公开(公告)号：US20110026034A1

公开(公告)日：2011-02-03

申请号：US12672535

申请日：2008-08-09

申请人： Guenter Gauglitz ,  Guenther Proll ,  Florian Proell ,  Lutz Steinle ,  Markus Schubert

发明人： Guenter Gauglitz ,  Guenther Proll ,  Florian Proell ,  Lutz Steinle ,  Markus Schubert

IPC分类号： G01J3/45 ,  H01L31/0376 ,  H01L31/0368

CPC分类号： G01N33/54373 ,  G01N21/45 ,  G01N21/8422 ,  G01N33/551

摘要： The invention relates to a carrier for a thin layer and a method for the analysis of molecular interactions on and/or in such a thin layer. A thin layer disposed on a carrier is illuminated with electromagnetic radiation from at least one radiation source and a reflected radiation part on boundary surfaces of the thin layer is detected by means of an optoelectronic converter that converts the detected radiation into a frequency- and intensity-dependant photocurrent. A reading voltage is applied to the optoelectronic converter. By changing the reading voltage, the spectral sensitivity of the optoelectronic converter is varied such that a substantially constant photocurrent is obtained. Alternatively or in addition to varying the spectral sensitivity by changing the reading voltage, the reflected radiation part is detected with an optoelectronic converter that is designed as a sensor layer in the carrier. The carrier is particularly characterized in that it comprises a substrate on which at least one sensor layer with optoelectronic properties is disposed.

摘要翻译： 本发明涉及一种用于薄层的载体和用于分析在这种薄层上和/或其中的分子相互作用的方法。 设置在载体上的薄层被来自至少一个辐射源的电磁辐射照射，并且通过光电转换器检测薄层边界表面上的反射辐射部分，该光电转换器将检测到的辐射转换成频率和强度 - 依赖光电流。 读取电压被施加到光电转换器。 通过改变读取电压，改变光电转换器的光谱灵敏度，使得获得基本恒定的光电流。 或者或通过改变读取电压来改变光谱灵敏度，反射的辐射部分被设计为载体中的传感器层的光电转换器来检测。 载体的特征在于其包括其上设置有至少一个具有光电特性的传感器层的基底。

公开(公告)号：US07879221B2

公开(公告)日：2011-02-01

申请号：US12300902

申请日：2007-05-11

申请人： Hermann Pütter ,  Markus Schubert ,  Ingo Richter ,  Ulrich Müller ,  Natalia Trukhan

发明人： Hermann Pütter ,  Markus Schubert ,  Ingo Richter ,  Ulrich Müller ,  Natalia Trukhan

IPC分类号： C25B3/12 ,  C07F15/00 ,  C07F3/00

CPC分类号： C25B3/12

摘要： The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode comprising the metal corresponding to at least one metal ion in a reaction medium in the presence of at least one first organic compound which is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S to form a reaction intermediate comprising the at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with at least one second organic compound which coordinates to the at least one metal ion, with the second organic compound being derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.

摘要翻译： 本发明涉及一种制备多孔金属有机骨架的方法，所述多孔金属有机骨架包括与至少一种金属离子配位的至少两种有机化合物，其包括以下步骤：（a）至少一个阳极的氧化，所述至少一个阳极包含对应于至少一种金属 在至少一种第一有机化合物存在下的反应介质中，所述第一有机化合物是任选取代的单环，双环或多环饱和或不饱和烃，其中至少两个环碳已经被选自N，O 和S形成包含所述至少一种金属离子和所述第一有机化合物的反应中间体; 和（b）将反应中间体在规定温度下与至少一种与至少一种金属离子配位的第二有机化合物反应，第二有机化合物衍生自二羧酸，三羧酸或四羧酸。

公开(公告)号：US20090281341A1

公开(公告)日：2009-11-12

申请号：US12297294

申请日：2007-04-17

申请人： Markus Schubert ,  Ulrich Müller ,  Stefan Marx

发明人： Markus Schubert ,  Ulrich Müller ,  Stefan Marx

IPC分类号： C07F7/00

CPC分类号： C07C51/412 ,  C07C29/70 ,  C07F7/003 ,  C07C63/28 ,  C07C63/14

摘要： The present invention relates to a porous metal-organic framework material comprising at least one at least bidentate organic compound which is bound to at least one metal ion by coordination, the at least one metal ion being zirconium, and the at least one at least bidentate organic compound being derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid. In addition, the invention relates to methods for production thereof and also use thereof.

摘要翻译： 多孔金属 - 有机骨架材料本发明涉及多孔金属 - 有机骨架材料，其包含至少一种至少二齿有机化合物，其通过配位与至少一种金属离子结合，所述至少一种金属离子是锆，以及所述至少一种至少二齿 有机化合物衍生自二羧酸，三羧酸或四羧酸。 此外，本发明涉及其生产方法及其用途。

公开(公告)号：US20090198079A1

公开(公告)日：2009-08-06

申请号：US12297289

申请日：2007-04-18

申请人： Markus Schubert ,  Ulrich Muller ,  Stefan Marx

发明人： Markus Schubert ,  Ulrich Muller ,  Stefan Marx

IPC分类号： C07F7/00

CPC分类号： C07C51/412 ,  C07F7/003 ,  C07C63/28

摘要： The present invention relates to a process for preparing a porous metal organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, which comprises the step reaction of at least one metal compound with at least one at least bidentate organic compound which can coordinate to the metal, with the metal ion of the at least one metal compound being selected from the group of metals consisting of titanium, zirconium and hafnium and the at least one at least bidentate organic compound being derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid, wherein the metal compound is an inorganic salt.

摘要翻译： 本发明涉及一种制备多孔金属有机骨架的方法，其包含与至少一种金属离子配位的至少一种至少二齿的有机化合物，其包括至少一种金属化合物与至少一种至少二齿有机物 可与金属配位的化合物，所述至少一种金属化合物的金属离子选自钛，锆和铪组成的金属组，所述至少一种至少二齿有机化合物衍生自二羧酸，三羧酸 或四羧酸，其中金属化合物是无机盐。

公开(公告)号：US20090183996A1

公开(公告)日：2009-07-23

申请号：US12300942

申请日：2007-05-11

申请人： Ingo Richter ,  Markus Schubert ,  Ulrich Müller

发明人： Ingo Richter ,  Markus Schubert ,  Ulrich Müller

IPC分类号： C25B3/02

CPC分类号： C07D233/54 ,  B01J20/226 ,  C07D235/22 ,  C25B3/12

摘要： Processes comprising: (i) providing an anode comprising zinc; and (ii) oxidizing the anode in a reaction medium in the presence of at least one organic compound to form a porous metal organic framework comprising the least one organic compound coordinated to at least one zinc ion; wherein the at least one organic compound comprises a ring system selected from the group consisting of compounds corresponding to the following structures wherein the ring system optionally bears one or more substituents selected independently from the group consisting of halogens, C1-6-alkyls, phenyl, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O—C1-6-alkyls, and wherein each C1-6-alkyl and phenyl substituent may independently and optionally bear one or more substituents selected independently from the group consisting of halogens, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O—C1-6-alkyls.

摘要翻译： 方法包括：（i）提供包含锌的阳极; 和（ii）在至少一种有机化合物的存在下在反应介质中氧化阳极以形成包含与至少一种锌离子配位的至少一种有机化合物的多孔金属有机骨架; 其中所述至少一种有机化合物包括选自对应于以下结构的化合物的环系统，其中所述环系统任选地带有一个或多个独立地选自卤素，C 1-6 - 烷基，苯基， NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，O-苯基和O-C 1-6 - 烷基，其中每个C 1-6 - 烷基和苯基取代基可以独立地和任选地 含有一个或多个独立地选自卤素，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，O-苯基和O-C 1-6 - 烷基的取代基。

公开(公告)号：US20080188677A1

公开(公告)日：2008-08-07

申请号：US11996976

申请日：2006-08-16

申请人： Markus Schubert ,  Ulrich Muller ,  Hendrick Mattenheimer ,  Markus Tonigold

发明人： Markus Schubert ,  Ulrich Muller ,  Hendrick Mattenheimer ,  Markus Tonigold

IPC分类号： C07F5/06

CPC分类号： C07F5/069 ,  C01B3/001 ,  C01B3/0015 ,  C01B3/0026 ,  C07C51/418 ,  Y02E60/327 ,  Y02E60/328 ,  C07C63/307

摘要： The present invention relates to a porous metal-organic framework comprising AlIII and at least one at least bidentate compound, wherein the at least one at least bidentate organic compound is a six-membered aromatic hydrocarbon ring A in which one or more ring carbons may be replaced by nitrogen and which has three substituents X and optionally one or more substituents selected from the group consisting of R, NRR′, OR, SR, F, Cl and Br, where R, R′ are each, independently of one another, hydrogen, methyl which may optionally be substituted by one or more fluorine atoms or ethyl which may optionally be substituted by one or more fluorine atoms and each X is, independently of the others, C(═O)O−, C(═S)O−, C(═O)S−, C(═S)S− or a protonated form thereof. The invention further provides a process for preparing it and provides for the use of the new porous metal-organic framework.

摘要翻译： 本发明涉及包含III-III族和至少一种至少二齿化合物的多孔金属 - 有机骨架，其中至少一种至少二齿的有机化合物是六元芳烃环A 其中一个或多个环碳可以被氮替代并且具有三个取代基X和任选的一个或多个选自R，NRR'，OR，SR，F，Cl和Br的取代基，其中R，R'是 各自独立地为氢，可以任选被一个或多个氟原子取代的甲基或可任选被一个或多个氟原子取代的乙基，并且每个X独立地为C（-O）O C（ - ）O - ， - （C（O）S） - ， - （C（O） / SUP>或其质子化形式。 本发明还提供了一种制备该方法并提供了新的多孔金属 - 有机骨架的用途。

公开(公告)号：US20070191212A1

公开(公告)日：2007-08-16

申请号：US10590978

申请日：2005-02-24

申请人： Markus Schubert ,  Jurgen Stephan ,  Volker Bohm ,  Andreas Brodhagen ,  Frank Poplow ,  Christian Weichert ,  Holger Borchert

发明人： Markus Schubert ,  Jurgen Stephan ,  Volker Bohm ,  Andreas Brodhagen ,  Frank Poplow ,  Christian Weichert ,  Holger Borchert

IPC分类号： B01J35/08

CPC分类号： B01J35/10 ,  B01J21/04 ,  B01J23/36 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0018 ,  C07C5/333 ,  C07C11/02 ,  C07C11/08

摘要： Supported catalyst comprising a support (S) in which Al2O3 is present in a proportion of at least 75% by weight and rhenium compounds as active component (A), wherein the maximum of the distribution function of the pore diameters in the mesopore range is at from 0.008 to 0.050 μm.

摘要翻译： 含有其中Al 2 O 3 N 3的载体（S）的负载型催化剂以至少75重量％的比例存在，铼化合物作为活性组分（A）， 其中中孔范围内孔径分布函数的最大值为0.008至0.050μm。

公开(公告)号：US20070135648A1

公开(公告)日：2007-06-14

申请号：US10589049

申请日：2005-02-08

申请人： Heiko Urtel ,  Markus Rosch ,  Andrea Haunert ,  Markus Schubert

发明人： Heiko Urtel ,  Markus Rosch ,  Andrea Haunert ,  Markus Schubert

IPC分类号： C07D307/02 ,  C07C27/04

CPC分类号： C07C29/149 ,  C07B41/02 ,  C07B53/00 ,  C07B2200/07 ,  C07C213/00 ,  C07D307/33 ,  C07C215/08 ,  C07C215/10 ,  C07C215/18 ,  C07C215/28 ,  C07C31/22 ,  C07C31/207 ,  C07C31/205 ,  C07C31/36 ,  C07C31/20 ,  C07C31/12

摘要： The present invention relates to a process for preparing optically active hydroxy-, alkoxy-, amino-, alkyl-, aryl- or chlorine-substituted alcohols or hydroxy carboxylic acids having from 3 to 25 carbon atoms or their acid derivatives or cyclization products by hydrogenating the correspondingly substituted optically active mono- or dicarboxylic acids or their acid derivatives in the presence of a catalyst whose active component consists of rhenium or of rhenium and comprises at least one further element having an atomic number of from 22 to 83, with the provisos that a. the at least one further element having an atomic number of from 22 to 83 is not ruthenium and b. in the case of the preparation of optically active 2-amino-, 2-chloro-, 2-hydroxy- and 2-alkoxy-1-alkanols by catalytically hydrogenating corresponding optically active 2-aminocarboxylic acids, 2-chlorocarboxylic acids, 2-hydroxycarboxylic acids and 2-alkoxycarboxylic acids or their acid derivatives, the at least one further element having an atomic number of from 22 to 83 is not palladium or platinum.

摘要翻译： 本发明涉及通过氢化制备光学活性羟基，烷氧基 - ，氨基 - ，烷基 - ，芳基 - 或氯取代的醇或具有3至25个碳原子的羟基羧酸或其酸衍生物或环化产物的方法 相应地取代的光学活性单羧酸或二羧酸或其酸衍生物在其活性组分由铼或铼组成的催化剂存在下，并且包含至少一种原子序数为22至83的另外的元素，条件是 一个。 原子序数为22〜83的至少一个以上的元素不是钌，而是b。 在通过催化氢化相应的光学活性2-氨基羧酸，2-氯羧酸，2-羟基羧酸的2-氨基 - ，2-氯 - ，2-羟基 - 和2-烷氧基-1-链烷醇的制备 酸和2-烷氧基羧酸或其酸衍生物，原子序数为22至83的至少一种另外的元素不是钯或铂。

公开(公告)号：US20060183627A1

公开(公告)日：2006-08-17

申请号：US10547293

申请日：2004-02-16

申请人： Jurgen Stephan ,  Markus Schubert ,  Christian Weichert ,  Wilhelm Ruppel ,  Peter Resch ,  Soeren Zimdahl ,  Frank Mrzena ,  Andreas Molitor ,  Stefan Berg ,  Mathias Fohrmann

发明人： Jurgen Stephan ,  Markus Schubert ,  Christian Weichert ,  Wilhelm Ruppel ,  Peter Resch ,  Soeren Zimdahl ,  Frank Mrzena ,  Andreas Molitor ,  Stefan Berg ,  Mathias Fohrmann

IPC分类号： B01J38/12

CPC分类号： B01J23/92 ,  B01J23/36 ,  B01J38/12 ,  B01J38/14 ,  C07C6/04 ,  Y02P20/584

摘要： Method of regenerating an Re2O7-doped supported catalyst which has been deactivated by use in the metathesis of a hydrocarbon mixture comprising C2-C6-olefins (C2-6= feed) (deactivated catalyst), which comprises treating the deactivated catalyst with an inert gas (regeneration gas K1) at from 400 to 800° C. and subsequently treating the deactivated catalyst which has been pretreated with regeneration gas K1 with an oxygen-containing gas (regeneration gas K2).

摘要翻译： 通过在包含C 2 -C 6烷基的烃混合物的复分解中使用已经失活的Re 2 O 2 O 7重掺合载体催化剂的再生方法， C 6 - 6 - 烯烃（C 2-6）进料）（失活催化剂），其包括用惰性气体处理失活的催化剂（再生 气体K 1），然后用含氧气体（再生气体K 2）处理已经用再生气体K 1预处理的失活催化剂。

公开(公告)号：US20060069416A1

公开(公告)日：2006-03-30

申请号：US11194017

申请日：2005-07-29

申请人： Wilfried Nisch ,  Martin Stelzle ,  Heinz-Gerhard Graf ,  Eberhart Zrenner ,  Markus Schubert ,  Hugo Haemmerle

发明人： Wilfried Nisch ,  Martin Stelzle ,  Heinz-Gerhard Graf ,  Eberhart Zrenner ,  Markus Schubert ,  Hugo Haemmerle

IPC分类号： A61N1/18

CPC分类号： A61N1/36046

摘要： The present invention relates to a retina implant for the functional electrostimulation of a retina as a function of incident light. The retina implant has a stimulation chip that is designed to be implanted in the area of the retina of an eye. It further includes a radiation receiver that provides energy for the stimulation chip as a function of invisible radiation that occurs. In accordance with one aspect of the present invention, the radiation receiver is designed so as to be implanted in the area of the eye in a fashion spatially separated from the stimulation chip. The stimulation chip also has decoupling means in order to separate invisible scattered radiation from impinging visible light.

摘要翻译： 本发明涉及视网膜植入物，用于根据入射光的功能性电刺激视网膜。 视网膜植入物具有被设计成植入眼睛视网膜区域的刺激芯片。 它还包括辐射接收器，其作为发生的不可见辐射的函数为刺激芯片提供能量。 根据本发明的一个方面，辐射接收器设计成以与刺激芯片空间分离的方式植入眼睛区域。 刺激芯片还具有去耦装置，以便将不可见的散射辐射与入射的可见光分开。