公开(公告)号：US20120252218A1

公开(公告)日：2012-10-04

申请号：US13424455

申请日：2012-03-20

申请人： Daisuke Kori ,  Takeshi Kinsho ,  Katsuya Takemura ,  Tsutomu Ogihara ,  Takeru Watanabe ,  Hiroyuki Urano

发明人： Daisuke Kori ,  Takeshi Kinsho ,  Katsuya Takemura ,  Tsutomu Ogihara ,  Takeru Watanabe ,  Hiroyuki Urano

IPC分类号： H01L21/311 ,  C08G61/02 ,  C07C39/17 ,  C09D165/02 ,  C09D171/12 ,  C09D5/00 ,  H01L21/312 ,  C08G65/38

CPC分类号： C07C39/17 ,  C09D161/12 ,  G03F7/091 ,  G03F7/094

摘要： A biphenyl derivative having formula (1) is provided wherein Ar1 and Ar2 denote a benzene or naphthalene ring, and x and z each are 0 or 1. A material comprising the biphenyl derivative or a polymer comprising recurring units of the biphenyl derivative is spin coated and heat treated to form a resist bottom layer having improved properties, optimum values of n and k, step coverage, etch resistance, heat resistance, solvent resistance, and minimized outgassing.

摘要翻译： 提供具有式（1）的联苯衍生物，其中Ar1和Ar2表示苯或萘环，x和z各自为0或1.包含联苯衍生物或包含联苯衍生物的重复单元的聚合物的材料是旋涂 并进行热处理以形成具有改进性能，n和k的最佳值，台阶覆盖率，耐蚀刻性，耐热性，耐溶剂性和最小化除气的抗蚀剂底层。

公开(公告)号：US5951913A

公开(公告)日：1999-09-14

申请号：US856710

申请日：1997-05-15

申请人： Takaaki Shimizu ,  Tsutomu Ogihara ,  Tatsushi Kaneko ,  Kenji Koizumi ,  Mutsuo Nakashima

发明人： Takaaki Shimizu ,  Tsutomu Ogihara ,  Tatsushi Kaneko ,  Kenji Koizumi ,  Mutsuo Nakashima

IPC分类号： C09K19/40 ,  C09K19/34 ,  C09K19/12

CPC分类号： C09K19/406

摘要： A liquid crystal composition having a liquid crystal component with a chemical structure of two saturated rings connected directly to one another, and an additional structural isomer thereof having a silane atom in a different position from the first component and having the structure set forth in formula (1) hereinbelow. ##STR1## This composition provides an improved effect with respect to enhancement in both response speed and T.sub.NI (nematic-isotropic transition temperature) as a high voltage hold ratio as required for TFT driving in addition to also lowering the voltage.

摘要翻译： 一种具有两个饱和环的化学结构的液晶组分的液晶组合物，其两个直接相互连接，并且其另外的结构异构体具有与第一组分不同位置的硅烷原子并且具有式（ 1）。 除了降低电压之外，该组合物还提供了作为TFT驱动所需的高电压保持率的响应速度和TNI（向列 - 各向同性转变温度）的增强效果。

公开(公告)号：US5866037A

公开(公告)日：1999-02-02

申请号：US828707

申请日：1997-03-31

申请人： Takaaki Shimizu ,  Tsutomu Ogihara ,  Tatsushi Kaneko ,  Toshiaki Takahashi ,  Mutsuo Nakashima ,  Takeshi Kinsho ,  Ryuichi Saito ,  Hideshi Kurihara

发明人： Takaaki Shimizu ,  Tsutomu Ogihara ,  Tatsushi Kaneko ,  Toshiaki Takahashi ,  Mutsuo Nakashima ,  Takeshi Kinsho ,  Ryuichi Saito ,  Hideshi Kurihara

IPC分类号： G02F1/13 ,  C09K19/40 ,  C09K19/42 ,  C09K19/34 ,  C09K19/06 ,  C09K19/30

CPC分类号： C09K19/406

摘要： Liquid crystal compositions which can improve the low .DELTA.n (refractive index anisotropy) of conventional liquid crystal compositions containing a silacyclohexane compound and which retain a low viscosity and hence show no decrease in response speed. Liquid crystal compositions having a high .DELTA.n of 0.13 to 0.25, a low viscosity of 30 cp or less, a low threshold voltage and a high voltage holding ratio can be obtained by adding thereto, as a required component, a compound having both a silacyclohexane ring and a tolan structure, or a miture of a compound having a silacyclohexane ring and a compound having a tolan structure.

摘要翻译： 可以提高含有硅环己烷化合物的常规液晶组合物的低DELTA n（折射率各向异性）并保持低粘度并因此显示出不会降低响应速度的液晶组合物。 通过向其中加入作为所需成分的具有硅环己烷的化合物，可以获得具有0.13〜0.25的高DELTA n，30cp以下的低粘度，低阈值电压和高电压保持率的液晶组合物 环和托兰结构，或具有硅环己烷环的化合物和具有托兰结构的化合物。

公开(公告)号：US5762826A

公开(公告)日：1998-06-09

申请号：US576319

申请日：1995-12-21

申请人： Takaaki Shimizu ,  Tatsushi Kaneko ,  Tsutomu Ogihara ,  Takeshi Kinsho ,  Kazuyuki Asakura ,  Mutsuo Nakashima

发明人： Takaaki Shimizu ,  Tatsushi Kaneko ,  Tsutomu Ogihara ,  Takeshi Kinsho ,  Kazuyuki Asakura ,  Mutsuo Nakashima

IPC分类号： C09K19/40 ,  C09K19/34 ,  C09K19/30

CPC分类号： C09K19/406

摘要： A liquid crystal composition comprising one or more types compounds represented by general formula II: ##STR1## and one or more types of compounds selected from the group consisting of: ##STR2## wherein R, rings A and B, X, Y1, Y2, Y3, Y4 and m are defined herein.

摘要翻译： 一种液晶组合物，其包含一种或多种由通式II表示的化合物：（II）和一种或多种选自以下的化合物：图像（I）图像（III） （IV）其中R，环A和B，X，Y 1，Y 2，Y 3，Y 4和m如本文所定义。

公开(公告)号：US5730901A

公开(公告)日：1998-03-24

申请号：US644775

申请日：1996-05-10

申请人： Takaaki Shimizu ,  Tsutomu Ogihara ,  Tatsushi Kaneko ,  Takanobu Takeda ,  Koji Hasegawa

发明人： Takaaki Shimizu ,  Tsutomu Ogihara ,  Tatsushi Kaneko ,  Takanobu Takeda ,  Koji Hasegawa

IPC分类号： C07F7/08 ,  C07F7/12 ,  C09K19/40 ,  C09K19/52 ,  G02F1/13

CPC分类号： C07F7/0896 ,  C07F7/0818 ,  C07F7/12 ,  C09K19/406

摘要： A silacyclohexane compound of the formulas (I) ##STR1## wherein R represents an organic residue, ##STR2## represents an unsubstituted or substituted silicon-containing cyclohexylene group or a 1,4-cyclohexylene group, ##STR3## represents an unsubstituted or substituted phenylene, an unsubstituted or substituted silicon-containing cyclohexylene group or trans-4-sila-1,4-cyclohexylene group, or a 1,4-cyclohexylene group provided that at least one of these residues represents a silicon-containing cyclohexylene group, m, n, i, k and l are, respectively, 0 or 1 provided that j+l=0 or 1 and m+k=1 or 2, L.sub.1 and L.sub.2, respectively, represent H or F, m and n are, respectively, 0 or 1, X.sub.1 and Y independently represent H, F or Cl, and X.sub.2 represents F or Cl. A liquid crystal composition comprising the silacyclohexane compound of the above formula is also described, along with a liquid crystal device comprising the composition.

摘要翻译： 式（I）的硅环己烷化合物其中R表示有机残基，“IMAGE”表示未取代或取代的含硅亚环己基或1,4-亚环己基， 未取代或取代的含硅亚环己基或反式-4-硅烷-1,4-亚环己基或1,4-亚环己基，条件是这些残基中的至少一个表示含硅亚环己基，m n，i，k和l分别为0或1，只要j + 1 = 0或1，m + k = 1或2，则L1和L2分别表示H或F，m和n分别为 ，0或1，X1和Y独立地表示H，F或Cl，X2表示F或Cl。 还描述了包含上式的硅环己烷化合物的液晶组合物以及包含该组合物的液晶装置。

公开(公告)号：US5679746A

公开(公告)日：1997-10-21

申请号：US576619

申请日：1995-12-21

申请人： Takaaki Shimizu ,  Tsutomu Ogihara ,  Kazuyuki Asakura ,  Takeshi Kinsho ,  Tatsushi Kaneko ,  Mutsuo Nakashima

发明人： Takaaki Shimizu ,  Tsutomu Ogihara ,  Kazuyuki Asakura ,  Takeshi Kinsho ,  Tatsushi Kaneko ,  Mutsuo Nakashima

IPC分类号： C07F7/08 ,  C07F7/12 ,  C09K19/40 ,  C09K19/34

CPC分类号： C07F7/0818 ,  C07F7/0896 ,  C07F7/12 ,  C09K19/406

摘要： A silacyclohexane compound represented by the following general formula (I): ##STR1## wherein R denotes a mono- or di-fluoroalkyl group with 1-10 carbons: ##STR2## denotes a trans-1-silacyclohexylene or a trans-4-silacyclohexylene group whose silicon at position 1 or position 4 has a substitutional group of H, F, Cl or CH.sub.3 ; X denotes a CN, F, Cl, CF.sub.3, CF.sub.2 Cl, CHFCl, OCF.sub.3, OCHF.sub.2, OCF.sub.2 Cl, OCHFCl, (O).sub.3 CY.sub.1 .dbd.CX.sub.1 X.sub.2 (X.sub.1 and Y.sub.1 denote H, F or Cl, and X.sub.2 denotes F or Cl) (O).sub.3 C.sub.p H.sub.q F.sub.r (p denotes 2, 3 or 4, and q and r are integers which satisfy the equation q+r=2p+1, and s denotes 0 or 1), the aforementioned R, or an alkyl or alkoxy group with 1-5 carbons; Y denotes H or F; and Z denotes H or F; and process of manufacturing same.

摘要翻译： 由以下通式（I）表示的硅环己烷化合物：其中R表示具有1-10个碳的单 - 或二 - 氟烷基：表示反式-1-硅杂环己烯或反式-4-硅杂环己烯 其位置1或位置4的硅具有H，F，Cl或CH 3的取代基; X表示CN，F，Cl，CF 3，CF 2 Cl，CHFCl，OCF 3，OCHF 2，OCF 2 Cl，OCHFCl，（O）3CY 1 = CX 1 X 2（X 1和Y 1表示H，F或Cl，X2表示F或Cl）（O） 3CpHqFr（p表示2,3或4，q和r是满足方程式q + r = 2p + 1，s表示0或1的整数），上述R 1或具有1-5个碳原子的烷基或烷氧基 碳; Y表示H或F; Z表示H或F; 和制造过程相同。

公开(公告)号：US5624601A

公开(公告)日：1997-04-29

申请号：US546254

申请日：1995-10-20

申请人： Takaaki Shimizu ,  Takeshi Kinsho ,  Tsutomu Ogihara ,  Tatsushi Kaneko ,  Mutsuo Nakashima ,  Hideshi Kurihara

发明人： Takaaki Shimizu ,  Takeshi Kinsho ,  Tsutomu Ogihara ,  Tatsushi Kaneko ,  Mutsuo Nakashima ,  Hideshi Kurihara

IPC分类号： C07F7/08 ,  C07F7/12 ,  C09K19/40 ,  C09K19/42 ,  C09K19/34 ,  C09K19/30

CPC分类号： C09K19/406 ,  C07F7/0812 ,  C07F7/0818 ,  C07F7/0896 ,  C07F7/12 ,  C09K19/42

摘要： A silacyclohexane compound of the following formula (I) ##STR1## wherein R represents an organic residue; ##STR2## represents a trans-1-sila-1,4-cyclohexylene group or trans-4-sila-1,4-cyclohexylene group having a substituent of H, F, Cl or CH.sub.3 ; L.sub.1 represents F, L.sub.2 and L.sub.3 independently represent H, F, Cl or CH.sub.3 ; X represents an organic residue, F or Cl; and n is an integer of 0, 1, or 2 and a and b are, respectively, 0 or 1 provided that a+b=1. Silacyclohexane compounds are useful in liquid crystal compositions and also in liquid crystal devices.

摘要翻译： 下式（I）的硅环己烷化合物其中R表示有机残基; 表示具有H，F，Cl或CH 3取代基的反式-1-硅烷-1,4-亚环己基或反式-4-硅烷-1,4-亚环己基; L1表示F，L2和L3独立地表示H，F，Cl或CH3; X表示有机残基F或Cl; 并且n是0,1或2的整数，并且a和b分别为0或1，条件是a + b = 1。 硅环己烷化合物可用于液晶组合物和液晶装置中。

公开(公告)号：US5587691A

公开(公告)日：1996-12-24

申请号：US478782

申请日：1995-06-07

申请人： Hiroshi Yabe ,  Tsutomu Ogihara

发明人： Hiroshi Yabe ,  Tsutomu Ogihara

IPC分类号： G04G3/02 ,  G06F1/14 ,  H03B19/00

CPC分类号： G04G3/02

摘要： A digital trimming circuit is used to produce a stable time reference signal. This type of reference time signal can be used in equipment, such as watches, which have motors and acoustic outputs that interfere with producing the time reference signal. A basic oscillation frequency, which is produced by an oscillator circuit, is frequency divided to form the generic time reference signal. The digital trimming circuit generates a control signal to shorten the period of the time reference signal by predetermined amounts based on correction data. The control signal is in the form of pulses which can be dispersively applied to create substantially equal intervals between pulses during one time period of the time reference time signal. While maintaining the necessary digital trimming amount in one digital trimming time period, an expansion/reduction amount of the time reference signal is suppressed at one digital trimming time instant. Therefore, interference between the digital trimming timing and the predetermined output timing can be avoided.

公开(公告)号：US5582765A

公开(公告)日：1996-12-10

申请号：US511276

申请日：1995-08-04

申请人： Takeshi Kinsho ,  Takaaki Shimizu ,  Tsutomu Ogihara ,  Tatsushi Kaneko ,  Mutsuo Nakashima

发明人： Takeshi Kinsho ,  Takaaki Shimizu ,  Tsutomu Ogihara ,  Tatsushi Kaneko ,  Mutsuo Nakashima

IPC分类号： C07F7/08 ,  C07F7/12 ,  C09K19/40 ,  C09K19/34 ,  C09K19/30

CPC分类号： C09K19/406 ,  C07F7/0818 ,  C07F7/0896 ,  C07F7/12

摘要： A triflate compound of the following general formula is provided ##STR1## wherein Ar represents a phenyl group or a tolyl group, R represents a phenyl group, a tolyl group, a linear alkyl group having from 1 to 10 carbon atoms, a mono or difluoroalkyl group having from 1 to 10 carbon atoms, a branched alkyl group having from 3 to 8 carbon atoms, an alkoxyalkyl group having from 2 to 7 carbon atoms and an alkenyl group having from 2 to 8 carbon atoms, Tf represents a trifluoromethanesulfonyl group, and Y represents H or F. A process for preparing silacyclohexane-based liquid crystal compounds from the triflate compound is also described.

摘要翻译： 提供以下通式的三氟甲磺酸酯化合物，其中Ar表示苯基或甲苯基，R表示苯基，甲苯基，具有1至10个碳原子的直链烷基，单或二氟烷基 具有1至10个碳原子的基团，具有3至8个碳原子的支链烷基，具有2至7个碳原子的烷氧基烷基和具有2至8个碳原子的链烯基，Tf表示三氟甲磺酰基， Y表示H或F.还描述了由三氟甲磺酸酯化合物制备硅环己烷基液晶化合物的方法。

公开(公告)号：US5527490A

公开(公告)日：1996-06-18

申请号：US434814

申请日：1995-05-04

申请人： Takeshi Kinsho ,  Takaaki Shimizu ,  Tsutomu Ogihara ,  Tatsushi Kaneko ,  Mutsuo Nakashima

发明人： Takeshi Kinsho ,  Takaaki Shimizu ,  Tsutomu Ogihara ,  Tatsushi Kaneko ,  Mutsuo Nakashima

IPC分类号： C07F7/08 ,  C07F7/10 ,  C07F7/12 ,  C07F7/18 ,  C09K19/40 ,  C09K19/30 ,  G02F1/13

CPC分类号： C09K19/406 ,  C07F7/0818 ,  C07F7/0896

摘要： A silacyclohexane carbaldehyde compound of the following formula (I) ##STR1## wherein Ar represents a phenyl group or a tolyl group, and R represents a phenyl group, a tolyl group, a linear alkyl group, a mono or difluoroalkyl group, a branched alkyl group, an alkoxyalkyl group or an alkenyl group. Processes for preparing a silacyclohexane-based liquid crystal compound of the following formula (II) or (III) from the silacyclohexane carbaldehyde are also described ##STR2## wherein X represents CN, F, Cl, CF.sub.3, CClF.sub.2, CHClF, OCF.sub.3, OCClF.sub.2, OCHF.sub.2, OCHClF, (O).sub.m CT=CX.sub.1 X.sub.2, O(CH.sub.2).sub.r (CF.sub.2).sub.s X.sub.3, R or OR wherein m is a value of 0 or 1, T and X.sub.1 independently represent H, F or Cl, X.sub.2 represents F or Cl, r and s are, respectively, a value of 0, 1 or 2 provided that r+s=2, 3 or 4, X.sub.3 represents H, F or Cl, and R has the same meaning as defined before, Y and Z independently represent a halogen or a methyl group, i and j are independently a value of 0, 1 or 2.

摘要翻译： 下式（I）的硅环己烷甲醛化合物其中Ar表示苯基或甲苯基，R表示苯基，甲苯基，直链烷基，单或二氟烷基， 支链烷基，烷氧基烷基或烯基。 还描述了从硅环己烷甲醛制备下式（II）或（III）的硅杂环己烷系液晶化合物的方法，其中X表示CN，F，Cl， CF 3，CClF 2，CHClF，OCF 3，OCClF 2，OCHF 2，OCHClF，（O）mCT = CX1X2，O（CH2）r（CF2）sX3，R或OR，其中m为0或1，T和X1独立地表示H ，F或Cl，X2表示F或Cl，r和s分别为0,1或2的值，条件是r + s = 2,3或4，X3表示H，F或Cl，并且R具有 与前述相同，Y和Z独立地表示卤素或甲基，i和j独立地为0,1或2的值。