BRANCHED POLYOLS CONTAINING ON AVERAGE TWO OR MORE HYDROXYL GROUPS PER MOLECULE,THEIR PREPARATION AND USE
    1.
    发明申请
    BRANCHED POLYOLS CONTAINING ON AVERAGE TWO OR MORE HYDROXYL GROUPS PER MOLECULE,THEIR PREPARATION AND USE 审中-公开
    包含平均每分子两个或多个羟基的分支的多元醇,其制备和使用

    公开(公告)号:US20110034628A1

    公开(公告)日:2011-02-10

    申请号:US12300535

    申请日:2007-05-09

    Abstract: Disclosed are branched polyols (A) having two or more hydroxyl groups per molecule prepared by providing a polyisocyanate (A1) containing per molecule two or more isocyanate groups and either two or more hard segments (a11) which as part of a thermoset three-dimensional network raise its glass transition temperature, or two or more soft segments which as part of a thermoset three-dimensional network lower its glass transition temperature; and reacting the polyisocyanate (A1) with a polyol (A2) in a molar ratio (A2):(A1) of ≧2 and an equivalent ratio of [X+OH]:NCO≧2; wherein polyol (A2) has the general formula I: X [—R(—OH)n]m, and the variables have the following definitions: n is a number from 1 to 5, m is 1 or 2, X is an isocyanate-reactive functional group, and R is a divalent to pentavalent organic radical, with the proviso that R comprises at least one hard segment (a11) if (A1) comprises soft segments.

    Abstract translation: 公开了每分子具有两个或多个羟基的支化多元醇(A),其通过提供每分子含有两个或更多个异氰酸酯基团和两个或更多个硬链段(a11)制备的多异氰酸酯(A1),所述硬链段作为热固性三维 网络提高其玻璃化转变温度,或两个或更多软段,作为热固性三维网络的一部分降低其玻璃化转变温度; 并使多异氰酸酯(A1)与摩尔比(A2):(A1)= 2的多元醇(A2)和当量的[X + OH]:NCO≥2的比例反应; 其中多元醇(A2)具有通式I:X [-R(-OH)n] m,并且变量具有以下定义:n为1至5的数,m为1或2,X为异氰酸酯 - 反应性官能团,R是二价至五价有机基团,条件是如果(A1)包含软链段,R包含至少一个硬链段(a11)。

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