公开(公告)号：US5958588A

公开(公告)日：1999-09-28

申请号：US18894

申请日：1998-02-05

Applicant: Rudiger Schutte ,  Hans Christian Alt ,  Catrin Becker-Balfanz ,  Manfred Sauer ,  Lukas Von Hippel ,  Oliver Feuer ,  Jurgen Lorosch

Inventor： Rudiger Schutte ,  Hans Christian Alt ,  Catrin Becker-Balfanz ,  Manfred Sauer ,  Lukas Von Hippel ,  Oliver Feuer ,  Jurgen Lorosch

IPC: C01C3/08 ,  C01C3/10 ,  B32B5/16

CPC classification number: C01C3/10 ,  C01C3/08 ,  C01P2004/32 ,  C01P2004/50 ,  C01P2004/61 ,  C01P2006/10 ,  C01P2006/90 ,  Y10T428/2982

Abstract: A process for the direct preparation of alkali metal cyanide and alkaline earth metal cyanide granules from an HCN-containing gas and an aqueous solution or suspension of an alkali metal or alkaline earth metal hydroxide. The reaction is performed in a reactor for fluidized bed spray granulation, wherein a solution or suspension of the hydroxide is sprayed onto seed granules of the cyanide being prepared and at the same time a hydrogen cyanide-containing gas is supplied to the reactor and water is evaporated by means of a fluidizing gas. The preferred fluidizing gas is steam. The reaction gases from a BMA or Andrussow process may be quenched with water and the gas mixture used as fluidizing gas. By using a CO.sub.2 -free HCN-containing gas, alkali metal cyanide granules with advantageous properties, including a combined concentration of alkali metal carbonate and alkali metal formate of less then 0.4 wt. %, are obtainable.

Abstract translation: 用于从含HCN的气体和碱金属或碱土金属氢氧化物的水溶液或悬浮液直接制备碱金属氰化物和碱土金属氰化物颗粒的方法。 该反应在流化床喷雾造粒反应器中进行，其中将氢氧化物的溶液或悬浮液喷雾在所制备的氰化物的种子颗粒上，同时将含有氰化氢的气体供应至反应器，水为 通过流化气体蒸发。 优选的流化气体是蒸汽。 来自BMA或Andrussow工艺的反应气体可以用水淬火并将气体混合物用作流化气体。 通过使用不含CO 2的气体，具有有利性质的碱金属氰化物颗粒，包括碱金属碳酸盐和碱金属甲酸盐的组合浓度小于0.4wt。 ％，可以获得。

公开(公告)号：US07332139B2

公开(公告)日：2008-02-19

申请号：US09934085

申请日：2001-08-22

Applicant: Rüdiger Schütte ,  Torsten Balduf ,  Catrin Becker ,  Ina Hemme ,  Birgit Bertsch-Frank ,  Werner Wildner ,  Jürgen Rollmann ,  Georg Markowz

Inventor： Rüdiger Schütte ,  Torsten Balduf ,  Catrin Becker ,  Ina Hemme ,  Birgit Bertsch-Frank ,  Werner Wildner ,  Jürgen Rollmann ,  Georg Markowz

IPC: B01J19/24 ,  B01J8/02

CPC classification number: F28F3/12 ,  B01F5/0403 ,  B01F13/0059 ,  B01F15/00935 ,  B01F2215/0036 ,  B01J19/0093 ,  B01J19/249 ,  B01J2208/022 ,  B01J2219/00265 ,  B01J2219/00835 ,  B01J2219/0086 ,  B01J2219/00889 ,  B01J2219/2453 ,  B01J2219/2458 ,  B01J2219/2462 ,  B01J2219/2465 ,  B01J2219/2467 ,  B01J2219/2479 ,  B01J2219/2481 ,  B01J2219/2485 ,  B01J2219/2487 ,  B01J2219/2493 ,  B01J2219/2495 ,  B01J2219/2497 ,  B01J2219/2498 ,  C01B15/029 ,  C07C45/35 ,  C07C51/252 ,  C07D301/12 ,  F28D9/0081 ,  C07C47/22 ,  C07C57/04

Abstract: Reactions between at least two fluid reactants are performed in a reactor comprising wall elements (1), slot-shaped reaction spaces (3) and cavities (5) for conducting a fluid heat-carrier through. Depending on the process and throughput, a modular structural design is chosen wherein an arbitrary number of wall elements (1) are assembled to a right-parallelepipedal block (24), the reaction spaces (3) are formed between lateral surfaces (2) of right-parallelepipedal wall elements (1), the reactants are introduced into the reaction spaces (3) from edge regions of one side of the block (24) and are conducted through the reaction spaces (3) in parallel flows and the fluid heat-carrier is conducted through the tubular cavities (5) extending in the interior of the wall elements (1).

Abstract translation: 在包括壁元件（1），槽形反应空间（3）和空腔（5）的反应器中进行至少两种流体反应物之间的反应，用于使流体热载体通过。 根据工艺和生产量，选择模块化结构设计，其中任意数量的壁元件（1）组装到右平行六面体块（24），反作用空间（3）形成在 右平行六面体壁元件（1），将反应物从块体（24）的一侧的边缘区域引入反应空间（3）中，并通过平行流动的反应空间（3） 载体通过在壁元件（1）的内部延伸的管状空腔（5）进行。

公开(公告)号：US6117409A

公开(公告)日：2000-09-12

申请号：US289603

申请日：1999-04-12

Applicant: Birgit Bertsch-Frank ,  Torsten Balduf ,  Catrin Becker-Balfanz ,  Ina Hemme ,  Jurgen Rollmann ,  Rudiger Schutte ,  Werner Wildner

Inventor： Birgit Bertsch-Frank ,  Torsten Balduf ,  Catrin Becker-Balfanz ,  Ina Hemme ,  Jurgen Rollmann ,  Rudiger Schutte ,  Werner Wildner

IPC: C01B15/029 ,  C01B15/01

CPC classification number: C01B15/029

Abstract: An aqueous solution of hydrogen peroxide is produced by direct synthesis from hydrogen and oxygen in the presence of a heterogeneous catalyst. According to the invention, a gas mixture comprising H.sub.2 and O.sub.2, essentially saturated or supersaturated with water (=containing fog) is fed into a reactor containing the catalyst. The volume ratio of the gas mixture fed in (standard liters per hour) to liquid removed (liters per hour) is adjusted to a value equal to or greater than 15,000, especially 20,000 to 50,000, and the gas mixture leaving the reactor is recycled after replenishment with H.sub.2, O.sub.2, and H.sub.2 O vapor. Solutions with high H.sub.2 O.sub.2 concentration can be obtained according to the invention without additional concentration.

Abstract translation: 过氧化氢水溶液是通过在非均相催化剂存在下从氢气和氧气直接合成生产的。 根据本发明，将包含H 2和O 2的基本上饱和或过饱和的（=含雾）的气体混合物进料到含有催化剂的反应器中。 以（标准升每小时）供给的气体混合物与去除的液体（升/小时）的体积比调节至等于或大于15,000，特别是20,000至50,000的值，并且离开反应器的气体混合物在 用H2，O2和H2O蒸气补充。 可以根据本发明获得具有高H 2 O 2浓度的溶液，而没有另外的浓度。