利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

87 条记录 (耗时 0.035 秒)

    Benzo-1,2,3-thiadiazole derivatives
    71.
    发明授权
    Benzo-1,2,3-thiadiazole derivatives 失效
    苯并-1,2,3-噻二唑衍生物

    公开(公告)号：US5248683A

    公开(公告)日：1993-09-28

    申请号：US893292

    申请日：1992-06-04

    申请人： Hans-Georg Brunner ,  Walter Kunz ,  Rolf Schurter

    发明人： Hans-Georg Brunner ,  Walter Kunz ,  Rolf Schurter

    IPC分类号： A01N43/82 ,  A01N43/828 ,  C07D285/14 ,  C07D405/06 ,  C07D409/06 ,  C07D417/06

    CPC分类号： C07D285/14 ,  A01N43/82 ,  C07D405/06 ,  C07D409/06 ,  C07D417/06

    摘要： Compounds of the formula ##STR1## in which A.sub.1 and A.sub.2 independently of one another are CO--C.sub.1 -C.sub.4 alkyl, COO--C.sub.1 -C.sub.4 alkyl, CO--CF.sub.3, CO--N(R).sub.2 or cyano;A.sub.1 and A.sub.2 together are CO(X).sub.n --C.sub.1 -C.sub.3 alkylene-(X).sub.n CO, CO(X).sub.n --C.sub.1 -C.sub.3 alkylene-(X).sub.n CO which is substituted by C.sub.1 -C.sub.4 alkyl, COOR, CON(R).sub.2, cyano or phenyl, it being possible for the phenyl ring, in turn, to be substituted by halogen, methyl, trifluoromethyl, methoxy, nitro or cyano; CO--N(R)--CO--N(R)--CO;R is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyl or C.sub.3 -C.sub.6 alkynyl;X is oxygen, sulfur or N(CH.sub.3);X.sub.1, X.sub.2 and X.sub.3 independently of one another are hydrogen, halogen, methyl, methylthio, methoxy or nitro;n is 0 or 1;including the salts of the compounds of the formula I with agriculturally acceptable organic or inorganic bases, and including the metal complexes; have valuable microbicidal properties.The novel compounds can be used in crop protection for preventing the attack of crop plants by phytopathogenic microorganisms and for the control of these pests.

    摘要翻译： 其中A 1和A 2彼此独立的式“IMAGE”的化合物是CO-C 1 -C 4烷基，COO-C 1 -C 4烷基，CO-CF 3，CO-N（R）2或氰基; A1和A2一起是被C1-C4烷基，COOR，CON（R）2取代的CO（X）n-C1-C3亚烷基 - （X）nCO，CO（X）n-C1-C3亚烷基 - （X） 氰基或苯基，苯环可以被卤素，甲基，三氟甲基，甲氧基，硝基或氰基取代; CO-N（R）-CO-N（R）-CO; R是氢，C 1 -C 6烷基，C 3 -C 6烯基或C 3 -C 6炔基; X是氧，硫或N（CH 3）; X1，X2和X3彼此独立地是氢，卤素，甲基，甲硫基，甲氧基或硝基; n为0或1; 包括式I化合物与农业上可接受的有机或无机碱的盐，并包括金属络合物; 具有有价值的杀菌特性。 新型化合物可用于作物保护，以防止植物病原微生物侵袭作物和控制这些害虫。

    Compositions for protecting plants against disease
    72.
    发明授权
    Compositions for protecting plants against disease 失效
    防治疾病的植物的组合物

    公开(公告)号：US5112840A

    公开(公告)日：1992-05-12

    申请号：US594889

    申请日：1990-10-09

    申请人： Helmut Zondler ,  Alfred Meyer ,  Wolfgang Eckhardt ,  Walter Kunz

    发明人： Helmut Zondler ,  Alfred Meyer ,  Wolfgang Eckhardt ,  Walter Kunz

    IPC分类号： A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  C07D213/81 ,  C07D401/06 ,  C07D401/12 ,  C07D401/14 ,  C07D413/14

    CPC分类号： C07D213/81 ,  A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  C07D401/06 ,  C07D401/12 ,  C07D401/14

    摘要： Novel substituted isonicotinic acid amides of the general formula ##STR1## in which X in ortho/ortho'-position are equal and represent fluorine, chlorine, bromine or iodine;Q.sub.1 is unsubstituted pyrimidin-4-yl, or pyrimidin-4-yl substituted by R.sub.1, R.sub.2 and R.sub.3 ;Q.sub.2 is unsubstituted pyrimidin-2-yl, or pyrimidin-2-yl substituted by R.sub.1,R.sub.2 and R.sub.3 ;Q.sub.3 is unsubstituted pyrimidin-5-yl, or pyrimidin-5-yl substituted by R.sub.1, R.sub.2 and R.sub.3 ;Q.sub.4 is pyridin-2-yl, pyridin-3-yl or pyridin-4-yl each of which is unsubstituted or substituted by R.sub.1, R.sub.2 and R.sub.3 ;Q.sub.5 is pyridazin-3-yl or pyridazin-4-yl each of which is unsubstituted or substituted by R.sub.1, R.sub.2 and R.sub.3 ;Q.sub.6 is unsubstituted pyrazin-2-yl, or pyrazin-2-yl substituted by R.sub.1, R.sub.2 and R.sub.3 ;R.sub.1, R.sub.2, R.sub.3 are hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl having from 1 to 3 halogen atoms, C.sub.1 -C.sub.6 alkoxy, C.sub.2 -C.sub.6 alkoxyalkyl, C.sub.1 -C.sub.6 thioalkyl, C.sub.1 -C.sub.6 haloalkoxy having from 1 to 5 halogen atoms, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 alkynyloxy, C.sub.3 -C.sub.6 thioalkenyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.3 -C.sub.6 cycloalkyl substituted by methyl, or nitro, cyano, the radical CH(OR.sub.4).sub.2 or COOR.sub.4 in which R.sub.4 is C.sub.1 -C.sub.4 alkyl; also phenyl, phenoxy, thiophenyl, benzyl, benzyloxy or thiobenzyl; or phenyl, phenoxy, thiophenyl, benzyl, benzyloxy or thiobenzyl each substituted at least once by C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 -alkoxy, C.sub.1 -C.sub.3 haloalkyl having from 1 to 3 halogen atoms, halogen, nitro or by cyano; and also N(R.sub.5)R.sub.6 in which R.sub.5 and R.sub.6, independently of one another, are each C.sub.1 -C.sub.6 alkyl; and furthermore piperidinyl, pyrrolidinyl, morpholinyl, imidazolyl or triazolyl, or piperidinyl, pyrrolidinyl, morpholinyl, imidazolyl or triazolyl each substituted by C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkyl having from 1 to 3 halogen atoms, halogen, nitro or by cyano.The novel ingredients have plant-protecting properties and are suitable especially for the preventive protection of plants against attack by phytopathogenic microorganisms such as fungi, bacteria and viruses.

    Microbicidal compositions
    73.
    发明授权
    Microbicidal compositions 失效

    公开(公告)号：US5068359A

    公开(公告)日：1991-11-26

    申请号：US537196

    申请日：1990-06-12

    申请人： Alica Huxley ,  Walter Kunz ,  Peter Ackermann ,  Marius Sutter

    发明人： Alica Huxley ,  Walter Kunz ,  Peter Ackermann ,  Marius Sutter

    IPC分类号： A01N43/12 ,  A01N43/36 ,  C07D307/79 ,  C07D333/54 ,  C07D333/62 ,  C07D405/04 ,  C07D409/04

    CPC分类号： C07D333/54 ,  A01N43/36 ,  C07D307/79 ,  C07D333/62 ,  C07D405/04 ,  C07D409/04

    摘要： Novel benzothiophene and benzofuran derivatives of the general formula I ##STR1## wherein X is oxygen or sulfur, R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 haloalkyl, R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 haloalkyl, R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or halogen and R is a 4-cyano-3-pyrrole radical of which the N atom carries one of the following substituents:A: hydrogen or CO--R.sub.4 in which R.sub.4 is unsubstituted C.sub.1 C.sub.6 alkyl or C.sub.1 -C.sub.6 alkyl substituted by halogen or by C.sub.1 -C.sub.3 alkoxy; C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, unsubstituted C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 alkoxy substituted by halogen or by C.sub.1 -C.sub.3 alkoxy; C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 cycloalkyl or tetrahydrofur2-yl;B: S-R.sub.5 in which R.sub.5 is C.sub.1 -C.sub.3 haloalkyl;C: CH(Y)R.sub.6 in which R.sub.6 is hydrogen or C.sub.1 -C.sub.8 haloalkyl and Y is hydroxy, halogen or OC(O)R.sub.7 in which R.sub.7 is C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 haloalkyl, C.sub.2 -C.sub.6 -alkenyl, 2-tetrahydrofuryl, 2-tetrahydropyranyl or C.sub.1 -C.sub.6 alkoxycarbonyl;D: CH.sub.2 -Z in which Z is one of the groups ##STR2## wherein R.sub.8 and R.sub.9 are each, independently of the other, hydrogen, unsubstituted C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkyl substituted by cyano or by C.sub.1 -C.sub.6 alkoxycarbonyl; C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.7 cycloalkyl, unsubstituted phenyl or phenyl substituted by halogen, by C.sub.1 -C.sub.6 alkyl, by C.sub.1 -C.sub.6 haloalkyl and/or by C.sub.1 -C.sub.6 alkoxy, with the proviso that only R.sub.8 or R.sub.9 may be hydrogen; R.sub.10 and R.sub.11 are each, independently of the other, hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxycarbonyl; R.sub.12 and R.sub.13 are each, independently of the other, hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxycarbonyl; and R.sub.15 is oxygen, sulfur, >C.dbd.0 or >N--R.sub.14, wherein R.sub.14 is hydrogen, C.sub.1 -C.sub.6 alkyl, formyl, C.sub.1 -C.sub.6 alkanoyl or C.sub.1 -C.sub.6 alkoxycarbonyl; and n is one of the numbers 0 or 1.The novel active ingredients serve to control harmful microorganisms, especially phytophathogenic fungi. They can be used together with suitable formulation adjuvants in the form of compositions, and are suitable also for preventing attack on cultivated plants by harmful microorganisms.

    Compositions for protecting plants against disease
    75.
    发明授权
    Compositions for protecting plants against disease 失效
    用于保护植物免受疾病的组合物

    公开(公告)号：US4959096A

    公开(公告)日：1990-09-25

    申请号：US324876

    申请日：1989-03-17

    申请人： Helmut Zondler ,  Walter Kunz

    发明人： Helmut Zondler ,  Walter Kunz

    IPC分类号： C07D249/08 ,  A01N43/40 ,  A01N43/50 ,  A01N43/653 ,  C07D213/79 ,  C07D233/54 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07D521/00

    CPC分类号： C07D213/79 ,  A01N43/40 ,  A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D405/12 ,  C07D409/12

    摘要： Novel substituted isonicotinic acid esters of the general formula ##STR1## in which Y is halogen;X is oxygen or sulfur;Q is C.sub.1 -C.sub.3 alkylene, propenylene, C.sub.1 -C.sub.3 alkylene mono- or di-substituted by R, or propenylene mono- or di-substituted by R;R is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl having from 1 to 3 halogen atoms, cyano, C.sub.2 -C.sub.5 alkoxycarbonyl, C.sub.3 -C.sub.6 cycloalkyl, phenyl, or phenyl substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, trifluoromethyl, tricholoromethyl, nitro or by cyano, or benzoyl or benzoyl substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, trifluoromethyl, trichloromethyl, nitro or by cyano;A is phenyl, biphenyl, phenoxyphenyl, naphthyl, pyridyl, furyl, thienyl, imidazolyl or triazolyl, it being possible for each of these radicals to be unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkoxy having from 1 to 3 halogen atoms, trifluoromethyl, nitro or by cyano; with the proviso (1) that if A is imidazolyl or triazolyl R may not be phenyl or benzoyl, and (2) that A and the R substituent in Q may together contain no more than 3 rings.The novel active ingredients have plant-protecting properties and are suitable especially for the preventive protection of plants against attack by phytopathogenic microorganisms, such as fungi, bacteria and viruses.

    摘要翻译： 新颖的通式为“IMAGE”的取代的异烟酸酯，其中Y是卤素; X是氧或硫; Q是C1-C3亚烷基，亚丙烯基，被R单取代或二取代的C1-C3亚烷基，或被R单取代或二取代的亚丙烯基; R是C1-C4烷基，具有1至3个卤素原子的C 1 -C 4卤代烷基，氰基，C 2 -C 5烷氧基羰基，C 3 -C 6环烷基，苯基或被C 1 -C 4烷基，C 1 -C 4烷氧基，卤素，三氟甲基，三氯甲基，硝基或 氰基或苯甲酰基或被C 1 -C 4烷基，C 1 -C 4烷氧基，三氟甲基，三氯甲基，硝基或氰基取代的苯甲酰基; A是苯基，联苯基，苯氧基苯基，萘基，吡啶基，呋喃基，噻吩基，咪唑基或三唑基，这些基团中的每一个可以是未取代的或被卤素，C 1 -C 4烷基，C 1 -C 3烷氧基，C 1 -C 3卤代烷氧基 至3个卤素原子，三氟甲基，硝基或氰基; 条件是（1）如果A是咪唑基或三唑基R可以不是苯基或苯甲酰基，和（2）A中的A和R中的R取代基可以一起含有不多于3个环。 新型活性成分具有植物保护性质，特别适用于植物防止植物病原微生物如真菌，细菌和病毒侵袭的预防性保护。

    Microbicidal 2-(1H-1,2,4-triazolylmethyl-1'-yl)-2-siloxy-2-phenyl-acetates
    77.
    发明授权
    Microbicidal 2-(1H-1,2,4-triazolylmethyl-1'-yl)-2-siloxy-2-phenyl-acetates 失效

    公开(公告)号：US4533659A

    公开(公告)日：1985-08-06

    申请号：US499725

    申请日：1983-05-31

    申请人： Wolfgang Eckhardt ,  Walter Kunz

    发明人： Wolfgang Eckhardt ,  Walter Kunz

    IPC分类号： C07D233/60 ,  A01N43/50 ,  A01N43/653 ,  A01N55/00 ,  A01N55/10 ,  C07F7/18 ,  A61K31/555 ,  C07D207/30

    CPC分类号： A01N55/00 ,  C07F7/1856

    摘要： The invention relates to microbicidal silyloxyalkane azoles of the formula I ##STR1## wherein X is the bridge member --CH.dbd. or --N.dbd.,Ar is a phenyl, diphenyl or naphthyl group,R.sub.1, R.sub.2 and R.sub.3 independently of one another are hydrogen, nitro, halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkyl,R is one of the groups --COOR.sub.5, --COSR.sub.6, ##STR2## or --CN, R.sub.5 is C.sub.2 -C.sub.10 alkenyl which is unsubstituted or substituted by halogen; C.sub.2 -C.sub.10 alkynyl which is unsubstituted or substituted by halogen; or is a C.sub.3 -C.sub.8 cycloalkyl group or a phenyl group which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --CN or --CF.sub.3 ; or is a C.sub.1 -C.sub.12 alkyl chain which from C.sub.2 alkyl may be interrupted by oxygen or sulfur and is unsubstituted or substituted by a member selected from the group consisting of halogen, phenyl, --COO--C.sub.1 --C.sub.4 alkyl, --CO--C.sub.1 --C.sub.4 alkyl, --CO--phenyl, an unsaturated or saturated 5- or 6-membered ring containing oxygen or sulfur as heteroatom, with each phenyl moiety being unsubstituted or substituted by one or more identical or different halogen atoms,R.sub.6 is C.sub.1 -C.sub.10 alkyl, or is a phenyl or benzyl group, each unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --CN or --CF.sub.3,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.7 cycloalkyl, or a phenyl or benzyl group in each of which the aromatic ring is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 alkoxy, --CN or --CF.sub.3, or one of R.sub.7 and R.sub.8 is also the --N(R.sub.9)(R.sub.10) group or both taken together form a 5- or 6-membered saturated or unsaturated heterocyclic ring which may additionally contain 1 or 2 further N atoms,R.sub.9 and R.sub.10, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl or a phenyl radical which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl, --CN or --CF.sub.3 ; andR.sub.4 is the --Si(R.sub.11)(R.sub.12)(R.sub.13) group, wherein each of R.sub.11, R.sub.12 and R.sub.13 independently is a radical selected from C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.7 alkenyl or phenyl, each unsubstituted or substituted by one or more halogen atoms,and the acid addition salts and metal complexes thereof.Also disclosed are methods of preparing these compounds and also pesticidal compositions which contain at least one of the novel compounds as active ingredient. A method of controlling phytopathogenic microorganisms with the aid of the novel compounds of the invention is also described.

    Azolylmandelic acid derivatives and use thereof for controlling microorganisms
    78.
    发明授权
    Azolylmandelic acid derivatives and use thereof for controlling microorganisms 失效
    唑基扁桃酸衍生物及其用于控制​​微生物的用途

    公开(公告)号：US4517194A

    公开(公告)日：1985-05-14

    申请号：US503966

    申请日：1983-06-13

    申请人： Walter Kunz ,  Wolfgang Eckhardt

    发明人： Walter Kunz ,  Wolfgang Eckhardt

    IPC分类号： A01N43/50 ,  A01N43/653 ,  A01N47/04 ,  C07D233/60 ,  C07D233/64 ,  C07D249/08 ,  C07D521/00 ,  A01N43/64 ,  C07D249/06

    CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  A01N47/04 ,  C07D233/56 ,  C07D249/08

    摘要： The invention relates to microbicidal mandelic acid derivatives of the formula I ##STR1## wherein X is the bridge member --CH.dbd. or --N.dbd.,Ar is a phenyl, diphenyl or naphthyl group,R.sub.1, R.sub.2 and R.sub.3 independently of one another are hydrogen, nitro, halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkyl,R is one of the groups ##STR2## R.sub.5 is C.sub.2 -C.sub.10 alkenyl which is unsubstituted or substituted by halogen; C.sub.2 -C.sub.10 alkynyl which is unsubstituted or substituted by halogen; or is a C.sub.3 -C.sub.8 cycloalkyl group or a phenyl group which is unsubstituted or substituted; or is a C.sub.1 -C.sub.12 alkyl chain which from C.sub.2 alkyl may be interrupted by oxygen or sulfur and is unsubstituted or substituted by a member selected from the group consisting of halogen, phenyl, --COO--C.sub.1 --C.sub.4 alkyl, --CO--C.sub.1 --C.sub.4 alkyl, --CO-phenyl, an unsaturated or saturated 5- or 6-membered ring containing oxygen or sulfur as heteroatom, with each phenyl moiety being unsubstituted or substituted by one or more identical or different halogen atoms, is C.sub.1 -C.sub.10 alkyl, or is a phenyl or benzyl group, each unsubstituted or substitutedR.sub.4 is C.sub.1 -C.sub.12 alkyl which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.4 alkyl, or is phenyl or benzyl, each unsubstituted or substituted or is the --N(R.sub.9)(R.sub.10) group, whereinR.sub.9 is C.sub.1 -C.sub.6 alkyl andR.sub.10 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkylsulfenyl, --SC.sub.6 H.sub.5 or --SC(CH.sub.3).sub.2 CN,and the acid addition salts and metal complexes thereof.

    摘要翻译： 本发明涉及式I（I）的杀微生物扁桃酸衍生物，其中X是桥连构成基团-CH =或-N =，Ar是苯基，二苯基或萘基，R 1，R 2和R 3独立地是一个 另一个是氢，硝基，卤素，C 1 -C 3烷基，C 1 -C 3烷氧基或C 1 -C 3卤代烷基，R是基团之一。R 5是未被取代或被卤素取代的C 2 -C 10烯基; 未被取代或被卤素取代的C 2 -C 10炔基; 或者是C3-C8环烷基或未取代或取代的苯基; 或者是C 2 -C 12烷基链，其可以被C 2 -C 12烷基取代或被氧或硫中断，并且未被取代或被选自卤素，苯基，-COO-C 1 -C 4烷基，-CO-C 1 -C 4烷基， CO-苯基，不饱和或饱和的含有氧或硫作为杂原子的5-或6-元环，每个苯基部分未被取代或被一个或多个相同或不同的卤素原子取代，是C 1 -C 10烷基，或是苯基或 苄基，每个未取代或取代的R4是未被取代或被卤素或C1-C4烷基取代的C1-C12烷基，或为苯基或苄基，各自未取代或取代或为-N（R9）（R10）基团，其中R9为 C1-C6烷基和R10是氢，C1-C4烷基，C1-C4卤代烷基亚磺酰基，-SC6H5或-SC（CH3）2CN，及其酸加成盐和金属配合物。

    Triazolylalkenes as fungicides and plant growth regulants
    79.
    发明授权
    Triazolylalkenes as fungicides and plant growth regulants 失效
    三唑基烯烃作为杀真菌剂和植物生长调节剂

    公开(公告)号：US4497647A

    公开(公告)日：1985-02-05

    申请号：US466825

    申请日：1983-02-16

    申请人： Alfred Meyer ,  Walter Kunz ,  Ludwig Maier ,  Hermann Rempfler

    发明人： Alfred Meyer ,  Walter Kunz ,  Ludwig Maier ,  Hermann Rempfler

    IPC分类号： A01N43/653 ,  A01N47/06 ,  A01N47/12 ,  C07D233/60 ,  C07D249/08 ,  C07D521/00 ,  C07F9/6518 ,  A01N43/50 ,  A01N43/64

    CPC分类号： C07D231/12 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08 ,  C07F9/65181

    摘要： The invention relates to novel azolyl-olefin derivatives of the general formula I ##STR1## wherein R.sub.1 is an azolyl group,R.sub.2 is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.4 alkyl substituted by unsubstituted or substituted phenyl, C.sub.1 -C.sub.4 alkoxycarbonyl or C.sub.2 -C.sub.6 alkenyl, or is C.sub.3 -C.sub.8 cycloalkyl which is substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl groups,R.sub.3 is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl which is substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl groups, or is the --C(R.sub.4)(R.sub.5)--[CH(R.sub.4)].sub.n --X--R.sub.6 group, wherein n is 0 or 1 andR.sub.4 and R.sub.5, each independently of the other, are hydrogen or C.sub.1 -C.sub.4 alkyl,X is oxygen or sulfur,R.sub.6 is a radical selected from the group consisting of C.sub.1 -C.sub.8 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, phenyl, naphthyl, biphenyl, benzylphenyl, benzoxyphenyl, phenoxyphenyl and aralkyl, which radical is substituted by one or more of halogen, cyano, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.5 alkoxy, C.sub.1 -C.sub.5 haloalkoxy, C.sub.1 -C.sub.3 alkylthio, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 haloalkylthio, nitro, --COOR.sub.7 or --CON(R.sub.8)(R.sub.9), whereinR.sub.7 is C.sub.1 -C.sub.4 alkyl andR.sub.8 and R.sub.9, each independently of the other, are hydrogen or C.sub.1 -C.sub.4 alkyl, and the acid addition salts quaternary azolium salts and metal complexes thereof.The invention also describes methods of preparing these compounds as well as agrochemical compositions which contain one of said compounds as active ingredient. The invention further describes a method of controlling phytopathogenic microorganisms and/or of regulating plant growth which comprises the use of the novel compounds.

    摘要翻译： 本发明涉及通式Ⅰ（I）的新的唑基 - 烯烃衍生物，其中R1是唑基，R2是C1-C12烷基，C3-C8环烷基，被未取代或取代的苯基取代的C1-C4烷基，C1-C4烷氧基羰基 或C 2 -C 6烯基，或者是被1至4个C 1 -C 4烷基取代的C 3 -C 8环烷基，R 3是C 1 -C 12烷基，被1至4个C 1 -C 4烷基取代的C 3 -C 8环烷基，或者是-C ）（R5） - [CH（R4）] nX-R6基团，其中n为0或1，R4和R5各自独立地为氢或C1-C4烷基，X为氧或硫，R6为自由基 选自C 1 -C 8烷基，C 3 -C 8环烷基，C 3 -C 6烯基，C 3 -C 6炔基，苯基，萘基，联苯基，苄基苯基，苯氧基苯基，苯氧基苯基和芳烷基，该基团被一个或多个卤素，氰基， C 1 -C 4烷基，C 1 -C 5烷氧基，C 1 -C 5卤代烷氧基，C 1 -C 3烷硫基，C 1 -C 3卤代烷基，C 1 -C 3卤代烷硫基，硝基，-COOR 7或-CON（R 8）（R 9） 9，各自独立地是氢或C 1 -C 4烷基，和酸加成盐季氮鎓盐及其金属络合物。 本发明还描述了制备这些化合物的方法以及含有所述化合物之一作为活性成分的农药组合物。 本发明还描述了一种控制植物病原微生物和/或调节植物生长的方法，其包括使用新化合物。

    Homoserine derivatives and their use as microbicides
    80.
    发明授权
    Homoserine derivatives and their use as microbicides 失效
    高丝氨酸衍生物及其作为杀微生物剂的用途

    公开(公告)号：US4442117A

    公开(公告)日：1984-04-10

    申请号：US199903

    申请日：1980-10-23

    申请人： Walter Kunz ,  Wolfgang Eckhardt ,  Adolf Hubele ,  Peter Riebli

    发明人： Walter Kunz ,  Wolfgang Eckhardt ,  Adolf Hubele ,  Peter Riebli

    IPC分类号： C07C231/12 ,  A01N37/46 ,  A01N41/04 ,  A01N43/08 ,  A01N43/50 ,  A01N43/56 ,  A01N43/653 ,  A01N47/12 ,  A01N47/16 ,  A01N47/20 ,  A01N53/00 ,  C07C233/54 ,  C07D307/24 ,  C07D521/00 ,  A01N37/22 ,  C07C103/66 ,  C07C103/737

    CPC分类号： C07D231/12 ,  A01N37/46 ,  A01N41/04 ,  A01N43/08 ,  A01N43/50 ,  A01N43/56 ,  A01N43/653 ,  A01N47/12 ,  A01N47/16 ,  A01N47/20 ,  A01N53/00 ,  C07D233/56 ,  C07D249/08 ,  C07D307/24

    摘要： There are described novel homoserine derivatives of the formula (I) ##STR1## which possess valuable microbicidal properties. In the formula: Ar is substituted phenyl or naphthyl; R.sub.1 is C.sub.2 -C.sub.6 alkyl optionally interrupted by oxygen or sulfur, 2-furyl, 2-tetrahydrofuryl, 1H-1,2,4-triazolylmethyl, 1-imidazolylmethyl, 1-pyrazolylmethyl, C.sub.2 -C.sub.4 alkenyl or cyclopropyl, each of which is optionally substituted by halogen; R.sub.2 is hydrogen or methyl; R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl; and B is halogen or an ester, thioester, sulfonic acid ester or sulfonic acid amide group. Additionally, where B is halogen, R.sub.1 may be halomethyl. The novel derivatives can be used for combating microorganisms harmful to plants, particularly for combating phytopathogenic fungi, and they have for practical requirements a very favorable curative and protective action for protecting cultivating plants, without the plants being impaired as a result of undesirable secondary effects. A notable feature is their stability to heat and to solar irradiation. They can be used in practice on their own or in the form of pesticidal compositions.

    摘要翻译： 描述了具有有价值的杀微生物性质的式（I）的新颖高丝氨酸衍生物。 式中Ar是取代的苯基或萘基; R1是任选被氧或硫中断的C 2 -C 6烷基，2-呋喃基，2-四氢呋喃基，1H-1,2,4-三唑基甲基，1-咪唑基甲基，1-吡唑基甲基，C 2 -C 4烯基或环丙基， 任选被卤素取代; R2是氢或甲基; R3是氢或C1-C4烷基; 和B是卤素或酯，硫酯，磺酸酯或磺酸酰胺基。 另外，当B是卤素时，R 1可以是卤代甲基。 新型衍生物可用于对抗对植物有害的微生物，特别是用于防治植物病原性真菌，并且它们具有非常有利的治疗和保护作用，用于保护栽培植物，而不会由于不期望的二次作用而损害植物。 它的一个显着特点是它们对热和太阳辐射的稳定性。 它们可以自己使用或以农药组合物的形式使用。