摘要:
New polyhydric phenol coesters are disclosed of polyhydric phenols, having 2 to 3 phenolic hydroxyl groups and 1 to 3 benzenoid rings, with carbonic acid and an inorganic acid which can be phosphorous acid, phosphoric acid, and boric acid. The new coesters have molecular weights from 700 to about 10,000, preferably from 1200 to 7000, and are highly effective stabilizers for a variety of synthetic resins.Stabilizer compositions comprising a polyhydric phenol coester and a known polymer stabilizer, as well as synthetic resins stabilized with such stabilizer compositions, are also disclosed.
摘要:
An information display device includes a two-dimensional array of cells, each cell including an opaque wall pierced by an aperture and containing an opaque ferromagnetic spherical shutter member movable by electromagnetic means to roll upon a vertical wall of the cell between limiting positions in which it respectively exposes and occults the aperture. The shutter members may be restrained in their limiting positions by friction or magnets embedded in the cell walls.
摘要:
An anti-yellowing additive is provided for environmentally acceptable stabilized vinyl chloride polymer compositions from which arsenic, cadmium, lead, mercury, and thallium are substantially excluded, comprising at least one basic inorganic compound of lithium, sodium, potassium, magnesium, calcium, strontium, barium, zinc, titanium, aluminum, zirconium, or tin, and a 1,3-diketone compound represented by the formula ##STR1## in which R is a hydrocarbon group having 1 to 18 carbon atoms, R' is a hydrogen atom, an acyl group ##STR2## or a hydrocarbon group having 1 to 18 carbon atoms, R' is a hydrogen atom or a hydrocarbon group having 1 to 18 carbon atoms, M is a hydrogen or one of the metals lithium, sodium, potassium, magnesium, calcium, strontium, barium, zinc, aluminum, and antimony, and n is the valence of the metal from 1 to 3.
摘要:
A stabilizer composition is disclosed for increasing the resistance to yellowing and loss of clarity of a vinyl halidepolymer upon heating, which comprises a thio-1,3-dicarbonyl compound represented by the formula ##STR1## in which M represents hydrogen, an organotin group or a metal, R represents hydrogen, a hydrocarbon group or a group ##STR2## each of R, R", and R'" represents hydrogen or an organic group, X is oxygen or sulfur, and n representing the valence of M is an integer from 1 to 4, and at least one heat stabilizer which is an alkyltin compound or a metal salt of a non-nitrogenous monocarboxylic acid or of a hydrocarbon-substituted phenol.Stabilized vinyl halide polymer compositions, in which the above stabilizer composition is used to improve the resistance to yellowing and the clarity, are also disclosed.
摘要:
The clarity of molded olefin polymer specimens is augmented by incorporating 0.005 to 5% by weight of the olefin polymer of a phenyl phosphate compound having the formula ##STR1## in which R.sub.1 and R.sub.2 are independently selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkoxy group having 1 to 18 carbon atoms, a cycloalkyl group having 5 to 12 carbon atoms, a phenyl group, a phenoxy group, and a group ##STR2## in which R.sub.5 is a hydrogen atom or an alkyl group having 1 to 18 carbon atoms; R.sub.3 is selected from the group consisting of an alkyl group having 1 to 18 carbon atoms, ##STR3## , and R.sub.4 ; and R.sub.4 is a hydrogen atom or a metal atom equivalent M.sub.1/a where a is the valence of the metal atom M.In the presence of such a phenyl phosphate, further improvements in clarity are obtained by also incorporating certain metal compounds.
摘要:
2,2,6,6-Tetramethyl-4-piperidone spiroketal carbinol compound of Formula I ##STR1## in which R.sub.1 represents hydrogen, alkyl of one to ten carbon atoms, or aralkyl of seven to ten carbon atoms, and R.sub.2 represents alkyl of one of one to six carbon atoms, is prepared by heating a mixture of a 2,2,6,6-tetramethyl-4-piperidone compound of Formula II ##STR2## or an acid addition salt thereof, and a 1,3 dioxane compound having the formula III ##STR3## in which R.sub.3 and R.sub.4 represent R.sub.1 or aryl of six to ten carbon atoms or taken together represent alkylene of four to eight carbon atoms, removing R.sub.3 R.sub.4 CO compound and recovering 2,2,6,6-tetramethyl-4-piperidonespiroketal compound.
摘要:
New polyhydric phenol coesters are disclosed of polyhydric phenols, having 2 to 3 phenolic hydroxyl groups and 1 to 3 benzenoid rings, with carbonic acid and an organophosphonic acid having linked to phosphorus as alkyl, aryl, aralkyl or alkaryl group optionally substituted with a phenolic hydroxyl group. The new coesters have molecular weights up to a maximum of about 10,000, preferably from 1000 to 9000, and are highly effective stabilizers for a variety of synthetic resins.Stabilizer compositions comprising a polyhydric phenol coester and a known polymer stabilizer, as well as synthetic resins stabilized with such stabilizer compositions, are also disclosed.