公开(公告)号：US09023937B2

公开(公告)日：2015-05-05

申请号：US13483664

申请日：2012-05-30

申请人： Takuya Sudo ,  Hisakatsu Hama

发明人： Takuya Sudo ,  Hisakatsu Hama

IPC分类号： C08C19/20 ,  C08C19/25 ,  C08K3/36 ,  C08K5/54 ,  C08K5/548 ,  C08J3/20

CPC分类号： C08K5/548 ,  C08C19/20 ,  C08C19/25 ,  C08J3/203 ,  C08J2309/00 ,  C08K3/36 ,  C08K5/54 ,  C08L9/00 ,  C08L9/06

摘要： A method for producing a rubber composition, the method comprising a step of producing a pre-kneaded rubber composition by kneading a butadiene-based rubber and 1 to 20 parts by weight of a silane coupling agent per 100 parts by weight of the butadiene-based rubber and a step of kneading the pre-kneaded rubber composition and 30 to 200 parts by weight of a silica per 100 parts by weight of the butadiene-based rubber used for producing the pre-kneaded rubber composition.

摘要翻译： 一种橡胶组合物的制造方法，其特征在于，将丁二烯系橡胶与丁二烯系橡胶100重量份混合1〜20重量份的硅烷偶联剂来制造预捏合橡胶组合物的工序 橡胶组合物的捏和和每100重量份用于制备预混合橡胶组合物的丁二烯基橡胶30至200重量份二氧化硅的步骤。

公开(公告)号：US08895670B2

公开(公告)日：2014-11-25

申请号：US13499508

申请日：2010-09-30

申请人： Steven Luo

发明人： Steven Luo

IPC分类号： C08C19/25 ,  C08F136/06 ,  C08F236/06 ,  C08C19/44

CPC分类号： C08C19/44 ,  C08F136/06 ,  C08F236/06 ,  C08F4/545

摘要： A method for preparing a functionalized polymer, the method comprising the steps of (i) polymerizing monomer with a coordination catalyst to form a reactive polymer; and (ii) reacting the reactive polymer with a carboxylic or thiocarboxylic ester containing a silylated amino group.

摘要翻译： 一种制备官能化聚合物的方法，所述方法包括以下步骤：（i）使单体与配位催化剂聚合以形成反应性聚合物; 和（ii）使反应性聚合物与含有甲硅烷基化氨基的羧酸或硫代羧酸酯反应。

公开(公告)号：US20130296475A1

公开(公告)日：2013-11-07

申请号：US13995805

申请日：2011-12-13

申请人： Nathalie Simon ,  Stéphanie De Landtsheer

发明人： Nathalie Simon ,  Stéphanie De Landtsheer

IPC分类号： C08L9/00 ,  C08C19/25

CPC分类号： C08L9/00 ,  B60C1/0016 ,  C08C19/25 ,  C08F8/42 ,  C08F2810/40 ,  C08K3/36 ,  C08K5/548 ,  C08L9/06 ,  C08L25/04 ,  C08L2205/03 ,  C08F112/08

摘要： The present invention relates to a diene rubber composition reinforced with an inorganic filler comprising a thermoplastic polymer bearing, at at least one end, a silanol or silyl ether functional group. The presence of the functional thermoplastic polymer makes it possible to improve the compromise of performances, which are the handling and the grip, of a tyre having a tread that is based on such a composition.

摘要翻译： 本发明涉及用无机填料增强的二烯橡胶组合物，所述无机填料包括在至少一端具有硅烷醇或甲硅烷基醚官能团的热塑性聚合物。 功能性热塑性聚合物的存在使得可以改进具有基于这种组合物的具有胎面的轮胎的性能（即处理和抓地力）的折衷。

公开(公告)号：US08415435B2

公开(公告)日：2013-04-09

申请号：US12528629

申请日：2008-02-27

申请人： Mayumi Oshima

发明人： Mayumi Oshima

IPC分类号： C08C19/25 ,  C08C19/22 ,  C08C19/44 ,  C08F4/48

CPC分类号： C08C19/25 ,  C08C19/44 ,  C08F36/04 ,  C08F236/14 ,  C08L15/00 ,  C08L21/00 ,  C08F4/48 ,  C08L2666/08

摘要： An object of the present invention is to provide a conjugated diene-based polymer capable of providing a polymer composition which is excellent in a reduction in fuel consumption when silica is incorporated as a filler, a process for producing the conjugated diene-based polymer, and a polymer composition comprising said conjugated diene-based polymers and silica. The present invention provides a conjugated diene-based polymer comprising a conjugated diene-based constitutional unit and a constitutional unit expressed by the following formula (I), wherein said constitutional unit expressed by the formula (I) is between one of the conjugated diene-based constitutional units and another one: (I) (wherein X1, X2 and X3 represent independently a group expressed by the following formula (II), a hydroxide group, or a hydrocarbon group, and at least one of X1, X2 and X3 is the group expressed by the formula (II), or a hydroxide group: (II) wherein R1 and R2 represent independently a hydrocarbon group having 1 to 6 carbon atoms which can contain a nitrogen atom, an oxygen atom, or a silicon atom, and R1 and R2 can be combined to form a ring structure).

摘要翻译： 本发明的目的是提供一种能够提供一种聚合物组合物，该聚合物组合物在掺入二氧化硅作为填料时燃料消耗降低，该共轭二烯系聚合物的制造方法和 包含所述共轭二烯基聚合物和二氧化硅的聚合物组合物。 本发明提供一种共轭二烯系结构单元和由下式（I）表示的结构单元的共轭二烯系聚合物，式（I）表示的结构单元为共轭二烯系结构单体之一， （I）（其中X1，X2和X3独立地表示由下式（II）表示的基团，氢氧基或烃基，X1，X2和X3中的至少一个为 由式（II）表示的基团或氢氧化物：（II）其中R1和R2独立地表示可以含有氮原子，氧原子或硅原子的具有1至6个碳原子的烃基，以及 R1和R2可以组合形成环结构）。

公开(公告)号：US08106130B2

公开(公告)日：2012-01-31

申请号：US12309586

申请日：2007-07-19

申请人： Ryoko Fukuoka ,  Haruo Yamada ,  Norifusa Ishimura

发明人： Ryoko Fukuoka ,  Haruo Yamada ,  Norifusa Ishimura

IPC分类号： C08C19/22 ,  C08C19/25

CPC分类号： C08C19/44 ,  C08F8/42 ,  C08F212/00

摘要： A modified conjugated diene polymer comprises a modifying group based on a low molecular weight compound having two or more tertiary amino groups and one or more alkoxysilyl groups in a molecule which bonds to a conjugated diene polymer obtained by polymerization of a conjugated diene compound or a conjugated diene polymer obtained by copolymerization of a conjugated diene compound and an aromatic vinyl compound. The process for producing the modified conjugated diene polymer comprises the steps of: polymerizing a conjugated diene compound or copolymerizing a conjugated diene compound and an aromatic vinyl compound in a hydrocarbon solvent using an alkali metal initiator and/or an alkaline earth metal initiator; and reacting active terminals of the resulting polymer with a low molecular weight compound having two or more tertiary amino groups and one or more alkoxysilyl groups in the molecule.

摘要翻译： 改性共轭二烯聚合物包含基于分子中具有两个或更多个叔氨基和一个或多个烷氧基甲硅烷基的低分子量化合物的改性基团，其与通过共轭二烯化合物或共轭二烯化合物的共聚获得的共轭二烯聚合物键合 通过共轭二烯化合物和芳香族乙烯基化合物的共聚得到的二烯系聚合物。 制备改性共轭二烯聚合物的方法包括以下步骤：使用碱金属引发剂和/或碱土金属引发剂在烃溶剂中聚合共轭二烯化合物或共轭二烯化合物和芳族乙烯基化合物; 并使所得聚合物的活性末端与分子中具有两个或更多个叔氨基和一个或多个烷氧基甲硅烷基的低分子量化合物反应。

公开(公告)号：US08071682B2

公开(公告)日：2011-12-06

申请号：US12140301

申请日：2008-06-17

申请人： Naoaki Maeda ,  Mayumi Oshima ,  Katsunari Inagaki

发明人： Naoaki Maeda ,  Mayumi Oshima ,  Katsunari Inagaki

IPC分类号： C08C19/25

CPC分类号： C08F36/04 ,  C08C19/44 ,  C08K3/013 ,  C08F4/48 ,  C08L15/00

摘要： A method for producing a conjugated diene polymer is provided that includes a step of polymerizing a conjugated diene-containing monomer in a hydrocarbon solvent in the presence of an alkali metal catalyst, thus giving a polymer having a catalyst-derived alkali metal at one terminus of a polymer chain comprising a conjugated diene-based monomer unit, and a step of reacting the polymer obtained in the step of polymerizing and a trialkoxysilane compound represented by the formula below. (In the formula, M denotes an oxygen atom or a sulfur atom, R1, R2, and R3 independently denote an alkyl group having 1 to 4 carbon atoms, m denotes an integer of 1 to 5, and n denotes an integer of 0 to 5.) There are also provided a conjugated diene polymer produced by the production method, and a polymer composition containing a rubber component that includes the conjugated diene polymer and carbon black and/or silica, the total content of the carbon black and the silica being 5 to 200 parts by weight relative to 100 parts by weight of the rubber component.

摘要翻译： 提供一种共轭二烯聚合物的制造方法，其包括在碱金属催化剂的存在下，在烃溶剂中使含共轭二烯的单体聚合的步骤，由此得到在一端具有催化剂衍生的碱金属的聚合物 包含共轭二烯基单体单元的聚合物链和使聚合步骤中获得的聚合物与由下式表示的三烷氧基硅烷化合物反应的步骤。 （式中，M表示氧原子或硫原子，R1，R2，R3分别表示碳原子数1〜4的烷基，m表示1〜5的整数，n表示0〜 5）还提供了通过制造方法制造的共轭二烯聚合物和含有共轭二烯聚合物和炭黑和/或二氧化硅的橡胶成分的聚合物组合物，炭黑和二氧化硅的总含量为 相对于100重量份的橡胶组分为5〜200重量份。

公开(公告)号：US07915349B2

公开(公告)日：2011-03-29

申请号：US11992306

申请日：2006-09-19

申请人： Haruo Yamada ,  Keiichi Toda ,  Norifusa Ishimura

发明人： Haruo Yamada ,  Keiichi Toda ,  Norifusa Ishimura

IPC分类号： C08C19/22 ,  C08C19/25

CPC分类号： C08C19/44 ,  C08F8/42 ,  C08L19/006 ,  C08F212/00

摘要： A process for producing a conjugated diene polymer composition, which comprises of polymerizing a conjugated diene compound or a conjugated diene compound and an aromatic vinyl compound in a hydrocarbon solvent in the presence of at least one compound selected from the group consisting of organoalkali metals and organoalkaline earth metals as an initiator and then reacting the active end of the resulting polymer with a low molecular compound represented by the following formula (1) or the following formula (2): wherein the variables R through R9 are as defined in the Specification.

摘要翻译： 一种共轭二烯聚合物组合物的制备方法，其包括在烃溶剂中在至少一种选自有机碱金属和有机碱金属的化合物存在下，使共轭二烯化合物或共轭二烯化合物和芳香族乙烯基化合物聚合 然后使所得聚合物的活性末端与下式（1）或下式（2）表示的低分子化合物反应：其中变量R至R9如本说明书中所定义。

公开(公告)号：US07825195B2

公开(公告)日：2010-11-02

申请号：US12611807

申请日：2009-11-03

申请人： Adel Farhan Halasa ,  Wen-Liang Hsu ,  Chad Aaron Jasiunas

发明人： Adel Farhan Halasa ,  Wen-Liang Hsu ,  Chad Aaron Jasiunas

IPC分类号： C08C19/25 ,  C08F8/18 ,  C08F36/04 ,  C08J3/24 ,  B60C1/00

CPC分类号： C08C19/44 ,  B60C1/0016 ,  C08G83/003 ,  C08L15/00 ,  C08L101/005 ,  Y10T152/10 ,  Y10T152/10495

摘要： This invention discloses a process for synthesizing a dendrimer of a rubbery polymer comprising: (a) reacting a lithium terminated rubbery polymer with a halogenated silicon containing compound to produce a polymer which is terminated with halogenated silicon moieties, wherein the halogenated silicon contain compound has at least four halogen atoms which are bonded directly to silicon atoms, wherein the ratio of the lithium terminated rubbery polymer to halogen atoms in the halogenated silicon containing compound is within the range of 2:n to (n-1):n, wherein n represents the number of halogen atoms that are bonded directly to silicon atoms in the halogenated silicon containing compound, wherein the halogenated silicon containing compound contains at least three halogen atoms which are bonded directly to a silicon atom; (b) reacting the polymer which is terminated with halogenated silicon moieties with a molar excess of a tertiary alcohol to produce a polymer which is terminated with hydroxy silyl moieties; and (c) allowing the polymer which is terminated with the hydroxy silyl moieties to couple under conditions sufficient to produce a dendrimer containing siloxane linkages. It has also be found that similar dendrimers having improved processability can be make utilizing halogenated tin containing compounds in stead of the halogenated silicon containing compound.

摘要翻译： 本发明公开了一种用于合成橡胶状聚合物树枝状聚合物的方法，其包括：（a）使锂封端的橡胶状聚合物与含卤化硅的化合物反应以制备用卤化硅部分封端的聚合物，其中卤化硅含有化合物在 至少四个与硅原子直接键合的卤素原子，其中锂封端的橡胶状聚合物与含卤化硅化合物中的卤素原子的比例在2：n至（n-1）：n的范围内，其中n表示 与卤代硅化合物中的硅原子直接键合的卤素原子数，其中含卤化硅的化合物含有至少三个与硅原子直接键合的卤素原子; （b）将用卤代硅部分封端的聚合物与摩尔过量的叔醇反应，以产生用羟基甲硅烷基部分封端的聚合物; 和（c）使在羟基甲硅烷基部分封端的聚合物在足以产生含有硅氧烷键的树枝状聚合物的条件下偶联。 还可以发现，具有改进加工性能的类似树枝状大分子可以利用含卤化锡的化合物代替含卤化硅的化合物。

公开(公告)号：US07781533B2

公开(公告)日：2010-08-24

申请号：US10496983

申请日：2002-11-27

申请人： Youichi Ozawa ,  Hajime Kondou ,  Noriko Endou

发明人： Youichi Ozawa ,  Hajime Kondou ,  Noriko Endou

IPC分类号： C08C19/25 ,  C08C19/34 ,  C08F36/04

CPC分类号： B60C1/00 ,  C08C19/38 ,  C08C19/44

摘要： A process for producing a conjugated diene-based polymer which comprises, in the first modification, modifying a conjugated diene-based polymer having active chain ends, which is obtained by polymerizing a diene-based monomer singly or with other monomers and has a content of a cis-1,4 unit of 75% by mole or greater in the conjugated diene portion of the main chain, by reacting the active chain ends with a hydrocarbyloxysilane compound and reacting the modified polymer with a specific compound such as a hydrocarbyloxysilane compound, and a rubber composition containing the polymer modified in accordance with the above process and, preferably, 10 to 100 parts by weight of silica and/or carbon black per 100 parts by weight of the rubber component containing the modified polymer, are provided. The rubber composition containing silica and/or carbon black exhibits improved fracture properties, abrasion resistance, low heat buildup property and excellent workability. A process for producing a conjugated diene-based polymer exhibiting improved cold flow, a polymer produced in accordance with the process, and a rubber composition and a tire using the polymer are also provided.

摘要翻译： 一种共轭二烯系聚合物的制造方法，其特征在于，在上述第1变形例中，对具有活性链末端的共轭二烯系聚合物进行单体或单体聚合而得到的共轭二烯系聚合物的含量为 在主链的共轭二烯部分中为75摩尔％以上的顺式-1,4-单元，通过使活性链末端与烃氧基硅烷化合物反应，并使改性聚合物与特定化合物如烃氧基硅烷化合物反应，和 提供含有根据上述方法改性的聚合物的橡胶组合物，优选每100重量份含有改性聚合物的橡胶组分10至100重量份的二氧化硅和/或炭黑。 含有二氧化硅和/或炭黑的橡胶组合物具有改进的断裂性能，耐磨性，低发热性和优异的可加工性。 还提供了一种制备显示出改善的冷流的共轭二烯基聚合物的方法，根据该方法制备的聚合物和使用该聚合物的橡胶组合物和轮胎。

公开(公告)号：US20100071818A1

公开(公告)日：2010-03-25

申请号：US12347017

申请日：2008-12-31

申请人： William L. Hergenrother ,  Chenchy Jeffrey Lin

发明人： William L. Hergenrother ,  Chenchy Jeffrey Lin

IPC分类号： B60C11/00 ,  C08C19/25 ,  B60C5/00

CPC分类号： C08K5/544 ,  C08G77/26 ,  C08G77/28 ,  C08K5/548 ,  C09D183/08 ,  Y02T10/862 ,  Y10T152/10 ,  Y10T152/10495 ,  Y10T428/2991 ,  Y10T428/2995

摘要： A vulcanizable rubber composition is presented that comprises an elastomer; a reinforcing filler selected from silica, carbon black, and mixtures thereof, a cure agent; and an amino alkoxy-modified silsesquioxane (AMS) comprising one or more compounds selected from the group consisting of an amino AMS, an amino/mercaptan co-AMS, an amino/blocked mercaptan co-AMS, mixtures thereof, and weak acid-neutralized solid and aqueous solutions thereof. Addition of such compounds to the rubber composition provides improved dynamic viscoelastic and mechanical properties of the vulcanized rubber compound and predict that tire components, especially tread stocks, will provide tires having improved snow traction, lower rolling resistance but equal wet traction, increased rebound, decreased hysteresis, and a general improvement in tire performance.

摘要翻译： 提供了一种可硫化的橡胶组合物，其包含弹性体; 选自二氧化硅，炭黑及其混合物的增强填料，固化剂; 和氨基烷氧基改性倍半硅氧烷（AMS），其包含一种或多种选自氨基AMS，氨基/硫醇共-AMS，氨基/封端的硫醇共-AMS，及其混合物和弱酸中和 其固体和水溶液。 将这些化合物加入到橡胶组合物中提供了硫化橡胶化合物的动态粘弹性和机械性能，并预测轮胎组分，特别是胎面胶料将提供具有改善的雪牵引力，较低滚动阻力但相等的湿牵引力，增加的回弹，降低的轮胎 滞后和轮胎性能的普遍改进。