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    Process for producing resin for optical material
    71.
    发明授权
    Process for producing resin for optical material 有权
    光学材料树脂生产工艺

    公开(公告)号：US08044165B2

    公开(公告)日：2011-10-25

    申请号：US12438750

    申请日：2007-10-09

    申请人： Masaru Kawaguchi ,  Shigetoshi Kuma ,  Mamoru Tanaka ,  Seiichi Kobayashi

    发明人： Masaru Kawaguchi ,  Shigetoshi Kuma ,  Mamoru Tanaka ,  Seiichi Kobayashi

    IPC分类号： C08G18/00

    CPC分类号： C08G18/758 ,  C08G18/3876 ,  C08G18/52 ,  C08G2120/00 ,  G02B1/041 ,  C08L75/04

    摘要： Disclosed is a process for producing effectively a high performance optical material (e.g. a lens) made of a polyurethane resin, which is transparent and colorless without a strain. In this process, the optical material is produced without causing striation or clouding by polymerizing a polymerizable composition comprising a polythiol compound and a polyiso(thio)cyanate compound, and characterized in that a water content in the composition is 10 to 300 ppm.

    摘要翻译： 公开了一种有效地制造透明且无应变的聚氨酯树脂的高性能光学材料（例如透镜）的方法。 在该方法中，通过聚合包含多硫醇化合物和多异（硫代）氰酸酯化合物的聚合性组合物而不产生条纹或混浊的光学材料，其特征在于组合物中的水含量为10〜300ppm。

    POLYMERIZABLE COMPOSITION FOR POLYTHIOURETHANE OPTICAL MATERIAL
    73.
    发明申请
    POLYMERIZABLE COMPOSITION FOR POLYTHIOURETHANE OPTICAL MATERIAL 有权
    聚四氟乙烯光学材料的可聚合组合物

    公开(公告)号：US20110190466A1

    公开(公告)日：2011-08-04

    申请号：US12280300

    申请日：2007-02-15

    申请人： Hidetoshi Hayashi ,  Nobuo Kawato ,  Masanori Iwazumi ,  Mamoru Tanaka ,  Seiichi Kobayshi

    发明人： Hidetoshi Hayashi ,  Nobuo Kawato ,  Masanori Iwazumi ,  Mamoru Tanaka ,  Seiichi Kobayshi

    IPC分类号： C08G75/04 ,  C08G18/00 ,  C08G18/73

    CPC分类号： C08L75/04 ,  C08G18/222 ,  C08G18/3876 ,  C08G18/757 ,  C08G18/7642 ,  G02B1/041 ,  G11B7/2533

    摘要： A polymerizable composition for polythiourethane optical materials comprising a compound represented by the general formula (1), M(L)n  (1) wherein, in the formula, M is Al, Fe, Cu, Zn, Zr or Bi; L is a dithiocarbamic acid group, a sulfonic acid group, a mono- or di-alkyl phosphoric acid ester group, a substituted acetylacetonato group or a halogen; and n is an integer of 1 to 5, one or two or more isocyanates selected from the group consisting of isocyanate compounds and isothiocyanate compounds, and one or two or more active hydrogen compounds each having a mercapto group. The compounds represented by the general formula (1) exhibit catalytic activity equal to or superior to that of organotin catalysts having been employed as catalysts for the production of polythiourethane optical materials from the past, and have high safety. Further, the thus obtained polythiourethane resins satisfactorily meet the property requirements for optical materials, in particular, excelling in weather resistance. Therefore, the proposed catalysts are available as novel catalysts replacing the organotin catalysts.

    摘要翻译： 一种聚硫氨酯类光学材料用聚合性组合物，其含有通式（1）表示的化合物，M（L）n（1），式中，M为Al，Fe，Cu，Zn，Zr或Bi; L是二硫代氨基甲酸基，磺酸基，一烷基或二烷基磷酸酯基，取代的乙酰丙酮基或卤素; n为1〜5的整数，选自由异氰酸酯化合物和异硫氰酸酯化合物组成的组中的一种或两种以上的异氰酸酯，以及一种或两种以上具有巯基的活性氢化合物。 由通式（1）表示的化合物具有等于或优于已经用作生产聚硫氨酯光学材料的催化剂的有机锡催化剂的催化活性，并且具有高安全性。 此外，由此得到的聚硫氨酯树脂令人满意地满足光学材料的性能要求，特别是耐候性优异。 因此，所提出的催化剂可用作替代有机锡催化剂的新型催化剂。

    Polythiourethane-based polymerizable composition and optical resin obtained from the same
    76.
    发明申请
    Polythiourethane-based polymerizable composition and optical resin obtained from the same 有权
    聚硫氨酯类聚合性组合物和由其得到的光学树脂

    公开(公告)号：US20090099329A1

    公开(公告)日：2009-04-16

    申请号：US11990616

    申请日：2006-08-04

    申请人： Akinori Ryu ,  Mamoru Tanaka ,  Kunio Okumura

    发明人： Akinori Ryu ,  Mamoru Tanaka ,  Kunio Okumura

    IPC分类号： C08G18/30

    CPC分类号： C08G18/757 ,  C08G18/3876 ,  G02B1/041 ,  C08L75/04 ,  C08L81/00

    摘要： Provided are a polymerizable composition for giving a resin which has a high refractive index and low dispersion, and is especially excellent in impact resistance and tintability; and a resin and an optical component each obtained by curing the composition. There used a polymerizable composition comprising (A) a compound represented by Formula (1) and/or by Formula (2), at least one compound as the following component (B), and at least one compound as the following component (C): (B) polythiol compounds optionally having at least one (poly)sulfide bond in a molecule, and (C) compounds represented by Formula (3): HO—[R1-(Y)n]m—R2-X  (3) (in above Formula (3), X is an OH group or a SH group; Y is an oxygen atom or a sulfur atom; R1 and R2 are each independently an optionally substituted methylene group or an optionally substituted alkylene group having carbon atoms of not smaller than 2 and not larger than 4; n is an integer of 0 or 1 when Y is an oxygen atom, or 0 or an integer of not smaller than 1 and not larger than 2 when Y is a sulfur atom; and m is 0 or an integer of not smaller than 1 and not larger than 3, provided that (carbon number of R1+n)×m+(carbon number of R2) is 3 or larger).

    摘要翻译： 提供一种用于赋予折射率高，分散性低的树脂的聚合性组合物，其耐冲击性和着色性特别优异; 以及通过固化该组合物而获得的树脂和光学部件。 使用包含（A）由式（1）表示的化合物和/或式（2）表示的化合物，至少一种下述成分（B）的化合物和至少一种下述成分（C）的化合物的聚合性组合物， ：（B）分子中任选具有至少一个（多）硫键的多硫醇化合物，和（C）式（3）表示的化合物：<？在线式描述=“在线式”末端=“ 引线“→HO- [R1-（Y）n] m-R2-X（3）<？in-line-formula description =”In-line Formulas“end =”tail“？> ），X是OH基或SH基; Y是氧原子或硫原子; R 1和R 2各自独立地是任选取代的亚甲基或任选取代的碳原子数不小于2且不大于2的亚烷基 当Y为氧原子时，n为0或1的整数，Y为硫原子时为0或1以上2以下的整数，m为0以下的整数。 1以上3以下 （碳数R1 + n）×m +（碳数R2）为3以上）。

    Ferrule for use with an optical fiber connector and method for production thereof
    78.
    发明授权
    Ferrule for use with an optical fiber connector and method for production thereof 失效

    公开(公告)号：US5989106A

    公开(公告)日：1999-11-23

    申请号：US140598

    申请日：1998-08-26

    申请人： Mamoru Tanaka ,  Shigeru Kitamura

    发明人： Mamoru Tanaka ,  Shigeru Kitamura

    IPC分类号： E04C2/04 ,  B24B5/04 ,  B24B5/50 ,  B24B19/00 ,  B24B41/06 ,  B28B11/08 ,  G02B6/36 ,  G02B6/38 ,  B24B1/00

    CPC分类号： G02B6/3837 ,  B24B41/062 ,  B24B5/04 ,  B24B5/50 ,  G02B6/3835 ,  G02B6/3855 ,  G02B6/3861 ,  G02B6/3865 ,  G02B6/3854

    摘要： A ferrule used for an optical fiber connector and a method for efficient production thereof are disclosed. The ferrule comprises a through-hole formed linearly along the axial line thereof and having a part of a small diameter for the insertion of an optical fiber, a part of a large diameter for the insertion of a sheathed optical fiber, and a diametrically tapered part intervening between the small diameter part and the large diameter part and diverging from the small diameter part to the large diameter part. The through-hole has a length of not less than 1 mm for the small diameter part and a length of less than 6 mm for the total of the small diameter part and the diametrically tapered part. In the production of this ferrule, the grinding work for the impartation of an outside diameter is implemented by causing the opposite end parts of a ceramic blank having an engaging part adapted to receive a rotational driving force to be rotatably supported with a double center cylindrical grinder and rotating a live center of the double center cylindrical grinder having formed thereon a fitting part for union with the engaging part thereby enabling the ceramic blank engaged with the live center to rotate and effecting the grinding work.

    Ferrule for use with an optical fiber connector and method for production thereof
    79.
    发明授权
    Ferrule for use with an optical fiber connector and method for production thereof 失效
    用于光纤连接器的套圈及其制造方法

    公开(公告)号：US5862280A

    公开(公告)日：1999-01-19

    申请号：US812264

    申请日：1997-03-06

    申请人： Mamoru Tanaka ,  Shigeru Kitamura

    发明人： Mamoru Tanaka ,  Shigeru Kitamura

    IPC分类号： E04C2/04 ,  B24B5/04 ,  B24B5/50 ,  B24B19/00 ,  B24B41/06 ,  B28B11/08 ,  G02B6/36 ,  G02B6/38 ,  G02B6/28

    CPC分类号： G02B6/3837 ,  B24B41/062 ,  B24B5/04 ,  B24B5/50 ,  G02B6/3835 ,  G02B6/3855 ,  G02B6/3861 ,  G02B6/3865 ,  G02B6/3854

    摘要： A ferrule used for an optical fiber connector and a method for efficient production thereof are disclosed. The ferrule comprises a through-hole formed linearly along the axial line thereof and having a part of a small diameter for the insertion of an optical fiber, a part of a large diameter for the insertion of a sheathed optical fiber, and a diametrically tapered part intervening between the small diameter part and the large diameter part and diverging from the small diameter part to the large diameter part. The through-hole has a length of not less than 1 mm for the small diameter part and a length of less than 6 mm for the total of the small diameter part and the diametrically tapered part. In the production of this ferrule, the grinding work for the impartation of an outside diameter is implemented by causing the opposite end parts of a ceramic blank having an engaging part adapted to receive a rotational driving force to be rotatably supported with a double center cylindrical grinder and rotating a live center of the double center cylindrical grinder having formed thereon a fitting part for union with the engaging part thereby enabling the ceramic blank engaged with the live center to rotate and effecting the grinding work.

    摘要翻译： 公开了一种用于光纤连接器的套圈及其有效生产方法。 套圈包括沿其轴线线性形成的通孔，其具有用于插入光纤的一部分小直径，用于插入护套光纤的一部分大直径，以及直径锥形部分 介于小直径部分和大直径部分之间并且从小直径部分发散到大直径部分。 通孔对于小直径部分具有不小于1mm的长度，对于小直径部分和直径锥形部分的总长度小于6mm。 在该套圈的制造中，用于赋予外径的研磨工作是通过使具有接合部的接合部的陶瓷坯料的相对端部接受旋转驱动力以由双中心圆柱形磨床可旋转地支撑 并且旋转双中心圆柱形研磨机的活动中心，其上形成有用于与接合部分结合的配合部分，从而使得与活体中心接合的陶瓷坯体能够旋转并进行研磨工作。

    Image forming method and apparatus thereof with control of dot position
    80.
    发明授权
    Image forming method and apparatus thereof with control of dot position 失效
    具有点位置控制的图像形成方法及其装置

    公开(公告)号：US5724090A

    公开(公告)日：1998-03-03

    申请号：US754476

    申请日：1996-11-22

    申请人： Mamoru Tanaka ,  Nobuyuki Ito

    发明人： Mamoru Tanaka ,  Nobuyuki Ito

    IPC分类号： B41J2/44 ,  H04N1/23 ,  H04N1/405 ,  B41J2/47

    CPC分类号： H04N1/4056

    摘要： An image forming method and apparatus which forms an image by using PWM to properly reproduce tones at a low density in the image formation, and attain a high-quality image without reducing the resolution in the dot formation corresponding to a high density value. A color laser beam printer using the PWM to which the present invention is applied forms a latent image onto a photosensitive drum by the laser beam irradiated from a semiconductor laser. The waveform of a chopped wave signal used in the PWM is set to be unique with respect to each color component, and be asymmetrical to the center of each pixel represented by the image signal in synchronization with the waveform of the chopped signal. Accordingly, the interval of dots formed to correspond to each color component is relatively wide when the density value is small, while the interval is relatively narrow when the density value is large.

    摘要翻译： 一种图像形成方法和装置，其通过使用PWM在图像形成中以低密度适当地再现色调，并且在不降低对应于高密度值的点形成中的分辨率的情况下获得高质量图像来形成图像。 使用使用本发明的PWM的彩色激光束打印机通过从半导体激光器照射的激光束在感光鼓上形成潜像。 在PWM中使用的斩波信号的波形被设置为对于每个颜色分量是唯一的，并且与由斩波信号的波形同步的由图像信号表示的每个像素的中心不对称。 因此，当密度值小时，形成为对应于每个颜色分量的点的间隔相对较宽，而当密度值大时间隔相对较窄。