摘要:
The present invention relates to a process for the production of derivatives of natural fats and oils that is characterized in that the fats that are solid at room temperature or which contain solid fractions, mixtures of these with free fatty acids, mono- and/or diglycerides are oxyalkylated at elevated temperatures in the presence of basic catalysts having at least one 1,2-epoxide and the conversion products so obtained, optionally, after epoxidization are sulphonated in a manner known per se. The products are particularly suitable for use as leather dubbing agents.
摘要:
The present invention relates to a process for the production of textiles that are coated with polyurethane, in which the material that is to be coated is coated with two oppositely charged aqueous ionic dispersions of polyurethanes that contain no free isocyanate groups and contain covalently bonded, solubility-enhancing ionic groups, dried and optionally waterproofed. Cationic and anionic polyurethane dispersions are preferred in a weight ratio of 1:1, and are applied to the textile material in a two-coat technique, wet-on-wet. In addition, the invention relates to textile material produced in this way, with improved waterproof qualities and the use of such textiles for the production of breathable, water- and wind resistant clothing, industrial textiles, and leather substitutes, all of which are permeable to water vapour.
摘要:
The invention relates to a process for improving the lightfastness of conventionally dyed leathers by treating the leathers before, during or after fatting with alkane and/or chloroalkane sulfonamides in amounts of about 0.1 to 8 weight percent, based on the shaved weight of the leather. Used as alkane sulfonamides and chloroalkane sulfonamides are preferably products with a chain length of about 10 to 35 carbon atoms and a chlorine content of about 10 to 40%. The alkane and/or chloroalkane sulfonamides are advantageously used in aqueous solution or in stable emulsion. A substantial improvement in lightfastness is obtained regardless of the type of the dye, tanning agent, fatting agent or other leather treating agent used.
摘要:
The present invention relates to water-soluble polymers built up of a) monoethylenically unsaturated dicarboxylic acids and/or their salts, b) monoethylenically unsaturated monocarboxylic acids and/or their salts, c) monounsaturated monomers which, after hydrolysis or saponification, can be converted into monomers having a hydroxyl group covalently bonded at the C—C-chain, d) monoethylenically unsaturated sulfonic acid groups or sulfate groups-containing monomers, and optionally e) further radically copolymerizable monomers, with the sum of the monomers of a) to e) amounting to 100%. The present invention further relates to a process for the production of these polymers by radical polymerization and hydrolysis in aqueous medium, and to the use of these polymers as additive or cobuilder in detergents and cleaners, in the pretreatment of cotton, as bleaching stabilizers, as auxiliary agent in textile printing, and in the manufacture of leather, as well as for the inhibition of water hardness, and as dispersing agent as well as detergents and cleaners.
摘要:
The present invention relates to superabsorbent cross-linked polymers for watery liquids, which are built-up of partially neutralized monomers having monoethylenlcally unsaturated acid groups, optionally further monomers copolymerizable therewith, as well as polymers optionally suitable as graft basis, and which can be manufactured by using a cross-linker/monomer combination of CH.sub.2 .dbd.CHR.sup.6 --CO--(OCHR.sup.3 --CHR.sup.3).sub.z O--CH.sub.2 --CHR.sup.6 .dbd.CH.sub.2 CH.sub.2 .dbd.CHR.sup.6 --R.sup.5 --(OCHR.sup.3 --CHR.sup.3).sub.v OR.sup.4R.sup.1 --�O(CHR.sup.3 --CHR.sup.3 O).sub.u --CO--R.sup.2 !.sub.x, and/or di- or triallylamine and/or bisacrylamide with R.sup.1 : multivalent C2-10-alkyl, R.sup.2 : linear or branched C2-10-alkenyl, R.sup.3 : H, CH.sub.3, C.sub.2 H.sub.5, R.sup.4 : H, linear or branched C1-10-alkyl, R.sup.6 : CO, CH.sub.2 R.sup.8 : H, CH.sub.3 x: 2-6 u: 0-15 V: 1-45 z: 3-20 As compared with the state of the art, the polymers according to the present invention have an improved combination of the properties retention, liquid absorption under pressure at 63 g/cm.sup.2 and soluble contents, moreover, they have an Increased permeability of the gel layer for watery liquids, a high suction rate, and a high swelling pressure. The polymers are used as absorbents for water and watery liquids in constructions for the absorption of body fluids, In electricity or light-conducting cables, and in plant raising.
摘要:
The present invention relates to a process to improve the organoleptic behaviour and the physical characteristics of leather by the use of aqueous solutions of copolymers of 90 to 20%-wt acrylic acid or methyacrylic acid, as well as 10 to 80%-wt of a monomer of the formula ##STR1## wherein R.sub.1 is hydrogen or methyl; R.sub.2 and R.sub.3, which are equal or different, are methyl or ethyl; x stands for an optionally branched alkylene radical with 1 to 5 carbon atoms; the amine nitrogen is optionally neutralized or quaternized; and the molecular weight of the copolymer, measured at a pH of 8.0, is less than 100,000. The concentration of the copolymer in the aqueous solution is 0.02 to 10%-wt, relative to the shaved weight of the leather.
摘要:
The antistatic composition for application to flat fibrous articles such as textiles, carpets, fabrics and the like which comprises a salt of a polymeric acid with an amine of the general formula ##STR1## wherein A=H, --OR.sub.2, ##STR2## R.sub.1 =H, a lower alkyl radical, a hydroxyalkyl, aminoalkyl, polyalkylene imine or polyalkylene glycol ether radical;R.sub.2 =H, a lower alkyl radical, a hydroxyalkyl, aminoalkyl, polyalkylene imine or polyalkylene glycol ether radical;R.sub.3 =H, a lower alkyl radical, a hydroxyalkyl, aminoalkyl, polyalkylene imine or polyalkylene glycol ether radical;R.sub.4 =H, a lower alkyl radical, a hydroxyalkyl, aminoalkyl, polyalkylene imine or polyalkylene glycol ether radical;X=a bivalent alkylene radical having 1 to 6 carbon atoms;B=H, a lower alkyl radical, a hydroxyalkyl, aminoalkyl, polyalkylene glycol ether or polyalkylene imine radical;n=small integers from 1 to 6, wherein when n=1 the grouping ##STR3## may stand for a bivalent 5- or 6-membered heterocyclic radical having one or more hetero atoms; a process for rendering a normally flat fibrous substance antistatic which comprises applying thereto such an antistatic composition including fibrous articles containing as a component of a coating thereof the novel antistatic agent.
摘要翻译:用于应用于诸如纺织品,地毯,织物等的扁平纤维制品的抗静电组合物,其包含聚合酸与通式为“IMAGE”的胺的盐,其中A = H,-OR 2,R 1 = H,低级烷基,羟烷基,氨基烷基,聚亚烷基亚胺或聚亚烷基二醇醚基; R2 = H,低级烷基,羟基烷基,氨基烷基,聚亚烷基亚胺或聚亚烷基二醇醚基; R3 = H,低级烷基,羟基烷基,氨基烷基,聚亚烷基亚胺或聚亚烷基二醇醚基; R4 = H,低级烷基,羟基烷基,氨基烷基,聚亚烷基亚胺或聚亚烷基二醇醚基; X =具有1至6个碳原子的二价亚烷基; B = H,低级烷基,羟基烷基,氨基烷基,聚亚烷基二醇醚或聚亚烷基亚胺基; n = 1至6的小整数,其中当n = 1时,分组可以代表具有一个或多个杂原子的二价5-或6-元杂环基团; 提供通常平坦的纤维物质抗静电剂的方法,其包括向其施加包含含有作为其新型抗静电剂的涂层组分的纤维制品的抗静电组合物。
摘要:
The present invention relates to biodegradable polymers built-up of a) monoethylenically unsaturated dicarboxylic acids and/or the salts thereof, b) monoethylenically unsaturated monocarboxylic acids and/or the salts thereof, c) monounsaturated monomers which, after hydrolysis, can be converted to monomers with a hydroxyl group covalently bonded to the C-C-chain, and, optionally, d) further radically copolymerizable monomers, with the sum of the monomers according to a) to d) amounting to 100%. The present invention further relates to a process of producing said polymers by radical polymerization and hydrolysis in aqueous medium, and to the use of said polymers as additive or cobuilder in detergents and cleaning agents, in the pretreatment of cotton, as bleaching stabilizers, as auxiliary agent in textile printing and in the manufacture of leather, as well as in the inhibition of water hardness and as dispersing agent.
摘要:
A process for the quaternization of triethanolamine fatty acid esters and imidazolinamides with customary quaternizing agents in a reaction medium containing alkoxylated naturally occurring fats or oils, or mixtures thereof with free fatty acids, monoglycerides and/or diglycerides in the substantial absence of 2-propanol, and the use of the resulting reaction mixtures as the active components in laundry softener compositions.
摘要:
A process for the quaternization of triethanolamine fatty acid esters and imidazolinamides with customary quaternizing agents in a reaction medium containing alkoxylated naturally occurring fats or oils, or mixtures thereof with free fatty acids, monoglycerides and/or diglycerides in the substantial absence of 2-propanol, and the use of the resulting reaction mixtures as the active components in laundry softener compositions.