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公开(公告)号：US4344868A
公开(公告)日：1982-08-17
申请号：US137943
申请日：1980-04-07
申请人： Clarence D. Chang , William H. Lang
发明人： Clarence D. Chang , William H. Lang
IPC分类号： B01J29/44 , B01J29/65 , B01J29/70 , B01J29/74 , C07C29/157 , C07C29/158 , C07C45/49 , C07C51/10 , B01J29/32
CPC分类号： C07C51/10 , B01J29/44 , C07C29/157 , C07C29/158 , C07C45/49 , B01J29/65 , B01J29/70 , Y02P20/52
摘要： The conversion of synthesis gas comprising hydrogen and carbon oxides to form oxygenate-containing mixtures which are limited compositionally in being virtually free of C.sub.11 + compounds, with a zeolite which is virtually free of acid sites and characterized by a silica to alumina mole ratio of at least about 12 and a constraint index within the range of 1 to 12, having intimately combined therewith a metal selected from the group consisting of rhodium, platinum, palladium and iridium.
摘要翻译： 包含氢和碳氧化物的合成气的转化形成含有化合物的混合物，其组成上实质上不含C 11+化合物，其中实际上不含酸性位点的沸石，其特征在于二氧化硅与氧化铝的摩尔比至少为 约12和1至12范围内的约束指数，其与选自铑，铂，钯和铱的金属紧密结合。
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82.发明授权Process for producing methanol from synthesis gas with palladium-calcium catalysts 失效用钯 - 钙催化剂从合成气生产甲醇的方法
公开(公告)号：US4289710A
公开(公告)日：1981-09-15
申请号：US105408
申请日：1979-12-19
申请人： Steven W. Kaiser
发明人： Steven W. Kaiser
IPC分类号： C07C29/15 , B01J23/00 , B01J23/58 , C07B61/00 , C07C27/00 , C07C29/157 , C07C31/04 , C07C67/00 , C07C27/06
CPC分类号： C07C29/157 , B01J23/58 , Y02P20/52
摘要： An improved catalytic process for the production of methanol from hydrogen and carbon monoxide at a temperature of from about 200.degree. C. to about 400.degree. C. and a pressure of from about 150 to about 20,000 psia which comprises effecting the reaction in the presence of a heterogeneous solid catalyst comprising palladium and calcium.
摘要翻译： 在约200℃至约400℃的温度和约150至约20,000psia的压力下从氢气和一氧化碳生产甲醇的改进的催化方法，其包括在存在下进行反应 包含钯和钙的非均相固体催化剂。
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公开(公告)号：US4133776A
公开(公告)日：1979-01-09
申请号：US842366
申请日：1977-10-14
IPC分类号： B01J31/20 , C07C29/153 , C07C29/156 , C07C29/157 , C07C29/158 , B01J31/22 , B01J31/24
CPC分类号： B01J31/2243 , B01J31/181 , B01J31/1815 , B01J31/1825 , B01J31/20 , C07C29/153 , C07C29/156 , C07C29/157 , C07C29/158 , B01J2231/648 , B01J2531/822 , B01J31/2234 , Y02P20/52
摘要： A catalyst composition useful in the process for the preparation of polyfunctional oxygen-containing compounds such as ethylene glycol and/or derivatives thereof which comprise reacting an oxide of carbon with hydrogen using a rhodium complex catalyst.
摘要翻译： 用于制备多官能含氧化合物如乙二醇和/或其衍生物的方法中的催化剂组合物，其包括使用铑配合物催化剂使碳氧化物与氢气反应。
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84.发明授权
公开(公告)号：US4119656A
公开(公告)日：1978-10-10
申请号：US797242
申请日：1977-05-16
IPC分类号： C07C29/15 , B01J23/00 , C07B61/00 , C07C27/00 , C07C29/151 , C07C29/157 , C07C31/04 , C07C67/00 , C07C27/06
CPC分类号： C07C29/157 , C07C29/1512 , Y02P20/52
摘要： A heterogeneous catalytic process for producing hydroxylated hydrocarbons containing from 1-2 carbon atoms which comprises: contacting a synthesis gas containing carbon monoxide and hydrogen with a catalyst consisting essentially of palladium at reaction conditions such that hydroxylated compounds are selectively produced while substantially avoiding the concomitant formation of methane or higher molecular weight hydrocarbons.
摘要翻译： 用于生产含有1-2个碳原子的羟基化烃的非均相催化方法，其包括：在反应条件下使含有一氧化碳和氢气的合成气与基本上由钯组成的催化剂接触，使得羟基化化合物被选择性地生产，同时基本上避免了伴随形成 的甲烷或更高分子量的烃。
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公开(公告)号：US3974259A
公开(公告)日：1976-08-10
申请号：US455380
申请日：1974-03-27
申请人： Earle S. Brown
发明人： Earle S. Brown
IPC分类号： B01J31/20 , C01G1/04 , C07C29/157 , C07C29/158 , C01G57/00
CPC分类号： B01J31/20 , C01G1/04 , C07C29/157 , C07C29/158 , B01J2231/641 , B01J2231/648 , B01J2531/0211 , B01J2531/822 , B01J2531/827 , B01J2531/845 , B01J2531/96 , Y02P20/52
摘要： This invention relates to novel carbonyl mixed metal salts, containing more than one metal and having the formula:M.sub.2 T.sub.y T'.sub.12.sub.-y (CO).sub.30wherein M is a monovalent metal cation which is one of lithium, sodium, potassium, rubidium, cesium, francium, rhodium, copper, silver, gold, iridium, indium, and thallium, T and T' are each different metals and each is one of cobalt, rhodium and iridium and y may have values from 1 to 11.These compounds are useful catalysts in the reaction between carbon monoxide and hydrogen to produce oxygenated compounds such as methanol, ethylene glycol, glycerine and 1,2-propylene glycol.
摘要翻译： 本发明涉及含有多于一种金属并具有下式的新型羰基混合金属盐：
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公开(公告)号：US3929969A
公开(公告)日：1975-12-30
申请号：US45537774
申请日：1974-03-27
申请人： UNION CARBIDE CORP
发明人： BROWN EARLE S
IPC分类号： B01J31/20 , C01G1/04 , C07C29/157 , C07C29/158 , C01F17/00
CPC分类号： C07C29/157 , B01J31/20 , B01J2231/641 , B01J2231/648 , B01J2531/0211 , B01J2531/822 , B01J2531/827 , B01J2531/845 , B01J2531/96 , C01G1/04 , C07C29/158 , Y02P20/52 , C07C31/202
摘要： This invention relates to novel carbonyl mixed metal salts, containing more than one metal and having the formula: M2(TyT''12 y (CO)30)3 wherein M is a trivalent metal cation which is one of aluminum, gallium, iridium, scandium, yttrium, and rhenium, T and T'' are each different metals selected from the group consisting of cobalt, iridium and rhodium, and y may be any whole number between 1 and 11. These compounds are useful catalysts in the reaction between carbon monoxide and hydrogen to produce oxygenated compounds such as methanol, ethylene glycol, glycerine and 1,2-propylene glycol.
摘要翻译： 本发明涉及含有多于一种金属并具有下式的新型羰基混合金属盐：
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公开(公告)号：US11865519B2
公开(公告)日：2024-01-09
申请号：US17273108
申请日：2019-09-05
申请人： TOTAL SE , ETH ZURICH
发明人： Joseph Stewart , Daniel Curulla-Ferre , Javier Perez-Ramirez , Cecilia Mondelli , Matthias Frei
IPC分类号： B01J23/44 , B01J23/62 , B01J6/00 , B01J23/42 , B01J35/02 , B01J37/03 , C07C1/04 , B01J21/06 , B01J23/08 , B01J35/00 , B01J35/10 , B01J37/02 , C07C29/157
CPC分类号： B01J23/62 , B01J6/001 , B01J21/066 , B01J23/08 , B01J23/42 , B01J23/44 , B01J35/006 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J37/0201 , B01J37/031 , C07C1/043 , C07C1/046 , C07C29/157
摘要： Method to prepare a catalyst for use in a process for the synthesis of methanol, comprising indium oxide in the form of In2O3, and at least one additional metal selected from a noble metal; and in that the average particle size of said noble metal phase is, preferably at least 0.05 nm, and less than 5 nm as determined by STEM-EDX, characterized in that the catalyst is prepared by co-precipitation of a saline solution at a pH above 8.5 comprising an indium salt and a salt of the at least one additional metal selected from a noble metal and optionally further comprising a salt of the at least one alkaline earth metal.
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88.发明授权公开(公告)号：US11752491B2
公开(公告)日：2023-09-12
申请号：US17035144
申请日：2020-09-28
申请人： Hyundai Motor Company , Kia Motors Corporation , Research & Business Foundation Sungkyunkwan University
发明人： Chae Hwan Hong , Jin Woo Choung , Jong Wook Bae , Tae Yeol Goag
CPC分类号： B01J23/44 , B01J23/08 , B01J23/10 , B01J35/1004 , B01J35/1038 , B01J37/08 , C07C29/157 , C07C31/04
摘要： Disclosed are a catalyst used for converting carbon dioxide to methanol by hydrogenation and a method preparing the sane. The caratlys may include: a mesoporous indium oxide; and a catalyst supported on the mesoporous indium oxide. Preferably, a porous structure of the mesoporous indium oxide may have Ia3d symmetry and may include mesopores and micropores interconnecting the mesopores.
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公开(公告)号：US20170342005A1
公开(公告)日：2017-11-30
申请号：US15497705
申请日：2017-04-26
IPC分类号： C07C29/158 , C07C31/10 , C07C31/08 , C07C31/04 , C07C29/32 , C07C31/12 , C07C29/157
CPC分类号： C07C29/32 , C07C29/1516 , C07C29/157 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12 , C07C31/202 , C07C31/205
摘要： The invention relates to processes for oxygenate synthesis and homologation, to equipment and materials useful in such processes, and to the use of such oxygenate for producing olefin and polyolefin.
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公开(公告)号：US09809519B1
公开(公告)日：2017-11-07
申请号：US15497705
申请日：2017-04-26
IPC分类号： C07C29/158 , C07C31/04 , C07C31/08 , C07C29/157 , C07C31/12 , C07C31/10 , C07C29/32
CPC分类号： C07C29/32 , C07C29/1516 , C07C29/157 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12 , C07C31/202 , C07C31/205
摘要： The invention relates to processes for oxygenate synthesis and homologation, to equipment and materials useful in such processes, and to the use of such oxygenate for producing olefin and polyolefin.
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