摘要:
Carbon-neutral fuels are produced from aragonite in a solar thermal decomposition process in which the carbon dioxide generated from the aragonite is catalytically converted to methane, ethanol, or Fischer-Tropsch liquids. Advantageously, heat from the aragonite production can be recovered and used in downstream processes to thereby minimize the carbon footprint of the fuel production.
摘要:
Nanoplatelet forms of metal hydroxide and metal oxide are provided, as well as methods for preparing same. The nanoplatelets are suitable for use as fire retardants and as agents for chemical or biological decontamination.
摘要:
A p-type oxide which is amorphous and is represented by the following compositional formula: xAO.yCu2O where x denotes a proportion by mole of AO and y denotes a proportion by mole of Cu2O and x and y satisfy the following expressions: 0≦x
摘要翻译:一种p型氧化物,其为无定形并由以下组成式表示:xAO.yCu2O其中x表示AO的摩尔比例,y表示Cu2O的摩尔比,x和y满足以下表达式:0 @ x <100和x + y = 100,A是Mg,Ca,Sr和Ba中的任一种,或含有选自Mg,Ca,Sr和Ba中的至少一种的混合物。
摘要:
A particulate, heterogeneous solid CO2 absorbent composition, comprising decomposition products of Ca3Al2O6 after having been heated to a temperature between 500° C. and 925° C. in the presence of H2O and CO2 for a period of time sufficient to allow the Ca3Al2O6 to react and form the particulate, heterogeneous absorbent composition which exhibits a higher concentration of aluminium than calcium in the particle core but a higher concentration of calcium than aluminium at the particle surface. The invention also comprises a method for preparing the particulate, heterogeneous product as well as a method for utilizing the composition for separating CO2 from a process gas.
摘要翻译:在H 2 O和CO 2存在下,将Ca 3 Al 2 O 6的分解产物加热到500℃至925℃之间的温度下,Ca 3 Al 2 O 6反应的时间足以使Ca 3 Al 2 O 6反应 并且形成颗粒状非均相吸收剂组合物,其在颗粒芯中表现出比钙更高的铝浓度,但在颗粒表面具有比铝高的钙浓度。 本发明还包括一种制备颗粒状非均质产品的方法以及一种利用该组合物从工艺气体中分离CO 2的方法。
摘要:
A method of producing a CO2 adsorbent and CO2 adsorbents. The method including the steps of: (a) producing a mixture of at least one calcium salt and at least one metal support cation in at least one solvent; (b) drying the mixture to produce a solid containing a calcium metal salt; and (c) calcining the dried solid to produce a sorbent of calcium oxide dispersed in a porous metal support.
摘要:
The present invention provides methods of utilizing biomass materials, in which biomass materials are mixed directly with the reactants and the biomass materials while in combustion can directly heat up the reactants to the temperature required for the chemical reaction to take place. Such chemical reaction takes advantage of the heat energy, carbon element and/or silicon element that are inherently contained within biomass materials. For instance, biomass materials produce powdery or lumpy alkali metal silicates when chemically reacting with alkali metal compounds, synthesize black powder when reacting with nitrates, redox sulfates and decompose carbonates, etc. The present invention is characterized with high heat utilization, no need for external heat source, low power consumption, greatly reduced equipment costs, and the significantly simplified process.
摘要:
PHOSPHORIS ACID CAN BE PREPARED FROM PHOSPHATE ROCK BY ACIDULATING THE ROCK FROM ABOUT 75-85% BY WIEGHT NITRIC ACID TO FORM AN ACIDULATE AND THEREAFDTER PRECIPITATING ANHYDROUS CALCIUM NITRATE BY RAISING THE NITRIC ACID CONTENT OF THE ACIDULATE. THE PRECIPITATED ANHYDROUS CALCIUM NITRATE CAN BE DECOMPOSED IN THE PRESENCE OF A NITROGEN OXIDE CONTAINING ATMOSPHERE AND THE PRODUCT GASES CAN BE USED TO FORM NITRIC ACID WHICH CAN BE RECYCLED TO THE ACIDULATION OR ANHYDROUS CALCIUM NITRATE PRECIPITATION STEPS. THE DECOMPOSITION GASES CAN ALSO BE RECYCLED DIRECTLY TO FORM NITRIC ACID IN SITU. BY DECOMPOSING THE PRECIPITATED CALCIUM NITRATE IN THE PRESENCE OF A NITROGEN OXIDE-CONTAINING ATMOSPHERE, A PRODUCT GAS STREAM CONTAINING A HIGH PROPORTION OF NITROGEN AND A RELATIVELY LOW PROPORTION OF UNDESIRED INERTS MAY BE OBATINED. THE CALCIUM NITRATE MAY BE DECOMPOSED IN THE PRESENCE OF A BED OF FLUIDIZED SOLIDS. THE BED MAY COMPRISE BY-PRODUCT LIME THAT IS HEATED AND RECYCLED TO THE DECOMPOSITION ZONE. A PORTION OF THE LPRODUCT GAS MAY BE RECYCLED TO THE DECOMPOSITION ZONE AT A BED FLUIDIZING VELOCITY. THE PRODUCT GASES, COMPRISING NITROGEN OXIDES AND OXYGEN, ARE PARTICULARLY SUITABLE FOR USE IN THE FORMATION OF CONCENTRATED NITRIC ACID. THIS ACID MAY CONVENIENTLY BE RECYCLED TO THE ACIDULATION OR ANHYDROUS CALCIUM NITRATE SEPARATION OPERATIONS. THE PRODUCT GASES MAY ALSO ADVANTAGEOUSLY BE RECYCLED DIRECTLY TO THE ACIDULATION MIXTURE SO AS TO FORM NITRIC ACID IN SITU.
摘要:
The present application pertains to methods for making metal oxides and/or citric acid. In one embodiment, the application pertains to a process for producing calcium oxide, magnesium oxide, or both from a material comprising calcium and magnesium. The process may include reacting a material comprising calcium carbonate and magnesium carbonate. Separating, concentrating, and calcining may lead to the production of oxides such as calcium oxide or magnesium oxide. In other embodiments the application pertains to methods for producing an alkaline-earth oxide and a carboxylic acid from an alkaline earth cation-carboxylic acid anion salt. Such processes may include, for example, reacting an alkaline-earth cation-carboxylic acid anion salt with aqueous sulfur dioxide to produce aqueous alkaline-earth-bisulfite and aqueous carboxylic acid solution. Other useful steps may include desorbing, separating, and/or calcining.
摘要:
The present application pertains to processes producing oxides using a weak acid intermediate. In one embodiment a material comprising calcium carbonate is reacted with a solution comprising aqueous carboxylic acid to form a gas comprising carbon dioxide and a solution comprising aqueous calcium carboxylate. The solution comprising aqueous calcium carboxylate is reacted with sodium sulfate to form a solution comprising aqueous sodium carboxylate and a solid comprising calcium sulfate. The solution comprising aqueous sodium carboxylate is reacted with sulfur dioxide to form sodium sulfite and an aqueous carboxylic acid. The sodium sulfite is separated from said aqueous carboxylic acid and reacted to form a solid comprising calcium sulfite which is decomposed to form calcium oxide and sulfur dioxide.