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公开(公告)号:US11111398B2
公开(公告)日:2021-09-07
申请号:US15403361
申请日:2017-01-11
Applicant: International Business Machines Corporation
Inventor: Brandon M. Kobilka , Joseph Kuczynski , Jacob T. Porter , Jason T. Wertz
Abstract: Methods and compositions related to subsurface modified silica materials are described. The silica materials include silicon- and carbon-containing groups covalently bonded to the silicon-oxygen matrix. The silica materials have tunable permeability, modulus, hardness, flexibility, and elongation. The silica materials are suitable for use as polymer fillers and as functional coatings.
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公开(公告)号:US11045927B2
公开(公告)日:2021-06-29
申请号:US15975988
申请日:2018-05-10
Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION
Inventor: Michael Kane , Colin E. Masterson , Suraush Khambati , Marie Cole , Jacob T. Porter
Abstract: Adjustable fastener tools are provided for engaging socket heads. The tool includes a support member, multiple engagement fingers, and an adjustment mechanism. The support member has multiple radially-extending tracks, and a central opening, and the fingers are associated with, and slidable along, the radially-extending tracks. The fingers include at radially inner ends jaws with respective contact surfaces for engaging the socket head. The adjustment mechanism resides, at least in part, within the central opening in the support member, and couples to the fingers. The adjustment mechanism includes an actuating member and multiple hinged trusses. A hinged truss of the trusses is hingedly coupled at one end to the actuating member and hingedly coupled at an other end to a respective finger of the engagement fingers. Movement of the actuating member results, via the hinged truss, in slidable movement of the respective finger along its associated radially-extending track.
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公开(公告)号:US10689580B2
公开(公告)日:2020-06-23
申请号:US16371689
申请日:2019-04-01
Applicant: International Business Machines Corporation
Inventor: Brandon M. Kobilka , Joseph Kuczynski , Jacob T. Porter , Jason T. Wertz
IPC: C09K21/12 , C08K5/5337 , C08K5/5313 , C08K5/5317 , C07D317/12 , C09K21/14 , C07F9/655 , C07F9/12 , C07F9/14 , C07F9/40 , C07C15/04
Abstract: A flame-retardant vanillin-derived monomer, a process for forming a flame-retardant polymer, and an article of manufacture comprising a material that contains flame-retardant vanillin-derived monomer are disclosed. The flame-retardant vanillin-derived monomer can be synthesized from vanillin obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety with phenyl, allyl, epoxide, or propylene carbonate substituents. The process for forming the flame-retardant polymer can include reacting a vanillin derivative and a flame-retardant phosphorus-based molecule to form the flame-retardant vanillin-derived monomer, and then polymerizing the flame-retardant vanillin-derived monomer. The material in the article of manufacture can be flame-retardant, and contain the flame-retardant vanillin-derived monomer. Examples of materials that can be in the article of manufacture can include resins, plastics, adhesives, polymers, etc.
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公开(公告)号:US10689577B2
公开(公告)日:2020-06-23
申请号:US16212954
申请日:2018-12-07
Applicant: International Business Machines Corporation
Inventor: Brandon M. Kobilka , Joseph Kuczynski , Jacob T. Porter , Jason T. Wertz
IPC: C09K21/12 , C08K5/5313 , C08K5/5317 , C08K5/5337 , C07F9/655 , C07F9/12 , C07F9/14 , C07F9/145 , C07F9/40 , C07F9/42 , C09K21/14 , C07F9/08
Abstract: A flame-retardant vanillin-derived molecule, a process for forming a flame-retardant resin, and an article of manufacture comprising a material that contains the flame-retardant vanillin-derived molecule are disclosed. The flame-retardant vanillin-derived molecule can be synthesized from vanillin obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety with phenyl, allyl, epoxide, propylene carbonate, or thioether substituents. The process for forming the flame-retardant resin can include reacting a vanillin derivative and a flame-retardant phosphorus-based molecule to form the flame-retardant vanillin-derived molecule, and binding the flame-retardant vanillin-derived molecule to a resin. The flame-retardant vanillin-derived molecules can also be bound to polymers. The material in the article of manufacture can be flame-retardant, and contain the flame-retardant vanillin-derived molecules. Examples of materials that can be in the article of manufacture can include resins, plastics, adhesives, polymers, etc.
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公开(公告)号:US20200165381A1
公开(公告)日:2020-05-28
申请号:US16775874
申请日:2020-01-29
Applicant: International Business Machines Corporation
Inventor: Brandon M. Kobilka , Joseph Kuczynski , Jacob T. Porter , Jason T. Wertz
IPC: C08G63/688 , C09J167/02 , C09D167/02 , C08G63/85 , C09J171/00 , C09D171/00 , C08L63/00 , C08L71/00 , C09J163/00 , C09D163/00 , C08G59/62 , C08L67/02 , C08G59/26 , C08G65/26 , C08G63/08 , C09D167/04 , C08G65/324 , C08G59/30
Abstract: An article of manufacture. The article of manufacture includes a ring-opened lactide copolymer. The ring-opened lactide copolymer is formed in a process that includes reacting a functionalized lactide monomer with a BPA-derived monomer. The reaction forms a lactide copolymer, which is reacted to form the ring-opened lactide copolymer.
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公开(公告)号:US20200048417A1
公开(公告)日:2020-02-13
申请号:US16100325
申请日:2018-08-10
Applicant: International Business Machines Corporation
Inventor: Jason T. Wertz , Brandon M. Kobilka , Joseph Kuczynski , Jacob T. Porter
IPC: C08G79/025 , C08G73/06 , C08G85/00 , C08L85/02 , C08J3/24
Abstract: An elastomer, a process for forming an elastomer, and an article of manufacture are disclosed. The elastomer comprises a phosphazene backbone and at least one polyhexahydrotriazine component. The process for forming the elastomer includes obtaining an amine-terminated cyclotriphosphazene, reacting it with a diamine to form a phosphazene-containing PHT polymer, and then reacting the phosphazene-containing PHT polymer with a side-chain modified cyclic phosphazene to form a PCPHT elastomer with halogen ligands. The PCPHT elastomer with halogen ligands is then reacted with an alkoxide to form a PCPHT elastomer with at least one ether-linked side chain. The article of manufacture comprises a material comprising an elastomer having a phosphazene backbone and at least one PHT component.
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公开(公告)号:US10544285B2
公开(公告)日:2020-01-28
申请号:US15782545
申请日:2017-10-12
Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION
Inventor: Brandon M. Kobilka , Joseph Kuczynski , Jacob T. Porter , Jason T. Wertz
IPC: C08F212/08 , C08F236/06 , C08F230/02 , C08F212/14 , C08F220/56 , C08F8/40 , C08K5/5399 , C08K5/00 , C07F9/6581
Abstract: An impact-modified composition and a method of making an impact-modified composition are provided. In an embodiment, the method includes reacting a phosphazene material with an acrylamide material to form a functionalized phosphazene material; initiating a polymerization reaction on a reaction mixture comprising the functionalized phosphazene material and one or more monomers to form an impact-modified phosphazene material; and adding the an impact-modified phosphazene material to a polymeric material.
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公开(公告)号:US10544264B2
公开(公告)日:2020-01-28
申请号:US15673513
申请日:2017-08-10
Applicant: International Business Machines Corporation
Inventor: Brandon M. Kobilka , Joseph Kuczynski , Jacob T. Porter , Jason T. Wertz
IPC: C08G73/06 , C09K21/14 , C08F12/28 , C08G12/08 , C08F212/14 , C08F236/06
Abstract: An impact resistant polyhexahydrotriazine polymer, a process for forming an impact resistant polyhexahydrotriazine polymer, and an article of manufacture comprising an impact resistant material containing an impact resistant polyhexahydrotriazine polymer are disclosed. The impact resistant polyhexahydrotriazine polymer includes at least one hexahydrotriazine group and at least one chain comprising an allylic portion and a styrenic portion. Variations in the chain control properties of the impact resistant polymer. The process of forming the impact resistant polyhexahydrotriazine polymer includes reactions between formaldehyde and at least two classes of monomer that form hexahydrotriazine groups and impact resistant chains. Adjusting relative monomer concentrations controls properties of the impact resistant polyhexahydrotriazine polymer. The article of manufacture contains a material that has an impact resistant polymer. Impact resistance of the impact resistant polyhexahydrotriazine polymer is dependent upon variation in relative amounts of monomers used in its synthesis.
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公开(公告)号:US10525671B2
公开(公告)日:2020-01-07
申请号:US15345196
申请日:2016-11-07
Applicant: International Business Machines Corporation
Inventor: Brandon M. Kobilka , Joseph Kuczynski , Jacob T. Porter , Jason T. Wertz
Abstract: A process of providing a coating having a hydrophobic, electrically conductive porous metallic surface on a substrate includes forming a metal-infused plastic lattice that includes a plastic lattice infused with metal particles, and then removing the plastic lattice from the metal-infused plastic lattice. A surface of at least some of the metal particles is textured to increase hydrophobicity by exposing the surface to laser light. In some embodiments, the metal particles are exposed to laser light from a femtosecond pulse laser to produce hydrophobic metal particles before the metal-infused plastic lattice is formed. In other embodiments, the surface of at least some of the metal particles is exposed to laser light from a femtosecond pulse laser after the metal-infused plastic lattice is formed.
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公开(公告)号:US10453584B2
公开(公告)日:2019-10-22
申请号:US15335859
申请日:2016-10-27
Applicant: International Business Machines Corporation
Inventor: Brandon M. Kobilka , Joseph Kuczynski , Jacob T. Porter , Jason T. Wertz
Abstract: A process of forming a hydrophobic, conductive barrier on a metallic surface includes coating the metallic surface with an organic, conductive material. The organic, conductive material includes a conductive group having two or more alkyne groups and a terminal thio group to bind the organic, conductive material to the metallic surface.
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