公开(公告)号：US5077179A

公开(公告)日：1991-12-31

申请号：US106425

申请日：1987-10-09

申请人： Akira Abe ,  Yoshihiro Fujita ,  Nobuo Sakai

发明人： Akira Abe ,  Yoshihiro Fujita ,  Nobuo Sakai

IPC分类号： G03C11/00 ,  G03C7/30 ,  G03C7/44 ,  G03C7/46

CPC分类号： G03C7/44 ,  G03C7/3046

摘要： A method for processing silver halide photosensitive materials comprises replenishing each of replenishers to water washing process and/or stabilization process in an amount of 1 to 50 times the volume of a solution carried over from a bath preceding the water washing process and/or the stabilization process per unit area of the photosensitive material and limiting the amount of calcium compounds included in a layer for constituting photograph of the photosensitive material to not more than 25 mg/m.sup.2 on the basis of the weight of elemental calcium. The method makes it possible to effectively suppress the contamination of the processed photosensitive materials, the increase in turbidity of the water washing and/or stabilization bath solutions and the proliferation of bacteria or molds in these baths. These effects are further enhanced by reducing the amount of calcium and magnesium present in the replenishers for washing and/or stabilization.

摘要翻译： 用于处理卤化银感光材料的方法包括补充每种补充剂至水洗过程和/或稳定过程，其量为从水洗过程之前的浴中携带的溶液的体积的1至50倍和/或稳定化 感光材料的每单位面积的过程，并且将用于构成感光材料的照片的层中包含的钙化合物的量基于元素钙的重量限制在25mg / m 2以下。 该方法可以有效地抑制处理的感光材料的污染，水洗和/或稳定浴溶液的浊度的增加以及这些浴中的细菌或霉菌的增殖。 通过减少用于洗涤和/或稳定的补充剂中存在的钙和镁的量来进一步增强这些效果。

公开(公告)号：US5063131A

公开(公告)日：1991-11-05

申请号：US541470

申请日：1990-06-22

申请人： Akira Abe ,  Yoshihiro Fujita ,  Keiji Mihayashi

发明人： Akira Abe ,  Yoshihiro Fujita ,  Keiji Mihayashi

IPC分类号： G03C7/26 ,  G03C7/30 ,  G03C7/392 ,  G03C11/00

CPC分类号： G03C7/39236 ,  G03C7/3046

摘要： A method for processing a silver halide color photographic photosensitive material comprises treating a silver halide photographic material with a bath having fixing ability and then washing with water and/or stabilizing the photosensitive material and characterized in that the amount of replenisher for water washing or stabilization is controlled so that it is 1 to 50 times the volume of liquid carried over by the photosensitive material processed from the bath preceding the water washing bath or the stabilization bath and that the photosensitive material comprises, for instance, compounds (13): ##STR1## The method makes it possible to substantially keep the image performance of the photosensitive material processed high while substantially saving the amount of washing water or the stabilization liquid and substantially shortening the water washing or the stabilization time.

摘要翻译： 一种用于处理卤化银彩色照相感光材料的方法包括用具有定影能力的浴处理卤化银照相材料，然后用水洗涤和/或稳定感光材料，其特征在于用于水洗或稳定的补充剂的量为 被控制使得其是由在洗涤水浴或稳定浴之前的浴中处理的感光材料承载的液体的体积的1至50倍，并且感光材料包括例如化合物（13）： 该方法使得可以基本上保持感光材料的图像性能得到高处理，同时基本上节省了洗涤水或稳定液体的量，并且基本上缩短了水洗或稳定时间。

公开(公告)号：US4952490A

公开(公告)日：1990-08-28

申请号：US162554

申请日：1988-03-01

申请人： Shunji Takada ,  Toshihiro Nishikawa ,  Kei Sakanoue ,  Akira Abe

发明人： Shunji Takada ,  Toshihiro Nishikawa ,  Kei Sakanoue ,  Akira Abe

IPC分类号： G03C1/035 ,  G03C7/30

CPC分类号： G03C7/3022 ,  G03C1/035 ,  G03C2001/0058 ,  G03C2001/03517

摘要： A photographic light-sensitive material comprises a support having thereon at least one silver halide emulsion layer. At least 70% of a total number of silver halide grains contained in the emulsion layer are regular crystal grains not having a twinning plane. At least 50 mol% of the regular grains are silver chloride. The regular crystal grains have a (111) crystal plane on 30% or more of a total grain surface and are chemically sensitized in the presence of a gold compound or sulfur and gold compounds.

摘要翻译： 照相感光材料包括其上具有至少一个卤化银乳剂层的载体。 包含在乳剂层中的卤化银颗粒总数的至少70％是不具有孪晶平面的规则晶粒。 至少50mol％的常规颗粒是氯化银。 规则晶粒在总颗粒表面的30％以上具有（111）晶面，并且在金化合物或硫和金化合物的存在下化学增感。

公开(公告)号：US4927533A

公开(公告)日：1990-05-22

申请号：US358289

申请日：1989-05-26

申请人： Haruo Takase ,  Kazushige Uenaka ,  Akira Abe ,  Yoshihiro Fujita

发明人： Haruo Takase ,  Kazushige Uenaka ,  Akira Abe ,  Yoshihiro Fujita

IPC分类号： C02F1/04 ,  C02F1/76 ,  C02F9/00

CPC分类号： C02F1/50 ,  C02F1/045 ,  C02F1/42 ,  C02F1/441 ,  C02F2103/40 ,  C02F2209/42 ,  C02F2303/04 ,  C02F2303/20

摘要： In photographic processing apparatus for developing, bleaching-fixing and washing photographic materials, a predetermined quantity of fresh wash water is supplied into a washing tank every time a predetermined amount of the photographic materials have been washed. The fresh wash water is provided by deionizing city water and is reservoired in a replenisher tank. In order to detect a predetermined loss of the fresh wash water in the replenisher tank, a conductivity increasing material is dissolved in the fresh wash water in the replenisher tank when a predetermined quantity of the deionized water is supplied so as to electrically connect a pair of electrodes disposed at a predetermined depth of the replenisher tank. A sterilizer is mixed in the fresh wash water to prevent bacterial growth in the replenisher tank. The conductivity increasing material and the sterilizer are prepared as a predetermined dose of mixture necessary and sufficient for the predetermined quantity of deionized water supplied into the replenisher tank.

公开(公告)号：US4857950A

公开(公告)日：1989-08-15

申请号：US155454

申请日：1988-02-12

申请人： Haruo Takase ,  Kazushige Uenaka ,  Akira Abe ,  Yoshihiro Fujita

发明人： Haruo Takase ,  Kazushige Uenaka ,  Akira Abe ,  Yoshihiro Fujita

IPC分类号： C02F1/04 ,  C02F1/76 ,  C02F9/00

CPC分类号： C02F1/50 ,  C02F1/045 ,  C02F1/42 ,  C02F1/441 ,  C02F2103/40 ,  C02F2209/42 ,  C02F2303/04 ,  C02F2303/20

摘要： In photographic processing apparatus for developing, bleaching-fixing and washing photographic materials, a predetermined quantity of fresh wash water is supplied into a washing tank every time a predetermined amount of the photographic materials have been washed. The fresh wash water is provided by deionizing city water and is reservoired in a replenisher tank. In order to detect a predetermined loss of the fresh wash water in the replenisher tank, a conductivity increasing material is dissolved in the fresh wash water in the replenisher tank when a predetermined quantity of the deionized water is supplied so as to electrically connect a pair of electrodes disposed at a predetermined depth of the replenisher tank. A sterilizer is mixed in the fresh wash water to prevent bacterial growth in the replenisher tank. The conductivity increasing material and the sterilizer are prepared as a predetermined dose of mixture necessary and sufficient for the predetermined quantity of deionized water supplied into the replenisher tank.

摘要翻译： 在用于显影，漂白固定和洗涤照相材料的照相处理设备中，每当洗涤预定量的照相材料时，将预定数量的新鲜洗涤水供应到洗涤槽中。 新鲜的洗涤水通过去离子水提供，并储存在补充剂罐中。 为了检测补充罐中新鲜洗涤水的预定损失，当提供预定量的去离子水时，将电导率增加材料溶解在补充液罐中的新鲜洗涤水中，以便电连接一对 设置在补充罐的预定深度的电极。 在新鲜的洗涤水中混合灭菌器以防止补充液罐中的细菌生长。 制备电导率增加材料和灭菌器作为预定剂量的混合物，必要且足够用于供给到补充液罐中的预定量的去离子水。

公开(公告)号：US4855218A

公开(公告)日：1989-08-08

申请号：US154200

申请日：1988-02-10

申请人： Yoshihiro Fujita ,  Akira Abe

发明人： Yoshihiro Fujita ,  Akira Abe

IPC分类号： G03C7/44

CPC分类号： G03C7/44

摘要： A method for processing silver halide photographic lightsensitive material in which there are used replenishers for water washing and/or stabilization processes in such manner that the concentrations of calcium and magnesium compounds present in the replenishers are not more than 5 mg/l on the basis of elemental calcium and magnesium respectively, and a part or whole of the overflow from the water washing and/or stabilization process is introduced into a process preceding the water washing and/or stabilization processes. This method makes it possible to save water, to diminish the amount of waste liquor and to make effective use of components contained in processing solutions, without impairing any properties of lightsensitive materials to be processed.

摘要翻译： 一种用于处理卤化银照相感光材料的方法，其中使用补充剂进行水洗和/或稳定化处理，使得补充剂中存在的钙和镁化合物的浓度不超过5mg / l，基于 元素钙和镁，并且将来自水洗和/或稳定化过程的部分或全部溢出物引入到水洗和/或稳定化过程之前的过程中。 该方法可以节约用水量，减少废液的量，有效地利用处理液中所含的成分，而不影响待处理的感光材料的任何特性。

公开(公告)号：US4775612A

公开(公告)日：1988-10-04

申请号：US938919

申请日：1986-12-08

申请人： Akira Abe ,  Jun Arakawa ,  Yasushi Nozawa

发明人： Akira Abe ,  Jun Arakawa ,  Yasushi Nozawa

IPC分类号： G03C11/00 ,  G03C7/30 ,  G03C5/24 ,  G03C5/38 ,  G03C7/00 ,  G03C7/32

CPC分类号： G03C7/3046

摘要： A method for processing a silver halide color photographic material is disclosed, wherein a washing bath is replenished with water in an amount of from 2 to 50 times the volume of the preceding bath which is carried over with the photographic material into the washing bath per unit area of the photographic material to be processed, and washing in the washing bath is carried out in the presence of at least one compound represented by formula (I): ##STR1## wherein A represents a n-valent aliphatic, aromatic or heterocyclic linking group, wherein when n is 1, A represents a monovalent aliphatic, aromatic, or heterocyclic group, or a hydrogen atom; X represents --O--, --S--, or ##STR2## R.sup.1 and R.sup.2 each represents substituted or unsubstituted lower alkyl group; R.sup.3 represents a lower alkylene group; R.sup.4 represents a lower alkyl group; or R.sup.1 and R.sup.2, R.sup.1 and A, R.sup.1 and R.sup.3, R.sup.2 and A, or R.sup.2 and R.sup.3 may be connected to each other to form a ring; Y represents an anion; l represents 0 or 1; m represents 0 or 1; n represents 1, 2, or 3; p represents 0 or 1; and q represents 0, 1, 2, or 3, and is a value which renders the molecule electrically neutral. The processing method can achieve a great saving of water for washing while protecting the processed color photographic material from mold, the formation of stains, and undergoing accelerated discoloration.

摘要翻译： 公开了一种处理卤化银彩色照相材料的方法，其中将洗涤浴补充的量为前一个浴的体积的2至50倍，该浴体用照相材料转移到每单位洗涤浴中 待处理的照相材料的面积和洗涤浴中的洗涤在至少一种由式（I）表示的化合物的存在下进行：其中A表示n价的脂族，芳族或 杂环连接基团，其中当n为1时，A表示一价脂族，芳族或杂环基团或氢原子; X表示-O-，-S-或者R 1，R 2各自表示取代或未取代的低级烷基; R3表示低级亚烷基; R4代表低级烷基; 或R 1和R 2，R 1和A，R 1和R 3，R 2和A或R 2和R 3可以彼此连接形成环; Y表示阴离子; l表示0或1; m表示0或1; n表示1,2或3; p表示0或1; 并且q表示0,1,2或3，并且是使分子电中性的值。 该处理方法可以大大节省洗涤水，同时保护加工的彩色照相材料免受霉菌侵蚀，形成污渍，并进行加速变色。

公开(公告)号：US4769313A

公开(公告)日：1988-09-06

申请号：US933517

申请日：1986-11-21

申请人： Hiroshi Fujimoto ,  Shinzo Kishimoto ,  Akira Abe ,  Junya Nakajima

发明人： Hiroshi Fujimoto ,  Shinzo Kishimoto ,  Akira Abe ,  Junya Nakajima

IPC分类号： G03C7/38 ,  G03C7/42 ,  G03C7/00 ,  G03C5/24 ,  G03C5/44 ,  G03C7/32

CPC分类号： G03C7/42 ,  G03C7/3825 ,  G03C7/38

摘要： A method of forming an image comprising, after color developmenmt of an exposed silver halide color photographic material, processing the developed silver halide color photographic material with a bath having a bleaching ability and subsequently with a bath having a bleach-fixing ability, wherein the silver halide color photographic material comprises a support having coated thereon at least one silver halide emulsion layer and at least one pyrazoloazole type magenta coupler represented by the following general formula (A): ##STR1## wherein R.sub.22 represents a hydrogen atom of a substituent; X represents a group capable of being split off upon a coupling reaction with an oxidation product of an aromatic primary amine developing agent; Za, Zb and Zc each represents a methine group, a substituted methine group, .dbd.N-- or --NH--, one of the Za--Zb bond and the Zb--ZC bond being a double bond and the other being a single bond; when the Zb--Zc bond is a carbon-carbon double bond, the Zb--Zc bond may be a part of a condensed aromatic ring; R.sub.22 or X may also form a polymer including a dimer or more; and when Za, Zb or Zc is a substituted methine group, the substituted methine group may form a polymer including a dimer or more. In accordance with the method of forming an image, desilveration is completed in a short period of time and color photographic images having excellent color reproducibility and fastness are obtained without the formation of magenta stain.

摘要翻译： 一种形成图像的方法，包括在曝光的卤化银彩色照相材料的显影后，用具有漂白能力的浴处理显影的卤化银彩色照相材料，随后用具有漂白定影能力的浴，其中银 卤化物彩色照相材料包括其上涂覆有至少一种卤化银乳剂层和至少一种由以下通式（A）表示的吡唑并唑型品红成色剂的载体：其中R22表示取代基的氢原子 ; X表示与芳族伯胺显影剂的氧化产物偶联反应时能够分离的基团; Za，Zb和Zc各自表示次甲基，取代的次甲基，= N-或-NH-，Za-Zb​​键和Zb-ZC键之一为双键，另一个为单键; 当Zb-Zc键​​为碳 - 碳双键时，Zb-Zc键​​可以是稠合芳环的一部分; R 22或X也可以形成包含二聚体或更多的聚合物; 当Za，Zb或Zc为取代的次甲基时，取代的次甲基可以形成包含二聚体或更多的聚合物。 根据形成图像的方法，在短时间内完成脱银，并且在没有形成品红色污点的情况下获得具有优异色彩再现性和牢度的彩色照相图像。

公开(公告)号：US4769312A

公开(公告)日：1988-09-06

申请号：US918260

申请日：1986-10-14

申请人： Shinzo Kishimoto ,  Akira Abe ,  Junya Nakajima

发明人： Shinzo Kishimoto ,  Akira Abe ,  Junya Nakajima

IPC分类号： G03C7/42 ,  G03C5/44 ,  G03C7/32 ,  G03C7/34

CPC分类号： G03C7/42

摘要： A method of processing silver halide color photographic materials which comprises image-wise exposing said silver halide color photographic materials, color developing and then desilvering them in a bath having bleaching ability, characterized in that the bath having bleaching ability comprises two baths, the oxidation-reduction potential of the first bath being higher than that of the second bath, the oxidation-reduction potential of the second bath falling in the range of +60 mV to -60 mV, the first bath containing a water-soluble bromide in an amount of 0.5 to 1.3 mole/l, and the second bath containing a water-soluble bromide in an amount of 0 to 0.5 mole/l.

摘要翻译： 一种处理卤化银彩色照相材料的方法，其包括使所述卤化银彩色照相材料成像曝光，着色显影，然后在具有漂白能力的浴中将其脱色，其特征在于具有漂白能力的浴液包括两个浴， 第一浴的还原电位高于第二浴，第二浴的氧化还原电位在+60mV至-60mV的范围内，第一浴含有一定量的水溶性溴化物 0.5至1.3摩尔/升，第二浴含有0至0.5摩尔/升的水溶性溴化物。

公开(公告)号：US4695529A

公开(公告)日：1987-09-22

申请号：US919110

申请日：1986-10-15

申请人： Akira Abe ,  Junya Nakajima ,  Toshihiro Nishikawa

发明人： Akira Abe ,  Junya Nakajima ,  Toshihiro Nishikawa

IPC分类号： G03C1/005 ,  G03C1/035 ,  G03C7/42 ,  G03C5/38

CPC分类号： G03C7/42

摘要： An image-forming process is disclosed, which comprises exposing a silver halide color photographic material comprising a support having provided thereon at least one silver halide emulsion layer containing tabular silver halide grains having a diameter-to-thickness ratio of 5 or more, subjecting the exposed photographic material to color development processing, then processing the photographic material in a bath mainly having a bleaching ability and successively in a bath having a bleach-fixing ability.

摘要翻译： 公开了一种图像形成方法，其包括将包含其上提供有至少一个包含直径与厚度比为5或更大的片状卤化银颗粒的至少一个卤化银乳剂层的卤化银彩色照相材料曝光， 曝光的照相材料进行显色处理，然后在主要具有漂白能力的浴中依次在具有漂白定影能力的浴中处理照相材料。