摘要:
The invention relates to cationic fluorescent whitening agents of the formula ##STR1## wherein A is the radical of a fluorescent whitening agent, Q is the direct bond or a bridge member, R.sub.1 to R.sub.5 are specific substituents and n is 1 or 2. A process for the manufacture of these compounds and a method of whitening organic material which comprises their use are also disclosed.
摘要:
Stilbene compounds of the formula ##STR1## in which the rings A, B and C can carry non-chromophoric substituents, R.sub.1 is hydrogen, alkyl which is unsubstituted or substituted by non-chromophoric substituents, or aryl which is unsubstituted or substituted by non-chromophoric substituents, and R.sub.2 is a carboxyl group or a functional derivative thereof, a cyano group, a sulphonic acid ester group, a sulphonamide group or a sulphonyl group, and the use thereof as fluorescent brightening agents for high-molecular organic material.
摘要:
Novel 1,4-bis-styryl-phenyl and 4,4'-bis-styryl-biphenyl derivatives, a process for their preparation, a process for optically brightening organic materials on using said compounds as well as detergent compositions containing said compounds are disclosed.
摘要:
A novel process for the production of compounds of the formula ##STR1## wherein A and A.sub.1, independently of one another, denote phenyl, naphthyl, diphenylyl, 2-phenyl-1,2,3-triazol-4-yl or pyridyl, it being possible for A and A.sub.1 to contain non-chromophoric substituents, and D denotes 4,4'-diphenylylene,1,5- or 2,6-naphthylene, or a 9,10-dihydrophenanthrene or dibenzofurane radical which is bonded to the vinylene groups in the 2,7-position, which comprises reacting in a first stage a compound of the formulaX-CH.sub.2 -D-CH.sub.2 -X (II)wherein X denotes halogen, especially chlorine or bromine, hydroxyl or a group ##STR2## wherein X.sub.1 represents an aliphatic cycloaliphatic or aromatic hydrocarbon radical, especially alkyl having 1 to 6 carbon atoms, or phenyl, and D has the indicated meaning, in a strongly acid medium, in a molar ratio of at least 1:2, with an organic sulphide containing 5 to 8 ring members, of the formula ##STR3## wherein B represents a polymethylene group of 4 to 7 methylene groups and wherein one of these methylene groups can be replaced by a hetero-atom and wherein these methylene groups can also contain alkyl groups with 1 to 4 carbon atoms as substituents, to give a sulphonium salt of the formula ##STR4## wherein M represents the anion of the strong acid used and n denotes the numbers 1 or 2; reacting, in a second stage, the resulting sulphonium salt with 2 mols of an aldehyde of the formula(V) A-CHOor (VI) A.sub.1 -CHOor their mixture, in the presence of strong bases, in a strongly polar, protic or aprotic, water-miscible solvent to give a diepoxide of the formula ##STR5## and subjecting in a 3rd stage, the diepoxide of the formula (VII), thus obtained, to a reduction according to processes which are in themselves known for the reduction of epoxides, with elimination of the epoxide oxygen and formation of vinylene groups.
摘要:
New diarylvinyl-dihydrophenanthrene compounds of the formula ##STR1## wherein R.sub.1, R.sub.1 ', R.sub.2, R.sub.2 ', R.sub.3 and R.sub.3 ' are identical or different and represent hydrogen, alkyl with 1 to 12 carbon atoms, aralkyl with 1 to 4 carbon atoms in the alkyl part, alkoxy with 1 to 18 carbon atoms, phenyl-alkoxy with 1 to 4 carbon atoms in the alkoxy part, alkenyloxy with 3 to 4 carbon atoms, halogen, nitrile, a sulphonic acid group or its salts or functional derivatives, a carboxyalkoxy or carboxyl group or their salts or functional derivatives, or a sulphone group. These compounds are particularly useful as optical brighteners.
摘要:
The wheels of the cart are arranged so that a front wheel and a rear wheel can be interconnected with each other and driven off a steering gear. Upon pivoting of the steering gear during turning of the cart, these front and rear wheels pivot in opposite directions so that the rear wheel follows in the wake of the front wheel. When disconnected from the steering gear, the front and rear wheels, as the remaining wheels, are freely rotatable.
摘要:
The invention provides a new process for the manufacture of aromatic compounds which at least once contain a benzene ring of an aromatic carbocyclic ring system bonded by an ethylene double bond in conjugation with a further aromatic ring system, i.e. contain the stilbene skeleton or stilbene analogon as central structural element, as well as certain classes of new compounds of this type. The process is characterized by the reaction of a Schiff base of an aromatic aldehyde with an aromatic carbocyclic six-membered ring compound which contains one to four methyl groups bonded to ring carbon atoms of a benzene ring, which furthermore contains aromatic rings which are exclusively six-membered carbocyclic rings, and wherein those benzene rings whose methyl groups are to be caused to react are free of other substituents which contain atoms which are replaceable by alkali metal. The reaction is carried out in the presence of (a) a strongly basic alkali compound and (b) an N-dialkyl-acylamide as solvent. The compounds obtainable according to this process show a marked fluorescence emission and therefore are suitable for all purposes where fluorescence properties are used, as for instance optical brighteners, scintillators fluorescence dyes, etc.
摘要:
The invention concerns new asymetrical distyrylbenzenes and a process for their preparation, these compounds having the formula ##SPC1##Wherein R.sub.1 and R.sub.2 can be identical or different from one another and denote hydrogen, chlorine or fluorine, lower alkyl or lower alkoxy groups, R.sub.a represents hydrogen, the nitrile group or a carboxyl group, its salts, esters or amides, M denotes a hydrogen, alkali, alkaline earth, ammonium or amine salt ion, m denotes the numbers 1 or 2 and n denotes the numbers 1, 2 or 3, with the proviso that I. at least one of the substituents R.sub.1, R.sub.2 and R.sub.a is different from hydrogen and II. in the case where R.sub.a is different from hydrogen, R.sub.2 represents hydrogen.The new compounds are valuable optical brightening agents, especially in combination with detergents.
摘要翻译:本发明涉及新的不对称二苯乙烯苯及其制备方法,这些具有式WHEREIN R 1和R 2的化合物可以相同或不同,表示氢,氯或氟,低级烷基或低级烷氧基,Ra表示氢, 腈基或羧基,其盐,酯或酰胺,M表示氢,碱,碱土金属,铵或胺盐离子,m表示数字1或2,n表示数字1,2或3,其中 条件是I.至少一个取代基R1,R2和Ra不同于氢和II。 在Ra与氢不同的情况下,R 2表示氢。