam comprising the aforementioned blowing agents.

摘要翻译： 本文公开了包含可用于可发泡组合物的碳氟化合物和/或氢氟烃的发泡剂。 还公开了形成包含上述发泡剂的泡沫体的方法。