Curable fluoroelastomeric compositions
    71.
    发明授权
    Curable fluoroelastomeric compositions 失效
    可固化的含氟弹性体组合物

    公开(公告)号:US5830381A

    公开(公告)日:1998-11-03

    申请号:US833534

    申请日:1997-04-07

    摘要: Curable flurooelastomeric compositions employable for preparing fuel hoses or O-rings for injectors comprising: A) 100 phr (parts) copolymers or terpolymers based on VDF with a content in fluorine of at least 67% by weight, the VDF being comprised from 30 to 5000 by weight, from 20 to 60% by weight of HFP optionally other monomeric units deriving from a monomer having ethylene unsaturation; the sum of the comonomers being 100; B) 1 to 5 phr of an adduct between an accelerator and a curing agent in molar ratio from 1:2 to 1:5, the accelerator being an onio-organic compound having a positive charge, the curing agent being a di- or polyhydroxy or di- or polythiol compound; the adduct being obtained by melting of the reaction product between accelerator and curing agent in the indicated molar ratios, or by melting of the adduct mixture 1:1 added with the curing agent in the indicated amounts.

    摘要翻译: 可用于制备用于注射器的燃料软管或O形环的可固化氟橡胶组合物,包括:A)基于VDF的100phr(份)共聚物或三元共聚物,其中氟含量为至少67重量%,VDF为30-5000 的20-60重量%的HFP任选地衍生自具有乙烯不饱和单体的单体的其它单体单元; 共聚单体的总和为100; B)1〜5phr摩尔比为1:2〜1:5的加速剂与固化剂之间的加合物,该促进剂为具有正电荷的有机有机化合物,该固化剂为二羟基或多羟基 或二硫醇或多硫醇化合物; 加合物通过以指定的摩尔比熔化加速剂和固化剂之间的反应产物,或通过以指定量加入固化剂的1:1加合物混合物熔化而获得。

    Curable fluoroelastomeric compositions
    72.
    发明授权
    Curable fluoroelastomeric compositions 失效
    可固化的含氟弹性体组合物

    公开(公告)号:US5648429A

    公开(公告)日:1997-07-15

    申请号:US451075

    申请日:1995-05-25

    CPC分类号: C08K5/0025

    摘要: Curable flurooelastomeric compositions used for O-rings comprising:A) parts (phr) of a curable fluoroelastomeric copolymer having a content in F

    摘要翻译: 用于O型圈的可固化氟橡胶组合物包括:A)部分(phr)可固化的含氟弹性体共聚物,其含量为F <67重量%,包含40至68重量%的VDF单元,20至50重量% HFP单元的重量,总和为100,以及任选的一种或多种具有乙烯不饱和度的共聚单体,所述共聚物具有至少0.5个链的多个离子末端; B)1至5phr摩尔比为1:3至1:5的促进剂和固化剂之间的加合物,加速剂为具有正电荷的有机化合物,固化剂为二 - 或 多羟基或二 - 或多硫醇化合物; 加合物通过以指定的摩尔比熔化加速剂和固化剂之间的反应产物,或通过以指定量加入固化剂的1:1加合物混合物熔化而获得。

    Polyvinylidenefluoride having high mechanical properties and high
thermochemical stability and the preparation process thereof
    74.
    发明授权
    Polyvinylidenefluoride having high mechanical properties and high thermochemical stability and the preparation process thereof 失效
    具有高机械性能和高热稳定性的聚偏二氟乙烯及其制备方法

    公开(公告)号:US5583190A

    公开(公告)日:1996-12-10

    申请号:US534671

    申请日:1995-09-27

    IPC分类号: C08F14/22 C08F4/32 C08F114/22

    CPC分类号: C08F114/22

    摘要: A polyvinylidenefluoride (PVDF) having high mechanical properties both at room temperature and at high temperatures, having very good processability and high thermochemical resistance to dehydrofluorination, is prepared by means of a polymerization process of vinylidenefluoride in aqueous emulsion at a temperature comprised between 95.degree. and 120.degree. C., in the presence of a chain transfer agent. In this way it is possible to obtain, using non-hazardous peroxidic initiators (for instance diterbutylperoxide), a PVDF particularly suitable for applications where high mechanical and thermochemical resistance properties are required, such as for instance the manufacture of articles for chemical industry (pipes, valves, fittings, tanks, heat exchangers, membranes, flanges, etc.).

    摘要翻译: 在室温和高温下具有高机械性能的聚偏二氟乙烯(PVDF),具有非常好的加工性能和对脱氟化氢的高耐热化学性能,是通过聚偏二氟乙烯在水乳液中的温度在95°和 120℃,在链转移剂存在下。 以这种方式,可以使用非危险的过氧化物引发剂(例如二叔丁基过氧化物)获得特别适用于需要高机械和耐热化学性能的应用的PVDF,例如用于化学工业的制品(管道 ,阀门,配件,罐,热交换器,膜,法兰等)。

    Fluoroelastomers based on vinylidene fluoride exhibiting superior
resistance to organic bases
    75.
    发明授权
    Fluoroelastomers based on vinylidene fluoride exhibiting superior resistance to organic bases 失效
    基于偏氟乙烯的氟弹性体显示出优异的耐有机碱性

    公开(公告)号:US5264509A

    公开(公告)日:1993-11-23

    申请号:US15063

    申请日:1993-02-08

    CPC分类号: C08F214/265 C08F214/225

    摘要: Fluoroelastomeric copolymers exhibiting high resistance to bases and alcohols, as well as high mechanical properties and low-temperature resistance, comprising, in moles:4-75% of units of vinylidene fluoride;12-40% of units of hexafluoropropene and/or perfluorovinylether and/or hydropentafluoropropene and/or chlorotrifluoroethylene;2-35% of units of an olefin containing up to 4 carbon atoms;2-60% of units of tetrafluoroethylene, provided that, when the sum of the olefin units and the perfluorovinylether units is equal to or greater than 70%, such copolymers possess a molecular weight sufficiently high to exhibit good mechanical characteristics.

    摘要翻译: 显示出对碱和醇的高抗性以及高机械性能和耐低温性的氟弹性共聚物,摩尔数:4-75%的偏二氟乙烯单元; 12-40%的六氟丙烯和/或全氟乙烯基醚和/或氢五氟丙烯和/或氯三氟乙烯的单元; 2-35%含有至多4个碳原子的烯烃单元; 2-60%的四氟乙烯单元,条件是当烯烃单元和全氟乙烯基醚单元的总和等于或大于70%时,这种共聚物的分子量足够高以表现出良好的机械特性。

    Method of producing adhesively bonded metal fluoroelastomer composites
    77.
    发明授权
    Method of producing adhesively bonded metal fluoroelastomer composites 失效
    粘合金属含氟弹性体复合材料的制备方法

    公开(公告)号:US5045143A

    公开(公告)日:1991-09-03

    申请号:US423559

    申请日:1989-10-16

    IPC分类号: B32B15/08 C08K5/5399

    摘要: Metal-fluoroelastomer composites constituted by a metal part and by a cured fluoroelastomer part bonded to each other with high adhesion strength, wherein the fluoroelastomeric part is constituted by a copolymer containing from 35 to 80 mol % T of vinylidene fluoride, from 15 to 35 mol % of hexafluoropropene, from 0 to 30 mol % of another comonomer selected from fluoro-olefins and/or perfluorovinyl ethers, and from 0.001 to 2 wt. % of bromine.

    摘要翻译: 金属 - 含氟弹性体复合材料由金属部分和固化的含氟弹性体部分组成,粘合强度高,其中氟弹性体部分由含有35至80摩尔%的偏二氟乙烯,15至35摩尔的共聚物构成 %的六氟丙烯,0至30mol%的选自氟代烯烃和/或全氟乙烯基醚的另一种共聚单体,和0.001至2wt。 %的溴。

    Assemblies for electrochemical devices
    80.
    发明授权
    Assemblies for electrochemical devices 有权
    电化学装置组件

    公开(公告)号:US09190687B2

    公开(公告)日:2015-11-17

    申请号:US12306883

    申请日:2007-06-25

    摘要: MEA 7-layer assemblies with gasket, comprising: a film of ionomeric membrane (3), containing functional acid groups —SO3H and/or —COOH, having in at least one direction, called direction x, a size variation lower than 0.08%; two GDL sheets (1) and (2) in porous material having on one surface an electrocatalytic layer, not shown in the Figures, of which: the first sheet DGL (1) is coextensive with the membrane (3) surface, positioned so as to overlap thereto; the second sheet GDL (2), having a lower width but the same length of the film of membrane (3), measured in the x direction; the two sheets (1) and (2) placed so that the electrocatalytic layer comes into contact, respectively, with each of the two membrane faces; a gasket positioned according to a frame shape along the assembly perimeter.

    摘要翻译: 具有垫片的MEA7层组件包括:包含官能酸基-SO 3 H和/或-COOH的离聚物膜(3)的膜,在至少一个方向上称为方向x,尺寸变化小于0.08%; 两个GDL片(1)和(2)在多孔材料中,在一个表面上具有电催化层,图中未示出,其中:第一片DGL(1)与膜(3)表面共同延伸, 与其重叠; 第二片材GDL(2)在x方向上测量的膜的宽度较低但长度相同; 将两片(1)和(2)放置成使得电催化层分别与两个膜面中的每一个接触; 沿着组件周边根据框架形状定位的垫圈。