Process of polymerizing olefins using organonickel catalyst compositions
    81.
    发明授权
    Process of polymerizing olefins using organonickel catalyst compositions 失效
    使用有机镍催化剂组合物聚合烯烃的方法

    公开(公告)号:US5461126A

    公开(公告)日:1995-10-24

    申请号:US235051

    申请日:1994-04-29

    IPC分类号: C08F4/60 C08F4/80 C08F10/00

    CPC分类号: C08F10/00

    摘要: Catalytic compositions and catalytic processes are provided. The catalytic compositions are produced by the process that comprises contacting an organonickel compound with a cyclicazacarbyl compound. Optionally, one or more catalytic promoters can be present in the catalytic compositions. Additionally, one or more olefins can be contacted with one or more of these catalytic compositions to form oligomerization products and/or polymerization products.

    摘要翻译: 提供催化组合物和催化方法。 催化组合物通过包括使有机镍化合物与环氮杂环戊基化合物接触的方法制备。 任选地,一种或多种催化促进剂可以存在于催化组合物中。 另外,一种或多种烯烃可以与一种或多种这些催化组合物接触以形成低聚产物和/或聚合产物。

    Catalyst compositions and catalytic processes
    83.
    发明授权
    Catalyst compositions and catalytic processes 失效
    催化剂组合物和催化方法

    公开(公告)号:US5332708A

    公开(公告)日:1994-07-26

    申请号:US979989

    申请日:1992-11-23

    CPC分类号: C08F10/00

    摘要: Catalytic compositions and catalytic processes are provided. The catalytic compositions are produced by the process that comprises contacting an organonickel compound with a cyclicazacarbyl compound. Optionally, one or more catalytic promoters can be present in the catalytic compositions. Additionally, one or more olefins can be contacted with one or more of these catalytic compositions to form oligomerization products and/or polymerization products.

    摘要翻译: 提供催化组合物和催化方法。 催化组合物通过包括使有机镍化合物与环氮杂环戊基化合物接触的方法制备。 任选地,一种或多种催化促进剂可以存在于催化组合物中。 另外,一种或多种烯烃可以与一种或多种这些催化组合物接触以形成低聚产物和/或聚合产物。

    Demetallization of hydrocarbon containing feed streams
    84.
    发明授权
    Demetallization of hydrocarbon containing feed streams 失效
    含烃进料流的脱金属化

    公开(公告)号:US4609638A

    公开(公告)日:1986-09-02

    申请号:US745552

    申请日:1985-06-17

    摘要: Metals contained in a hydrocarbon containing feed stream are removed by contacting the hydrocarbon containing feed stream under suitable demetallization conditions with hydrogen and a catalyst composition comprising zirconium phosphate, cobalt phosphate and iron phosphate. The life and activity of the catalyst composition may be increased by introducing a decomposable metal compound selected from the group consisting of the metals of Group V-B, Group VI-B, Group VII-B and Group VIII of the Periodic Table into the hydrocarbon containing feed stream prior to contacting the hydrocarbon containing feed stream with the catalyst composition.

    摘要翻译: 通过在合适的脱金属条件下将含烃进料流与氢和包含磷酸锆,磷酸钴和磷酸铁的催化剂组合物接触来除去含烃进料流中的金属。 催化剂组合物的寿命和活性可以通过将选自由VB组,VI-B族,VII-B族和VIII族元素周期表的金属组成的组中的可分解的金属化合物引入到含烃进料中 在将含烃进料流与催化剂组合物接触之前的流。

    Polyolefin polymerization process, method of producing catalyst, and
catalyst
    87.
    发明授权
    Polyolefin polymerization process, method of producing catalyst, and catalyst 失效
    聚烯烃聚合工艺,催化剂生产方法和催化剂

    公开(公告)号:US5235011A

    公开(公告)日:1993-08-10

    申请号:US938922

    申请日:1992-08-31

    CPC分类号: C08F10/00 Y10S526/903

    摘要: A process for preparing a polymerization catalyst useful for the polymerization of olefins is provided comprising contacting a metal dihalide compound wherein the metal is selected from Group 2 and Group 12 of the Periodic Table and a transition metal compound which is a hydrocarbyloxide of a transition metal selected from Group 4 and Group 5 to form a first catalyst component; contacting the first catalyst component with at least one organoaluminum precipitating agent, wherein at least at the commencement of this step, the temperature at which such contacting is carried out is greater than about 70.degree. C. to about 150.degree. C. to form a solid product, and contacting the solid product with an activating agent to form a catalyst. Other aspects of the invention provide a catalyst prepared by the above described method and a polymerization process employing the thus prepared catalyst.

    Polyolefin polymerization process and catalyst
    88.
    发明授权
    Polyolefin polymerization process and catalyst 失效
    聚烯烃聚合工艺和催化剂

    公开(公告)号:US4544716A

    公开(公告)日:1985-10-01

    申请号:US623310

    申请日:1984-06-22

    申请人: Gil R. Hawley

    发明人: Gil R. Hawley

    IPC分类号: C08F10/00 C08F4/02 C08F10/06

    CPC分类号: C08F10/00

    摘要: A catalyst and its method of preparation and use involving reacting a magnesium dihalide, an alkoxytitanium compound and water, followed by reaction with an organoaluminum compound and then with a halide ion exchanging source.

    摘要翻译: 一种催化剂及其制备和使用方法,包括使二卤化镁,烷氧基钛化合物和水反应,随后与有机铝化合物反应,然后与卤离子交换源反应。

    Polyolefin polymerization process and catalyst
    89.
    发明授权
    Polyolefin polymerization process and catalyst 失效
    聚烯烃聚合工艺和催化剂

    公开(公告)号:US4537870A

    公开(公告)日:1985-08-27

    申请号:US630172

    申请日:1984-07-12

    申请人: Gil R. Hawley

    发明人: Gil R. Hawley

    CPC分类号: C08F10/00

    摘要: A catalyst prepared by reacting a dihalide, such as MgCl.sub.2 ; a titanium compound, such as a titanium tetraalkoxide; and an electron donor to form a first catalyst component; then reacting that component with an organoaluminum halide; then reacting the resulting solid with TiCl.sub.4 ; and then reacting the solid after that step with HSiCl.sub.3. Also the use of the catalyst in olefin polymerization is disclosed.

    摘要翻译: 通过使二卤化物如MgCl 2反应制备的催化剂; 钛化合物,例如四烷氧基钛; 和电子给体以形成第一催化剂组分; 然后使该组分与有机铝卤化物反应; 然后使所得固体与TiCl 4反应; 然后使该步骤后的固体与HSiCl 3反应。 还公开了在烯烃聚合中使用催化剂。