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公开(公告)号：US06821920B2
公开(公告)日：2004-11-23
申请号：US10351338
申请日：2003-01-27
申请人： Nancy W. Eilerts , Gil R. Hawley
发明人： Nancy W. Eilerts , Gil R. Hawley
IPC分类号： C08F470
CPC分类号： B01J31/2234 , B01J31/143 , B01J31/1805 , B01J2531/847 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2500/12 , C08F2500/07 , C08F2500/08 , C08F4/7006
摘要： Novel catalyst systems which comprise diimine nickel complexes comprising additional ligands selected from the group consisting of acetylacetonate, hexaflourylacetylacetonate, halogens and mixtures thereof can be used with methylaluminoxane in slurry polymerization processes to polymerize mono-1-olefins and, optionally one or more higher mono-1-olefin comonomer(s), to produce high molecular weight polymers.
摘要翻译： 包含二亚胺镍络合物的新型催化剂体系包括选自乙酰丙酮化物，六氟乙酰丙酮化合物，卤素及其混合物的另外的配体，可用于淤浆聚合方法中的甲基铝氧烷以聚合单-1-烯烃和任选的一种或多种高级单 - 1-烯烃共聚单体，以产生高分子量聚合物。
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公开(公告)号：US06521727B2
公开(公告)日：2003-02-18
申请号：US09933357
申请日：2001-08-20
申请人： Nancy W. Eilerts , Gil R. Hawley
发明人： Nancy W. Eilerts , Gil R. Hawley
IPC分类号： C08F470
CPC分类号： B01J31/2234 , B01J31/143 , B01J31/1805 , B01J2531/847 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2500/12 , C08F2500/07 , C08F2500/08 , C08F4/7006
摘要： Novel catalyst systems which comprise diimine nickel complexes comprising additional ligands selected from the group consisting of acetylacetonate, hexaflourylacetylacetonate, halogens and mixtures thereof can be used with methylaluminoxane in slurry polymerization processes to polymerize mono-1-olefins and, optionally one or more higher mono-1-olefin comonomer(s), to produce high molecular weight polymers.
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公开(公告)号：US07629284B2
公开(公告)日：2009-12-08
申请号：US11845205
申请日：2007-08-27
申请人： Michael D. Jensen , Gil R. Hawley , Max P. McDaniel , Tony Crain , Elizabeth A. Benham , Joel L. Martin , Qing Yang
发明人： Michael D. Jensen , Gil R. Hawley , Max P. McDaniel , Tony Crain , Elizabeth A. Benham , Joel L. Martin , Qing Yang
IPC分类号： C08F4/02 , C08F4/6392 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65925 , C08F4/65927 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/65912 , C08F4/65916 , C08F4/6492 , C08F210/14
摘要： This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, typically using a supported catalyst composition. In one aspect, this invention encompasses precontacting a metallocene with an olefin or alkyne monomer and an organoaluminum compound, prior to contacting this mixture with the acidic activator-support.
摘要翻译： 本发明涉及烯烃聚合催化剂组合物领域，以及烯烃聚合和共聚的方法，通常使用负载型催化剂组合物。 在一个方面，本发明包括在使该混合物与酸性活化剂 - 载体接触之前预先接触茂金属与烯烃或炔单体和有机铝化合物。
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公开(公告)号：US07294599B2
公开(公告)日：2007-11-13
申请号：US10877039
申请日：2004-06-25
申请人： Michael D. Jensen , Gil R. Hawley , Max P. McDaniel , Tony Crain , Elizabeth A. Benham , Joel L. Martin , Qing Yang
发明人： Michael D. Jensen , Gil R. Hawley , Max P. McDaniel , Tony Crain , Elizabeth A. Benham , Joel L. Martin , Qing Yang
IPC分类号： C08F4/02 , C08F4/6392
CPC分类号： C08F10/00 , C08F4/65925 , C08F4/65927 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/65912 , C08F4/65916 , C08F4/6492 , C08F210/14
摘要： This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, typically using a supported catalyst composition. In one aspect, this invention encompasses precontacting a metallocene with an olefin or alkyne monomer and an organoaluminum compound, prior to contacting this mixture with the acidic activator-support.
摘要翻译： 本发明涉及烯烃聚合催化剂组合物领域，以及烯烃聚合和共聚的方法，通常使用负载型催化剂组合物。 在一个方面，本发明包括在使该混合物与酸性活化剂 - 载体接触之前预先接触茂金属与烯烃或炔单体和有机铝化合物。
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5.发明授权公开(公告)号：US06653416B2
公开(公告)日：2003-11-25
申请号：US10085931
申请日：2002-02-28
申请人： Max P. McDaniel , Kathy S. Collins , James L. Smith , Elizabeth A. Benham , Marvin M. Johnson , Anthony P. Eaton , Michael D. Jensen , Joel L. Martin , Gil R. Hawley
发明人： Max P. McDaniel , Kathy S. Collins , James L. Smith , Elizabeth A. Benham , Marvin M. Johnson , Anthony P. Eaton , Michael D. Jensen , Joel L. Martin , Gil R. Hawley
IPC分类号： C08F442
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65925 , C08F110/02 , Y10S526/943 , C08F4/025 , C08F4/65916 , C08F2500/12 , C08F2500/03
摘要： This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises a post-contacted organometal compound, a post-contacted organoaluminum compound, and a post-contacted fluorided solid oxide compound.
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公开(公告)号：US06613852B2
公开(公告)日：2003-09-02
申请号：US10037016
申请日：2001-12-21
申请人： Max P. McDaniel , Kathy S. Collins , Anthony P. Eaton , Elizabeth A. Benham , Michael D. Jensen , Joel L. Martin , Gil R. Hawley
发明人： Max P. McDaniel , Kathy S. Collins , Anthony P. Eaton , Elizabeth A. Benham , Michael D. Jensen , Joel L. Martin , Gil R. Hawley
IPC分类号： C08F442
CPC分类号： B01J31/143 , B01J21/12 , B01J27/125 , B01J31/1608 , B01J31/1616 , B01J31/2295 , B01J31/38 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , Y10S526/943 , C08F4/65916 , C08F4/025
摘要： This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises a post-contacted organometal compound, a post-contacted organoaluminum compound, and a post-contacted fluorided silica-alumina.
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7.发明授权Organometal catalyst compositions with solid oxide supports treated with fluorine and boron 有权具有用氟和硼处理的固体氧化物载体的有机金属催化剂组合物公开(公告)号：US06613712B1
公开(公告)日：2003-09-02
申请号：US09448631
申请日：1999-11-24
申请人： Max P. McDaniel , Kathy S. Collins , Elizabeth A. Benham , Anthony P. Eaton , Michael D. Jensen , Joel L. Martin , Gil R. Hawley
发明人： Max P. McDaniel , Kathy S. Collins , Elizabeth A. Benham , Anthony P. Eaton , Michael D. Jensen , Joel L. Martin , Gil R. Hawley
IPC分类号： B01J3100
CPC分类号： C08F4/65916 , C08F4/65912 , C08F4/65925 , C08F110/02 , Y10S526/943
摘要： The invention provides for compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein the composition comprises a post-contacted organometal compound, a post-contacted organoaluminum compound, and a post-contacted solid oxide compound treated with boron and fluoride.
摘要翻译： 本发明提供了可用于聚合至少一种单体以产生聚合物的组合物，其中组合物包含后接触的有机金属化合物，后接触的有机铝化合物和用硼和氟化物处理的后接触固体氧化物 。
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公开(公告)号：US06573344B1
公开(公告)日：2003-06-03
申请号：US09599387
申请日：2000-06-22
IPC分类号： C08F444
CPC分类号： C08F210/06 , C08F4/65912 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F4/025 , C08F4/65916 , C08F2500/12 , C08F2500/15 , C08F2500/18
摘要： A process to produce a propylene polymer is provided. The process comprising contacting at least one organometal compound, at least one organoaluminum compound, at least one treated solid oxide compound, propylene, and ethylene in a polymerization zone under polymerization conditions to produce the propylene polymer.
摘要翻译： 提供了制备丙烯聚合物的方法。 该方法包括在聚合条件下在聚合区中使至少一种有机金属化合物，至少一种有机铝化合物，至少一种经处理的固体氧化物化合物，丙烯和乙烯接触以制备丙烯聚合物。
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公开(公告)号：US06548441B1
公开(公告)日：2003-04-15
申请号：US09427800
申请日：1999-10-27
申请人： Max P. McDaniel , Kathy S. Collins , Anthony P. Eaton , Elizabeth A. Benham , Michael D. Jensen , Joel L. Martin , Gil R. Hawley
发明人： Max P. McDaniel , Kathy S. Collins , Anthony P. Eaton , Elizabeth A. Benham , Michael D. Jensen , Joel L. Martin , Gil R. Hawley
IPC分类号： B01J2116
CPC分类号： B01J31/1616 , B01J21/04 , B01J31/143 , B01J31/2295 , B01J31/28 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F110/02 , Y10S526/943 , C08F4/65916 , C08F4/70 , C08F4/02
摘要： This invention provides a catalyst composition for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises an organometal compound, an organoaluminum compound, and a treated solid oxide compound comprising nickel, a halogen, and a solid oxide compound.
摘要翻译： 本发明提供了用于使至少一种单体聚合以制备聚合物的催化剂组合物，其中所述催化剂组合物包含有机金属化合物，有机铝化合物和包含镍，卤素和固体氧化物化合物的经处理的固体氧化物化合物。
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10.发明授权Polymerization catalyst compositions and processes to produce polymers and bimodal polymers 有权聚合催化剂组合物和生产聚合物和双峰聚合物的方法公开(公告)号：US06528448B1
公开(公告)日：2003-03-04
申请号：US09561306
申请日：2000-04-28
申请人： Michael D. Jensen , Max P. McDaniel , Elizabeth A. Benham , Anthony P. Eaton , Joel L. Martin , Gil R. Hawley , Tony R. Crain , Martha J. Tanner
发明人： Michael D. Jensen , Max P. McDaniel , Elizabeth A. Benham , Anthony P. Eaton , Joel L. Martin , Gil R. Hawley , Tony R. Crain , Martha J. Tanner
IPC分类号： C08F464
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F210/16 , C08F2410/01 , Y10S526/943 , C08F4/6592 , C08F2500/12 , C08F210/14 , C08F2500/05
摘要： A process to produce a first catalyst composition is provided. The process comprises contacting at least one first organometal compound, oxygen bridged mono-cyclopentadienyl transition metal dimer, and at least one activator to produce the first catalyst composition. The activator is selected from the group consisting of aluminoxanes, fluoro-organo borates, and treated solid oxide components in combination with at least one organoaluminum compound. In another embodiment of this invention, a process to produce a second catalyst composition for producing bimodal polymers is provided. The process comprises contacting at least one first organometal compound, at least one activator, and at least one second organometal compound to produce the second catalyst composition. The first and second catalyst compositions are also provided as well as polymerization processes using these compositions to produce polymers.
摘要翻译： 提供了生产第一催化剂组合物的方法。 该方法包括使至少一种第一有机金属化合物，氧桥连的单环戊二烯基过渡金属二聚物和至少一种活化剂接触以产生第一催化剂组合物。 活化剂选自铝氧烷，氟代有机硼酸盐和经处理的固体氧化物组分与至少一种有机铝化合物的组合。 在本发明的另一个实施方案中，提供了制备用于生产双峰聚合物的第二催化剂组合物的方法。 该方法包括使至少一种第一有机金属化合物，至少一种活化剂和至少一种第二有机金属化合物接触以产生第二催化剂组合物。 还提供了第一和第二催化剂组合物以及使用这些组合物生产聚合物的聚合方法。
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