公开(公告)号：US10326133B2

公开(公告)日：2019-06-18

申请号：US15267167

申请日：2016-09-16

Applicant: TODA KOGYO CORP.

Inventor： Sven Albrecht ,  Michael Kruft ,  Stefan Malcus

IPC: H01M4/525 ,  C01G53/00 ,  H01M4/485 ,  H01M4/505 ,  C01G51/00 ,  H01M10/0525 ,  H01M10/052 ,  H01M4/02

Abstract: The invention relates to a chemical compound of the formula NibM1cM2d(O)x(OH)y, wherein M1 denotes at least one element from the group consisting of Fe, Co, Mg, Zn, Cu and/or mixtures thereof, M2 denotes at least one element from the group consisting of Mn, Al, B, Ca, Cr and/or mixtures thereof, wherein b≤0.8, c≤0.5, d≤0.5, and x is a number between 0.1 and 0.8, y is a number between 1.2 and 1.9, and x+y=2. A process for the preparation thereof, and the use thereof as a precursor for the preparation of cathode material for secondary lithium batteries are described.

公开(公告)号：US09952524B2

公开(公告)日：2018-04-24

申请号：US14404543

申请日：2013-05-30

Applicant: TODA KOGYO CORP.

Inventor： Kaori Kinoshita ,  Eiichi Kurita

IPC: G03G9/113 ,  G03G9/107 ,  G03G9/10

CPC classification number: G03G9/1135 ,  G03G9/10 ,  G03G9/107 ,  G03G9/1075 ,  G03G9/1131 ,  G03G9/1133 ,  G03G9/1136

Abstract: The present invention relates to a magnetic carrier for an electrophotographic developer comprising spherical composite core particles comprising at least ferromagnetic iron oxide fine particles and a cured phenol resin, and having an average particle diameter of 20 to 60 μm, the magnetic carrier for an electrophotographic developer satisfying the formula (1): σ1−σ0=−2 to 0 wherein σ0 represents a saturation magnetization (Am2/kg) of the carrier particles having a particle diameter in the vicinity of the average particle diameter of the magnetic carrier for an electrophotographic developer; and σ1 represents a saturation magnetization (Am2/kg) of the carrier particles having a particle diameter of less than 20 μm, and a two-component system developer using the magnetic carrier. The two-component system developer of the present invention includes a magnetic carrier used for an electrophotographic developer which can exhibit a good durability, is free from occurrence of carrier adhesion, and can maintain a high quality of images produced for a long period of time, and comprises the magnetic carrier for an electrophotographic developer and a toner.

公开(公告)号：US09147873B2

公开(公告)日：2015-09-29

申请号：US13896825

申请日：2013-05-17

Applicant: JX NIPPON OIL & ENERGY CORPORATION ,  TODA KOGYO CORP.

Inventor： Takashi Suzuki ,  Noriyo Ishimaru ,  Takashi Oyama ,  Tamotsu Tano ,  Toshiyuki Oda ,  Ippei Fujinaga ,  Tomoaki Urai ,  Seiji Okazaki ,  Katsuaki Kurata ,  Toshiaki Hiramoto ,  Akino Sato ,  Wataru Oda

IPC: C01B31/02 ,  H01M4/133 ,  H01M4/583 ,  H01M4/587 ,  H01M10/052

CPC classification number: H01M4/133 ,  C01B32/05 ,  C10B55/00 ,  C10B57/045 ,  H01M4/583 ,  H01M4/587 ,  H01M10/052

Abstract: A method for producing an amorphous carbon material for a negative electrode of a lithium-ion secondary battery includes the steps of; pulverizing and classifying a raw coke composition obtained from a heavy-oil composition undergone coking by delayed coking process to obtain powder of the raw coke composition, the raw coke composition having a H/C atomic ratio that is a ratio of hydrogen atoms H and carbon atoms C of 0.30 to 0.50 and having a micro-strength of 7 to 17 mass %; giving compressive stress and shear stress to the powder of the raw coke composition to obtain a carbonized composition precursor; and heating the carbonized composition precursor under an inert atmosphere at a temperature from 900° C. to 1,500° C. so that a size of a crystallite Lc(002) is in a range of 2 nm to 8 nm, the size being calculated from a (002) diffraction line obtained by X-ray wide-angle diffractometry.

Abstract translation: 锂离子二次电池的负极用无定形碳材料的制造方法包括以下工序： 对通过延迟焦化处理进行焦化的重油组合物得到的生焦炭组合物进行粉碎和分级，得到原料焦炭组合物的粉末，该原料焦炭组合物的H / C原子比为氢原子H与碳的比例 原子C为0.30〜0.50，微观强度为7〜17质量％。 对原料焦炭组合物的粉末赋予压应力和剪切应力以获得碳化组合物前体; 并在惰性气氛下，在900℃至1500℃的温度下加热碳化组合物前体，使得微晶Lc（002）的尺寸在2nm至8nm的范围内，其尺寸由 通过X射线广角衍射法获得的（002）衍射线。

公开(公告)号：US09142832B2

公开(公告)日：2015-09-22

申请号：US13866843

申请日：2013-04-19

Applicant: JX NIPPON OIL & ENERGY CORPORATION ,  TODA KOGYO CORP.

Inventor： Takashi Suzuki ,  Noriyo Ishimaru ,  Takashi Oyama ,  Tamotsu Tano ,  Toshiyuki Oda ,  Ippei Fujinaga ,  Tomoaki Urai ,  Seiji Okazaki ,  Katsuaki Kurata ,  Toshiaki Hiramoto ,  Akino Sato ,  Wataru Oda

IPC: H01M4/133 ,  C01B31/04 ,  H01M4/587

CPC classification number: H01M4/133 ,  C01B32/20 ,  H01M4/587

Abstract: A graphite material for a negative electrode is provided which can suppress capacity degradation due to repeated charging and discharging cycles, storage in a charged state, and floating charging.A method of manufacturing a graphite material for a negative electrode of a lithium ion secondary battery is provided in which an atomic ratio H/C of hydrogen atoms H and carbon atoms C in the raw coke composition is in a range of 0.30 to 0.50 and a microstrength of the raw coke composition is in a range of 7 wt % to 17 wt %.

Abstract translation: 提供一种用于负极的石墨材料，其可以抑制由于重复的充电和放电循环而导致的容量劣化，在充电状态下的存储和浮动充电。 提供一种锂离子二次电池的负极用石墨材料的制造方法，其中原料焦炭组合物中氢原子H和碳原子数C的原子比H / C为0.30〜0.50， 生焦炭组合物的微观强度在7重量％至17重量％的范围内。

公开(公告)号：US20150037677A1

公开(公告)日：2015-02-05

申请号：US14380523

申请日：2013-02-22

Applicant: TODA KOGYO CORP.

Inventor： Kazumichi Koga ,  Ryuta Masaki ,  Akihisa Kajiyama ,  Hiroaki Masukuni

IPC: H01M4/36 ,  H01M10/0525 ,  H01M4/50

CPC classification number: H01M4/364 ,  C01G25/00 ,  C01P2002/32 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/62 ,  H01M4/485 ,  H01M4/502 ,  H01M4/505 ,  H01M8/04671 ,  H01M10/0525 ,  H01M2220/30 ,  Y02E60/122 ,  Y02P70/54

Abstract: The present invention relates to positive electrode active substance particles for non-aqueous electrolyte secondary batteries, comprising an oxide having a spinel structure and comprising at least Li and Mn as main components and an oxide comprising at least Li and Zr, in which the oxide comprising at least Li and Zr forms a mixed phase comprising two or more phases, and a content of the oxide comprising at least Li and Zr in the positive electrode active substance particles is 0.1 to 4% by weight. The present invention provides positive electrode active substance particles for non-aqueous electrolyte secondary batteries which are excellent in high-temperature characteristics and a process for producing the positive electrode active substance particles, and a non-aqueous electrolyte secondary battery.

Abstract translation: 本发明涉及非水电解质二次电池用正极活性物质粒子，其包含具有尖晶石结构且至少包含Li和Mn作为主要成分的氧化物和至少包含Li和Zr的氧化物，其中包含 至少Li和Zr形成包含两相或更多相的混合相，并且正极活性物质颗粒中至少包含Li和Zr的氧化物的含量为0.1至4重量％。 本发明提供高温特性优异的非水电解质二次电池用正极活性物质粒子和正极活性物质粒子的制造方法以及非水电解质二次电池。

公开(公告)号：US20140326363A1

公开(公告)日：2014-11-06

申请号：US14342930

申请日：2012-08-30

Applicant: Nobuhiro Katayama ,  Hirofumi Kawasaki ,  Koichiro Morimoto

Inventor： Nobuhiro Katayama ,  Hirofumi Kawasaki ,  Koichiro Morimoto

IPC: H01F1/057 ,  H01F41/02

CPC classification number: H01F1/0571 ,  C22C33/02 ,  C22C38/00 ,  C22C38/002 ,  C22C38/005 ,  C22C38/06 ,  C22C38/10 ,  C22C38/14 ,  C22C2202/02 ,  H01F1/0573 ,  H01F1/0576 ,  H01F1/0578 ,  H01F41/0266

Abstract: The present invention provides R-T-B-based rare earth magnet particles comprising no expensive rare resources such as Dy and having an excellent coercive force which can be produced by HDDR treatment without any additional steps. The present invention relates to R-T-B-based rare earth magnet particles comprising crystal grains comprising a magnetic phase of R2T14B, and a grain boundary phase, in which the grain boundary phase has a composition comprising R in an amount of not less than 13.5 atom % and not more than 35.0 atom % and Al in an amount of not less than 1.0 atom % and not more than 7.0 atom %. The R-T-B-based rare earth magnet particles can be obtained by controlling heat treatment conditions in the DR step of the HDDR treatment in the course of subjecting a raw material alloy to the HDDR treatment.

Abstract translation: 本发明提供了不含昂贵稀有资源如Dy的R-T-B系稀土磁体颗粒，具有优异的矫顽力，可通过HDDR处理而无需任何附加步骤。 本发明涉及包含R2T14B的磁性相的晶粒和晶界相的RTB系稀土类磁铁粒子，其中，晶界相的组成为不低于13.5原子％的R， 不大于35.0原子％，Al为1.0原子％以上7.0原子％以下的Al。 通过控制HDDR处理的DR步骤中的原料合金进行HDDR处理的过程中的热处理条件，可以得到R-T-B系稀土类磁体粒子。

公开(公告)号：US20140248493A1

公开(公告)日：2014-09-04

申请号：US14349515

申请日：2012-10-02

Applicant: TODA KOGYO CORP

Inventor： Seiji Okazaki ,  Wataru Oda ,  Tomoaki Urai ,  Akio Sakamoto

IPC: H01M4/587

CPC classification number: H01M4/587 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/182 ,  Y10T428/2982

Abstract: The present invention provides a spherical carbon material in the form of isotropic particles which undergoes a considerably less change in shape even after subjected to carbonization or graphitization, and has a good crystal growth property. The present invention relates to a raw coke spherical carbon material in which an average of a plane-direction sphericity and an elevation-direction sphericity of particles of the spherical carbon material as measured in plane and elevation directions of particles of the spherical carbon material, respectively, by observation using a scanning electron microscope is not less than 60%, and a shape retention rate of the spherical carbon material after being heated at 1200° C. for 5 hr and then at 2800° C. for 3 hr is not less than 70%; a process for producing the above raw coke spherical carbon material, comprising the step of applying a compression shear stress to raw coke particles comprising particles having a particle diameter that is not more than 1/3 of an average particle diameter (D50) thereof in an amount of not less than 5% to subject the raw coke particles to dry granulation sphericalization treatment; a carbonaceous spherical carbon material obtained by carbonizing the above raw coke spherical carbon material and a process for producing the carbonaceous spherical carbon material; and a graphite spherical carbon material obtained by graphitizing the above raw coke spherical carbon material and a process for producing the graphite spherical carbon material.

Abstract translation: 本发明提供一种各向同性粒子形状的球形碳材料，其即使经过碳化或石墨化也经历了相当小的形状变化，并且具有良好的晶体生长性能。 本发明涉及一种原焦炭球形碳材料，其中分别在球形碳材料颗粒的平面和高度方向上测量球形碳材料颗粒的平面方向球形度和高度方向球形度 通过使用扫描电子显微镜的观察不低于60％，并且在1200℃下加热5小时，然后在2800℃下3小时后的球形碳材料的形状保持率不小于 70％; 一种生产上述原料焦炭球形碳材料的方法，包括将压缩剪切应力施加到原料焦炭颗粒的步骤中，所述原料焦炭颗粒包含粒径不大于其平均粒径（D50）的1/3的颗粒， 数量不少于5％，使原焦颗粒干燥造粒球化; 通过碳化上述原料焦炭球形碳材料获得的碳质球形碳材料和碳质球形碳材料的制造方法; 以及通过石墨化上述原料焦炭球形碳材料得到的石墨球形碳材料和石墨球形碳材料的制造方法。

公开(公告)号：US08323725B2

公开(公告)日：2012-12-04

申请号：US12816833

申请日：2010-06-16

Applicant: Toru Maeda ,  Naoto Igarashi ,  Haruhisa Toyoda ,  Hirokazu Kugai ,  Kazuyuki Hayashi ,  Hiroko Morii ,  Seiji Ishitani

Inventor： Toru Maeda ,  Naoto Igarashi ,  Haruhisa Toyoda ,  Hirokazu Kugai ,  Kazuyuki Hayashi ,  Hiroko Morii ,  Seiji Ishitani

IPC: H01F1/20

CPC classification number: B22F1/02 ,  B22F2998/10 ,  H01F1/24 ,  H01F1/26 ,  H01F41/0246 ,  Y10T428/2991 ,  B22F3/02 ,  B22F3/24

Abstract: A soft magnetic material is a soft magnetic material including a composite magnetic particle (30) having a metal magnetic particle (10) mainly composed of Fe and an insulating coating (20) covering metal magnetic particle (10), and insulating coating (20) contains an iron phosphate compound and an aluminum phosphate compound. The atomic ratio of Fe contained in a contact surface of insulating coating (20) in contact with metal magnetic particle (10) is larger than the atomic ratio of Fe contained in the surface of insulating coating (20). The atomic ratio of Al contained in the contact surface of insulating coating (20) in contact with metal magnetic particle (10) is smaller than the atomic ratio of Al contained in the surface of insulating coating (20). Thus, iron loss can be reduced.

Abstract translation: 软磁性材料是包括具有主要由Fe构成的金属磁性粒子（10）和覆盖金属磁性粒子（10）的绝缘涂层（20）的复合磁性体（30）和绝缘涂层（20）的软磁性材料， 含有磷酸铁化合物和磷酸铝化合物。 包含在与金属磁性颗粒（10）接触的绝缘涂层（20）的接触表面中的Fe的原子比大于绝缘涂层（20）表面中所含的Fe的原子比。 绝缘涂层（20）与金属磁性颗粒（10）接触的接触表面中所含的Al的原子比小于绝缘涂层（20）表面中的Al的原子比。 因此，可以减少铁损。

公开(公告)号：US20120164320A1

公开(公告)日：2012-06-28

申请号：US13409850

申请日：2012-03-01

Applicant: Toru Maeda ,  Naoto Igarashi ,  Haruhisa Toyoda ,  Seiji Ishitani ,  Hiroko Morii ,  Kazuyuki Hayashi

Inventor： Toru Maeda ,  Naoto Igarashi ,  Haruhisa Toyoda ,  Seiji Ishitani ,  Hiroko Morii ,  Kazuyuki Hayashi

IPC: B05D5/12

CPC classification number: H01F1/24 ,  B22F1/02 ,  B22F2998/10 ,  C22C33/02 ,  H01F1/26 ,  H01F3/08 ,  H01F41/0246 ,  Y10T428/2991 ,  Y10T428/2998 ,  B22F1/007 ,  B22F3/02 ,  B22F3/10

Abstract: A manufacturing method of a soft magnetic material has a step of preparing a metal magnetic particle containing iron as the main component, and a step of forming an insulating film surrounding the surface of the metal magnetic particle. The step of forming the insulating film includes a step of mixing and stirring the metal magnetic particle, aluminum alkoxide, silicon alkoxide, and phosphoric acid.

Abstract translation: 软磁性材料的制造方法具有制备以铁为主要成分的金属磁性体的工序，以及形成包围金属磁性体的表面的绝缘膜的工序。 形成绝缘膜的步骤包括混合和搅拌金属磁性颗粒，醇铝，硅烷氧化物和磷酸的步骤。

公开(公告)号：US08153256B2

公开(公告)日：2012-04-10

申请号：US12160079

申请日：2006-11-22

Applicant: Toru Maeda ,  Naoto Igarashi ,  Haruhisa Toyoda ,  Seiji Ishitani ,  Hiroko Morii ,  Kazuyuki Hayashi

Inventor： Toru Maeda ,  Naoto Igarashi ,  Haruhisa Toyoda ,  Seiji Ishitani ,  Hiroko Morii ,  Kazuyuki Hayashi

IPC: B32B5/16 ,  H01F1/12 ,  H01F1/24

CPC classification number: H01F1/24 ,  B22F1/02 ,  B22F2998/10 ,  C22C33/02 ,  H01F1/26 ,  H01F3/08 ,  H01F41/0246 ,  Y10T428/2991 ,  Y10T428/2998 ,  B22F1/007 ,  B22F3/02 ,  B22F3/10

Abstract: The soft magnetic material includes a plurality of composite magnetic particles having a metal magnetic particle and an insulating film surrounding the surface of the metal magnetic particle. The metal magnetic particle contains iron as the main component. The insulating film contains aluminum, silicon, phosphorus, and oxygen. The insulating film satisfies the relationship 0.4≦MAl/(MAl+MSi)≦0.9 and the relationship of 0.25≦(MAl+MSi)/MP≦1.0 in the case that molar amount of aluminum contained in the insulating film is represented by MAl, the sum of the molar amount of aluminum contained in the insulating film and the molar amount of silicon contained in the insulating film is represented by (MAl+MSi), and the molar amount of phosphorus contained in the insulating film is represented by MP.

Abstract translation: 软磁性材料包括具有金属磁性颗粒的多个复合磁性颗粒和围绕金属磁性颗粒表面的绝缘膜。 金属磁性粒子含有铁作为主要成分。 绝缘膜含有铝，硅，磷和氧。 在绝缘膜中包含的铝的摩尔量表示的情况下，该绝缘膜满足关系0.4＆nlE; MA1 /（MA1 + MSi）＆nlE; 0.9以及0.25＆nlE;（MA1 + MSi）/MP_nlE1.0的关系 通过MA1，绝缘膜中所含的铝的摩尔量和绝缘膜中所含的硅的摩尔量之和由（MA1 + MSi）表示，绝缘膜中所含的磷的摩尔量由 MP。