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    FLUOROPOLYMER DISPERSION AND METHOD FOR MAKING THE SAME
    81.
    发明申请
    FLUOROPOLYMER DISPERSION AND METHOD FOR MAKING THE SAME 有权
    氟聚合物分散体及其制备方法

    公开(公告)号：US20070149695A1

    公开(公告)日：2007-06-28

    申请号：US11275331

    申请日：2005-12-23

    申请人： Klaus Hintzer ,  Harald Kaspar ,  Helmut Traunspurger ,  Tilman Zipplies

    发明人： Klaus Hintzer ,  Harald Kaspar ,  Helmut Traunspurger ,  Tilman Zipplies

    IPC分类号： D06M15/277

    CPC分类号： D06M15/277 ,  C08F14/18 ,  C08F2/24

    摘要： A method for polymerizing, in an aqueous medium, at least one fluorinated monomer in the presence of a non-copolymerizable, non-fluorinated surfactant. The surfactant is generally selected from a non-ionic surfactant, a primary anionic surfactant, or a combination thereof. Fluorinated surfactants are not utilized. The resulting partially fluorinated polymer in the aqueous medium is either a semi-crystalline polymer or a crystalline polymer.

    摘要翻译： 一种在水性介质中在不可共聚的非氟化表面活性剂存在下聚合至少一种氟化单体的方法。 表面活性剂通常选自非离子表面活性剂，初级阴离子表面活性剂或其组合。 不使用氟化表面活性剂。 在水性介质中得到的部分氟化聚合物是半结晶聚合物或结晶聚合物。

    METHOD OF REMOVING FLUORINATED CARBOXYLIC ACID FROM AQUEOUS LIQUID
    83.
    发明申请
    METHOD OF REMOVING FLUORINATED CARBOXYLIC ACID FROM AQUEOUS LIQUID 有权

    公开(公告)号：US20070027251A1

    公开(公告)日：2007-02-01

    申请号：US11420416

    申请日：2006-05-25

    申请人： Klaus Hintzer ,  Michael Jurgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Lochhaas ,  Andreas Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  George Moore ,  Jay Schulz ,  Richard Flynn

    发明人： Klaus Hintzer ,  Michael Jurgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Lochhaas ,  Andreas Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  George Moore ,  Jay Schulz ,  Richard Flynn

    IPC分类号： C08L27/12

    CPC分类号： C08L27/12 ,  C08L71/02 ,  Y02C20/30 ,  C08L2666/22

    摘要： A method for removing a fluorinated carboxylic acid or salt thereof from an aqueous liquid by contacting the aqueous liquid with adsorbent particles. The fluorinated carboxylic acid or salt thereof is selected from the group consisting of (i) partially fluorinated carboxylic acids or salts thereof corresponding to the general formula: [PF1—O-L1-COO−]iXi+  (I) wherein PF1 represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, L1 represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group with the proviso that when PF1 is fully fluorinated, L1 is a linear partially fluorinated alkylene group or an aliphatic hydrocarbon group, Xi+ represents a cation having the valence i and i is 1, 2 or 3; and (ii) fully fluorinated carboxylic acids or salts thereof corresponding to one of the following general formulas: [PF2—O—(CF2)p—COO−]iXi+  (II) wherein PF2 represents a linear fully fluorinated aliphatic group or a linear fully fluorinated aliphatic group interrupted with one or more oxygen atoms, p is an integer of 2 to 6 and Xi+ and i have the same meaning as in formula (I); or [PF3-(L2)f-O—CF2—COO−]iXi+  (III) wherein PF3 represents a linear fully fluorinated aliphatic group or a linear fully fluorinated aliphatic group interrupted with one or more oxygen atoms, L2 represents —O(CF2)x— wherein x is an integer of 1 or 3 to 6, —(O—CF2CF2)s— wherein s is 1, 2 or 3 or —(OCF2)u— wherein u is an integer of 1 to 6, f is 0 or 1 with the proviso that when f is 0, PF3 represents F(CF2)1— wherein 1 is 1, 2, 4, 5 or 6 and with the proviso that when f is 1 and L2 represents —(O—CF2CF2)s—, PF3 represents CF3 or CF3CF2 and Xi+ and i have the same meaning as in formula (I).

    Treatment of fluorocarbon feedstocks
    84.
    发明授权
    Treatment of fluorocarbon feedstocks 失效
    氟碳原料的处理

    公开(公告)号：US07166198B2

    公开(公告)日：2007-01-23

    申请号：US10203252

    申请日：2001-02-09

    申请人： Izak Jacobus Van Der Walt ,  Klaus Hintzer ,  Werner Schwertfeger ,  Gerald Lee Bauer

    发明人： Izak Jacobus Van Der Walt ,  Klaus Hintzer ,  Werner Schwertfeger ,  Gerald Lee Bauer

    IPC分类号： B01J19/08

    CPC分类号： B01J19/088 ,  B01D5/0096 ,  B01J19/18 ,  B01J19/185 ,  B01J2219/00094 ,  B01J2219/0809 ,  B01J2219/0813 ,  B01J2219/0839 ,  B01J2219/0841 ,  B01J2219/0871 ,  B01J2219/0898 ,  C07C17/361 ,  C07C17/367

    摘要： A method of treating a fluorocarbon feedstock includes generating, in a high temperature zone, an electrical arc between at least one cathode and at least one anode, generating in the high temperature zone and by means of the electrical arc and a plasma gas, a thermal plasma having a tail flame, allowing a fluorocarbon feedstock comprising at least one fluorocarbon compound to form a reactive thermal mixture with the thermal plasma tail flame, with the fluorocarbon compound dissociating into at least one fluorocarbon precursor or reactive species having fewer carbon atoms than the fluorocarbon compound, and cooling the reactive thermal mixture to form, from the fluorocarbon precursor or reactive species, a fluorocarbon product.

    摘要翻译： 一种处理氟碳原料的方法包括在高温区域中在至少一个阴极和至少一个阳极之间产生电弧，在高温区域中产生电弧，并通过电弧和等离子体气体产生热 具有尾焰的等离子体，允许包含至少一种碳氟化合物的碳氟化合物原料与热等离子体尾焰形成反应性热混合物，其中氟碳化合物解离成至少一种氟碳前体或具有比碳氟化碳少的碳原子的反应性物质 并且将反应性热混合物冷却从碳氟化合物前体或反应性物质形成碳氟化合物产物。

    Fluoropolymer for making a fluoroelastomer
    86.
    发明申请
    Fluoropolymer for making a fluoroelastomer 失效
    用于制造含氟弹性体的含氟聚合物

    公开(公告)号：US20060135717A1

    公开(公告)日：2006-06-22

    申请号：US11280880

    申请日：2005-11-16

    申请人： Klaus Hintzer ,  Michael Jurgens ,  Harald Kaspar ,  Kai Lochhaas ,  Werner Schwertfeger

    发明人： Klaus Hintzer ,  Michael Jurgens ,  Harald Kaspar ,  Kai Lochhaas ,  Werner Schwertfeger

    IPC分类号： C08F214/18

    CPC分类号： C08F214/186 ,  C08F214/18

    摘要： The present invention relates to a fluoropolymer comprising repeating units derived from one or more gaseous fluorinated olefins and having one or more cure sites comprising (a) a halogen capable of participating in a peroxide cure reaction or (b) a nitrile group, said fluoropolymer further comprising repeating units derived from one or more fluorinated allyl ethers of the formula: CF2═CF—CF(Z)—O—Rf  (I) wherein Z represents F or CF3 and Rf represents a fluorinated alkyl group that may contain one or more catenary oxygen atoms. The fluoropolymer can be cured to a fluoroelastomer. The invention also relates to a curable fluoroelastomer composition comprising the fluoropolymer and a curing agent.

    摘要翻译： 本发明涉及包含衍生自一种或多种气态氟化烯烃并具有一个或多个固化位点的重复单元的含氟聚合物，其包含（a）能够参与过氧化物固化反应的卤素或（b）腈基，所述含氟聚合物进一步 包含衍生自下列通式的一种或多种氟化烯丙基醚的重复单元：<？in-line-formula description =“In-line Formulas”end =“lead”？> CF 2 -CF-CF （Z）-OR（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中Z表示F或CF 3 < R 3和R 3表示可以含有一个或多个链状氧原子的氟化烷基。 氟聚合物可以固化成含氟弹性体。 本发明还涉及含氟聚合物和固化剂的可固化含氟弹性体组合物。

    Emulsifier free aqueous emulsion polymerization to produce copolymers of a fluorinated olefin and hydrocarbon olefin
    87.
    发明授权
    Emulsifier free aqueous emulsion polymerization to produce copolymers of a fluorinated olefin and hydrocarbon olefin 失效
    无乳化剂水性乳液聚合制备氟化烯烃和烃烯烃的共聚物

    公开(公告)号：US07064170B2

    公开(公告)日：2006-06-20

    申请号：US10690088

    申请日：2003-10-21

    申请人： Harald Kaspar ,  Peter J. Scott ,  Klaus Hintzer ,  Gernot Löhr

    发明人： Harald Kaspar ,  Peter J. Scott ,  Klaus Hintzer ,  Gernot Löhr

    IPC分类号： C08F12/20

    CPC分类号： C08F214/18

    摘要： Provided is a process for making a copolymer of fluorinated olefin and hydrocarbon olefin selected from ethylene, propylene and mixtures thereof, the process comprising a substantially emulsifier free aqueous emulsion polymerization of said fluorinated olefin and said hydrocarbon olefin, optionally in the presence of fluoropolymer particles and/or fluorinated liquid in a form suitable to improve the copolymerization of fluorinated olefin and hydrocarbon olefin.

    摘要翻译： 提供了制备氟化烯烃和选自乙烯，丙烯及其混合物的烃烯烃的共聚物的方法，该方法包括所述氟化烯烃和所述烃烯烃的基本上无乳化剂的水乳液聚合，任选在含氟聚合物颗粒和 /或氟化液体，其形式适合改善氟化烯烃和烃烯烃的共聚。

    Method of recovering fluorinated acid surfactants from adsorbent particles loaded therewith
    88.
    发明申请
    Method of recovering fluorinated acid surfactants from adsorbent particles loaded therewith 有权
    从装载有吸附剂的颗粒中回收氟化表面活性剂的方法

    公开(公告)号：US20050177000A1

    公开(公告)日：2005-08-11

    申请号：US11036432

    申请日：2005-01-14

    申请人： Stephan Fuhrer ,  Klaus Hintzer ,  Gernot Lohr ,  Egon Obermaier ,  Werner Schwertfeger

    发明人： Stephan Fuhrer ,  Klaus Hintzer ,  Gernot Lohr ,  Egon Obermaier ,  Werner Schwertfeger

    IPC分类号： C07C51/493 ,  C07C53/21

    CPC分类号： C07C51/493 ,  C07C53/21

    摘要： The present invention provides a method of recovering a fluorinated acid surfactant or salt thereof from adsorbent particles to which said fluorinated acid surfactant has been adsorbed. The method comprises mixing adsorbent particles having adsorbed fluorinated acid surfactant or salt thereof with an alcohol and optionally an acid. The mixture is generally heated to cause esterification of the fluorinated acid surfactant or salt thereof with the alcohol so as to form an ester derivative of the fluorinated acid surfactant, distilling the mixture to form a distillate comprising the ester derivative, separating the ester derivative from the distillate and optionally feeding the remainder of the distillate back into the mixture.

    摘要翻译： 本发明提供一种从吸附了氟化酸表面活性剂的吸附剂颗粒中回收氟化酸表面活性剂或其盐的方法。 该方法包括将具有吸附的氟化酸表面活性剂或其盐的吸附剂颗粒与醇和任选的酸混合。 通常加热混合物以使氟化酸表面活性剂或其盐与醇进行酯化，以形成氟化酸表面活性剂的酯衍生物，蒸馏该混合物以形成包含酯衍生物的馏出物，将酯衍生物与 馏出物和任选地将剩余的馏出物反馈回混合物中。

    Fluoropolymers with improved characteristics
    89.
    发明授权
    Fluoropolymers with improved characteristics 有权
    具有改进特性的含氟聚合物

    公开(公告)号：US06489420B1

    公开(公告)日：2002-12-03

    申请号：US09604178

    申请日：2000-06-27

    申请人： Denis Duchesne ,  Harald Kaspar ,  Lisa P. Chen ,  Klaus Hintzer ,  Attila Molnar ,  Ludwig Mayer ,  Gernot Löhr

    发明人： Denis Duchesne ,  Harald Kaspar ,  Lisa P. Chen ,  Klaus Hintzer ,  Attila Molnar ,  Ludwig Mayer ,  Gernot Löhr

    IPC分类号： C08F21422

    CPC分类号： C08F214/222 ,  C08F214/184 ,  C08F214/262 ,  Y10T428/3154 ,  Y10T428/31544

    摘要： A fluoropolymer composition is provided. The polymer comprises interpolymerized units derived from (i) tetrafluoroethylene, (ii) vinylidene fluoride, (iii) at least one ethylenically unsaturated monomer of the formula CF2═CFRf where Rf is a perfluoroalkyl or a perfluoroalkoxy of 1 to 8 carbon atoms, and (iv) a perfluorovinyl ether of the formula CF2═CF—(OCF2CF(Rf))aOR′f where Rf is as described in (iii), R′f is a perfluoroaliphatic, preferably a perfluoroalkyl or a perfluoroalkoxy, of 1 to 8, preferably 1 to 3, carbon atoms, and a has a value of 0 to 3.

    摘要翻译： 提供含氟聚合物组合物。 聚合物包含衍生自（i）四氟乙烯，（ii）偏二氟乙烯，（iii）至少一种式CF 2 = CFR f的烯键式不饱和单体的共聚单元，其中Rf是1至8个碳原子的全氟烷基或全氟烷氧基，和（ iv）式CF 2 = CF-（OCF 2 CF（R f））aOR'f的全氟乙烯醚，其中R f如（iii）中所述，R 1f是1至8的全氟脂族基，优选全氟烷基或全氟烷氧基， 优选为1〜3个碳原子，a为0〜3。