Abstract:
A process for the conditioning of contaminated waste through cementing. Dry waste is cemented, especially waste which is recovered as ashes subsequent to the combustion of burnable waste, or as a dry residue during the treatment of sludge. In the process there is added to the dry waste a cement component not less than about 50% by weight of the weight of the waste, wherein subsequent to the admixing of the waste with the cement, there is mixed in water to the cement in a slightly excess stoichiometric ratio of effecting the setting, and the mixture is compacted under pressure and then encased.
Abstract:
A solid fixation product of harmful, water-containing waste materials and cement, which product is highly resistant to leaching by water and salt solutions. The product has a high content of 20 to 50% of waste materials based on the dry weight of the waste in the product and a water content corresponding to a water-to-cement ratio of 0.2 to 0.45. The method according to the invention which permits producing of such products is characterized in that evaporation of the water-containing waste materials and the mixing with the fixation matrix takes place concurrently at temperatures of 100.degree. to 180.degree. C. The resulting solid fixation product is of relatively small volume and, accordingly, requires only relatively little storage space.
Abstract:
Disclosed is a method for rapidly forming a solid monolith of an aqueous mixture of an ion exchange resin and boric acid. A fouling agent and sufficient basic accelerator to neutralize the mixture are added. Cement is then added which hardens in a few hours. Also disclosed is a composition of the ion exchange resin, boric acid, water, a fouling agent, a basic accelerator, and cement.
Abstract:
Provided herein are methods and compositions utilizing one or more cementitious replacement materials, one or more alkaline activating materials, and, optionally one or more bonding materials and/or one or more setting time enhancer materials. The one or more cement precursors comprises one or more of non-radioactive nuclear waste; swarf, insoluble hydroxide of carbonate salts, radioactive wastes, petroleum coke, spent solvent wastes, electroporating and other metal finishing wastes, dioxin-bearing wastes, chlorinated aliphatic hydrocarbons production, wood preserving wastes, petroleum refinery wastewater treatment sludges, multisource leachate, organic chemicals manufacturing waste, pesticide manufacturing waste, petroleum refining waste, human pharmaceuticals manufacturing waste; veterinary pharmaceuticals manufacturing waste; inorganic pigment manufacturing waste; inorganic chemicals manufacturing waste; explosives manufacturing waste; iron and/or steel production waste; primary aluminum production waste; secondary lead processing waste; ink formulation waste; coking waste; or a combination thereof. The one or more alkaline activating agents comprises potassium silicate, potassium hydroxide, sodium hydroxide, sodium silicate, calcium hydroxide, magnesium hydroxide, reactive magnesium oxide, calcium chloride, sodium carbonate, silicone dioxide, sodium aluminate, calcium sulfate, sodium sulfate, or dolomite, or a combination thereof. The system comprises a vertical impact mill.
Abstract:
A hazardous material storage bank includes a wellbore extending into the Earth and including an entry at least proximate a terranean surface, the wellbore including a substantially vertical portion, a transition portion, and a substantially horizontal portion; a storage area coupled to the substantially horizontal portion of the well bore, the storage area within or below a shale formation, the storage area vertically isolated, by the shale formation, from a subterranean zone that includes mobile water; a storage container positioned in the storage area, the storage container sized to fit from the wellbore entry through the substantially vertical, the transition, and the substantially horizontal portions of the wellbore, and into the storage area, the storage container including an inner cavity sized enclose hazardous material; and a seal positioned in the wellbore, the seal isolating the storage portion of the wellbore from the entry of the wellbore.
Abstract:
A method for conditioning a contaminated ion exchange resin includes mixing the contaminated ion exchange resin with water and at least partly breaking up the contaminated ion exchange resin into water-soluble components or fragments through the use of an oxidizing agent added to the water. A resulting aqueous solution is consolidated with a binder, optionally after concentration by evaporation of water.
Abstract:
Masses for obtaining poured concrete, concrete for bricks, concrete for tiles or mortar are known, in which Portland cement and Colemanite, water and additives to regulate the process are involved as aggregate.The invention achieves a remarkable increase in the capacity of neutron radiation protection of the material. For this, Portland cement is replaced by Alumina cement and a new component is inserted into the mass, specifically anhydrous calcium sulfate, the Colemanite staying as aggregate.
Abstract:
Apparatus for transferring settled or suspended solids from an open vessel into a closed vessel, the apparatus comprising a suction line which extends from the closed vessel to the open vessel via drive means, such as a pump or compressor, and a solids feed line which extends from a solids outlet in the open vessel to a solids inlet in the closed vessel, a fluidising apparatus being provided to fluidise the solids in the open vessel.
Abstract:
Treatment of a radioactive waste stream is provided by adding sodium hydroxide (NaOH) and/or potassium hydroxide (KOH) together with a rapidly dissolving form of silica, e.g., fumed silica or fly ash. Alternatively, the fumed silica can be first dissolved in a NaOH/KOH solution, which is then combined with the waste solution. Adding a binder that can be a mixture of metakaolin (Al2O3.2SiO2), ground blast furnace slag, fly ash, or other additives. Adding an “enhancer” that can be composed of a group of additives that are used to further enhance the immobilization of heavy metals and key radionuclides such as 99Tc and 129I. An additional step can involve simple mixing of the binder with the activator and enhancer, which can occur in the final waste form container, or in a mixing vessel prior to pumping into the final waste form container, depending on the particular application.
Abstract:
The present disclosure describes solid waste forms and methods of processing waste. In one particular implementation, the invention provides a method of processing waste that may be particularly suitable for processing hazardous waste. In this method, a waste component is combined with an aluminum oxide and an acidic phosphate component in a slurry. A molar ratio of aluminum to phosphorus in the slurry is greater than one. Water in the slurry may be evaporated while mixing the slurry at a temperature of about 140-200° C. The mixed slurry may be allowed to cure into a solid waste form. This solid waste form includes an anhydrous aluminum phosphate with at least a residual portion of the waste component bound therein.