公开(公告)号：US08062830B2

公开(公告)日：2011-11-22

申请号：US12425759

申请日：2009-04-17

申请人： Yusuke Fuji ,  Junji Shigematsu ,  Takayuki Miyagawa ,  Nobuo Ando ,  Ichiki Takemoto

发明人： Yusuke Fuji ,  Junji Shigematsu ,  Takayuki Miyagawa ,  Nobuo Ando ,  Ichiki Takemoto

IPC分类号： G03F7/004

CPC分类号： G03F7/0397 ,  G03F7/0045 ,  G03F7/0046 ,  G03F7/0395 ,  G03F7/2041 ,  Y10S430/108 ,  Y10S430/111

摘要： The present invention provides a chemically amplified resist composition comprising: a resin (A) which contains no fluorine atom and a structural unit (a1) having an acid-labile group in a side chain, a resin (B) which contains a structural unit (b2) having a fluorine-containing group in a side chain and at least one structural unit selected from the group consisting of a structural unit (b1) having an acid-labile group, a structural unit (b3) having a hydroxyl group and a structural unit (b4) having a lactone structure in a side chain, and an acid generator, wherein the content of the structural unit (b1) based on the total units of the resin (B) is less than 10 mol %.

摘要翻译： 本发明提供了一种化学放大抗蚀剂组合物，其包含：不含氟原子的树脂（A）和侧链具有酸不稳定基团的结构单元（a1），含有结构单元的树脂（B） b2）和具有酸不稳定基团的结构单元（b1），具有羟基的结构单元（b3）和结构单元（b3）的至少一种结构单元，在侧链中具有含氟基团， 在侧链中具有内酯结构的单元（b4）和酸产生剂，其中基于树脂（B）的总单元的结构单元（b1）的含量小于10摩尔％。

公开(公告)号：US07932334B2

公开(公告)日：2011-04-26

申请号：US11642628

申请日：2006-12-21

申请人： Nobuo Ando ,  Ichiki Takemoto ,  Isao Yoshida ,  Yukako Harada

发明人： Nobuo Ando ,  Ichiki Takemoto ,  Isao Yoshida ,  Yukako Harada

IPC分类号： C08F12/30

CPC分类号： C08F220/38 ,  C08F220/18 ,  C08F220/28 ,  C08J3/075

摘要： The present invention provides a resin which generates an acid by irradiation and is a salt of an organic cation and an anionic polymer wherein the anionic polymer has no carbon-carbon unsaturated bond. The present invention further provides a chemically amplified resist composition comprising the same.

摘要翻译： 本发明提供一种通过照射产生酸的树脂，并且是阴离子聚合物不具有碳 - 碳不饱和键的有机阳离子和阴离子聚合物的盐。 本发明还提供一种包含其的化学放大抗蚀剂组合物。

公开(公告)号：US20100330431A1

公开(公告)日：2010-12-30

申请号：US12873934

申请日：2010-09-01

申请人： Ryuji Shiozaki ,  Nobuo Ando ,  Satoko Kaneko ,  Masahiko Taniguchi

发明人： Ryuji Shiozaki ,  Nobuo Ando ,  Satoko Kaneko ,  Masahiko Taniguchi

IPC分类号： H01M4/48 ,  H01M4/02 ,  H01M4/583 ,  H01G9/04

CPC分类号： H01M4/131 ,  H01G11/46 ,  H01G11/50 ,  H01G11/86 ,  H01M4/133 ,  H01M4/1391 ,  H01M4/1393 ,  H01M10/0525 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022 ,  Y10T29/49108

摘要： An electrode laminate unit 12 of an electric storage device 10 is composed of positive electrodes 14 and negative electrodes 15, which are alternately laminated, and a lithium electrode 16 is arranged at the outermost part of the electrode laminate unit 12 so as to oppose to the negative electrode 15. A charging/discharging unit 21 having first and second energization control units 21a and 21b is connected to a positive-electrode terminal 18, negative-electrode terminal 19, and a lithium-electrode terminal 20. Electrons are moved from the lithium electrode 16 to the positive electrode 14 through the first energization control unit 21a, and lithium ions are doped into the positive electrode 14 from the lithium electrode 16. Electrons are moved from the lithium electrode 16 to the negative electrode 15 through the second energization control unit 21b, and lithium ions are doped into the negative electrode 15 from the lithium electrode 16. The lithium ions are doped into both of the positive electrode 14 and the negative electrode 15 as described above, whereby the doping time can dramatically be shortened.

摘要翻译： 蓄电装置10的电极层叠单元12由交替层叠的正极14和负极15构成，锂电极16配置在电极层叠单元12的最外侧，以与电极层叠单元12相对。 负极15.具有第一和第二通电控制单元21a和21b的充电/放电单元21连接到正极端子18，负极端子19和锂电极端子20.电子从锂 电极16通过第一通电控制单元21a连接到正极14，并且锂离子从锂电极16掺杂到正极14中。电子通过第二通电控制单元从锂电极16移动到负极15 21b，并且锂离子从锂电极16掺杂到负极15中。锂离子掺杂到两者中 如上所述，由此可以显着地缩短掺杂时间。

公开(公告)号：US07848081B2

公开(公告)日：2010-12-07

申请号：US11874338

申请日：2007-10-18

申请人： Hiroaki Tanizaki ,  Nobuo Ando ,  Yukinori Hatou

发明人： Hiroaki Tanizaki ,  Nobuo Ando ,  Yukinori Hatou

IPC分类号： H01G9/02

CPC分类号： H01G11/32 ,  H01G11/06 ,  H01G11/24 ,  H01G11/50 ,  Y02E60/13 ,  Y02T10/7022

摘要： The invention provides a negative electrode material for use with a lithium-ion capacitor, which is high in energy density, output density and excellent in durability. When graphite of which an average distance between 002 lattice planes thereof is within a range from 0.335 nm to 0.337 nm is used for an active material of a negative electrode of a lithium-ion capacitor, the energy density of the capacitor is increased. The output characteristic and the cycle durability can be improved when D10, D50 and D90 are set within predetermined ranges.

摘要翻译： 本发明提供一种与锂离子电容器一起使用的负极材料，其能量密度高，输出密度高，耐久性优异。 对于锂离子电容器的负极的活性物质，当其002个晶面之间的平均距离在0.335nm〜0.337nm的范围内的石墨被使用时，电容器的能量密度增加。 当D10，D50和D90设定在预定范围内时，可以提高输出特性和循环耐久性。

公开(公告)号：US07846219B2

公开(公告)日：2010-12-07

申请号：US12127989

申请日：2008-05-28

申请人： Ryuji Shiozaki ,  Nobuo Ando ,  Satoko Kaneko ,  Masahiko Taniguchi

发明人： Ryuji Shiozaki ,  Nobuo Ando ,  Satoko Kaneko ,  Masahiko Taniguchi

IPC分类号： H01M10/38 ,  H01M10/44 ,  H01M4/04

CPC分类号： H01M4/131 ,  H01G11/46 ,  H01G11/50 ,  H01G11/86 ,  H01M4/133 ,  H01M4/1391 ,  H01M4/1393 ,  H01M10/0525 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022 ,  Y10T29/49108

摘要： An electrode laminate unit of an electric storage device is composed of positive electrodes and negative electrodes, which are alternately laminated, and a lithium electrode arranged at the outermost part of the electrode laminate unit so as to oppose the negative electrode. A charging/discharging unit having first and second energization control units connected to a positive-electrode terminal, negative-electrode terminal, and a lithium-electrode terminal. Electrons are moved from the lithium electrode to the positive electrode through the first energization control unit, and lithium ions are doped into the positive electrode from the lithium electrode. Electrons are moved from the lithium electrode to the negative electrode through the second energization control unit, and lithium ions are doped into the negative electrode from the lithium electrode. The lithium ions are doped into both of the positive and negative electrodes, whereby the doping time can be dramatically shortened.

摘要翻译： 蓄电装置的电极层叠单元由交替层叠的正极和负极以及布置在电极层叠单元的最外部的锂电极与负极相对。 具有连接到正极端子，负极端子和锂电极端子的第一和第二通电控制单元的充电/放电单元。 电子通过第一通电控制单元从锂电极移动到正电极，并且从锂电极将锂离子掺杂到正极中。 电子通过第二通电控制单元从锂电极移动到负极，并且锂离子从锂电极掺杂到负极中。 锂离子被掺杂到正电极和负电极中，由此可以显着缩短掺杂时间。

公开(公告)号：US20100035150A1

公开(公告)日：2010-02-11

申请号：US12506390

申请日：2009-07-21

申请人： Nobuo Ando ,  Mitsuru Nagai ,  Takashi Utsunomiya ,  Ken Baba

发明人： Nobuo Ando ,  Mitsuru Nagai ,  Takashi Utsunomiya ,  Ken Baba

IPC分类号： H01M4/64

CPC分类号： H01M10/0525 ,  H01G9/016 ,  H01G9/058 ,  H01G9/155 ,  H01G11/50 ,  H01G11/70 ,  H01M4/70 ,  H01M4/742 ,  H01M10/0413 ,  H01M10/0585 ,  Y02E60/122 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

摘要： An electrode laminate unit of an electric storage device includes positive electrodes, negative electrodes and a lithium electrode connected to the negative electrode. When an electrolyte solution is injected into the electric storage device, lithium ions are emitted from the lithium electrode to the negative electrode. A positive and a negative electrode current collector have through-holes that guide the lithium ions in the laminating direction. The aperture ratio of the through-holes at the edge parts where the electrolyte solution is easy to be permeated is set to be smaller than the aperture ratio at central parts in order to suppress the permeation. Thus, the distribution of the electrolyte solution is made uniform, whereby the doping amount is made uniform.

摘要翻译： 蓄电装置的电极层叠单元包括正极，负极和与负极连接的锂电极。 当电解液注入蓄电装置时，锂离子从锂电极发射到负极。 正极集电体和负极集电体具有在层叠方向上引导锂离子的通孔。 为了抑制渗透，将电解质溶液容易渗透的边缘部分的通孔的孔径比设定为小于中心部分的开口率。 因此，使电解质溶液的分布均匀，从而使掺杂量均匀。

公开(公告)号：US20090269695A1

公开(公告)日：2009-10-29

申请号：US12425942

申请日：2009-04-17

申请人： Yusuke Fuji ,  Junji Shigematsu ,  Takayuki Miyagawa ,  Nobuo Ando ,  Ichiki Takemoto

发明人： Yusuke Fuji ,  Junji Shigematsu ,  Takayuki Miyagawa ,  Nobuo Ando ,  Ichiki Takemoto

IPC分类号： G03F7/004

CPC分类号： G03F7/0397 ,  G03F7/0045 ,  G03F7/0046 ,  G03F7/0395 ,  G03F7/2041 ,  Y10S430/108 ,  Y10S430/111

摘要： The present invention provides a chemically amplified resist composition comprising: a resin (A) which contains no fluorine atom and a structural unit (a1) having an acid-labile group in a side chain, a resin (B) which contains a structural unit (b2) having a fluorine-containing group in a side chain and at least one structural unit selected from the group consisting of a structural unit (b1) having an acid-labile group, a structural unit (b3) having a hydroxyl group and a structural unit (b4) having a lactone structure in a side chain, and an acid generator, wherein the amount of the resin (B) is 2 parts by weight or less per 100 parts by weight of the resin (A).

摘要翻译： 本发明提供了一种化学放大抗蚀剂组合物，其包含：不含氟原子的树脂（A）和侧链具有酸不稳定基团的结构单元（a1），含有结构单元的树脂（B） b2）和具有酸不稳定基团的结构单元（b1），具有羟基的结构单元（b3）和结构单元（b3）的至少一种结构单元，在侧链中具有含氟基团， 在侧链中具有内酯结构的单元（b4）和酸产生剂，其中树脂（B）的量相对于树脂（A）每100重量份为2重量份以下。

公开(公告)号：US20090246633A1

公开(公告)日：2009-10-01

申请号：US12410631

申请日：2009-03-25

申请人： Ryuji Shiozaki ,  Satoko Kaneko ,  Nobuo Ando

发明人： Ryuji Shiozaki ,  Satoko Kaneko ,  Nobuo Ando

IPC分类号： H01M4/58 ,  H01M4/88

CPC分类号： H01M4/131 ,  H01M4/485 ,  H01M10/0525

摘要： When a layered crystal material of vanadium pentoxide that can be used as a positive electrode active material is manufactured, a sulfur-containing organic material is not used as a raw material in the present invention. Therefore, uncertain adhesion of the sulfur-containing organic material to the layered crystal material is eliminated. The property of the suspension containing a vanadium compound and plural lithium compounds such as lithium sulfide and lithium hydroxide is adjusted by using these lithium compounds. By this adjustment, the pentavalence of the vanadium ions is controlled to be a desired ratio. Consequently, an active material having reproducibility can be manufactured. First discharge energy of a lithium ion secondary battery using the active material can be enhanced.

摘要翻译： 当制造可用作正极活性物质的五氧化二钒的层状结晶材料时，在本发明中不使用含硫有机材料作为原料。 因此，消除了含硫有机材料对层状结晶材料的粘附性的不确定性。 通过使用这些锂化合物调节含有钒化合物的悬浮液的性质和多种锂化合物如硫化锂和氢氧化锂。 通过这种调整，钒离子的五价态被控制为期望的比例。 因此，可以制造具有再现性的活性材料。 可以提高使用活性物质的锂离子二次电池的第一放电能量。

公开(公告)号：US20090246629A1

公开(公告)日：2009-10-01

申请号：US12410609

申请日：2009-03-25

申请人： Mitsuru Nagai ,  Nobuo Ando ,  Takashi Utsunomiya ,  Yutaka Sato ,  Ken Baba

发明人： Mitsuru Nagai ,  Nobuo Ando ,  Takashi Utsunomiya ,  Yutaka Sato ,  Ken Baba

IPC分类号： H01M4/00 ,  C23F1/00 ,  H01G9/04 ,  B32B3/10

CPC分类号： H01M4/0404 ,  H01M4/0459 ,  H01M4/139 ,  H01M4/70 ,  H01M4/742 ,  H01M10/052 ,  Y10T29/49108 ,  Y10T29/53135 ,  Y10T428/24331

摘要： In a current collector laminating step, a current-collector laminate unit 30 composed of current-collector materials 31 and 32 and a film material 33 is formed. Resist layers 34 having a predetermined pattern are formed on both surfaces of the current-collector laminate unit 30. An etching process is performed with the resist layers 34 used as a mask, whereby through-holes 20a and 23a are formed on the respective current-collector materials 31 and 32. The resist layers 34 are removed from the current-collector laminate unit 30. Since the etching process is performed on the plural current-collector materials 31 and 32, productivity of an electrode can be enhanced. During the application of the slurry, the film material 33 prevents the leakage of the electrode slurry. Therefore, the current-collector laminate unit 30 can be conveyed in the horizontal direction, whereby the productivity of the electrode can be enhanced.

摘要翻译： 在集电体层叠工序中，形成集电体31,32构成的集电体层叠体30和膜材33。 在集电体层叠单元30的两个表面上形成具有预定图案的抗蚀剂层34.以抗蚀剂层34作为掩模进行蚀刻处理，由此在各自的电流 - 层叠单元30上形成通孔20a和23a。 集电体材料31和32.从集电体层压单元30去除抗蚀剂层34.由于在多个集电体材料31和32上执行蚀刻处理，可以提高电极的生产率。 在施加浆料期间，膜材料33防止电极浆料的泄漏。 因此，集电体层叠单元30能够在水平方向上输送，能够提高电极的生产率。

公开(公告)号：US20090246624A1

公开(公告)日：2009-10-01

申请号：US12407077

申请日：2009-03-19

申请人： Kenji Kojima ,  Nobuo Ando

发明人： Kenji Kojima ,  Nobuo Ando

IPC分类号： H01M10/26 ,  H01G9/042

CPC分类号： H01M10/0525 ,  H01G11/24 ,  H01G11/32 ,  H01M4/587 ,  H01M2004/021 ,  Y02E60/13

摘要： Mesoporous graphite is used as an active material of a negative electrode constituting a lithium ion secondary battery or a lithium ion capacitor. Specifically, the mesoporous graphite has a specific area within the range of 0.01 m2/g or more and 5 m2/g or less, and the total volume of mesopores within the range of 0.005 mL/g or more and 1.0 mL/g or less, wherein a volume of mesopores each having a pore diameter of 10 nm or more and 40 nm or less is 25% or more and 85% or less of the total volume of mesopores. By this structure, an output characteristic is enhanced.

摘要翻译： 中孔石墨用作构成锂离子二次电池或锂离子电容器的负极的活性物质。 具体而言，中孔石墨的比面积为0.01m 2 / g以上且5m 2 / g以下，中孔的总体积为0.005mL / g以上且1.0mL / g以下 其中孔径为10nm以上且40nm以下的中孔的体积为中孔总体积的25％以上且85％以下。 通过这种结构，输出特性得到提高。