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1.发明申请Electrolytic Apparatus, System and Method for the Safe Production of Nitrogen Trifluoride 有权用于安全生产三氟化磷的电解设备，系统和方法公开(公告)号：US20120181182A1
公开(公告)日：2012-07-19
申请号：US13008649
申请日：2011-01-18
Applicant: James Joseph Hart , Reinaldo Mario Machado , Howard Paul Withers, JR. , Sai-Hong A. Lo , Edward Jay Cialkowski , Krishnakumar Jambunathan
Inventor： James Joseph Hart , Reinaldo Mario Machado , Howard Paul Withers, JR. , Sai-Hong A. Lo , Edward Jay Cialkowski , Krishnakumar Jambunathan
Abstract: An electrolytic cell and system used for making nitrogen trifluoride consisting of a computer and an electrolytic cell having a body, an electrolyte, at least one anode chamber that produces an anode product gas, at least one cathode chamber, and one or more fluorine adjustment means to maintain fluorine or hydrogen in the anode product gas within a target amount by adjusting the concentration of fluorine in said anode product gas, and the process that controls the system.
Abstract translation: 一种用于制造由计算机组成的三氟化氮的电解槽和系统，具有主体，电解质，产生阳极产物气体的至少一个阳极室，至少一个阴极室和一个或多个氟调节装置 通过调节所述阳极产物气体中的氟的浓度以及控制系统的过程来将阳极产物气体中的氟或氢维持在目标量内。
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2.发明授权公开(公告)号：US07074962B2
公开(公告)日：2006-07-11
申请号：US10076813
申请日：2002-02-15
Applicant: Reinaldo Mario Machado , James Edward Koniski , Stephen Kohler
Inventor： Reinaldo Mario Machado , James Edward Koniski , Stephen Kohler
IPC: C07C209/00
CPC classification number: C07C209/36 , B01J3/04 , B01J8/0292 , B01J10/007 , B01J19/006 , B01J19/1875 , B01J19/2485 , B01J2208/00176 , B01J2208/00203 , B01J2219/00083 , B01J2219/00094 , B01J2219/00768 , B01J2219/00777 , B01J2219/30203 , B01J2219/30215 , B01J2219/30475 , C07C211/46 , C07C211/47
Abstract: This invention relates to apparatus particularly a monolith catalytic reactor in a stirred tank reactor. The stirred tank reactor including the fixed bed catalytic reactor apparatus comprises: an housing having an open top and open bottom portion supportably maintained with said tank, said housing having a substantially outwardly extending, horizontal baffle near its top portion said baffle having a least one perforation in its surface, and said housing having at least one perforation in the wall near its top portion; a fixed bed catalyst system supportably retained within said housing permitting both liquid and gas flow therethrough; and, an agitator shaft terminating in a turbine blade substantially adjacent the perforation in the wall of said housing, said agitator having a passageway including an opening in an upper portion thereof to the interior of an upper part of said tank and terminating in an opening adjacent the turbine blade.
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公开(公告)号：US06506361B1
公开(公告)日：2003-01-14
申请号：US09573726
申请日：2000-05-18
Applicant: Reinaldo Mario Machado , Robert Roger Broekhuis
Inventor： Reinaldo Mario Machado , Robert Roger Broekhuis
IPC: B01J1000
CPC classification number: B01J19/26 , B01J8/025 , B01J19/1881 , B01J19/2485 , B01J2219/00024 , B01J2219/00033 , B01J2219/00094 , B01J2219/00162 , B01J2219/00166 , Y10S423/13
Abstract: This invention relates to process for carrying out gas-liquid reactions such as those employed in the hydrogenation or oxidation of organic compounds. In the catalytic reaction of a liquid reactant and a gaseous reactant to form a product, the improvement which comprises: pressurizing a liquid reactant and, then, introducing the resultant pressurized liquid reactant to a liquid motive gas ejector wherein it is mixed with the gaseous reactant. The mixture is passed to and reacted in a monolith catalytic reactor. The products are removed from the monolith catalytic reactor at a reduced pressure and, then introduced to a tank. The unreacted materials in the reaction product then are recirculated back to the ejector.
Abstract translation: 本发明涉及进行气 - 液反应的方法，例如在有机化合物的氢化或氧化中使用的那些。 在液体反应物和气体反应物的催化反应中形成产物的改进包括：对液体反应物加压，然后将所得的加压液体反应物引入到液体运动气体喷射器中，其中与气体反应物 。 将混合物送入并在整体式催化反应器中反应。 将产物在减压下从整体催化反应器中除去，然后引入罐中。 然后将反应产物中的未反应物质再循环回喷射器。
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4.发明授权Two stage reactor for continuous three phase slurry hydrogenation and method of operation 有权连续三相浆料氢化两相反应器及其操作方法
公开(公告)号：US06080372A
公开(公告)日：2000-06-27
申请号：US151625
申请日：1998-09-11
Applicant: Reinaldo Mario Machado
Inventor： Reinaldo Mario Machado
IPC: B01J25/02 , B01J8/00 , B01J8/22 , B01J8/26 , B01J19/00 , B01J19/18 , C07B61/00 , C07C29/141 , C07C31/26 , B01J8/08
Abstract: A continuous stirred tank reactor is paired with a bubble column reactor to enhance conversion in a continuous process, e.g. hydrogenation, wherein a gaseous reactant is mixed with a liquid. The continuous stirred reactor is fitted with a specialized impeller system to circulate the liquid and enhance contact of the liquid with reactant gas carried over from the bubble column.
Abstract translation: 连续搅拌釜反应器与鼓泡塔反应器配对以增强连续过程中的转化，例如 氢化，其中气态反应物与液体混合。 连续搅拌的反应器配有专门的叶轮系统以使液体循环并增强液体与气泡塔承载的反应气体的接触。
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5.发明授权Method and apparatus for achieving maximum yield in the electrolytic preparation of group IV and V hydrides 有权在IV族和V型氢化物的电解制备中获得最大产率的方法和装置公开(公告)号：US08591720B2
公开(公告)日：2013-11-26
申请号：US13208418
申请日：2011-08-12
Applicant: Reinaldo Mario Machado , Christopher L. Hartz , James E. Hollen , Rebecca J. Mohr , George L. Ryals
Inventor： Reinaldo Mario Machado , Christopher L. Hartz , James E. Hollen , Rebecca J. Mohr , George L. Ryals
CPC classification number: C25B1/00 , C23C16/4488 , C25B15/08
Abstract: A method for generating hydride gas of metal M1 in electrochemical cell comprising cathode comprising metal M1, sacrificial anode comprising metal M2, an initial concentration of aqueous electrolyte solution comprising metal hydroxide M3OH, wherein the sacrificial metal anode electrochemically oxidizes in the presence of the aqueous electrolyte solution to form metal salt, and hydride gas of metal M1 is formed by reducing the metal M1 of the cathode. The method also comprises steps of determining solubility profile curves of metal salt as M3OH is consumed and metal oxide is formed by oxidation reaction at various concentrations of M3OH; determining the maximum concentration of M3OH that does not yield a concentration of metal salt that precipitates out of the electrolyte solution; and choosing a concentration of M3OH that is in the range of at and within 5% less than the maximum concentration of M3OH to be the initial concentration of M3OH.
Abstract translation: 一种用于在电化学电池中产生金属M1的氢化物气体的方法，其包括含有金属M1的阴极，包含金属M2的牺牲阳极，包含金属氢氧化物M3OH的初始浓度的电解质水溶液，其中所述牺牲金属阳极在水性电解质存在下电化学氧化 溶液形成金属盐，通过还原金属M1形成金属M1的氢化物气体。 该方法还包括以下步骤：测定在M3OH被消耗的金属盐的溶解度曲线曲线，并且通过在不同浓度的M3OH下的氧化反应形成金属氧化物; 确定不产生从电解液中析出的金属盐浓度的M3OH的最大浓度; 并选择在M3OH的最大浓度以下且小于5％的范围内的M3OH浓度成为M3OH的初始浓度。
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Patent Agency Ranking
6.发明授权Polymer network/carbon layer on monolith support and monolith catalytic reactor 失效聚合物网/碳层在整体支撑和整体催化反应器上公开(公告)号：US06610628B2
公开(公告)日：2003-08-26
申请号：US09867959
申请日：2001-05-30
Applicant: Andrew Francis Nordquist , Frederick Carl Wilhelm , Francis Joseph Waller , Reinaldo Mario Machado
Inventor： Andrew Francis Nordquist , Frederick Carl Wilhelm , Francis Joseph Waller , Reinaldo Mario Machado
IPC: B01J3106
CPC classification number: C07C209/36 , B01J21/18 , B01J23/44 , B01J35/04 , B01J35/10 , B01J35/1009 , B01J35/1014 , B01J37/0219 , B01J37/084 , C07C211/46
Abstract: The present invention relates to an improved monolith catalytic reactor and a monolith support. The improvement in the support resides in a polymer network/carbon coating applied to the surface of a porous substrate and a catalytic metal, preferably a transition metal catalyst applied to the surface of the polymer network/carbon coating. The monolith support has from 100 to 800 cells per square inch and a polymer network/carbon coating with surface area of from 0.1 to 15 m2/gram as measured by adsorption of N2 or Kr using the BET method.
Abstract translation: 本发明涉及一种改进的整体催化反应器和整料载体。 载体的改进在于施加到多孔基材表面的聚合物网络/碳涂层和催化金属，优选应用于聚合物网络/碳涂层表面的过渡金属催化剂。 整体式载体具有100至800个/平方英寸的单体和通过使用BET法吸附N 2或Kr测量的表面积为0.1至15m 2 / g的聚合物网络/碳涂层。
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7.发明授权Electrolytic apparatus, system and method for the safe production of nitrogen trifluoride 有权用于安全生产三氟化氮的电解设备，系统和方法公开(公告)号：US08945367B2
公开(公告)日：2015-02-03
申请号：US13008649
申请日：2011-01-18
Applicant: James Joseph Hart , Reinaldo Mario Machado , Howard Paul Withers, Jr. , Sai-Hong A. Lo , Edward Jay Cialkowski , Krishnakumar Jambunathan
Inventor： James Joseph Hart , Reinaldo Mario Machado , Howard Paul Withers, Jr. , Sai-Hong A. Lo , Edward Jay Cialkowski , Krishnakumar Jambunathan
Abstract: An electrolytic cell and system used for making nitrogen trifluoride consisting of a computer and an electrolytic cell having a body, an electrolyte, at least one anode chamber that produces an anode product gas, at least one cathode chamber, and one or more fluorine adjustment means to maintain fluorine or hydrogen in the anode product gas within a target amount by adjusting the concentration of fluorine in said anode product gas, and the process that controls the system.
Abstract translation: 一种用于制造由计算机组成的三氟化氮的电解槽和系统，具有主体，电解质，产生阳极产物气体的至少一个阳极室，至少一个阴极室和一个或多个氟调节装置 通过调节所述阳极产物气体中的氟的浓度以及控制系统的过程来将阳极产物气体中的氟或氢维持在目标量内。
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公开(公告)号：US20120055803A1
公开(公告)日：2012-03-08
申请号：US12874503
申请日：2010-09-02
Applicant: Krishnakumar Jambunathan , Kerry Renard Berger , Reinaldo Mario Machado , Daniel James Ragsdale
Inventor： Krishnakumar Jambunathan , Kerry Renard Berger , Reinaldo Mario Machado , Daniel James Ragsdale
IPC: C25B1/00
CPC classification number: C25B1/00 , C25B9/08 , Y02E60/366
Abstract: The invention relates to the electrolysis of aqueous electrolyte solutions containing GeO2; hydroxide and water with metal alloy electrodes, such as, copper or tin rich alloy electrodes with alloying elements such as Sn, Pb, Zn, Cu etc, to generate Germane (GeH4). Cu-rich alloy electrodes have been demonstrated to increase the GeH4 current efficiency by almost 20% compared to Cu metal electrodes. Germanium deposition has been found to be either absent or minimal by using Cu-rich alloy electrodes. Several different methods for maintaining the cell performance or restoring the cell performance after a reduction in current efficiency over time, have been identified. A titration-based method for the analysis of the electrolyte, to obtain the concentration of GeO2 and the concentration of hydroxide has also been disclosed.
Abstract translation: 本发明涉及含有GeO 2的电解质水溶液的电解; 氢氧化物和水与金属合金电极，例如具有合金元素如Sn，Pb，Zn，Cu等的铜或锡丰富的合金电极，以产生锗（GeH 4）。 与Cu金属电极相比，已证明富Cu合金电极将GeH4电流效率提高近20％。 通过使用富Cu合金电极，发现锗沉积不存在或不存在。 已经确定了用于在电流效率随时间降低的情况下维持电池性能或恢复电池性能的几种不同的方法。 还公开了用于分析电解质，获得GeO 2浓度和氢氧化物浓度的基于滴定的方法。
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9.发明申请DIVIDED ELECTROCHEMICAL CELL AND LOW COST HIGH PURITY HYDRIDE GAS PRODUCTION PROCESS 审中-公开分解电化学细胞和低成本高纯度气相色谱法制备方法公开(公告)号：US20090159454A1
公开(公告)日：2009-06-25
申请号：US11961396
申请日：2007-12-20
Applicant: REINALDO MARIO MACHADO , ATHANASIOS GEORGIOS TSIRUKIS , CHRISTOPHER L. HARTZ , JAMES ROBERT LEENHOUTS , WILLIAM F. SCHULZE
Inventor： REINALDO MARIO MACHADO , ATHANASIOS GEORGIOS TSIRUKIS , CHRISTOPHER L. HARTZ , JAMES ROBERT LEENHOUTS , WILLIAM F. SCHULZE
CPC classification number: C25B15/02 , C23C16/4488 , C25B1/00 , C25B9/08 , C25B9/16 , Y02E60/366
Abstract: This invention is an apparatus and a method for continuously generating a hydride gas of metal M1 which is substantially free of oxygen in a divided electrochemical cell. An impermeable partition or a combination of an impermeable partition and a porous diaphragm can be used to divide the electrochemical cell. The divided electrochemical cell has an anode chamber and a cathode chamber, wherein the cathode chamber has a cathode comprising metal M1, the anode chamber has an anode capable of generating oxygen, an aqueous electrolyte solution comprising a metal hydroxide M2OH partially filling the divided electrochemical cell. Hydride gas generated in the cathode chamber and oxygen generated in the anode chamber are removed through independent outlets.
Abstract translation: 本发明是一种在分割的电化学电池中连续生成基本上不含氧的金属M1的氢化物气体的装置和方法。 可以使用不透水隔板或不透水隔板和多孔隔膜的组合来分隔电化学电池。 分电化学电池具有阳极室和阴极室，其中阴极室具有包括金属M1的阴极，阳极室具有能够产生氧的阳极，包含部分填充分隔电化学电池的金属氢氧化物M2OH的水性电解质溶液 。 在阴极室中产生的氢化物气体和在阳极室中产生的氧气通过独立的出口去除。
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10.发明申请Method and Apparatus for Achieving Maximum Yield in the Electrolytic Preparation of Group IV and V Hydrides 有权在IV和V族氢化物的电解制备中获得最大产率的方法和装置公开(公告)号：US20070240997A1
公开(公告)日：2007-10-18
申请号：US11687947
申请日：2007-03-19
Applicant: Reinaldo Mario Machado , Christopher L. Hartz , James E. Hollen , Rebecca J. Mohr , George L. Ryals
Inventor： Reinaldo Mario Machado , Christopher L. Hartz , James E. Hollen , Rebecca J. Mohr , George L. Ryals
CPC classification number: C25B1/00 , C23C16/4488 , C25B15/08
Abstract: A method for generating a hydride gas of metal M1 in an electrochemical cell comprising a cathode comprising metal M1, a sacrificial anode comprising metal M2, an initial concentration of aqueous electrolyte solution comprising a metal hydroxide, M3OH, wherein the sacrificial metal anode electrochemically oxidizes in the presence of the aqueous electrolyte solution comprising M3OH to form a metal salt, and the hydride gas of metal M1 is formed by reducing the metal M1 of the cathode. The method comprises the steps of determining solubility profile curves of the metal salt as the M3OH is consumed and the metal oxide is formed by the oxidation reaction at various concentrations of M3OH; determining a maximum concentration of M3OH that, as it is consumed, does not yield a concentration of metal salt that precipitates out of the electrolyte solution; and choosing a concentration of M3OH that is in the range of at and within 5% less than the maximum concentration of M3OH to be the initial concentration of M3OH.
Abstract translation: 一种用于在电化学电池中产生金属M 1 1的氢化物气体的方法，该电化学电池包括包含金属M 1的阴极，包括金属M 2 N的牺牲阳极 >，包含金属氢氧化物M 3 OH的含水电解质溶液的初始浓度，其中所述牺牲金属阳极在包含M 3 N 3 OH的电解质水溶液存在下电化学氧化， OH以形成金属盐，金属M 1 H 2的氢化物气体通过还原阴极的金属M 1 N而形成。 该方法包括以下步骤：当消耗M 3 OH时，确定金属盐的溶解度曲线曲线，并且通过氧化反应在不同浓度的M 3 OH; 确定当其被消耗时不会产生从电解液中析出的金属盐的浓度的M 3 OH的最大浓度; 并且选择在3％以下的范围内的M 3 OH的浓度小于M 3 OH的最大浓度，作为M 3的初始浓度， SUB> 3 OH。
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