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    Polyvinyl chloride, and epoxide crosslinked with amine-ketone condensation product
    84.
    发明授权
    Polyvinyl chloride, and epoxide crosslinked with amine-ketone condensation product 失效
    聚氯乙烯和与胺 - 酮缩合产物交联的环氧化物

    公开(公告)号：US3234165A

    公开(公告)日：1966-02-08

    申请号：US24487562

    申请日：1962-12-17

    申请人： CIBA LTD

    发明人： JAMES HAYES BARRIE

    IPC分类号： C08F8/00 ,  C08G59/28 ,  C08G59/40 ,  C08G59/54 ,  C08L27/06 ,  C08L63/00 ,  C09D127/06 ,  C09D163/00 ,  C09J127/06 ,  C09J163/00

    CPC分类号： C08L63/00 ,  C08F8/00 ,  C08G59/28 ,  C08G59/4042 ,  C08G59/54 ,  C08K5/0025 ,  C08L27/06 ,  C08L57/08 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/28 ,  C09D127/06 ,  C09D163/00 ,  C09J127/06 ,  C09J163/00 ,  C08L61/20 ,  C08L79/08 ,  C08F14/00 ,  C08L2666/04

    摘要： Compositions curable by heat comprise a halogen-containing vinyl polymer, a plasticizer therefor in which the polymer is insoluble at room temperature, an epoxide resin having an epoxide equivalency greater than one and as curing agent a condensation product containing no primary amino groups and made by condensing an amine containing two or more primary amino groups with a volatile ketone, the composition also comprising sufficient moisture to be curable by heat. Specified halogen-containing polymers are polyvinyl chloride; copolymers of vinyl chloride with vinyl acetate, ethylene, acrylic esters, acrylonitrile, maleic anhydride and vinylidene chloride; and chlorinated polyvinyl chloride, partially hydrolysed polyvinyl acetates and acetals. Specified plasticizers are phthalates, sebacates, phosphates, epoxidised unsaturated fatty acids and alcohols and esters thereof. Specified epoxide resins are polyglycidyl ethers of polyhydric compounds, e.g. butane-1, 4-diol, glycerol, N-phenyldiethanolamine, resorcinol, 2, 2-bis (4-hydroxyphenyl) propane and phenol-aldehyde condensates; polyglycidyl esters of polycarboxylic acids, e.g. phthalic acid; aminopolyepoxides obtained by dehydrohalogenating reaction products of epihalohydrins with amines, e.g. n-butylamine, aniline and 4,41-di(monomethylamino)-diphenylmethane; and epoxidised unsaturated polyolefins. The curing agent may be derived from acetone, methyl ethyl ketone, methyl isopropyl ketone, diisopropyl ketone, methyl isobutyl ketone or methyl cyclohexanone, and an alkylene diamine or polyalkylene polyamine, bis(4-amino -3- methylcyclohexyl) methane, 3-(3-aminocyclohexyl) n-propylamine, bis(4-aminophenyl) methane, bis(4-aminophenyl) sulphone or m-phenylenediamine. The compositions may also contain fillers, reinforcements, pigments and dyes, and water liberating materials such as hydrated calcium sulphate. The compositions may be used for coating metals, glass, wood, ceramics and polyester and polyamide textiles, and as adhesives. Examples describe compositions comprising polyvinyl chloride, adipate plasticizer, polyethylene oxide, epoxidised soya bean oil, organotin stabilizer and (1) the reaction products of epichlorhydrin and 2,2-bis(4-hydroxyphenyl) propane and of diethylene triamine and methyl isobutyl ketone; (2) the reaction products of epichlorhydrin and N-phenyldiethanolamine and of diethylene triamine and methyl isobutyl ketone; and (3) a vinyl chloride/vinyl acetate/maleic anhydride terpolymer, silica and reaction products of epichlorhydrin and 2,2-bis(4-hydroxyphenyl) propane and of ethylene diamine and methyl isobutyl ketone. Specification 777,052 is referred to.ALSO:Substrates such as metals, e.g. mild steel and aluminium, glass, wood and ceramics may be coated with heat curable compositions comprising a halogen-containing vinyl polymer, a plasticizer therefor in which the polymer is insoluble at room temperature, an epoxide resin having an epoxide equivalency greater than one and as curing agent a condensation product containing no primary amino groups and made by condensing an amine containing two or more primary amino groups with a volatile ketone, the composition also comprising sufficient moisture to be curable by heat. Specified polymers are polymers and copolymers of vinyl chloride, and chlorinated polyvinyl chloride, partially hydrolysed polyvinyl acetates and acetals. Specified plasticizers are phthalates, sebacates, phosphates, epoxidized unsaturated fatty acids and alcohols and esters thereof. Specified epoxide resins are polyglycidyl ethers of polyhydric compounds, e.g. butane-1,4-diol, glycerol, N-phenyldiethanolamine, resorcinol, 2,2-bis(4-hydroxyphenyl) propane and phenol-aldehyde condensates; polyglycidyl esters of polycarboxylic acids, e.g. phthalic acid; aminopolyepoxides obtained by dehydrohalogenating reaction products of epihalohydrins with amines, e.g. n-butylamine, aniline and 4,41-di(monomethylamino)-diphenylmethane; and epoxidized unsaturated polyolefins. The curing agent may be derived from acetone, methyl ethyl ketone, methyl isopropyl ketone, diisopropyl ketone, methyl isobutyl ketone or methyl cyclohexanone, and an alkylene diamine, polyalkylene polyamine, bis(4-amino-3-methylcyclohexyl) methane, 3(3-aminocyclohexyl)n-propylamine, bis(4-aminophenyl) methane, bis(4-aminophenyl) sulphone or m-phenylene diamine. The compositions may also comprise fillers, pigments, dyes, and water liberating materials such as hydrated calcium sulphate. Examples describe the coating of shot blasted mild steel panels with compositions comprising polyvinyl chloride, adipate plasticizer, polyethylene oxide, organotin stabilizer, epoxidized soya bean oil, a condensate of diethylene triamine and methyl isobutyl ketone and (1) a condensate of epichlorhydrin and 2,2-bis(4-hydroxyphenyl) propane and (2) a condensate of epichlorhydrin and N-phenyl diethanolamine. Specification 777,052 is referred to.

    SEALANT COMPOSITION AND SEALANT
    88.
    发明申请
    SEALANT COMPOSITION AND SEALANT 审中-公开

    公开(公告)号：US20190185657A1

    公开(公告)日：2019-06-20

    申请号：US16311232

    申请日：2017-05-12

    申请人： SEKISUI POLYMATECH CO., LTD.

    发明人： Hitomi AIZAWA

    IPC分类号： C08L53/02 ,  C08F20/20 ,  C08F2/46 ,  C08G59/28 ,  C08G59/50 ,  H01L23/29

    CPC分类号： C08L53/02 ,  C08F2/44 ,  C08F2/46 ,  C08F20/20 ,  C08G59/28 ,  C08G59/50 ,  C08L25/04 ,  C08L63/00 ,  C08L2203/20 ,  H01L23/29 ,  H01L23/293 ,  H01L23/31 ,  H05K3/28

    摘要： Provided are a sealant that is affixed to an electronic device provided on an electronic substrate or the like or to an exposed metal portion to protect the electronic device or other adherend from moisture and the like and a sealant composition before being cured to become the sealant. The sealant and the sealant composition have form stability, flexibility, and adhesiveness.The sealant composition contains, as essential components, a cured epoxy resin having a flexible backbone, a monofunctional (meth)acrylic ester monomer, a photo-radical polymerization initiator, and a styrene-based elastomer. The monofunctional (meth)acrylic ester monomer is curable by irradiation with light. The sealant composition has form stability and also has a flexibility such that a load measured when the sealant composition having a thickness of 1 mm is compressed by 25% with a cylindrical probe having a bottom end with a diameter of 10 mm is 0.19 to 3.2 N. The sealant is obtained by photocuring the sealant composition.

    MECHANO-RESPONSIVE COMPOSITION
    89.
    发明申请
    MECHANO-RESPONSIVE COMPOSITION 有权
    机械响应组合物

    公开(公告)号：US20160168314A1

    公开(公告)日：2016-06-16

    申请号：US15011934

    申请日：2016-02-01

    申请人： Henkel AG & Co. KGaA

    发明人： Haiping Wu ,  Jingfen Zhang ,  Rainer Schoenfeld ,  Thomas Bachon

    IPC分类号： C08G59/28 ,  C08G59/68 ,  C08G59/66

    CPC分类号： C08G59/28 ,  C08G59/3227 ,  C08G59/66 ,  C08G59/686 ,  C08K5/00

    摘要： The present invention provides a two-part mechano-responsive composition, comprising: Part I: a tetra-glycidyl amine multifunctional epoxy resin represented by the general formula (I); and Part II: a polythiol and an amine. The cured composition has a mechano-responsive property without adding any dyes or luminescence agents, and by subjected to mechanical stimuli, the cured composition changes its colour, and the colour is in the visible spectrum range, which can be easily checked with naked eyes; and the colour change is reversible.

    摘要翻译： 本发明提供两部分机械响应组合物，其包含：第一部分：由通式（I）表示的四缩水甘油胺多官能环氧树脂; 和第二部分：多硫醇和胺。 固化的组合物具有机械响应性能，而不添加任何染料或发光剂，并且经受机械刺激，固化的组合物改变其颜色，并且颜色处于可见光谱范围，其可以用肉眼容易地检查; 颜色变化是可逆的。

    Thermally hardenable epoxy resin composition having an improved impact resistance at low temperatures
    90.
    发明授权
    Thermally hardenable epoxy resin composition having an improved impact resistance at low temperatures 有权
    在低温下具有改善的耐冲击性的热固化性环氧树脂组合物

    公开(公告)号：US09221969B2

    公开(公告)日：2015-12-29

    申请号：US10538877

    申请日：2003-12-17

    申请人： Andreas Kramer ,  Jurgen Finter

    发明人： Andreas Kramer ,  Jurgen Finter

    IPC分类号： C08L63/00 ,  C08G59/28 ,  C09J163/00

    CPC分类号： C08L63/00 ,  C08G59/28 ,  C08L2666/22 ,  C09J163/00

    摘要： The invention relates to compositions containing at least one epoxide adduct A that comprises an average of more than one epoxide group per molecule, at least one polymer B of formula (I), at least one thixotropic agent C based on a urea derivative in a non-diffusing carrier material, and at least one hardener D for epoxy resins, which is activated at an increased temperature. Said composition is used especially as an adhesive and is provided with an extraordinarily high impact peel working value, especially at low temperatures. The invention further relates to epoxide group-terminal impact strength modifiers of formula (I), which significantly increase the impact resistance in epoxy resin compositions, particularly two-component epoxy resin compositions.

    摘要翻译： 本发明涉及至少一种包含至少一种环氧化物加合物A的组合物，其每分子平均含有多于一个环氧基团，至少一种式（I）的聚合物B，至少一种基于非衍生物的脲衍生物的触变剂C， 以及至少一种用于环氧树脂的硬化剂D，其在升高的温度下被活化。 所述组合物特别用作粘合剂，并且具有特别高的冲击剥离工作值，特别是在低温下。 本发明还涉及式（I）的环氧基团 - 末端冲击强度改性剂，其显着提高了环氧树脂组合物，特别是双组分环氧树脂组合物的耐冲击性。