摘要:
Solid catalyst component for the polymerization of olefins, includes the product of the direct reaction, with no subsequent reactions with reducing organometallic compounds, between a titanium compound and a support obtained by contacting a metal oxide containing hydroxyl groups with a solution containing A) a magnesium chloride; B) from 1 to 6 moles of an alcohol per mole of magnesium chloride, in a halogenated hydrocarbon or aromatic hydrocarbon organic solvent C) capable of bringing the magnesium chloride in solution in quantities greater than or equal to 5 grams per liter in the presence of the above-mentioned quantities of alcohol B), the solvent not being able to form adducts with the magnesium chloride.
摘要:
A multistage process for the continuous production of an emulsion comprising subjecting at least two immiscible liquids to a sequence of at least two mixing stages carried out in at least two successive stator-rotor devices, wherein a peripheral outlet from a first stator-rotor device is connected to an axial inlet in the successive stator-rotor device by means of a duct in which the Reynold number ReT inside said duct is higher than 5000, and the peripheral velocity of each rotor of said stator-rotor devices ranges from 5 to 60 m/s.
摘要:
Process for preparing TiO2 powders starting from a liquid comprising chlorinated titanium compounds, the process comprising: a) atomizing said liquid and reacting the atomized liquid with a flow of steam and air at a temperature of 100-250° C. for converting said chlorinated titanium compounds to titanium dioxide TiO2; b) the gaseous phase and the entrained TiO2 powders obtained from step a) are then fed to an oven operated at a temperature in the range 400-900° C. to remove the residual organic compounds and hydrochloridic acid from said powders.
摘要:
Process for preparing TiO2 powders starting from a liquid comprising chlorinated titanium compounds, the process comprising: a) atomizing said liquid and then reacting the atomized liquid with a flow of steam and air at a temperature of 100-250° C. for converting said chlorinated titanium compounds to titanium dioxide TiO2; b) the gaseous phase and the entrained TiO2 powders obtained from step a) are then fed to an oven operated at a temperature in the range 400-900° C. to remove the residual organic compounds and hydrochloridic acid from said powders.
摘要:
A multistage process for the continuous production of an emulsion comprising subjecting at least two immiscible liquids to a sequence of at least two mixing stages carried out in at least two successive stator-rotor devices, wherein a peripheral outlet from a first stator-rotor device is connected to an axial inlet in the successive stator-rotor device by means of a duct in which the Reynold number ReT inside said duct is higher than 5000, and the peripheral velocity of each rotor of said stator-rotor devices ranges from 5 to 60 m/s.
摘要:
A process for preparing spherical support particles used in the preparation of catalytic components for the polymerization of olefins by (a) forming an emulsion of an adduct of a Mg dihalide and a Lewis base compound in a liquid medium, and (b) cooling the emulsion by transferring it into a cooling bath containing a cooling liquid in motion wherein the cooling liquid is moving inside a tubular zone and the ratio Ve/Vref of the velocity (Ve) of the emulsion coming from step (a) to the velocity of the cooling liquid (Vref) of step (b) is between 0.25 and 4. The resulting spherical support particles have a very narrow size distribution and particularly regular morphology.
摘要:
A process, particularly a gas phase fluidised bed process, for the production of polymers avoids formation of sheets or chunks within the reactor, without the need to use antistatic agents, which can reduce the activity of the catalyst or alter the characteristics of the yielded product. According to the invention, a device generates a corona discharge in the polymerisation reactor during the polymerisation process; an AC voltage difference is applied between the elements which constitute the discharging pair of the device.
摘要:
A method and apparatus for the classification of solid particles, in particular powdery catalytic components for the polymerization of olefins, which comprises sending solid particles suspended in a transporting gas flow through a screening device. Immediately upstream to the screening device there is an auxiliary fluidized bed classifier, in which the top of the bed is at the level of the lower part of the screening device.