Abstract:
There is provided a novel chain-end functionalized PEO of formulas (I) to (IV) prepared via living anionic polymerization and chain-end functionalization, as well as a simple method of preparing nano-sized transition metal or metal salt particles using the same, which can be readily stabilized even in an aqueous medium. The water-soluble PEO-based polymers having various functional groups (including a drug group such as vitamin and anti-cancer agent) and the process of preparing nano-sized transition metal or metal salt particles using the same can be advantageously used in the development of new materials for drug delivering system and imaging, e.g., a contrast agent and an anti-cancer agent simultaneously.
Abstract:
Disclosed herein is a method of forming a pattern, comprising: attaching a single-layer or multi-layer sacrificial film made of a semi-solid or solid material on part or all of the surface of a substrate; irradiating the sacrificial film with a focusable energy beam such as a laser beam to form a region to be charged with a functional material; charging the functional material into the formed region using a method such as an inkjet; drying the functional material; and removing the sacrificial film, thus obtaining the desired pattern.
Abstract:
Disclosed is a method for forming a pattern, which comprises the steps of: (a) providing a substrate having a sacrificial layer made of a first material, partially or totally formed on the substrate; (b) forming pattern grooves, which are free from the first material and have a line width of a first resolution or lower, on the sacrificial layer by using a first means; (c) filling the pattern grooves with a second material by using a second means; and (d) removing the first material present in a remaining sacrificial layer by way of irradiation or heating, wherein the first material has a threshold fluence of less than a threshold fluence of the second material, the first material is removed in step (d) under a dose ranging from the threshold fluence of the first material to that of the second material, and the pattern is formed on the substrate by the second material. A substrate having a pre-pattern formed by the method is also disclosed. The method for forming a pattern provides a high-resolution pattern with little or no waste of the second material, thereby reducing production costs. The method includes use of the first means with a high resolution, such as focused energy beams of laser, combined with the second means with a low resolution, such as ink-jet, and provides a high-resolution pattern with high processing efficiency.
Abstract:
The present invention relates to a process for preparing copolymer hydrogels with controlled molecular weights and having both thermo- and pH-responsive properties, wherein the process comprises the steps of (a) providing sulfonamide type styrenic or (meth)acrylamide-based monomers exhibiting different pKa values; (b) providing poly(N-isopropylacrylamide) or crosslinked poly(N-isopropylacrylamide-co-methylene bisacrylamide) hydrogels having thermo-responsive properties; and (c) providing several hydrogels exhibiting pH-sensitive properties and random or block copolymerizations of the sulfonamide type styrenic or (meth)acrylamide-based monomers prepared in step (a) with N-isopropylacrylamide and/or methylene bisacrylamide monomers used in step (b) in a polar or non-polar solvent; wherein said steps (b) and (c) are carried out by controlled/living radical polymerization using alkyl halides as the initiators and the transition metals with phosphine or amine ligands as the catalysts. The present invention also relates to the copolymer hydrogels made by the aforesaid process.
Abstract:
The present invention relates to a luminous advertisement sheet. The luminous advertisement sheet includes a light-transmitting print sheet having an EL advertisement region formed in at least one area of the print sheet, and a general advertisement region formed in the other area thereof. The EL advertisement region has at least one of a fixed pattern portion in which a transparent electrode layer, an EL layer and a dielectric layer are sequentially laminated and a variable pattern portion in which a transparent electrode layer, an EL layer, a dielectric layer and a plurality of pixel electrode layers are sequentially laminated. The general advertisement region allows general dye printing to be performed therein. The luminous advertisement sheet further includes a pattern electrode layer laminated and printed with a conductive ink material to have a predetermined luminous pattern in at least one area of the dielectric layer laminated in the fixed pattern portion and/or the variable pattern portion. Accordingly, there are provided a luminous advertisement sheet that exhibits excellent advertisement effects and can be easily produced in a multi-line small-batch production manner and at remarkably reduced manufacturing costs, and a method of manufacturing the same.
Abstract:
Disclosed are nano-sized metals and metal salts stabilized by using semi-telechelic and telechelic polymers prepared through living anionic polymerization, and their synthetic methods, and a nanostructure wherein the nano-sized particles are self-assembled by mixing block copolymers and film-casting. The present invention provides a new method for preparing nano-sized particles capable of easily accomplishing nanostructure by merely mixing, especially with block copolymers, and having excellent stability.
Abstract:
Disclosed herein is a method for forming a pattern, comprising: attaching a single-layer or multi-layer dry film resist made of a semi-solid or solid material to part or all of the surface of a substrate; exposing the dry film resist to light either by irradiating a focusable energy beam directly onto the resist or by projecting a specific wavelength range of light onto the resist, to form a region to be filled with a functional material; charging the functional material into the formed region using a method such as inkjetting; drying the functional material; and removing the dry film resist, thus obtaining the desired pattern.
Abstract:
A printing apparatus having an automatic printing sheet feeder integrated thereto to improve mass productivity. The printing apparatus includes a base, a moving stage, an automatic printing sheet feeder, and a printing roll. The moving stage is linearly movable along the base, and has a lithographic plate seated on the top surface thereof, the lithographic plate having a printing pattern thereon. The automatic printing sheet feeder is installed on the moving stage. The automatic printing sheet feeder includes an unwinding roll, which supplies the printing sheet, a rewinding roll, which collects the printing sheet, and a plurality of guide rolls, which guide the printing sheet to pass through the printing area of the moving stage. The printing roll is installed on the base, and performs printing by transferring ink from recesses of a printing pattern of the lithographic plate to the printing sheet on the moving stage.
Abstract:
Disclosed is an anti-cancer medicine comprising a chain end functionalized polymer, a contrast material such as iron oxide and a chemotherapeutic agent such as doxorubicin or pharmaceutically acceptable salts thereof. The anti-cancer medicine performs diagnosis and treatment of cancer at the same time, remarkably reduces a cardiotoxic side effect of the doxorubicin and has an excellent targeting function to the cancer part to considerably increase the anti-cancer effect. At the same time, the anti-cancer medicine is provided as MRI contrast medium which can diagnose the cancer and monitor a progress of the disease. In particular, the anti-cancer medicine is disclosed which is superior to the diagnosis and treatment of the solid cancer and can effectively perform the diagnosis and treatment of the metastatic cancer as well as the primary cancer at the same time.
Abstract:
Disclosed is an integrated apparatus for supplying ink and regulating pressure, which comprises a chamber accommodating ink, a main chamber preliminarily storing ink to be supplied to the chamber, a nozzle communicating with the chamber and jetting ink transferred from the chamber to an outside, a first valve blocking or letting flow of ink between the main chamber and the chamber, a second valve blocking and letting flow of ink between the chamber and the nozzle, a piston placed above ink accommodated in the chamber and reciprocating rectilinearly while sealing ink inside the chamber, a piston driver providing a driving force to the piston, a sensor installed in the chamber and sensing pressure due to weight of ink, and a controller receiving a sensed signal from the sensor and outputting a signal for controlling the piston to the piston, wherein the piston moves down as a level of ink accommodated in the chamber is lowered when ink is discharged to the outside through the nozzle, and the piston moves up and the first valve and the second valve are respectively opened and closed when ink is filled in the chamber.