Metallic compound and organic electroluminescence device comprising the same
    2.
    发明授权
    Metallic compound and organic electroluminescence device comprising the same 有权
    金属化合物和包含其的有机电致发光器件

    公开(公告)号:US07968715B2

    公开(公告)日:2011-06-28

    申请号:US11913216

    申请日:2007-01-08

    IPC分类号: C07F7/02

    CPC分类号: C07F15/0033

    摘要: The present invention relates to a light-emitting transition metal compound represented by the Chemical Formula 1 and Chemical Formula 2 and an organic electroluminescence device including the same.In the Chemical Formulae 1 and 2, M is Ir, Pt, Rh, Re, Os, and the like, m is 2 or 3, n is 0 or 1, the sum of m and n is 3, provided that the sum of m and n is 2 when M is Pt, X, and Z are the same or different, N or P, and Y and Q are O, S, or Se, R1 and R5 are hydrogen, a C1 to C20 alkyl excluding an aromatic cyclic substituent, a cycloalkyl, a halogen, a linear or branched substituent including at least one halogen, or a linear or branched substituent including at least one heteroatom, and R2, R3, R4, R6, R7, R8, R9, and R10 are hydrogen, a C1 to C20 alkyl, an aryl, a cycloalkyl, a halogen, a linear or branched substituent including at least one halogen, a linear or branched substituent including at least one heteroatom, carbonyl, vinyl, or acetylenyl, or may form a cycle, and may be the same or different.

    摘要翻译: 本发明涉及由化学式1和化学式2表示的发光过渡金属化合物和包含其的有机电致发光器件。 在化学式1和2中,M是Ir,Pt,Rh,Re,Os等,m是2或3,n是0或1,m和n之和是3,条件是 m,当M为Pt时,n为2,X和Z相同或不同,N或P,Y和Q为O,S或Se,R 1和R 5为氢,不包括芳香族的C 1〜C 20烷基 环状取代基,环烷基,卤素,包含至少一个卤素的直链或支链取代基,或包括至少一个杂原子的直链或支链取代基,R2,R3,R4,R6,R7,R8,R9和R10分别为 氢,C1至C20烷基,芳基,环烷基,卤素,直链或支链的取代基,包括至少一个卤素,包括至少一个杂原子,羰基,乙烯基或乙炔基的直链或支链取代基,或可形成 循环,并且可以相同或不同。

    Polyarylether containing N-substituted imide groups and process for
producing the same
    5.
    发明授权
    Polyarylether containing N-substituted imide groups and process for producing the same 失效
    含有N-取代的酰亚胺基团的聚芳醚基及其制备方法

    公开(公告)号:US6018055A

    公开(公告)日:2000-01-25

    申请号:US892707

    申请日:1997-07-15

    CPC分类号: C07D487/04 C08G73/0672

    摘要: A polyarylether of the formula (VIII) ##STR1## wherein wherein Z' is 1-3 optionally substituted rings selected from the group consisting of an aromatic ring, a hetero aromatic ring or an aliphatic ring.A is --R.sub.1 --Z--Y in which R.sub.1 is H, C.sub.1 -C.sub.30 -alkyl or -aralkyl or phenyl, Z is a direct bond or CH.sub.2, S, O or NH, Y is CH.sub.3, OR.sub.3, SR.sub.3, NHR.sub.3, N(R.sub.3).sub.2, COOR.sub.3, COOM, SO.sub.3 R.sub.3 or SO.sub.3 M in which R.sub.3 is C.sub.1 -C.sub.30 alkyl and M is alkali metal,produced from 3,6-dihalogen- or -dintro-1,2,4,5-diimide having an N,N-substituent and which is suitable for use as a monomer for high temperature structural and functional polymers, and a process for producing the same are disclosed.

    摘要翻译: 式(VIII)的聚芳醚,其中Z'为1-3个选自芳香环,杂芳环或脂族环的任选取代的环。 A是-R1-ZY,其中R1是H,C1-C30 - 烷基或 - 烷基或苯基,Z是直接键或CH2,S,O或NH,Y是CH3,OR3,SR3,NHR3,N )2,CO 3,COOM,SO 3 R 3或SO 3 M,其中R 3为C 1 -C 30烷基且M为碱金属,由具有N,N的3,6-二卤代 - 或二苯并1,2,4,5-二酰亚胺 并且其适合用作高温结构和功能性聚合物的单体,并且公开了其制备方法。

    Polyamideimide for optical communications and method for preparing the
same
    6.
    发明授权
    Polyamideimide for optical communications and method for preparing the same 有权
    用于光通信的聚酰胺酰胺及其制备方法

    公开(公告)号:US6013759A

    公开(公告)日:2000-01-11

    申请号:US206230

    申请日:1998-12-07

    CPC分类号: C08G73/14

    摘要: A polyamideimide for optical communications, having a minimum optical loss in a near infrared light wavelength range, high thermal resistance and good film processibility, and a method for preparing the same are provided. The polyamideimide is very useful as an optical material in the optical communications field adopting the light of near infrared light wavelength.

    摘要翻译: 提供了一种用于光通信的聚酰胺酰亚胺,其具有近红外光波长范围内的最小光损耗,高热阻和良好的膜加工性及其制备方法。 聚酰胺酰亚胺在采用近红外光波长的光的通信领域中作为光学材料是非常有用的。

    (3-oxoisoindolin-1-ylidine)propandinitrile derivatives and method for
preparing the same
    7.
    发明授权
    (3-oxoisoindolin-1-ylidine)propandinitrile derivatives and method for preparing the same 有权
    (3-氧代异吲哚啉-1-基)丙腈衍生物及其制备方法

    公开(公告)号:US5962658A

    公开(公告)日:1999-10-05

    申请号:US156904

    申请日:1998-09-18

    摘要: Derivatives of (3-oxoisoindolin-1-ylidine)propandinitrile, and a method for preparing the derivatives, are disclosed herein. The (3-oxoisoindolin-1-ylidine)propandinitrile derivatives can be prepared easily and at low cost. Also, the derivatives show good heat resistance at temperatures required for manufacturing an electro-optic device, and can minimize light loss at a near infrared light wavelength range by replacing hydrogen of the C--H bond with halogen atom. As a result, the derivatives of the present invention are useful as an optical material for an electro-optic device. In addition, the (3-oxoisoindolin-1-ylidine)propandinitrile derivatives can be used as an intermediate for synthesizing a new compound having good electro-optic characteristics and heat resistance.

    摘要翻译: (3-氧代异吲哚啉-1-基)丙腈的衍生物及其衍生物的制备方法。 (3-氧代异吲哚啉-1-基)吡啶衍生物可以容易且低成本地制备。 此外,衍生物在制造电光器件所需的温度下显示出良好的耐热性,并且通过用卤素原子代替C-H键的氢,可以使近红外光波长范围的光损失最小化。 结果,本发明的衍生物可用作电光器件的光学材料。 此外,(3-氧代异吲哚啉-1-基)吡啶衍生物可以用作合成具有良好的电光特性和耐热性的新化合物的中间体。

    Process for preparing polyamideimide resins by direct polymerization
    8.
    发明授权
    Process for preparing polyamideimide resins by direct polymerization 失效
    通过直接聚合制备聚酰胺酰亚胺树脂的方法

    公开(公告)号:US5955568A

    公开(公告)日:1999-09-21

    申请号:US956923

    申请日:1997-10-23

    IPC分类号: C08G73/14 C08G69/28

    CPC分类号: C08G73/14

    摘要: The disclosure describes a process for preparing a polyamideimide resin having high molecular weight in a simple manner wherein major problems of the prior processes such as low heat resistance and low melt flowability are improved. The process comprises condensation of an aromatic tricarboxylic acid anhydride and an aromatic diamine in a polar solvent, subjecting the resulting diimidedicarboxylic acid to acyl halogenating agent treatment to give an intermediate having good reactivity at low temperature, and then subjecting the latter to direct polymerization by using diamine as a nucleophilic agent to give a polyamideimide resin having high molecular weight. The polyamideimide resin prepared by the present invention can be used as major heat resistant structural material in advanced industries and as paint, sheet, adhesives, sliding material, fiber and film having heat resistance.

    摘要翻译: 本公开内容描述了以简单的方式制备具有高分子量的聚酰胺酰亚胺树脂的方法,其中诸如低耐热性和低熔融流动性的现有方法的主要问题得到改善。 该方法包括在极性溶剂中将芳族三羧酸酐和芳族二胺缩合,将所得二酰亚胺二羧酸进行酰卤处理,得到在低温下具有良好反应性的中间体,然后使用后者通过使用 二胺作为亲核剂,得到具有高分子量的聚酰胺酰亚胺树脂。 本发明制备的聚酰胺酰亚胺树脂可用作先进工业中的主要耐热结构材料,可用作具有耐热性的油漆,片材,粘合剂,滑动材料,纤维和薄膜。

    Process for preparing polyamideimide resins having high molecular weight
    9.
    发明授权
    Process for preparing polyamideimide resins having high molecular weight 失效
    制备高分子量聚酰胺酰亚胺树脂的方法

    公开(公告)号:US5532334A

    公开(公告)日:1996-07-02

    申请号:US339391

    申请日:1994-11-14

    IPC分类号: C08G73/14 H01B3/30 C08G69/26

    CPC分类号: C08G73/14 H01B3/303

    摘要: A process for preparing polyamideimide resins having high molecular weights as described wherein major problems of prior art processes such as low heat resistance and low melt flowability are improved. Polyamideimide resins having an intrinsic viscosity of 0.4 to 1.50 dl/g as measured on a solution of dimethylacetamide as a solvent at a concentration of 0.5 g/dl at 30.degree. C., are prepared by reacting an aromatic tricarboxylic acid anhydride with an aromatic diamine in N-methyl pyrrolidone solvent in the presence of a first catalyst selected from a group consisting of thionyl chloride, p-toluenesulphonly chloride, sulfuryl chloride, cyanuric chloride and phosphorus trichloride at a temperature of 50.degree. C. to 130.degree. C. over a period of 1 to 5 hours and further reacting the resultant reaction mixture in the presence of a second catalyst which is a compound of the formula (RO).sub.3 P wherein R is an aliphatic or aromatic substituent, or a compound which is phosphoric acid, pyrophosphoric acid, phosphorous pentaoxide or phosphorous pentachloride as a second catalyst at a temperature of 50.degree. C. to 130.degree. C. over a period of 1 to 5 hours.

    摘要翻译: 制备如上所述的具有高分子量的聚酰胺酰亚胺树脂的方法,其中提高了诸如低耐热性和低熔融流动性的现有技术方法的主要问题。 通过在30℃下以0.5g / dl的浓度作为溶剂的二甲基乙酰胺溶液测定的特性粘度为0.4至1.50dl / g的聚酰胺酰亚胺树脂通过芳族三羧酸酐与芳族二胺 在N-甲基吡咯烷酮溶剂中,在50℃至130℃的温度下,在选自亚硫酰氯,对甲苯磺酰氯,磺酰氯,氰尿酰氯和三氯化磷的第一催化剂存在下,在 时间为1至5小时,并且在第二催化剂存在下进一步反应,所述第二催化剂是式(RO)3P的化合物,其中R是脂族或芳族取代基,或者是磷酸化合物,焦磷酸 ,五氧化二磷或五氯化磷作为第二催化剂,温度为50〜130℃,时间为1〜5小时。