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    Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons
    1.
    发明授权
    Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons 有权
    包含至少一种结构类型为NES和铼的沸石的催化剂及其用于烷基芳烃的烷基转移的用途

    公开(公告)号：US06613709B1

    公开(公告)日：2003-09-02

    申请号：US09642020

    申请日：2000-08-21

    申请人： Elisabeth Merlen ,  Fabio Alario ,  Nathalie Ferrer ,  Olivia Martin

    发明人： Elisabeth Merlen ,  Fabio Alario ,  Nathalie Ferrer ,  Olivia Martin

    IPC分类号： B01J2906

    CPC分类号： C07C6/126 ,  B01J29/74 ,  B01J29/78 ,  B01J2229/16 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42 ,  C07C2529/70

    摘要： The present invention concerns a catalyst which contain at least one zeolite with structure type NES, preferably NU-87, comprising silicon and at least one element T selected from the group formed by aluminium, iron, gallium and boron. Preferably, element T has been extracted so that the overall Si/T atomic ratio is more than 20. This zeolite is at least partially in its acid form. The binder is preferably alumina. The catalyst also contains at least one metal selected from the group formed by group VIIB, group VIB and iridium, preferably rhenium. Finally, the catalyst optionally also contains at least one metal selected from the group formed by elements from groups III and IV of the periodic table, preferably indium or tin. The present invention also concerns the use of the catalyst in a process for transalkylating alkylaromatic hydrocarbons such as toluene and alkylaromatic compounds containing at least 9 carbon atoms. In particular, this catalyst is highly effective in treating C9+ aromatic feeds containing more than 5% by weight of aromatic olefins containing 10 carbon atoms and more, this feed possibly also containing benzene.

    摘要翻译： 本发明涉及含有至少一种结构类型为NES，优选为NU-87的沸石的催化剂，其包含硅和选自由铝，铁，镓和硼形成的基团中的至少一种元素T. 优选地，提取元素T使得总Si / T原子比大于20.该沸石至少部分为其酸形式。 粘合剂优选为氧化铝。 该催化剂还含有选自由ⅦB族，ⅥB族和铱族，优选铼形成的族中的至少一种金属。 最后，催化剂任选地还含有至少一种选自元素周期表III和IV族的元素形成的金属，优选为铟或锡。 本发明还涉及催化剂在烷基化烷基芳烃如甲苯和含有至少9个碳原子的烷基芳族化合物的方法中的用途。 特别地，该催化剂在处理含有大于5重量％的含有10个碳原子的芳族烯烃和更多的芳族烯烃的C9 +芳族原料方面是非常有效的，该进料还可能含有苯。

    Process for preparing a zeolite with structure type EUO
    2.
    发明授权
    Process for preparing a zeolite with structure type EUO 有权
    制备结构型EUO的沸石的方法

    公开(公告)号：US06342200B1

    公开(公告)日：2002-01-29

    申请号：US09432120

    申请日：1999-11-02

    申请人： Loic Rouleau ,  Sylvie Lacombe ,  Fabio Alario ,  Elisabeth Merlen ,  Frédéric Kolenda ,  Julia Magne-Drisch

    发明人： Loic Rouleau ,  Sylvie Lacombe ,  Fabio Alario ,  Elisabeth Merlen ,  Frédéric Kolenda ,  Julia Magne-Drisch

    IPC分类号： C01B3904

    CPC分类号： B01J29/7023 ,  B01J20/18 ,  B01J29/04 ,  B01J2229/62 ,  C01B39/48 ,  C07C5/2708 ,  C07C2529/70 ,  C10G35/095 ,  C10G45/64 ,  Y02P20/588 ,  C07C15/067

    摘要： The present invention concerns a process for preparing a zeolite with structure type EUO comprising at least one element X selected from silicon and germanium and at least one element T selected from iron, aluminium, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese, characterized in that seeds of at least one zeolitic material are used comprising at least one element X′ selected from silicon and germanium and at least one element T′ selected from iron, aluminium, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese with a ratio X′/T′ of less than 200, said seeds being different from the zeolite with structure type EUO being prepared. The present invention also concerns the use of the zeolite obtained as a catalyst in a process for converting hydrocarbon-containing feeds, as an adsorbent to control pollution and as a molecular sieve for separation, and more particularly as a catalyst in a process for isomerizing aromatic compounds containing 8 carbon atoms.

    摘要翻译： 本发明涉及一种制备具有结构型EUO的沸石的方法，该方法包括至少一种选自硅和锗的元素X和选自铁，铝，镓，硼，钛，钒，锆，钼，砷中的至少一种元素T ，锑，铬和锰，其特征在于使用至少一种沸石材料的种子，其包含至少一种选自硅和锗的元素X'和至少一种选自铁，铝，镓，硼，钛， 钒，锆，钼，砷，锑，铬和锰，其比例X'/ T'小于200，所述种子与制备具有结构类型EUO的沸石不同。 本发明还涉及在烃类进料转化方法中作为催化剂使用的沸石，作为用于控制污染的吸附剂和用于分离的分子筛，更特别地，作为用于异构化芳族化合物的方法中的催化剂 含有8个碳原子的化合物。

    Process for isomerizing aromatic C8 cuts in the presence of a catalyst based on mordenite containing at least one group VIII metal and at least one group III metal
    4.
    发明授权
    Process for isomerizing aromatic C8 cuts in the presence of a catalyst based on mordenite containing at least one group VIII metal and at least one group III metal 有权
    在基于含有至少一种VIII族金属和至少一种III族金属的丝光沸石的催化剂存在下异构化芳族C 8馏分的方法

    公开(公告)号：US06465705B1

    公开(公告)日：2002-10-15

    申请号：US09630812

    申请日：2000-08-02

    申请人： Elisabeth Merlen ,  Fabio Alario

    发明人： Elisabeth Merlen ,  Fabio Alario

    IPC分类号： C07C522

    CPC分类号： B01J29/20 ,  C07C5/2724 ,  C07C2521/04 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/40 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/74 ,  C07C2523/755 ,  C07C2529/22 ,  C07C2529/24 ,  Y02P20/52 ,  C07C15/067

    摘要： The present invention relates to a process for isomerizing aromatic C8 cuts in the presence of a catalyst containing a mordenite which is slightly or not dealuminated and a binder. This mordenite is generally present at least in part in its acid form and its Si/Al atomic ratio is less than 20, preferably in the range 5 to 15, and more preferably in the range 5 to 10. The catalyst also contains at least one metal from group VIII of the periodic table, preferably selected from the group formed by palladium and platinum. Finally, the catalyst further contains at least one metal from group III of the periodic table, namely gallium, indium or thallium, preferably indium, and optionally at least one metal from group IV of the periodic table, namely germanium, tin or lead, preferably tin. The present invention also relates to the catalyst used in the isomerization process and to a process for its preparation.

    摘要翻译： 本发明涉及在含有轻微或不脱铝的丝光沸石的催化剂存在下使芳族C8馏分异构化的方法和粘合剂。 该丝光沸石通常至少部分地以其酸形式存在，其Si / Al原子比小于20，优选在5至15范围内，更优选在5至10范围内。催化剂还含有至少一种 元素周期表第VIII族的金属，优选选自钯和铂形成的基团。 最后，催化剂还含有至少一种元素周期表III族金属，即镓，铟或铊，优选铟，以及任选的至少一种元素周期表IV族金属，即锗，锡或铅，优选 锡。 本发明还涉及用于异构化方法的催化剂及其制备方法。

    Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons
    7.
    发明申请
    Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons 审中-公开
    包含至少一种结构类型为NES和铼的沸石的催化剂及其用于烷基芳烃的烷基转移的用途

    公开(公告)号：US20050256355A1

    公开(公告)日：2005-11-17

    申请号：US11048751

    申请日：2005-02-03

    申请人： Elisabeth Merlen ,  Fabio Alario ,  Nathalie Ferrer ,  Olivia Martin

    发明人： Elisabeth Merlen ,  Fabio Alario ,  Nathalie Ferrer ,  Olivia Martin

    IPC分类号： B01J29/06 ,  B01J29/78 ,  C07C6/12 ,  C10G45/64

    CPC分类号： B01J29/78 ,  B01J2229/42 ,  C07C6/126 ,  C07C2523/28 ,  C07C2529/70 ,  C07C2529/78 ,  C10G45/64

    摘要： The present invention concerns catalysts which contain at least one zeolite with structure type NES, preferably NU-87, comprising silicon and at least one element T selected from the group formed by aluminium, iron, gallium and boron. Preferably, element T has been extracted so that the overall Si/T atomic ratio is more than 20. This zeolite is at least partially in its acid form. The binder is preferably alumina. The catalyst also contains at least one metal selected from the group formed by group VIIB, group VIB and iridium, preferably molybdenum. Finally, the catalyst optionally also contains at least one metal selected from the group formed by elements from groups IIIA and IVA of the periodic table, preferably indium or tin. The present invention also concerns the use of the catalyst in a process for transalkylating alkylaromatic hydrocarbons such as toluene and alkylaromatic compounds containing at least 9 carbon atoms. In particular, this catalyst is highly effective in treating C9+ aromatic feeds containing more than 5% by weight of aromatic olefins containing 10 carbon atoms and more, this feed possibly also containing benzene.

    摘要翻译： 本发明涉及含有至少一种结构类型NES，优选NU-87的沸石的催化剂，其包含硅和至少一种选自由铝，铁，镓和硼形成的基团的元素T. 优选地，提取元素T使得总Si / T原子比大于20.该沸石至少部分为其酸形式。 粘合剂优选为氧化铝。 该催化剂还含有至少一种选自由ⅦB族，ⅥB族和铱族化合物形成的金属，优选为钼。 最后，催化剂任选地还含有选自元素周期表IIIA和IVA族元素形成的族中的至少一种金属，优选为铟或锡。 本发明还涉及催化剂在烷基化烷基芳烃如甲苯和含有至少9个碳原子的烷基芳族化合物的方法中的用途。 特别地，该催化剂在处理含有大于5重量％的含有10个碳原子的芳族烯烃和更多的芳族烯烃的C9 +芳族原料方面是非常有效的，该进料还可能含有苯。

    Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons
    8.
    发明授权
    Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons 失效
    包含至少一种结构类型为NES和铼的沸石的催化剂及其用于烷基芳烃的烷基转移的用途

    公开(公告)号：US06864400B2

    公开(公告)日：2005-03-08

    申请号：US10428033

    申请日：2003-05-02

    申请人： Elisabeth Merlen ,  Fabio Alario ,  Nathalie Ferrer ,  Olivia Martin

    发明人： Elisabeth Merlen ,  Fabio Alario ,  Nathalie Ferrer ,  Olivia Martin

    IPC分类号： B01J29/076 ,  B01J23/16 ,  B01J23/46 ,  B01J29/06 ,  B01J29/74 ,  B01J29/78 ,  C07B61/00 ,  C07C5/22 ,  C07C5/52 ,  C07C6/06 ,  C07C6/12 ,  C07C15/08

    CPC分类号： C07C6/126 ,  B01J29/74 ,  B01J29/78 ,  B01J2229/16 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42 ,  C07C2529/70

    摘要： The present invention concerns a catalyst which contain at least one zeolite with structure type NES, preferably NU-87, comprising silicon and at least one element T selected from the group formed by aluminium, iron, gallium and boron. Preferably, element T has been extracted so that the overall Si/T atomic ratio is more than 20. This zeolite is at least partially in its acid form. The binder is preferably alumina. The catalyst also contains at least one metal selected from the group formed by group VIIB, group VIB and iridium, preferably rhenium. Finally, the catalyst optionally also contains at least one metal selected from the group formed by elements from groups III and IV of the periodic table, preferably indium or tin. The present invention also concerns the use of the catalyst in a process for transalkylating alkylaromatic hydrocarbons such as toluene and alkylaromatic compounds containing at least 9 carbon atoms. In particular, this catalyst is highly effective in treating C9+ aromatic feeds containing more than 5% by weight of aromatic olefins containing 10 carbon atoms and more, this feed possibly also containing benzene.

    摘要翻译： 本发明涉及含有至少一种结构类型为NES，优选为NU-87的沸石的催化剂，其包含硅和选自由铝，铁，镓和硼形成的基团中的至少一种元素T. 优选地，提取元素T使得总Si / T原子比大于20.该沸石至少部分为其酸形式。 粘合剂优选为氧化铝。 该催化剂还含有选自由ⅦB族，ⅥB族和铱族，优选铼形成的族中的至少一种金属。 最后，催化剂任选地还含有至少一种选自元素周期表III和IV族的元素形成的金属，优选为铟或锡。 本发明还涉及催化剂在烷基化烷基芳烃如甲苯和含有至少9个碳原子的烷基芳族化合物的方法中的用途。 特别地，该催化剂在处理含有大于5重量％的含有10个碳原子的芳族烯烃和更多的芳族烯烃的C9 +芳族原料方面是非常有效的，该进料还可能含有苯。

    Process for the production of an isomer of xylenes in three stages: separation, isomerization in the presence of a catalyst based on an EUO zeolite and transalkylation
    9.
    发明授权
    Process for the production of an isomer of xylenes in three stages: separation, isomerization in the presence of a catalyst based on an EUO zeolite and transalkylation 有权
    在三阶段生产二甲苯异构体的方法：在基于EUO沸石和烷基转移反应的催化剂存在下进行分离，异构化

    公开(公告)号：US06528695B1

    公开(公告)日：2003-03-04

    申请号：US09598486

    申请日：2000-06-22

    申请人： Julia Magne-Drisch ,  Gérard Hotier ,  Jean-François Joly ,  Elisabeth Merlen ,  Fabio Alario

    发明人： Julia Magne-Drisch ,  Gérard Hotier ,  Jean-François Joly ,  Elisabeth Merlen ,  Fabio Alario

    IPC分类号： C07C1512

    CPC分类号： C07C15/08 ,  C07C5/2724 ,  C07C6/126 ,  C07C7/13 ,  C07C2529/18 ,  C07C2529/74 ,  Y02P20/52 ,  C07C15/067

    摘要： The invention relates to a process for the production of at least one isomer of xylenes, preferably paraxylene, as well as benzene, starting from a C8-aromatic fraction, whereby said process comprises a zone for separation of xylenes, a zone for isomerization of aromatic compounds with 8 carbon atoms used in the presence of a catalyst that comprises at least one EUO-structural-type zeolite that is selected from among the EU-1, TPZ-3, ZSM-50 zeolites and at least one metal of group VIII of the periodic table, and finally a transalkylation zone of C7- and C9-aromatic compounds. The invention makes it possible to produce paraxylene and benzene with a high yield, starting from a C8-aromatic fraction that comprises a large amount of ethylbenzene with improved performance levels of the isomerization stage and a good conversion of ethylbenzene in the transalkylation stage.

    摘要翻译： 本发明涉及从C8-芳族馏分开始生产二甲苯，优选对二甲苯以及苯的至少一种异构体的方法，其中所述方法包括用于分离二甲苯的区域，芳族异构化区 在催化剂存在下使用的具有8个碳原子的化合物，其包含至少一种选自EU-1，TPZ-3，ZSM-50沸石和至少一种VIII族金属的EUO结构型沸石 周期表，最后是C7-和C9-芳族化合物的烷基转移区。 本发明使得可以从包含大量乙苯的C8芳族馏分开始以高产率制备对二甲苯和苯，具有改进的异构化阶段的性能水平和乙烷在烷基转移反应阶段中的良好转化率。