Polymer electrolyte membranes crosslinked by nitrile trimerization
    72.
    发明申请
    Polymer electrolyte membranes crosslinked by nitrile trimerization 失效
    通过腈三聚交联的聚合物电解质膜

    公开(公告)号:US20050107489A1

    公开(公告)日:2005-05-19

    申请号:US10712589

    申请日:2003-11-13

    IPC分类号: C08J5/22 C08G2/00

    CPC分类号: C08J5/225 C08J2327/12

    摘要: A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, by trimerization of nitrile groups contained on groups pendant from the polymer. The resulting polymer electrolyte membrane comprises a highly fluorinated polymer comprising: a perfluorinated backbone, first pendent groups which comprise sulfonic acid groups, and crosslinks comprising trivalent groups according to the formula: The first pendent groups are typically according to the formula: —R1—SO3H, where R1 is a branched or unbranched perfluoroalkyl or perfluoroether group comprising 1-15 carbon atoms and 0-4 oxygen atoms, most typically —O—CF2—CF2—CF2—CF2—SO3H or —O—CF2—CF(CF3)—O—CF2—CF2—SO3H.

    摘要翻译: 提供了一种制备交联聚合物电解质的方法,通常是通过聚合物悬浮在基团上的腈基的三聚作用,在电解池如燃料电池中用作聚合物电解质膜的膜形式。 所得聚合物电解质膜包括高度氟化的聚合物,其包含:全氟化骨架,包含磺酸基团的第一侧基和包含根据下式的三价基团的交联:第一侧基通常根据下式:-R

    Process for modifying a polymeric surface
    75.
    发明授权
    Process for modifying a polymeric surface 失效
    改性聚合物表面的方法

    公开(公告)号:US06752894B2

    公开(公告)日:2004-06-22

    申请号:US10022761

    申请日:2001-12-14

    IPC分类号: C08J704

    摘要: This invention concerns a process for modifying a polymeric substrate by contacting the surface with a photoreactive solution of an inorganic photochemical electron donor while irradiating the surface with actinic radiation. Patterns of modified and unmodified surfaces can be produced. Polymeric substrates with modified surfaces may be effectively bonded to polymer films to form composite articles. The process has particular applicability to the surface modification of fluorinated polymers.

    摘要翻译: 本发明涉及一种通过使表面与无机光化学电子给体的光反应溶液接触,同时用光化辐射照射表面来改性聚合物基材的方法。 可以生产修饰和未改性表面的图案。 具有改性表面的聚合物基材可以有效地结合到聚合物膜上以形成复合制品。 该方法特别适用于氟化聚合物的表面改性。

    Optical elements comprising a fluoropolymer surface treatment
    76.
    发明授权
    Optical elements comprising a fluoropolymer surface treatment 有权
    含有氟聚合物表面处理的光学元件

    公开(公告)号:US06734227B2

    公开(公告)日:2004-05-11

    申请号:US09961669

    申请日:2001-09-24

    IPC分类号: C08K904

    摘要: The present invention relates to optical elements comprising fluorochemical surface treatments. The invention further relates to articles such as retroreflective sheetings, pavement markings and beaded projection screens comprising a binder and the surface treated optical elements. The surface treatment comprises at least one fluoropolymer selected from a) fluoropolymers comprising a fluorinated hydrocarbon backbone and side chains comprising at least one of fluoroalkyl, fluoroether alkyl, fluoroalkoxy and mixtures thereof; and b) fluoropolymers comprising a hydrocarbon backbone and side chains comprising at least one of fluoroether alkyl, fluoroalkoxy and mixtures thereof.

    摘要翻译: 本发明涉及包含含氟表面处理的光学元件。 本发明还涉及诸如逆反射片材,路面标记和包括粘合剂和经表面处理的光学元件的串珠投影屏幕的制品。 表面处理包括至少一种含氟聚合物,其选自:a)包含氟化烃主链的含氟聚合物和包含氟代烷基,氟醚烷基,氟代烷氧基及其混合物中的至少一种的侧链; 和b)包含烃骨架和包含氟醚烷基,氟代烷氧基及其混合物中的至少一种的侧链的含氟聚合物。

    Multi-layer compositions comprising a fluoropolymer
    77.
    发明授权
    Multi-layer compositions comprising a fluoropolymer 失效
    包含含氟聚合物的多层组合物

    公开(公告)号:US06649005B1

    公开(公告)日:2003-11-18

    申请号:US09676196

    申请日:2000-09-28

    IPC分类号: C09J502

    摘要: This invention provides a method of bonding substantially non-fluorinated polymeric material to dissimilar polymers, particularly fluoropolymer materials, utilizing a bonding composition comprising base-treated amine group-containing substantially non-fluorinated polymer. Multi-layer articles and composite constructions, including retroreflective sheeting, fuel line hoses, and adhesive articles made of a fluoropolymer layer and a substantially non-fluorinated layer are also provided.

    摘要翻译: 本发明提供了使用包含碱处理的含胺基的基本上非氟化聚合物的粘合组合物将基本上非氟化聚合物材料粘合到不同聚合物,特别是含氟聚合物材料的方法。 还提供了由氟聚合物层和基本上非氟化层制成的多层制品和复合结构,包括回射片材,燃料管线和粘合剂制品。

    Non-film-forming electrophoretic latexes in fluorocarbon solvents
    80.
    发明授权
    Non-film-forming electrophoretic latexes in fluorocarbon solvents 有权
    在氟碳溶剂中的非成膜电泳胶乳

    公开(公告)号:US06384124B1

    公开(公告)日:2002-05-07

    申请号:US09604894

    申请日:2000-06-28

    IPC分类号: C08K502

    摘要: The present invention provides a non-film-forming latex of dispersed particles which may be used in an electrophoretic display, comprising: a) a highly fluorinated liquid solvent, and b) dispersed particles comprising a polymer comprising units according to formula I: wherein each (fcp) is independently selected from highly fluorinated polymer chains and each Q is independently selected from —H and straight or branched non-fluorinated polymer chains (hcp). Latexes of dispersed particles having a very small particle size are especially provided.

    摘要翻译: 本发明提供了可用于电泳显示器中的分散颗粒的非成膜胶乳,其包含:a)高度氟化的液体溶剂,以及b)包含包含根据式I的单元的聚合物的分散颗粒:其中每个 (fcp)独立地选自高度氟化的聚合物链,并且每个Q独立地选自-H和直链或支链非氟化聚合物链(hcp)。 特别提供了具有非常小粒径的分散颗粒的乳胶。