摘要:
Strontium carbonate can be calcined in a rotary kiln without excessive liquid formation if it is admixed with at least 8 percent finely divided carbon and the kiln is operated with not less than 2 percent combustibles in the exit gases when at least 85 percent of the strontium carbonate feed passes a 325 mesh screen. Under these conditions, the mixture of strontium carbonate and carbon forms agglomerates soon after entering the kiln, minimizing premature burning of the carbon and preventing sticking of the strontium carbonate to the kiln wall.
摘要:
Fine-grained material, such as lime, dolomite and magnesite, is subjected to a thermic treatment in suspension in a hot gas stream and the desired product is subsequently separated in a separator. A vertically disposed treatment chamber is divided into two vertical parallel reaction zones and is connected at its lower end with a hot gas producer whose hot gases pass through the treatment zones and into separator. The material to be treated is so introduced into the treatment chamber that the coarser fraction of the material drops in one of the reaction zones into an upstream of the hot gas having a relatively low velocity while subsequently in the other reaction zone the material is caused to flow with increased velocity and then into the separator. The exhaust gas leaving the separator is conducted to a preheater, preferably a multistage cyclone heat exchanger, and the dust discharge conduit of the latter is connected with one of the two reaction zones of the treatment zone. The treated material which leaves the separator is cooled and the extracted heat is conducted to the hot gas producer as additional combustion air.
摘要:
Systems and methods for using calcium oxide as a carbon dioxide capture tool. The calcium oxide is repeatedly formed from calcium carbonate and is reacted with calcium dioxide back to calcium carbonate where liberated calcium dioxide from calcination of the calcium carbonate is done in a flash calciner and liberated carbon dioxide is captured using a different carbon capture methodology. This method allows for carbon dioxide capture at a location where other methodologies would not be useable and where the stable and generally safe nature of calcium carbonate allows for efficient transport of captured carbon dioxide.
摘要:
This invention discloses a calcination process to produce high purity CO2 from solids containing CaCO3 which operates cyclically and continuously on the solids, arranged in a packed or a moving bed, and wherein each cycle comprises a first step where the combustion at atmospheric pressure of a fuel in the bed of solids containing CaCO3 heats them up to 800-900° C. and a second step wherein a vacuum pressure between 0.05 and 0.5 atm is applied to extract pure CO2 from the solids containing CaCO3 while cooling them by 30-200° C. Said combustion can be carried out directly with air, oxygen enriched air or O2/CO2 mixtures when the process is applied to the calcination of a continuous flow of limestone in a moving bed shaft kiln. The process is also applied to calcine CaCO3 formed in reversible calcium looping processes comprising a carbonation reaction step to form CaCO3 from CaO.
摘要:
The present application pertains to processes producing oxides using a weak acid intermediate. In one embodiment a material comprising calcium carbonate is reacted with a solution comprising aqueous carboxylic acid to form a gas comprising carbon dioxide and a solution comprising aqueous calcium carboxylate. The solution comprising aqueous calcium carboxylate is reacted with sodium sulfate to form a solution comprising aqueous sodium carboxylate and a solid comprising calcium sulfate. The solution comprising aqueous sodium carboxylate is reacted with sulfur dioxide to form sodium sulfite and an aqueous carboxylic acid. The sodium sulfite is separated from said aqueous carboxylic acid and reacted to form a solid comprising calcium sulfite which is decomposed to form calcium oxide and sulfur dioxide.
摘要:
The disclosure discloses a method for preparing calcium oxide using multistage suspension preheater kiln. The steps of the method are: (1) the limestone powder is fed to the multistage suspension preheater kiln for preheating to 800° C. to 900° C.; (2) A preheated material is fed to a decomposition furnace, and calcined at 900° C. to 1100° C. for 25 s to 35 s; (3) A calcined material is fed to a rotary kiln, and calcined at 1100° C. to 1300° C. for 25 to 35 minutes, and finally cooled to obtain calcium oxide.