公开(公告)号：US20050049393A1

公开(公告)日：2005-03-03

申请号：US10648524

申请日：2003-08-26

申请人： Norberto Silvi ,  Mark Giammattei ,  Jan Keulen ,  David Woodruff ,  Paul Wilson ,  Paul Buckley ,  Norman Johnson

发明人： Norberto Silvi ,  Mark Giammattei ,  Jan Keulen ,  David Woodruff ,  Paul Wilson ,  Paul Buckley ,  Norman Johnson

IPC分类号： C08J3/12 ,  B29C47/00 ,  B29C47/76 ,  C08F6/10 ,  C08F6/12 ,  C08G63/89 ,  C08G65/46 ,  C08G73/10 ,  C08G75/20 ,  C08G77/34 ,  C08J3/215 ,  C08G2/00

CPC分类号： C08G65/46 ,  B29C47/0009 ,  B29C47/0871 ,  B29C47/767 ,  B82Y30/00 ,  C08F6/10 ,  C08F6/12 ,  C08G63/89 ,  C08G73/1053 ,  C08G75/20 ,  C08G77/34

摘要： A method of separating a polymer-solvent mixture is described wherein a polymer-solvent mixture is heated prior to its introduction into an extruder comprising an upstream vent and/or a side feeder vent to allow flash evaporation of the solvent, and downstream vents for removal of remaining solvent. The one-step method is highly efficient having very high throughput rates while at the same time providing a polymer product containing low levels of residual solvent.

公开(公告)号：US06828361B2

公开(公告)日：2004-12-07

申请号：US10006714

申请日：2001-12-10

申请人： Julius Peter ,  Winfried Heidrich ,  Dirk Gross ,  Heinrich Sandau

发明人： Julius Peter ,  Winfried Heidrich ,  Dirk Gross ,  Heinrich Sandau

IPC分类号： C08J322

CPC分类号： C08K5/548 ,  B29B7/005 ,  B29B7/183 ,  B29B7/7466 ,  B29B7/7495 ,  B29B7/82 ,  B29B7/845 ,  B29C47/767 ,  B29C47/965 ,  B29K2021/00 ,  C08K3/36 ,  C08L21/00

摘要： A method for making a silicic acid containing rubber base composition includes providing composition ingredients of rubber, silicic acid, silane and additional additives except for vulcanization ingredients. First and second mixers separate from each other are provided wherein the ingredients except for the vulcanization ingredients can be mixed. All of the composition ingredients are introduced into the first mixer except for the vulcanization ingredients simultaneously or at time intervals. The composition ingredients introduced into the first mixer are mixed to a composition. The composition formed in the first mixer is transferred directly into the second mixer without an intermediate storage thereof. The transferred composition formed in the first mixer is mixed at least almost to completion in the second mixer with the temperature lying in the temperature range of 130° C. to 180° C. at least over the greatest part of the dwell time of the composition in the second mixer wherein the silicic acid reacts acceleratedly with the silane.

摘要翻译： 制备含硅酸橡胶基础组合物的方法包括提供除了硫化成分之外的橡胶，硅酸，硅烷和其它添加剂的组合物成分。 提供了彼此分离的第一和第二混合器，其中除了硫化成分之外的成分可以混合。 除了硫化成分同时或间隔地将所有组合物成分引入第一混合器中。 将引入第一混合器的组合物成分混合到组合物中。 在第一混合器中形成的组合物直接转移到第二混合器中，而不中间储存。 在第一混合器中形成的转移组合物在第二混合器中混合至少几乎完成，其温度至少在组合物的停留时间的最大部分的130℃至180℃的温度范围内 在其中硅酸与硅烷加速反应的第二混合器中。

公开(公告)号：US06790929B2

公开(公告)日：2004-09-14

申请号：US10389009

申请日：2003-03-17

申请人： Norberto Silvi ,  Mark Howard Giammattei ,  Patrick Joseph McCloskey ,  Alberto Nisoli ,  James Day ,  Narayan Ramesh ,  Paul Michael Smigelski, Jr. ,  Paul Russell Wilson

发明人： Norberto Silvi ,  Mark Howard Giammattei ,  Patrick Joseph McCloskey ,  Alberto Nisoli ,  James Day ,  Narayan Ramesh ,  Paul Michael Smigelski, Jr. ,  Paul Russell Wilson

IPC分类号： C08G6400

CPC分类号： B29C47/0004 ,  B29C47/0009 ,  B29C47/60 ,  B29C47/76 ,  B29C47/767 ,  B29C67/246 ,  B29K2069/00 ,  C08G64/081 ,  C08G64/14 ,  C08G64/205 ,  C08G64/307

摘要： This invention relates to an extrusion method preparing polycarbonates from a solution of an oligomeric polycarbonate. A mixture of bis(methyl salicyl)carbonate (BMSC), BPA and a transesterification catalyst are first equilibrated at moderate temperatures to provide a solution of polycarbonate oligomer in methyl salicylate. The solution is then fed to a devolatilizing extruder, where the polymerization reaction is completed and the methyl salicylate solvent is removed. The solution comprising the oligomeric polycarbonate can also be pre-heated under pressure to a temperature above the boiling point of methyl salicylate and subsequently fed to a devolatilizing extruder equipped for rapid flashing off the solvent. The method provides polycarbonate with greater efficiency than the corresponding process in which unreacted monomers are fed to the extruder. Additionally, the method of the invention does not require the isolation of a precursor polycarbonate comprising ester-substituted phenoxy terminal groups.

摘要翻译： 本发明涉及从低聚聚碳酸酯溶液制备聚碳酸酯的挤压方法。 首先在中等温度下平衡双（甲基水杨酸）碳酸酯（BMSC），BPA和酯交换催化剂的混合物，以提供聚碳酸酯低聚物在水杨酸甲酯中的溶液。 然后将溶液进料到脱挥发分挤出机中，其中聚合反应完成并除去水杨酸甲酯溶剂。 包含低聚物聚碳酸酯的溶液也可以在压力下预加热到高于水杨酸甲酯沸点的温度，随后进料到脱挥发分的挤出机中，以便迅速地从溶剂中闪蒸。 该方法提供聚碳酸酯比未反应的单体进料到挤出机的相应方法具有更高的效率。 另外，本发明的方法不需要分离包含酯取代的苯氧基末端基团的前体聚碳酸酯。

公开(公告)号：US06713004B2

公开(公告)日：2004-03-30

申请号：US09832096

申请日：2001-04-11

申请人： Tomohiro Maekawa ,  Kenji Manabe

发明人： Tomohiro Maekawa ,  Kenji Manabe

IPC分类号： B29C4776

CPC分类号： B29C47/767 ,  B29C47/0021

摘要： A process for producing an article of resin made from at least about 50% by weight of methyl methacrylate is provided, which comprises a step of melt-processing the resin with an extruder, wherein an oxygen concentration of a gaseous phase in a resin feed zone of the extruder falls within a range of from about 0.7% by volume to about 10% by volume. The article is excellent in curbing the coloring in melt processing.

摘要翻译： 提供了由至少约50重量％的甲基丙烯酸甲酯制备的树脂制品的方法，其包括用挤出机熔融加工树脂的步骤，其中树脂进料区中的气相氧浓度 的挤出机在约0.7体积％至约10体积％的范围内。 该制品在抑制熔融加工中的着色方面非常出色。

公开(公告)号：US20030154859A1

公开(公告)日：2003-08-21

申请号：US09509946

申请日：2000-04-04

发明人： MASASI SIMONARU ,  TORU SAWAKI ,  KATSUSHI SASAKI ,  KAZUKI HATONO ,  EIJI ITO

IPC分类号： B01D047/00 ,  B29C047/00

CPC分类号： B29C47/605 ,  B29C47/0009 ,  B29C47/0871 ,  B29C47/1063 ,  B29C47/38 ,  B29C47/402 ,  B29C47/404 ,  B29C47/6037 ,  B29C47/762 ,  B29C47/767 ,  B29C67/246 ,  B29K2069/00 ,  B29K2105/0005 ,  Y10S425/243

摘要： An aromatic polycarbonate extruder which is a twin screw extruder for kneading components into a molten aromatic polycarbonate, the extruder comprising at least one module consisting of a kneading unit, a material seal unit, a back kneading unit and a full-flight unit which are arranged from an upstream side to a downstream side and a method of kneading components into an aromatic polycarbonate by using the above extruder. The present invention can provide a kneading apparatus and method for producing an aromatic polycarbonate which has an extremely small content of foreign matter and is free from residence deterioration such as coloration, cross-linking or gelation when the aromatic polycarbonate is to be kneaded with various components.

摘要翻译： 一种芳族聚碳酸酯挤出机，其是用于将组分捏合成熔融芳族聚碳酸酯的双螺杆挤出机，该挤出机包括至少一个由捏合单元，材料密封单元，后捏合单元和全飞行单元组成的模块， 从上游侧到下游侧，以及通过使用上述挤出机将成分捏合成芳香族聚碳酸酯的方法。 本发明可以提供一种用于制备芳香族聚碳酸酯的混合装置和方法，其中当芳族聚碳酸酯与各种组分混合时，其异物含量非常小，并且不会着色，交联或凝胶化等停留劣化 。

公开(公告)号：US06583261B2

公开(公告)日：2003-06-24

申请号：US10056954

申请日：2002-01-25

申请人： Franco Bandera ,  Enrico Venegoni

发明人： Franco Bandera ,  Enrico Venegoni

IPC分类号： C08F600

CPC分类号： B29C47/767 ,  B29C47/0011 ,  B29C47/38 ,  B29C47/402 ,  B29C47/6025 ,  B29K2067/00

摘要： Polyethyleneterephthalate extrusion equipment of material in granule form, still humid, coming from both ground recovered products and also virgin material, comprising a chassis (29), containing a co-rotating, oil-thermoregulated extruder with two screws (31, 32), which comprises a first zone (A), equipped with an opening (34) where there is an aspiration hood (35) for a first “open top” degassing, a second zone (C) where there is at least one stack (37, 38) for a further degassing, between the two zones (A, C), there being a tight zone (B), and a carrying and loading zone (E) activated by the screws (31, 32). The description also relates to an extrusion process of polyethyleneterephthalate effected in a co-rotating twin-screw extruder which comprises in a first zone (A) an “open top” degassing phase, followed by a stack (37, 38) degassing phase, between the two phases there being a tight zone which does not deteriorate the material, followed by a carrying, loading and amalgamation phase of the molten material and a final pumping phase with the extrusion of polyethyleneterephthalate.

公开(公告)号：US06562936B1

公开(公告)日：2003-05-13

申请号：US09786523

申请日：2001-06-11

申请人： Kazuki Hatono ,  Masumi Hirata ,  Hiroaki Kaneko ,  Toru Sawaki ,  Wataru Funakoshi ,  Katsushi Sasaki ,  Masasi Simonaru ,  Kouji Kiyoshige

发明人： Kazuki Hatono ,  Masumi Hirata ,  Hiroaki Kaneko ,  Toru Sawaki ,  Wataru Funakoshi ,  Katsushi Sasaki ,  Masasi Simonaru ,  Kouji Kiyoshige

IPC分类号： C08G6400

CPC分类号： B29C47/767 ,  B29C47/0009 ,  B29C47/38 ,  B29C47/402 ,  C08G64/205 ,  C08G64/307

摘要： A method of producing a polycarbonate or the like which is excellent in hydrolysis and heat stability such as a reduction in molecular weight at the time of molding and color retention and moldability such as releasability and transferability, rarely experiences residence deterioration such as coloring, crosslinking and gel formation and has an extremely small content of foreign matter by employing a special structure for an opening in the side surface of a horizontal cylindrical vacuum resin treating apparatus, supplying a molten polycarbonate into a unidirectional rotary intermeshing double-screw extruder under specific conditions, adding a specific agent under specific conditions and cleaning the inner surface of a production apparatus by a specific method.

摘要翻译： 水解和热稳定性优异的聚碳酸酯等的制造方法，例如成型时的分子量的降低和保色性以及脱模性和转印性等成型性，很少发生着色，交联等的停留劣化， 凝胶形成，并且通过采用水平圆筒形真空树脂处理装置的侧表面中的开口的特殊结构，并且在特定条件下将熔融聚碳酸酯供给到单向旋转啮合双螺杆挤出机中，并且具有非常少的异物含量， 在特定条件下的特定试剂，并通过具体方法清洗生产装置的内表面。

公开(公告)号：US20020185771A1

公开(公告)日：2002-12-12

申请号：US10134615

申请日：2002-04-30

申请人： THE JAPAN STEEL WORKS, LTD.

发明人： Makoto Tojyo

IPC分类号： B29C047/00 ,  D04H001/00 ,  B29C053/00 ,  B29C059/00

CPC分类号： B29B11/14 ,  B29B9/06 ,  B29C47/0011 ,  B29C47/767

摘要： A method and apparatus for making pellets of wood meal compound according to the present invention is constructed in such a manner that synthetic resin material and wood meal material are supplied into a hopper (3) in a most upstream position, and kneaded in a long kneading section (6) having no side feeder (2), thereby to obtain pellets from mixed material having more uniform properties than in the prior art.

摘要翻译： 按照本发明的制备木粉化合物颗粒的方法和装置是以合成树脂材料和木粉材料供给到最上游位置的料斗（3）中的方式构成的，并且在长时间捏合 （6）没有侧进料器（2），从而获得具有比现有技术更均匀性能的混合材料的颗粒。

公开(公告)号：US20020123555A1

公开(公告)日：2002-09-05

申请号：US10006714

申请日：2001-12-10

发明人： Julius Peter ,  Winfried Heidrich ,  Dirk Gross ,  Heinrich Sandau

IPC分类号： C08K003/34

CPC分类号： C08K5/548 ,  B29B7/005 ,  B29B7/183 ,  B29B7/7466 ,  B29B7/7495 ,  B29B7/82 ,  B29B7/845 ,  B29C47/767 ,  B29C47/965 ,  B29K2021/00 ,  C08K3/36 ,  C08L21/00

摘要： A method for making a silicic acid containing rubber base composition includes providing composition ingredients of rubber, silicic acid, silane and additional additives except for vulcanization ingredients. First and second mixers separate from each other are provided wherein the ingredients except for the vulcanization ingredients can be mixed. All of the composition ingredients are introduced into the first mixer except for the vulcanization ingredients simultaneously or at time intervals. The composition ingredients introduced into the first mixer are mixed to a composition. The composition formed in the first mixer is transferred directly into the second mixer without an intermediate storage thereof. The transferred composition formed in the first mixer is mixed at least almost to completion in the second mixer with the temperature lying in the temperature range of 130null C. to 180null C. at least over the greatest part of the dwell time of the composition in the second mixer wherein the silicic acid reacts acceleratedly with the silane.

摘要翻译： 制备含硅酸橡胶基础组合物的方法包括提供除了硫化成分之外的橡胶，硅酸，硅烷和其它添加剂的组合物成分。 提供了彼此分离的第一和第二混合器，其中除了硫化成分之外的成分可以混合。 除了硫化成分同时或间隔地将所有组合物成分引入第一混合器中。 将引入第一混合器的组合物成分混合到组合物中。 在第一混合器中形成的组合物直接转移到第二混合器中，而不中间储存。 在第一混合器中形成的转移组合物在第二混合器中混合至少几乎完成，其温度至少在组合物的停留时间的最大部分的130℃至180℃的温度范围内 在其中硅酸与硅烷加速反应的第二混合器中。

公开(公告)号：US20020100995A1

公开(公告)日：2002-08-01

申请号：US10056954

申请日：2002-01-25

发明人： Franco Bandera ,  Enrico Venegoni

IPC分类号： B29C047/60 ,  B29C047/76

CPC分类号： B29C47/767 ,  B29C47/0011 ,  B29C47/38 ,  B29C47/402 ,  B29C47/6025 ,  B29K2067/00

摘要： Polyethyleneterephthalate extrusion equipment of material in granule form, still humid, coming from both ground recovered products and also virgin material, comprising a chassis (29), containing a co-rotating, oil-thermoregulated extruder with two screws (31, 32), which comprises a first zone (A), equipped with an opening (34) where there is an aspiration hood (35) for a first nullopen topnull degassing, a second zone (C) where there is at least one stack (37, 38) for a further degassing, between the two zones (A, C), there being a tight zone (B), and a carrying and loading zone (E) activated by the screws (31, 32). The description also relates to an extrusion process of polyethyleneterephthalate effected in a co-rotating twin-screw extruder which comprises in a first zone (A) an nullopen topnull degassing phase, followed by a stack (37, 38) degassing phase, between the two phases there being a tight zone which does not deteriorate the material, followed by a carrying, loading and amalgamation phase of the molten material and a final pumping phase with the extrusion of polyethyleneterephthalate.

摘要翻译： 聚对苯二甲酸乙二醇酯挤出设备的颗粒形式，仍然是潮湿的，来自两个研磨的回收产物和原始材料的材料，包括底盘（29），其包含具有两个螺钉（31,32）的同向旋转的油 - 温调挤出机，其中 包括配备有开口（34）的第一区域（A），其中存在用于第一“开顶”脱气的抽吸罩（35），其中存在至少一个堆叠（37,38）的第二区域 ）在两个区域（A，C）之间进一步脱气，存在紧密区域（B）以及由螺钉（31,32）启动的搬运和装载区域（E）。 描述还涉及在同向旋转双螺杆挤出机中实现的聚对苯二甲酸乙二醇酯的挤出方法，其包括在第一区（A）“开顶”脱气阶段，随后是堆（37,38）脱气阶段 两相在其中存在不会使材料变质的紧密区域，随后是熔融材料的承载，加载和合并阶段以及挤出聚对苯二甲酸乙二醇酯的最终泵送阶段。