摘要:
This invention relates to organopolysiloxane-modified graft copolymers obtained by a method comprising heating a mixture comprising an ethylenically unsaturated monomer, a polyethylene-polybutylene macromonomer, an organopolysiloxane macromonomer, a free radical initiator, and optionally a solvent. The copolymers of this invention find utility in adhesives such as pressure sensitive adhesives, contact adhesives. laminating adhesives, and assembly adhesives, and release coatings.
摘要:
Compositions and a method for performing the room temperature vulcanization of silicone elastomers are disclosed. The compositions and method utilize specifically-defined hydroxy-terminated polyorganosiloxanes, cross-linking agents which contain a hydrolyzable moiety, a catalyst which exhibits catalytic action in the condensation reaction between the hydroxy groups of the polyorganosiloxanes and the hydrolyzable groups of the cross-linking agents, and a formamide-type cure accelerator component. It has been found that these compositions can be stably stored under substantially moisture-free conditions and be readily vulcanized to form solid elastomers when exposed to moisture in the air. The vulcanization process provides a fast cure and a final silicone rubber product which exhibits good depth of hardening and excellent physical properties.
摘要:
To provide a release modifier which provides a heavy release force to a cured release layer of silicone coating composition. The release modifier comprises an organopolysiloxane resin-organopolysiloxane condensation reaction product that is obtained by the condensation reaction of (a1) 100 weight parts of MQ-type organopolysiloxane resin in which the molar ratio of the M unit to the Q unit is 0.6 to 1.0 and the content of the hydroxyl group or alkoxy group is 0.3 to 2.0 weight % with (a2) 20 to 150 weight parts of chain-form diorganopolysiloxane that has an average degree of polymerization of 100 to 1000 and at least one hydroxyl group or alkoxy group; this organopolysiloxane resin-organopolysiloxane condensation reaction product preferably has a prescribed hydroxyl group content.
摘要:
Problem: To provide a silicone-based releasable adhesive composition that is capable of easily controlling peeling force of a releasable adhesive layer by the composition, and whereby the silicone-based releasable adhesive composition has excellent attachment characteristics and releasability characteristics. A further object is to provide a sheet-form substrate and a releasable adhesive sheet that have a releasable adhesive layer formed by curing this composition.Resolution Means: The silicone-based releasable adhesive composition includes an organopolysiloxane resin-organopolysiloxane condensation reaction product obtained by condensation reaction between (a1) 100 weight parts of an MQ type organopolysiloxane resin containing hydroxyl groups or alkoxy groups in a range of 0.3 to 2.0 weight % and having an M unit to Q unit molar ratio of 0.6 to 1.0, and (a2) 20 to 150 weight parts of a chain-like diorganopolysiloxane having an average degree of polymerization of 100 to 1,000 and having at least one hydroxyl group or alkoxy group, wherein the organopolysiloxane resin-organopolysiloxane condensation reaction product preferably includes a certain hydroxyl group content.
摘要:
To provide a release modifier which provides a heavy release force to a cured release layer of silicone coating composition. The release modifier comprises an organopolysiloxane resin-organopolysiloxane condensation reaction product that is obtained by the condensation reaction of (a1) 100 weight parts of MQ-type organopolysiloxane resin in which the molar ratio of the M unit to the Q unit is 0.6 to 1.0 and the content of the hydroxyl group or alkoxy group is 0.3 to 2.0 weight % with (a2) 20 to 150 weight parts of chain-form diorganopolysiloxane that has an average degree of polymerization of 100 to 1000 and at least one hydroxyl group or alkoxy group; this organopolysiloxane resin-organopolysiloxane condensation reaction product preferably has a prescribed hydroxyl group content.