摘要:
There is provided a novel, useful dehydroxyfluorination agent containing sulfuryl fluoride (SO2F2) and an organic base that is free from a free hydroxyl group in the molecule. According to the present dehydroxyfluorination agent, it is not necessary to use perfluoroalkanesulfonyl fluoride, which is not preferable in large-scale use, and it is possible to advantageously produce optically-active fluoro derivatives, which are important intermediates of medicines, agricultural chemicals and optical materials, for example, 4-fluoroproline derivatives, 2′-deoxy-2′-fluorouridine derivatives, optically-active α-fluorocarboxylate derivatives, and monofluoromethyl derivatives, even in large scale.
摘要翻译:提供了含有硫酰氟(SO 2 F 2)和分子中不含游离羟基的有机碱的新型有用的脱羟基氟化剂。 根据现有的脱羟基氟化剂,不需要使用全氟烷基磺酰氟,其在大规模使用中是不优选的,并且可以有利地制备作为药物,农药和光学的重要中间体的光学活性氟衍生物 材料,例如4-氟脯氨酸衍生物,2'-脱氧-2'-氟尿苷衍生物,光学活性α-氟代羧酸酯衍生物和单氟甲基衍生物,甚至大规模。
摘要:
A hydraulic circuit for a working machine includes hydraulic actuators which respectively drive a plurality of kinds of working devices and which are driven by a drive circuit having circuit states that correspond to the working devices, a directional control valve unit which, when one of the working devices is attached to the attachment, switches in response to a signal from a controller to select one of the circuit states, a detection sensor that detects the actual circuit state, and a display operated by the controller. The controller activates the display when the detected actual circuit state and the selected circuit state do not match.
摘要:
It is an object of the invention to provide a method of producing a crosslinked poly(meth)acrylic acid compound, in particular a method of producing a crosslinked poly(meth)acrylic acid nitroxide compound, which is a radical compound excellent in solvent stability.The invention is a method of producing a crosslinked poly(meth)acrylic acid compound resulting from crosslinking of a poly(meth)acrylic acid compound represented by the general formula (1): (in the formula, n Z1s represent a hydrogen atom(s) and/or an oxygen atom(s) having one unpaired electron, R represents a hydrogen atom or a methyl group and n represents an integer of 5 to 1000000), which method is characterized by comprising a polymerization step of polymerizing a (meth)acrylic acid compound represented by the general formula (2): (in the formula, Z2 represents a hydrogen atom when Z1 is a hydrogen atom, or a hydrogen atom or an oxygen atom having one unpaired electron when Z1 is an oxygen atom having one unpaired electron; and R represents the same group as R in the above general formula (1)) in the presence of a crosslinking agent.
摘要:
The present invention relates to a process for producing an optically active 1-alkyl-substituted 2,2,2-trifluoroethylamine, which is an important intermediate of medicines and agricultural chemicals, and which is represented by the formula [3] [in the formula R represents a lower alkyl group of a carbon and * represents an asymmetric carbon], or its salt by subjecting an optically active imine represented by the formula [1] to an asymmetric reduction under hydrogen atmosphere using a metal catalyst of Group VIII to convert it into an optically active secondary amine represented by the formula [2] and then by subjecting the secondary amine or its salt to hydrogenolysis.[Chem. 23]
摘要:
1-β-D-Arabinofuranosyluracil in 3′,5′-hydroxyl-protected form is reacted with a trifluoromethanesulfonylating agent in the presence of an organic base to convert it into a 2′-triflate form, and then it is reacted with a fluorinating agent containing “a salt or complex formed by an organic base and hydrofluoric acid” to produce 2′-deoxy-2′-fluorouridine in 3′,5′-hydroxyl-protected form. A deprotecting agent is further caused to act thereon to obtain 2′-deoxy-2′-fluorouridine. The 2′-deoxy-2′-fluorouridine obtained can efficiently be purified by temporarily converting it into a 3′,5′-diacetyl form, recrystallizing the 3′,5′-diacetyl form, and then deacetylating it. Thus, high-purity 2′-deoxy-2′-fluorouridine can be produced.
摘要:
A firmware updating method for updating firmware for an information processing apparatus that includes setting a communications device as a boot device according to an instruction from a remote management server, resetting the information processing apparatus in system reset according to a system reset instruction from the remote management server under an environment of an operating system of the information processing system operating, booting the information processing apparatus by the communications device thereby to update the firmware stored in the storage via the network, setting the storage as a boot device thereby to control off a power supply of the information processing apparatus in response to a request from the remote management server, controlling on the power supply in response to another request from the remote management server, and reading and executing the firmware updated in the storage of the information processing apparatus.
摘要:
The bearing rings 1 and 2 of a rolling bearing is formed of one kind of titanium alloys of &bgr; type titanium alloys, near &bgr; type titanium alloys and &agr;+&bgr; type titanium alloys. The titanium alloy has a surface hardness of Hv 400 or more and less than Hv 600 for increasing the corrosion resistance and wear resistance of the bearing ring. Spherical rolling elements 3 rolling on the raceway surfaces 1a and 2a of the bearing rings 1 and 2 are formed of ceramics such as silicon nitride. When &bgr; type titanium alloys or &agr;+&bgr; type titanium alloys after a solution treatment and applied with an oxidation treatment at a low temperature of 400 to 600° C. are used as the material for the bearing ring, a bearing ring made of titanium alloy suitable to use under a circumstance requiring corrosion resistance is obtained.
摘要:
A high-frequency heating apparatus is designed to maximize the input current while securing a uniform margin relative to the cutoff current, thereby enabling maximized and efficient output of high-frequency waves. The high-frequency heating apparatus includes: a power supply unit; an input current detector; a power converting unit for converting the power from the power supply unit into high-frequency waves; an inverter controller for controlling a semiconductor device; a magnetron for radiating electromagnetic waves; and a circuit for implementing negative feedback control, in the inverter control circuit, of the output from the input current detector. The apparatus further includes a control circuit having a microcomputer for outputting signals to the inverter controller so as to control the input current such that the input current characteristic of the high-frequency heating apparatus will approximate the current cutoff characteristic of the overcurrent circuit breaker with respect to the elapsed time.
摘要:
In a steel cage for rolling bearing which is nitrided to form a compound layer on the surface thereof, when the thickness of a dense layer in the compound layer 1 is predetermined to a range of from 3 &mgr;m to 20 &mgr;m, the abrasion can be inhibited, improving the abrasion resistance. Further, when a porous layer which acts as a lubricant reservoir is predetermined to a range of from 2 &mgr;m to 25 &mgr;m, the exhaustion of lubricant can be inhibited, improving the seizing resistance.
摘要:
The object of the present invention is to simplify the process of connecting a reservoir for charging and discharging 2 or more fluids with a pipeline for conveying said fluid and to assist the automation of this process.In the present invention, a reservoir, having, at its end face, 2 or more openings for fluids for charging and discharging 2 or more fluids respectively, is connected with pipelines by using a connecting means having flow paths for 2 or more fluids and, at its end face, 2 or more openings for fluids corresponding to each of the flow paths, and each of the respective fluids is passed, when by aligning the center of 1 of the openings for fluids of the reservoir end face with 1 of the openings for fluids of the connecting means end face and by linking said openings for fluids to each other, closed passage spaces are respectively formed which are common to the 1 or more other opening(s) for fluids of the reservoir end face and to the 1 or more corresponding other opening(s) of the connecting means end face respectively, and each fluid is passed via said spaces respectively.