Inorganic organic coester stabilizers
    3.
    发明授权
    Inorganic organic coester stabilizers 失效
    无机有机酯稳定剂

    公开(公告)号:US4257927A

    公开(公告)日:1981-03-24

    申请号:US948888

    申请日:1978-10-05

    IPC分类号: C08K5/51 C08K5/52

    CPC分类号: C08K5/51

    摘要: New polyhydric phenol coesters are disclosed of polyhydric phenols, having 2 to 3 phenolic hydroxyl groups and 1 to 3 benzenoid rings, with carbonic acid and an inorganic acid which can be phosphorous acid, phosphoric acid, and boric acid. The new coesters have molecular weights from 700 to about 10,000, preferably from 1200 to 7000, and are highly effective stabilizers for a variety of synthetic resins.Stabilizer compositions comprising a polyhydric phenol coester and a known polymer stabilizer, as well as synthetic resins stabilized with such stabilizer compositions, are also disclosed.

    摘要翻译: 公开了具有2至3个酚羟基和1至3个苯环的多元酚,具有碳酸和可以是亚磷酸,磷酸和硼酸的无机酸。 新的酯类具有700至10,000,优选1200至7000的分子量,并且是各种合成树脂的高效稳定剂。 还公开了包含多元酚酯酯和已知的聚合物稳定剂的稳定剂组合物以及用这种稳定剂组合物稳定的合成树脂。

    Information display device
    4.
    发明授权
    Information display device 失效
    信息显示设备

    公开(公告)号:US3995386A

    公开(公告)日:1976-12-07

    申请号:US593179

    申请日:1975-07-03

    IPC分类号: G09F9/37

    CPC分类号: G09F9/375

    摘要: An information display device includes a two-dimensional array of cells, each cell including an opaque wall pierced by an aperture and containing an opaque ferromagnetic spherical shutter member movable by electromagnetic means to roll upon a vertical wall of the cell between limiting positions in which it respectively exposes and occults the aperture. The shutter members may be restrained in their limiting positions by friction or magnets embedded in the cell walls.

    摘要翻译: 信息显示装置包括二维的单元阵列,每个单元包括一个由孔刺穿的不透明壁,并且包含一个不透明的铁磁球形闸门构件,可以通过电磁装置移动,以便在限定位置之间滚动单元的垂直壁 分别曝光并遮住光圈。 活门构件可以通过嵌入单元壁中的摩擦或磁体来限制在它们的限制位置。

    Anti-yellowing composition
    5.
    发明授权
    Anti-yellowing composition 失效
    抗黄变组合物

    公开(公告)号:US4221687A

    公开(公告)日:1980-09-09

    申请号:US921814

    申请日:1978-07-03

    IPC分类号: C08K3/00 C08K5/07

    CPC分类号: C08K3/0075 C08K5/07

    摘要: An anti-yellowing additive is provided for environmentally acceptable stabilized vinyl chloride polymer compositions from which arsenic, cadmium, lead, mercury, and thallium are substantially excluded, comprising at least one basic inorganic compound of lithium, sodium, potassium, magnesium, calcium, strontium, barium, zinc, titanium, aluminum, zirconium, or tin, and a 1,3-diketone compound represented by the formula ##STR1## in which R is a hydrocarbon group having 1 to 18 carbon atoms, R' is a hydrogen atom, an acyl group ##STR2## or a hydrocarbon group having 1 to 18 carbon atoms, R' is a hydrogen atom or a hydrocarbon group having 1 to 18 carbon atoms, M is a hydrogen or one of the metals lithium, sodium, potassium, magnesium, calcium, strontium, barium, zinc, aluminum, and antimony, and n is the valence of the metal from 1 to 3.

    摘要翻译: 为环境可接受的稳定的氯乙烯聚合物组合物提供了一种抗黄变添加剂,其中砷,镉,铅,汞和铊基本上被排除在外,包含至少一种碱金属的无机化合物,包括锂,钠,钾,镁,钙,锶 ,钡,锌,钛,铝,锆或锡,以及由式为“IMAGE”表示的1,3-二酮化合物,其中R是具有1至18个碳原子的烃基,R'是氢原子, 酰基基团或具有1至18个碳原子的烃基,R'是氢原子或具有1至18个碳原子的烃基,M是氢或金属之一,锂,钠,钾,镁 ,钙,锶,钡,锌,铝和锑,n是金属的价数从1到3。

    Stabilized halogen-containing resin composition
    6.
    发明授权
    Stabilized halogen-containing resin composition 失效
    稳定的含卤素树脂组合物

    公开(公告)号:US4217258A

    公开(公告)日:1980-08-12

    申请号:US33570

    申请日:1979-04-27

    摘要: A stabilizer composition is disclosed for increasing the resistance to yellowing and loss of clarity of a vinyl halidepolymer upon heating, which comprises a thio-1,3-dicarbonyl compound represented by the formula ##STR1## in which M represents hydrogen, an organotin group or a metal, R represents hydrogen, a hydrocarbon group or a group ##STR2## each of R, R", and R'" represents hydrogen or an organic group, X is oxygen or sulfur, and n representing the valence of M is an integer from 1 to 4, and at least one heat stabilizer which is an alkyltin compound or a metal salt of a non-nitrogenous monocarboxylic acid or of a hydrocarbon-substituted phenol.Stabilized vinyl halide polymer compositions, in which the above stabilizer composition is used to improve the resistance to yellowing and the clarity, are also disclosed.

    摘要翻译: 公开了一种稳定剂组合物,用于增加乙烯基卤化聚合物在加热时的耐黄变性和透明度的丧失,其包含由式“IMAGE”表示的硫代-1,3-二羰基化合物,其中M表示氢,有机锡基团或 R表示氢或有机基团,X表示氧或硫,n表示M的化合价,R表示氢,烃基或基团, 1〜4的整数,至少1种作为烷基锡化合物或非含氮一元羧酸或烃取代苯酚的金属盐的热稳定剂。 还公开了其中使用上述稳定剂组合物以改善耐黄变性和透明度的稳定的卤化乙烯聚合物组合物。

    Clarified olefin polymer composition
    8.
    发明授权
    Clarified olefin polymer composition 失效
    澄清的烯烃聚合物组合物

    公开(公告)号:US4258142A

    公开(公告)日:1981-03-24

    申请号:US937961

    申请日:1978-08-30

    IPC分类号: C08K5/098 C08K5/523 C09K3/00

    摘要: The clarity of molded olefin polymer specimens is augmented by incorporating 0.005 to 5% by weight of the olefin polymer of a phenyl phosphate compound having the formula ##STR1## in which R.sub.1 and R.sub.2 are independently selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkoxy group having 1 to 18 carbon atoms, a cycloalkyl group having 5 to 12 carbon atoms, a phenyl group, a phenoxy group, and a group ##STR2## in which R.sub.5 is a hydrogen atom or an alkyl group having 1 to 18 carbon atoms; R.sub.3 is selected from the group consisting of an alkyl group having 1 to 18 carbon atoms, ##STR3## , and R.sub.4 ; and R.sub.4 is a hydrogen atom or a metal atom equivalent M.sub.1/a where a is the valence of the metal atom M.In the presence of such a phenyl phosphate, further improvements in clarity are obtained by also incorporating certain metal compounds.

    摘要翻译: 通过加入0.005至5重量%的具有式“IMAGE”的苯基磷酸酯化合物的烯烃聚合物,其中R 1和R 2独立地选自氢原子, 具有1至18个碳原子的烷基,具有1至18个碳原子的烷氧基,具有5至12个碳原子的环烷基,苯基,苯氧基和其中R 5是氢原子的基团 或具有1至18个碳原子的烷基; R3选自具有1至18个碳原子的烷基,< IMAGE>和R4; R4是氢原子或金属原子当量M1 / a,其中a是金属原子M的化合价。在这种磷酸苯酯的存在下,通过还掺入某些金属化合物可以进一步提高透明度。

    Process for preparing 4-piperidone spiroketal compounds
    9.
    发明授权
    Process for preparing 4-piperidone spiroketal compounds 失效
    4-哌啶酮螺缩酮化合物的制备方法

    公开(公告)号:US4250313A

    公开(公告)日:1981-02-10

    申请号:US117464

    申请日:1980-02-01

    IPC分类号: C07D491/10 C07D405/04

    CPC分类号: C07D491/10

    摘要: 2,2,6,6-Tetramethyl-4-piperidone spiroketal carbinol compound of Formula I ##STR1## in which R.sub.1 represents hydrogen, alkyl of one to ten carbon atoms, or aralkyl of seven to ten carbon atoms, and R.sub.2 represents alkyl of one of one to six carbon atoms, is prepared by heating a mixture of a 2,2,6,6-tetramethyl-4-piperidone compound of Formula II ##STR2## or an acid addition salt thereof, and a 1,3 dioxane compound having the formula III ##STR3## in which R.sub.3 and R.sub.4 represent R.sub.1 or aryl of six to ten carbon atoms or taken together represent alkylene of four to eight carbon atoms, removing R.sub.3 R.sub.4 CO compound and recovering 2,2,6,6-tetramethyl-4-piperidonespiroketal compound.

    摘要翻译: 式Ⅰ的2,2,6,6-四甲基-4-哌啶酮螺甲醇甲醇化合物其中R 1表示氢,1至10个碳原子的烷基或7至10个碳原子的芳烷基,R 2 代表1-6个碳原子之一的烷基,是通过加热式II II的2,2,6,6-四甲基-4-哌啶酮化合物或其酸加成盐和 具有式III的III二恶烷化合物其中R 3和R 4表示R 1或6至10个碳原子的芳基或一起代表4至8个碳原子的亚烷基,除去R 3 R 4 CO化合物并回收2, 2,6,6-四甲基-4-哌啶酮缩酮化合物。