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![PROCESS FOR THE PREPARATION OF 2-OXO-[1,3] DIOXOLANE-4-CARBOXYLIC ACID ESTERS](/abs-image/US/2012/05/17/US20120123136A1/abs.jpg.150x150.jpg)
81.发明申请PROCESS FOR THE PREPARATION OF 2-OXO-[1,3] DIOXOLANE-4-CARBOXYLIC ACID ESTERS 审中-公开制备2-氧代 - [1,3]二氧杂环戊烷-4-羧酸酯的方法公开(公告)号：US20120123136A1
公开(公告)日：2012-05-17
申请号：US13295447
申请日：2011-11-14
IPC分类号： C07D317/36
CPC分类号： C07D317/36
摘要： A process for the preparation of 2-oxo-[1,3] dioxolane-4-carboxylic acid esters of formula I with R being an organic group comprising 1 to 10 carbon atoms, wherein an oxirane-2-carboxylic acid ester of formula II is reacted with carbon dioxide (CO2) at a pressure of at least 35 bars and a temperature of 60 to 80° C.
摘要翻译： 制备式I的2-氧代 - [1,3]二氧戊环-4-甲酸酯的方法，其中R是含有1-10个碳原子的有机基团，其中式II的环氧乙烷-2-羧酸酯 在至少35巴的压力和60至80℃的温度下与二氧化碳（CO 2）反应。
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公开(公告)号：US20120088935A1
公开(公告)日：2012-04-12
申请号：US13269016
申请日：2011-10-07
IPC分类号： C07C45/29
CPC分类号： C07C45/28 , C07C45/62 , C07C2601/18 , C07C49/587 , C07C49/385
摘要： Ketones of the formula II where A is optionally alkyl-substituted C2-C12-alkanediyl, R1 and R2 are each, independently of one another, C1-C6-alkyl, or R1 and R2 together form optionally alkyl-substituted C3-C10-alkanediyl, and R3 is hydrogen or C1-C6-alkyl, are prepared by reacting a cyclic olefin of the formula I with dinitrogen monoxide to form the ketone of the formula II. The ketone of the formula II can be further hydrogenated to form the saturated ketone of the formula III. Macrocyclic ketones of the formula III, e.g. muscone, are sought after as fragrances.
摘要翻译： 式II的酮，其中A任选为烷基取代的C 2 -C 12 - 烷二基，R 1和R 2各自彼此独立地为C 1 -C 6 - 烷基，或者R 1和R 2一起形成烷基取代的C 3 -C 10 - 烷二基 R 3是氢或C 1 -C 6烷基，是通过使式I的环状烯与一氧化二氮反应形成式II的酮制备的。 式II的酮可以进一步氢化以形成式III的饱和酮。 式III的大环酮，例如 肌肉，被追捧为香水。
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公开(公告)号：US20110152576A1
公开(公告)日：2011-06-23
申请号：US13060545
申请日：2009-08-26
申请人： Joaquim Henrique Teles , Wilhelm Ruppel , Ulrike Wegerle , Anton Meier , Thomas Genger , Michael Schelper , Peter Resch
发明人： Joaquim Henrique Teles , Wilhelm Ruppel , Ulrike Wegerle , Anton Meier , Thomas Genger , Michael Schelper , Peter Resch
CPC分类号： C07C45/28 , C07C45/82 , C07C2601/08 , Y02P20/582 , C07C49/403 , C07C49/395 , C07C49/413
摘要： The present invention relates to a process for preparing at least one monocyclic ketone having from 4 to 20 carbon atoms by reacting a mixture G1 comprising at least one monocyclic olefin having from 4 to 20 carbon atoms with a mixture G2 comprising at least dinitrogen monoxide, wherein said reaction is performed adiabatically.
摘要翻译： 本发明涉及一种制备至少一种具有4-20个碳原子的单环酮的方法，该方法是使包含至少一种具有4-20个碳原子的单环烯烃的混合物G1与至少包含一氧化二氮的混合物G2反应，其中 所述反应是绝热的。
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公开(公告)号：US07833498B2
公开(公告)日：2010-11-16
申请号：US10586135
申请日：2005-01-20
IPC分类号： F28D15/02
CPC分类号： B01J8/067 , B01J19/2425 , B01J19/243 , B01J19/2445 , B01J2208/00849 , B01J2219/1944 , F28D7/024 , F28F1/02 , F28F1/08
摘要： Process and apparatus for the continuous preparation of a chemical compound in at least one reactor, where at least one of the reactors is a shell-and-tube reactor which has a shell and at least one internal tube located within the shell, wherein at least one of the internal tubes has, at least in part, a noncircular cross section and a helical configuration in the region in which it is surrounded by the shell.
摘要翻译： 用于在至少一个反应器中连续制备化学化合物的方法和装置，其中至少一个反应器是壳管式反应器，其具有壳和位于壳内的至少一个内管，其中至少 内管中的一个至少部分地具有在其被壳包围的区域中的非圆形横截面和螺旋形构造。
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公开(公告)号：US07754172B2
公开(公告)日：2010-07-13
申请号：US12094731
申请日：2006-11-21
CPC分类号： C07C45/28 , B01D53/14 , B01D53/1493 , B01D2257/402 , C01B21/22 , C01P2006/80 , Y02C20/10 , Y02P20/153
摘要： The present invention relates to a process for purifying a gas mixture G-0 comprising dinitrogen monoxide, at least comprising the absorption of the gas mixture G-0 in an organic solvent, subsequent desorption of a gas mixture G-1 from the laden organic solvent, absorption of the gas mixture G-1 in water and subsequent desorption of a gas mixture G-2 from the laden water, and also to the use of a purified gas mixture which comprises dinitrogen monoxide and is obtainable by such a process as an oxidizing agent for olefins.
摘要翻译： 本发明涉及一种纯化包含一氧化二氮的气体混合物G-0的方法，该方法至少包括在有机溶剂中吸收气体混合物G-0，随后将气体混合物G-1从含有机溶剂中解吸 ，将气体混合物G-1吸收在水中并随后从含水的气体中吸收气体混合物G-2，以及使用包含一氧化二氮的纯化气体混合物，并且可以通过氧化方法 烯烃试剂。
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公开(公告)号：US20100003173A1
公开(公告)日：2010-01-07
申请号：US12556961
申请日：2009-09-10
申请人： Ulrich Müller , Georg Krug , Peter Rudolf , Joaquim Henrique Teles , Hans-Georg Göbbel , Peter Bassler
发明人： Ulrich Müller , Georg Krug , Peter Rudolf , Joaquim Henrique Teles , Hans-Georg Göbbel , Peter Bassler
CPC分类号： C07D301/12 , Y02P20/52
摘要： Process for preparing propylene oxide, which comprises at least the steps (i) and (ii): (i) providing a catalyst comprising at least one porous oxidic material; (ii) reacting propene with a hydroperoxide in at least one nitrile as solvent or in a solvent mixture comprising at least one nitrile in the presence of the catalyst of (i), wherein the at least one porous oxidic material is a zeolite which is assigned X-ray-crystallographically to the MWW type.
摘要翻译： 制备环氧丙烷的方法，其至少包括步骤（i）和（ii）：（i）提供包含至少一种多孔氧化物质的催化剂; （ii）使丙烯与至少一种腈作为溶剂中的氢过氧化物反应或在包含至少一种腈的溶剂混合物中，在（i）的催化剂存在下反应，其中所述至少一种多孔氧化物质是被分配的沸石 X射线晶体学到MWW型。
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87.发明授权Method for continuously operated pure distillation of oxiranes, especially propylene oxide 失效环氧乙烷，特别是环氧丙烷的连续运行纯蒸馏方法公开(公告)号：US07550064B2
公开(公告)日：2009-06-23
申请号：US10517368
申请日：2003-07-23
IPC分类号： B01D3/14 , C07D301/12 , C07D301/32
CPC分类号： B01D3/141 , B01D3/14 , B01D3/4222 , C07D301/32 , Y10S203/20
摘要： The invention relates to a continuously operated process for the purification by distillation of the oxirane formed in the oxirane synthesis by reaction of a hydroperoxide with an organic compound, wherein the crude oxirane is separated in a dividing wall column into low-, intermediate- and high-boiling fractions and the oxirane is taken off as intermediate boiler at the side offtake in a concentration of at least 99.9%.
摘要翻译： 本发明涉及通过氢过氧化物与有机化合物的反应蒸馏在环氧乙烷合成中形成的环氧乙烷进行纯化的连续操作方法，其中将粗环氧乙烷在分隔壁塔中分离成低，中，高 - 沸腾馏分，环氧乙烷作为中间锅炉在浓度为99.9％以上的出口侧取出。
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88.发明授权公开(公告)号：US07527652B2
公开(公告)日：2009-05-05
申请号：US10571772
申请日：2004-09-10
IPC分类号： C14C1/00 , C07D301/12 , C07C323/02 , C07F11/00
CPC分类号： C07D407/04 , C07C323/12
摘要： Mixtures of (A) from 55 to 65 mol % of erythro-dithiol of formula erythro-IV: and (B) from 35 to 45 mol % of threo-dithiol of formula threo-IV or threo-IV′: and their corresponding alkali metal salts and ammonium salts, are useful for treating animal hides.
摘要翻译： （A）55至65摩尔％的赤藓-4-肟的赤式二硫醇和（B）35至45摩尔％的式Ⅳ-Ⅳ或钍-IV'的二硫代硫醇的混合物及其相应的碱 金属盐和铵盐可用于治疗动物皮肤。
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公开(公告)号：US07408074B2
公开(公告)日：2008-08-05
申请号：US10553516
申请日：2004-04-16
IPC分类号： C07D301/12
CPC分类号： C07D301/12
摘要： Process for preparing an alkene oxide, which comprises at least the steps (i), (ii) and (v): (i) providing a stream S1 comprising compressed, liquid alkene; (ii) depressurizing at least part of the stream S1 with absorption of heat and with at least partial vaporization of the liquid alkene; (v) reacting the alkene obtained in (ii) with a hydroperoxide in the presence of at least one solvent and at least one catalyst to give a mixture comprising alkene oxide and the solvent or solvents.
摘要翻译： 制备氧化烯的方法，其至少包括步骤（i），（ii）和（v）：（i）提供包含压缩的液体烯烃的料流S1; （ii）吸收热量并至少部分汽化液态烯烃使至少部分流S1减压; （v）使（ii）中获得的烯烃与至少一种溶剂和至少一种催化剂存在下的氢过氧化物反应，得到包含烯烃氧化物和溶剂或溶剂的混合物。
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公开(公告)号：US07351587B2
公开(公告)日：2008-04-01
申请号：US10467278
申请日：2002-02-05
IPC分类号： G01N33/00 , G01N21/01 , G01N21/00 , C07D301/12
CPC分类号： G01N21/75 , Y10T436/206664
摘要： A process for the on-line determination of the hydrogen peroxide content of a mixture obtained in a chemical reaction comprises at least the following steps: (1) admixing the mixture comprising hydrogen peroxide with at least one reagent which is capable of forming a substance which can be detected by optical methods on reaction with hydrogen peroxide, so as to form this substance, (2) determining the amount of the substance present by measuring its specific absorption in an appropriate wavelength range.
摘要翻译： 用于在线测定化学反应中获得的混合物中过氧化氢含量的方法至少包括以下步骤：（1）将包含过氧化氢的混合物与至少一种能够形成物质的试剂混合， 可以通过与过氧化氢反应的光学方法检测，从而形成该物质，（2）通过在适当的波长范围内测量其比吸收来测定物质的存在量。
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