公开(公告)号：US4188336A

公开(公告)日：1980-02-12

申请号：US903270

申请日：1978-05-05

Applicant: Clarence D. Chang ,  William H. Lang

Inventor： Clarence D. Chang ,  William H. Lang

IPC: B01J23/26 ,  B01J29/48 ,  C07C1/04 ,  C07C15/02

CPC classification number: C07C1/0445 ,  B01J23/26 ,  B01J29/48 ,  C07C2523/06 ,  C07C2523/26 ,  C07C2529/04 ,  C07C2529/06 ,  C07C2529/076

Abstract: Synthesis gas is converted to aromatic hydrocarbons over an intimate mixture of catalysts comprising a first component of ZnO-Cr.sub.2 O.sub.3 mixed catalyst, characterized by catalytic activity for the reduction of hydrogen of carbon monoxide, wherein the Zn:Cr atomic ratio is less than about 4:1 and a second component selected from a selective class of acidic crystalline alumino-silicates having a silica:alumina ratio greater than 12:1 and a pore dimension greater than about 5 Angstroms.

Abstract translation: 合成气体在包含ZnO-Cr 2 O 3混合催化剂的第一组分的催化剂的紧密混合物中转化成芳族烃，其特征在于还原一氧化碳的氢气的催化活性，其中Zn:Cr原子比小于约4： 1和选自二氧化硅：氧化铝比大于12:1且孔尺寸大于约5埃的酸性结晶铝硅酸盐的选择性类别的第二组分。

公开(公告)号：US4086262A

公开(公告)日：1978-04-25

申请号：US733982

申请日：1976-10-20

Applicant: Clarence D. Chang ,  William H. Lang ,  Anthony J. Silvestri

Inventor： Clarence D. Chang ,  William H. Lang ,  Anthony J. Silvestri

IPC: B01J29/46 ,  C07C1/04 ,  C07C9/14 ,  C07C1/16

CPC classification number: C07C1/044 ,  B01J29/46 ,  C07C1/043 ,  C07C1/0435 ,  C07C2523/06 ,  C07C2523/12 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2529/40 ,  Y02P20/52 ,  Y10S208/95

Abstract: Contacting a mixture of carbon monoxide and hydrogen with an intimate mixture of a carbon monoxide reduction catalyst, such as a Fischer-Tropsch catalyst or a methanol synthesis catalyst, and an acidic crystalline aluminosilicate having a pore dimension greater than about 5 Angstroms to produce hydrocarbon mixtures useful in the manufacture of heating fuels, high octane gasoline, aromatic hydrocarbons, and chemicals intermediates.

Abstract translation: 将一氧化碳和氢气的混合物与一氧化碳还原催化剂如费 - 托催化剂或甲醇合成催化剂的紧密混合物和孔尺寸大于约5埃的酸性结晶硅铝酸盐接触以产生烃混合物 可用于制造加热燃料，高辛烷值汽油，芳烃和化学品中间体。

公开(公告)号：US06538162B2

公开(公告)日：2003-03-25

申请号：US09772775

申请日：2001-01-30

Applicant: Clarence D. Chang ,  Jose G. Santiesteban

Inventor： Clarence D. Chang ,  Jose G. Santiesteban

IPC: C07C4109

CPC classification number: C07C41/09 ,  C07C27/16 ,  C07C29/12 ,  C07C41/01 ,  C07C303/24 ,  C07C305/06 ,  C07C31/04 ,  C07C43/043 ,  C07C43/06 ,  C07C43/04

Abstract: The invention discloses a method for converting alkane to oxygenate which comprises the following steps: (i) contacting an alkane-containing gas with non-metal, regenerable, electrophile ions in a concentrated sulfuric acid medium under conditions sufficient to provide electrophilicly activated alkane and reduced electrophile ions; (ii) contacting said electrophilicly activated alkane with sulfate to form a sulfate ester; (iii) exposing the sulfate ester to hydrolyzing conditions sufficient to convert it to oxygenate; and (iv) collecting the oxygenate.

公开(公告)号：US06365767B1

公开(公告)日：2002-04-02

申请号：US09322880

申请日：1999-08-20

Applicant: Clarence D. Chang ,  Zhaozhong Jiang ,  Rene B. LaPierre ,  Suzanne E. Schramm ,  Hye Kyung Cho Timken

Inventor： Clarence D. Chang ,  Zhaozhong Jiang ,  Rene B. LaPierre ,  Suzanne E. Schramm ,  Hye Kyung Cho Timken

IPC: C07C6996

CPC classification number: C07C68/065 ,  C07C69/96

Abstract: A method is provided for co-producing dialkyl carbonate and alkanediol by reacting alkylene carbonate with alkanol in the presence of a zeolite catalyst which contains alkali metal, alkaline earth metal, or a combination thereof present in excess of a stoichiometric amount.

Abstract translation: 提供了一种通过在含有超过化学计量的碱金属，碱土金属或其组合的沸石催化剂存在下使碳酸亚烷基酯与链烷醇反应来共同生产碳酸二烷基酯和链烷二醇的方法。

公开(公告)号：US06258962B1

公开(公告)日：2001-07-10

申请号：US09332725

申请日：1999-06-14

Applicant: J. Scott Buchanan ,  Clarence D. Chang ,  Robert A. Crane ,  Lorenzo C. DeCaul ,  Zhaozhong Jiang ,  Jose G. Santiesteban ,  Hye Kyung Cho Timken

Inventor： J. Scott Buchanan ,  Clarence D. Chang ,  Robert A. Crane ,  Lorenzo C. DeCaul ,  Zhaozhong Jiang ,  Jose G. Santiesteban ,  Hye Kyung Cho Timken

IPC: C07D32100

CPC classification number: C07D319/06 ,  C07D317/36

Abstract: A process for the synthesis of alkylene carbonates, such as ethylene carbonate, by reacting alkylene oxides with carbon dioxide in the presence of a porous solid support catalyst containing an alkali or alkaline earth metal component.

Abstract translation: 在含有碱金属或碱土金属组分的多孔固体载体催化剂存在下，通过使环氧烷与二氧化碳反应来合成碳酸亚烷基酯如碳酸亚乙酯的方法。

公开(公告)号：US6106594A

公开(公告)日：2000-08-22

申请号：US235527

申请日：1999-01-22

Applicant: Clarence D. Chang ,  Suzanne Elaine Schramm ,  Clarence Edward Chase

Inventor： Clarence D. Chang ,  Suzanne Elaine Schramm ,  Clarence Edward Chase

IPC: B01D53/14 ,  B01D47/06

CPC classification number: B01D53/1493 ,  B01D53/1487 ,  Y02C10/06

Abstract: The present invention provides a method for selectively recovering methane from a gas stream including carbon dioxide using a bisglycoluril derivative to selectively extract the methane.

Abstract translation: 本发明提供了一种使用双甘脲衍生物从包括二氧化碳的气流中选择性回收甲烷以选择性提取甲烷的方法。

公开(公告)号：US5726114A

公开(公告)日：1998-03-10

申请号：US516435

申请日：1995-08-17

Applicant: Clarence D. Chang ,  John D. Lutner ,  Sharon B. McCullen ,  Paul G. Rodewald ,  David S. Shihabi

Inventor： Clarence D. Chang ,  John D. Lutner ,  Sharon B. McCullen ,  Paul G. Rodewald ,  David S. Shihabi

IPC: B01J29/40 ,  B01J31/02 ,  B01J37/08 ,  C07C6/12 ,  B01J29/06

CPC classification number: C07C6/123 ,  B01J29/40 ,  B01J37/086 ,  B01J2229/12 ,  B01J2229/32 ,  B01J2229/42 ,  C07C2529/00

Abstract: A method of preparing a modified catalytic molecular sieve for enhanced shape selective hydrocarbon conversions in which a catalytic molecular sieve is modified by being exposed to at least one ex situ selectivation sequence, each sequence including an impregnation of the molecular sieve with a selectivating agent in an aqueous emulsion and a subsequent calcination of the impregnated molecular sieve. The selectivating agent compositions for the ex situ selectivation method are also described, including the selectivating agents, the surfactants, and the aqueous components. Also, a method for moderate steaming of the ex situ selectivated molecular sieve. Also a method for in situ trim-selectivating the ex situ selectivated catalytic molecular sieve. Also described is the modified catalytic molecular sieve modified by this method. Also described is a process for shape selective hydrocarbon conversion comprising contacting a hydrocarbon feedstream under conversion conditions with the modified catalytic molecular sieve.

Abstract translation: 一种制备用于增强形状选择性烃转化的改性催化分子筛的方法，其中催化分子筛通过暴露于至少一种非原位选择活性序列来修饰，每个序列包括用选择性试剂浸渍分子筛 水性乳液，随后煅烧浸渍的分子筛。 还描述了用于异位选择方法的选择性试剂组合物，包括选择性试剂，表面活性剂和水性组分。 另外，用于非原位选择性分子筛的中等蒸度的方法。 还有一种用于原位选择活化的催化分子筛的原位选择方法。 还描述了通过该方法改性的改性催化分子筛。 还描述了一种用于形状选择性烃转化的方法，其包括在转化条件下使烃进料流与改性的催化分子筛接触。

公开(公告)号：US5719097A

公开(公告)日：1998-02-17

申请号：US679238

申请日：1996-07-22

Applicant: Clarence D. Chang ,  Jose G. Santiesteban ,  David L. Stern

Inventor： Clarence D. Chang ,  Jose G. Santiesteban ,  David L. Stern

IPC: B01J21/06 ,  B01J23/24 ,  B01J23/28 ,  B01J23/30 ,  B01J23/652 ,  C01G25/02 ,  C07C5/27 ,  C10G67/04 ,  B01J23/00 ,  B01J23/40 ,  B01J23/42

CPC classification number: C07C5/2724 ,  B01J21/06 ,  B01J21/066 ,  B01J23/24 ,  B01J23/28 ,  B01J23/30 ,  B01J23/652 ,  B01J23/6527 ,  C01G25/02 ,  C07C5/2791 ,  C01P2002/54 ,  C10G2400/10

Abstract: There is provided a catalyst comprising a hydrogenation/dehydrogenation component, such as a noble metal, and an acidic solid component comprising a Group IVB metal oxide modified with an oxyanion of a Group VIB metal. An example of this catalyst is zirconia, modified with tungstate and platinum. There is also provided a method for preparing this catalyst. This catalyst may be used, for example, to isomerize C.sub.4 to C.sub.8 paraffins. The feed to this paraffin isomerization reaction may, optionally, include cyclic hydrocarbons, such as benzene or cyclohexane, which may undergo ring opening reactions during the course of the isomerization reaction.

Abstract translation: 提供了包含氢化/脱氢组分如贵金属的催化剂和包含用VIB族金属的氧阴离子改性的IVB族金属氧化物的酸性固体组分。 该催化剂的实例是用钨酸盐和铂改性的氧化锆。 还提供了制备该催化剂的方法。 该催化剂可用于例如使C4至C8链烷烃异构化。 这种链烷烃异构化反应的进料可以任选地包括在异构化反应过程中可能经历开环反应的环烃，例如苯或环己烷。

公开(公告)号：US5349113A

公开(公告)日：1994-09-20

申请号：US22205

申请日：1993-02-25

Applicant: Clarence D. Chang ,  Paul G. Rodewald

Inventor： Clarence D. Chang ,  Paul G. Rodewald

IPC: B01J29/40 ,  B01J31/02 ,  C07C6/12 ,  C07C5/52

CPC classification number: C07C6/123 ,  B01J29/40 ,  B01J2229/12 ,  B01J2229/123 ,  B01J2229/32 ,  B01J2229/42

Abstract: A process for a shape selective hydrocarbon conversion such as toluene disproportionation involves contacting a reaction stream under conversion conditions with a catalytic molecular sieve which has been pre-selectivated and concurrently activated by contact with a substantially aqueous solution of an organosilicon compound. The invention also includes a method for concurrently preselectivating and activating a catalyst and the shape selectivated, activated catalyst which results from this method.

Abstract translation: 形成选择性碳氢化合物转化的方法如甲苯歧化过程包括使转化条件下的反应物流与催化分子筛接触，所述催化分子筛已经预选择并通过与基本上有机硅化合物的水溶液接触同时活化。 本发明还包括同时预选择和活化催化剂和由该方法产生的形状选择活化的催化剂的方法。

公开(公告)号：US5288927A

公开(公告)日：1994-02-22

申请号：US11574

申请日：1993-02-01

Applicant: Clarence D. Chang ,  Stuart D. Hellring

Inventor： Clarence D. Chang ,  Stuart D. Hellring

IPC: C07C37/14 ,  C07C37/16

CPC classification number: C07C37/14 ,  C07C37/16

Abstract: There is provided a process for reacting phenol with butene or butanol over fairly large-pore zeolites to give butylphenol with high para-selectivity. Particular zeolites for use in this reaction include ZSM-12 and zeolite beta. A particular butene or butanol reactant is isobutanol. The product of this reaction may have a high content of the mono-alkylated, tert-butyl product.

Abstract translation: 提供了在相当大孔沸石上使苯酚与丁烯或丁醇反应以产生具有高对位选择性的丁基苯酚的方法。 用于该反应的特定沸石包括ZSM-12和β沸石。 特殊的丁烯或丁醇反应物是异丁醇。 该反应的产物可以具有高含量的单烷基化叔丁基产物。