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166 条记录 (耗时 0.029 秒)

    Method for producing 2-cyclododecyl-1-propanol
    71.
    发明授权
    Method for producing 2-cyclododecyl-1-propanol 失效
    2-环十二烷基-1-丙醇的制备方法

    公开(公告)号：US06303836B1

    公开(公告)日：2001-10-16

    申请号：US09424258

    申请日：1999-12-01

    申请人： Klaus Ebel ,  Rolf Pinkos

    发明人： Klaus Ebel ,  Rolf Pinkos

    IPC分类号： C07C3520

    CPC分类号： C07C51/353 ,  C07C29/149 ,  C07C67/347 ,  C07C2601/20 ,  C07C53/134 ,  C07C69/608 ,  C07C31/133

    摘要： 2-Cyclododecyl-propanol [sic], which is in demand as musk scent, is prepared in an advantageous industrial process by reacting cyclododecene with an excess of propionic acid or of a propionic acid derivative in the presence of catalytic amounts of a free-radical initiator, and subsequently catalytically hydrogenating the 2-cyclododecylpropionic acid which is formed or the corresponding 2-cyclododecylpropionic acid derivatives.

    摘要翻译： 在有利的工业过程中，通过使环十二烯与过量的丙酸或丙酸衍生物在催化量的自由基存在下反应制备作为麝香香味的2-环十二烷基 - 丙醇[sic] 引发剂，随后催化氢化形成的2-环十二烷基丙酸或相应的2-环十二烷基丙酸衍生物。

    Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores
    72.
    发明授权
    Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores 有权

    公开(公告)号：US06284917B1

    公开(公告)日：2001-09-04

    申请号：US09581843

    申请日：2000-06-19

    申请人： Melanie Brunner ,  Arnd Böttcher ,  Boris Breitscheidel ,  Klaus Halbritter ,  Jochem Henkelmann ,  Lucien Thil ,  Rolf Pinkos

    发明人： Melanie Brunner ,  Arnd Böttcher ,  Boris Breitscheidel ,  Klaus Halbritter ,  Jochem Henkelmann ,  Lucien Thil ,  Rolf Pinkos

    IPC分类号： C07C6974

    CPC分类号： C08K5/12 ,  C07C51/36 ,  C07C67/303 ,  C07C69/75 ,  C07C2601/14 ,  C07C61/09

    摘要： A process for hydrogenating a benzenepolycarboxylic acid or a derivative thereof or a mixture of two or more thereof by bringing the benzenepolycarboxylic acid or the derivative thereof or the mixture of two or more thereof into contact with a hydrogen-containing gas is carried out in the presence of a catalyst which comprises as active metal at least one metal of transition group VIII of the Periodic Table alone or together with at least one metal of transition group I or VII of the periodic table applied to a support which contains macropores with the proviso that if dimethyl terephthalate is hydrogenated, the hydrogenation using a catalyst which comprises as active metal ruthenium either alone or together with at least one metal of transition group I, VII or VIII of the Periodic Table applied to a support, where the support has a mean pore diameter of at least 50 nm and a BET surface area of at most 30 m2/g and the amount of the active metal is from 0.01 to 30% by weight, based on the total weight of the catalyst, and the ratio of the surface areas of the active metal and the catalyst support is less than 0.05, and/or a catalyst which comprises as active metal ruthenium either alone or together with at least one metal of transition group I, VII or VIII of the Periodic Table in an amount of from 0.01 to 30% by weight, based on the total weight of the catalyst, applied to a support, where from 10 to 50% of the pore volume of the support is formed by macropores having a pore diameter in the range from 50 nm to 10,000 nm and from 50 to 90% of the pore volume of the support is formed by mesopores having a pore diameter in the range from 2 to 50 nm, where the sum of the pore volumes adds up to 100%, is excluded, and novel hydrogenation products, obtainable by hydrogenating benzenepolycarboxylic acid (derivatives) as well as their use as plasticizers in plastics.

    Method for producing aliphatic alcohols
    74.
    发明授权
    Method for producing aliphatic alcohols 有权
    生产脂肪醇的方法

    公开(公告)号：US06204417B1

    公开(公告)日：2001-03-20

    申请号：US09423876

    申请日：1999-11-15

    申请人： Rolf Fischer ,  Rolf Pinkos ,  Joachim Wulff-Döring

    发明人： Rolf Fischer ,  Rolf Pinkos ,  Joachim Wulff-Döring

    IPC分类号： C07C3118

    CPC分类号： C07C29/149 ,  B01J23/56 ,  B01J23/6567 ,  B01J23/89 ,  C07C31/12 ,  C07C31/207 ,  C07C31/125 ,  C07C31/20

    摘要： In a process for preparing aliphatic alcohols by hydrogenating aliphatic carboxylic acids or anhydrides or esters thereof or lactones in the presence of a catalyst comprising Pt and Re, in the form of the metal or an oxide in each case, the catalyst further comprises at least one further element from the groups 5 to 12 and 14 and the lanthanides of the Periodic Table of the Elements in the form of the metal or an oxide.

    摘要翻译： 在通过在包含Pt和Re的催化剂的存在下，在每种情况下以金属或氧化物的形式加氢脂族羧酸或其酸酐或其酯或内酯的方法中，催化剂还包含至少一种 第5〜12和14族的元素，元素周期表的镧系元素为金属或氧化物。

    Hydrogenation of polyenes to monoenes
    75.
    发明授权
    Hydrogenation of polyenes to monoenes 失效
    将多烯氢化成单烯

    公开(公告)号：US06194624B1

    公开(公告)日：2001-02-27

    申请号：US09444316

    申请日：1999-11-22

    申请人： Rolf Pinkos

    发明人： Rolf Pinkos

    IPC分类号： C07C502

    CPC分类号： C07C5/05 ,  C07C2523/46

    摘要： A process for hydrogenating polyenes, especially 1,5,9-cyclododecatriene, to the corresponding monoenes, especially cyclododecene, using homogeneous ruthenium catalysts comprises hydrogenating in the presence of a carboxylic acid, advantageously a C1-C20 monocarboxylic acid, a C2-C6 dicarboxylic acid, cyclohexylcarboxylic acid, benzoic acid, terephthalic acid, phthalic acid or phenylacetic acid, especially acetic acid, propionic acid, succinic acid or adipic acid or a C12-C20 fatty acid. The homogeneous ruthenium catalyst is advantageously generated in situ prior to the hydrogenation. The in situ generation is carried out in the additional presence of CO or formaldehyde and the hydrogenation in the additional presence of triphenylphosphine.

    摘要翻译： 使用均匀的钌催化剂将多烯，特别是1,5,9-环十二碳三烯氢化成相应的单烯，特别是环十二碳烯的方法包括在羧酸存在下，有利的是C 1 -C 20一元羧酸，C 2 -C 6二羧酸 酸，环己基羧酸，苯甲酸，对苯二甲酸，邻苯二甲酸或苯乙酸，特别是乙酸，丙酸，琥珀酸或己二酸或C 12 -C 20脂肪酸。均匀的钌催化剂有利地在氢化之前原位产生 。 原位产生在CO或甲醛的另外存在下进行，并且在另外存在三苯基膦的情况下进行氢化。

    Process for preparing tetrahydrofuran from dialkoxybutenes
    76.
    发明授权
    Process for preparing tetrahydrofuran from dialkoxybutenes 失效
    从二烷氧基丁烯制备四氢呋喃的方法

    公开(公告)号：US06169189A

    公开(公告)日：2001-01-02

    申请号：US09180482

    申请日：1998-11-12

    申请人： Rolf Fischer ,  Rolf Pinkos ,  Martin Sch{umlaut over (a)}fer ,  Arthur Höhn ,  Peter Schwab

    发明人： Rolf Fischer ,  Rolf Pinkos ,  Martin Sch{umlaut over (a)}fer ,  Arthur Höhn ,  Peter Schwab

    IPC分类号： C07D30708

    CPC分类号： C07C41/18 ,  C07C41/26 ,  C07C41/32 ,  C07D307/08 ,  C07C43/15 ,  C07C43/13

    摘要： A process for preparing tetrahydrofuran, which comprises reacting 1,4-butenediol diethers of the formulae I and/or II RO—CH2—CH═CH—CH2—OR  I RO—CH2—CH2═CH—CH2—OR  II, where the R radicals can be identical or different and are C1-C15-alkyl or cycloalkyl radicals, C6-C12-aryl radicals or C7-C15-aralkyl radicals, with water and hydrogen at from 20 to 300° C. under from 1 to 300 bar in the presence of catalysts or catalyst combinations which comprise components which are both capable of hydrogenation and have acidic or basic centers and a novel process for preparing 1,4-butanediol diethers of the formula I by metathesis are described.

    摘要翻译： 一种制备四氢呋喃的方法，其包括使式I和/或II的1,4-丁烯二醇二醚反应，其中R基团可以相同或不同，为C 1 -C 15 - 烷基或环烷基，C 6 -C 12 - 芳基或C 7 -C 15 - 芳烷基，其中水和氢在20-300℃，在1-300巴下，在催化剂或催化剂组合的存在下，其包含能够氢化并具有酸性或碱性中心的组分，以及新颖的 描述了通过复分解制备式I的1,4-丁二醇二醚的方法。

    Preparation of .gamma.-butyrolactone
    78.
    发明授权
    Preparation of .gamma.-butyrolactone 失效
    γ-丁内酯的制备

    公开(公告)号：US5646307A

    公开(公告)日：1997-07-08

    申请号：US640879

    申请日：1996-05-16

    申请人： Rolf Pinkos ,  Rolf Fischer

    发明人： Rolf Pinkos ,  Rolf Fischer

    IPC分类号： C07D307/33 ,  B01J23/36 ,  B01J23/656 ,  B01J23/72 ,  B01J23/86 ,  C07B61/00 ,  C07D307/32 ,  C07D315/00 ,  C07D307/02

    CPC分类号： C07D315/00 ,  Y02P20/582

    摘要： A process for the preparation of .gamma.-butyrolactone, in which 2,5-dihydrofuran or 2,3-dihydrofuran or a mixture of these two dihydrofurans is caused to react in the gas phase in the presence of water and in the presence or absence of additional hydrogen at elevated temperature over a hydrogenating catalyst.

    摘要翻译： PCT No.PCT / EP94 / 03683第 371日期：1996年5月16日 102（e）日期1996年5月16日PCT 1994年11月9日PCT公布。 WO95 / 14010 PCT出版物 日期1995年5月26日制备γ-丁内酯的方法，其中使2,5,5-二氢呋喃或2,3-二氢呋喃或这两种二氢呋喃的混合物在气相中在水的存在下反应， 在升高的温度下在氢化催化剂上存在或不存在另外的氢。

    Preparation of polyether glycols
    79.
    发明授权
    Preparation of polyether glycols 失效
    聚醚二醇的制备

    公开(公告)号：US5561217A

    公开(公告)日：1996-10-01

    申请号：US427274

    申请日：1995-04-24

    申请人： Hans-Juergen Weyer ,  Rolf Fischer ,  Rolf Pinkos

    发明人： Hans-Juergen Weyer ,  Rolf Fischer ,  Rolf Pinkos

    IPC分类号： C08G65/00 ,  C08G18/48 ,  C08G65/02 ,  C08G65/20 ,  C08G65/26 ,  C08G65/32 ,  C08G65/321 ,  C08F8/04

    CPC分类号： C08G65/266 ,  C08G18/48 ,  C08G65/20 ,  C08G65/2693 ,  C08G65/32 ,  C08G65/321

    摘要： A process for the preparation of polyoxyalkylene glycols or polyoxyalkylene glycol copolymers from polyoxyalkylene glycol formates or the formates of polyoxyalkylene glycol copolymers comprises reacting the formates of polyoxyalkylene glycols or of polyoxyalkylene glycol copolymers in the liquid phase in the presence of a heterogeneous catalyst which contains, as catalytically active component, rhenium and/or at least one element from sub-group VIII of the Periodic Table of the Elements.

    摘要翻译： 从聚氧亚烷基二醇甲酸酯或聚氧亚烷基二醇共聚物的甲酸酯制备聚氧亚烷基二醇或聚氧亚烷基二醇共聚物的方法包括在多相催化剂存在下使聚氧亚烷基二醇或聚氧亚烷基二醇共聚物的甲酸酯在液相中反应， 催化活性组分，铼和/或元素周期表第VIII族中的至少一种元素。