One-component adhesive compositions

    公开(公告)号:US11667821B2

    公开(公告)日:2023-06-06

    申请号:US17348199

    申请日:2021-06-15

    Applicant: STEPAN COMPANY

    CPC classification number: C09J163/04

    Abstract: One-component (1K) adhesive compositions (“PEEP” compositions) and a process for making them are disclosed. A polyepoxide is reacted with a polyether polyol composition, a polyester polyol composition, or both in the presence of a heat-activated Lewis acid catalyst at a temperature within the range of 100° C. to 220° C. for a time effective to cure the adhesive. The compositions are storage-stable under ambient conditions. Compared with conventional epoxy compositions, the 1K PEEP compositions offer improved room temperature lap shear strength, better resilience, and higher elongation. The 1K PEEP systems deliver a desirable balance of physical and mechanical properties while avoiding polyisocyanates and polyamine crosslinkers.

    IMIDE-CONTAINING POLYESTER POLYOLS AND INTUMESCENT RIGID FOAMS

    公开(公告)号:US20220411567A1

    公开(公告)日:2022-12-29

    申请号:US17775249

    申请日:2020-11-05

    Applicant: STEPAN COMPANY

    Abstract: Rigid polyurethane or polyisocyanurate foams, polyester polyols used to produce them, and methods for formulating the foams are disclosed. The foams comprise a reaction product of a polyisocyanate, a polyester polyol, water, a surfactant, a catalyst and optional ingredients. The polyester polyols comprise a phthalimide-containing polyacid, a phthalimide-containing polyol, or a combination thereof. Rigid foams produced from the polyester polyols exhibit higher thermal stability and/or greater intumescence when compared with foams made from other polyester polyols. The phthalimide-containing polyester polyols should allow formulators to improve the flammability performance of rigid foams with reduced levels of flame retardants and/or lower index and should facilitate the production of thinner insulation panels.

    CORROSION-INHIBITING SURFACTANTS
    84.
    发明申请

    公开(公告)号:US20220363977A1

    公开(公告)日:2022-11-17

    申请号:US17622678

    申请日:2020-07-29

    Applicant: STEPAN COMPANY

    Abstract: A method for inhibiting corrosion of pipelines and other metal surfaces, particularly those used in the oil-and-gas industry, is disclosed. The method comprises treating a brine-exposed metal surface with a film-forming composition. The composition comprises a quaternary surfactant, which is made by reacting a polyalkylene glycol (PAG), a haloalkanoic acid, and a tertiary fatty amine that optionally incorporates amide or ester functionality. The surfactant comprises a PAG monoester quat and a PAG diester diquat and may have other components. The quaternary surfactants provide good corrosion protection and can partition effectively from an oily phase into a brine phase in the absence of agitation. The surfactants are easy to synthesize economically and have structures that can be tailored to meet local HLB requirements.

    Corrosion inhibitors for oilfield applications

    公开(公告)号:US11203811B2

    公开(公告)日:2021-12-21

    申请号:US16807683

    申请日:2020-03-03

    Applicant: Stepan Company

    Abstract: A corrosion inhibitor active and method for reducing corrosion of a metal surface in contact with a corrosive environment is disclosed. The corrosion inhibitor active is an organic sulfonated compound that is derived from the sulfonation of one or more carboxylic acids, internal olefins, or alpha-olefins having a carbon chain length of 15 to 26 carbon atoms. The method of reducing corrosion includes contacting the metal surface with an effective amount of the corrosion inhibitor active. The corrosion inhibitor active is useful in high temperature corrosive environments, such as those found in oil and gas operations.

    Low VOC polyurethane adhesive
    88.
    发明授权

    公开(公告)号:US11168238B2

    公开(公告)日:2021-11-09

    申请号:US16579301

    申请日:2019-09-23

    Applicant: Stepan Company

    Abstract: A low-VOC, two-component polyurethane adhesive is provided. The polyurethane adhesive has an A-side that includes an isocyanate and a non-reactive plasticizer, and a B-side that includes an aliphatic polyester polyol, a non-polyester polyol, and a urethane catalyst. The A-side and the B-side are reacted at a volume ratio of 1:1 and formulated at an NCO/OH index within the range of 0.90 to 1.10. The polyurethane adhesive is solvent-free and is particularly suitable for adhering a polymeric membrane to a substrate.

    ONE-COMPONENT ADHESIVE COMPOSITIONS

    公开(公告)号:US20210309895A1

    公开(公告)日:2021-10-07

    申请号:US17348199

    申请日:2021-06-15

    Applicant: STEPAN COMPANY

    Abstract: One-component (1K) adhesive compositions (“PEEP” compositions) and a process for making them are disclosed. A polyepoxide is reacted with a polyether polyol composition, a polyester polyol composition, or both in the presence of a heat-activated Lewis acid catalyst at a temperature within the range of 100° C. to 220° C. for a time effective to cure the adhesive. The compositions are storage-stable under ambient conditions. Compared with conventional epoxy compositions, the 1K PEEP compositions offer improved room temperature lap shear strength, better resilience, and higher elongation. The 1K PEEP systems deliver a desirable balance of physical and mechanical properties while avoiding polyisocyanates and polyamine crosslinkers.

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