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1.发明授权
公开(公告)号：US5877330A
公开(公告)日：1999-03-02
申请号：US776543
申请日：1997-01-29
IPC分类号： B01J23/22 , C07C5/48 , C07C45/36 , C07C67/40 , C07C253/24 , C07D307/77
摘要： Vanadium-containing catalysts are obtained by using polyvanadic acid as a source of vanadium. Vanadium-containing catalysts are obtained by mixing catalyst components other than vanadium, or their precursors, with a polyvanadic acid sol which is formed by ion-exchanging a metavanadic acid aqueous solution with a proton-type cation-exchange resin and performing polycondensation, and by drying and/or calcining the mixture. Such vanadium-containing catalysts can fully exhibit their catalytic activity under mild reaction conditions, and can be suitably used for various reactions, such as synthesis of phthalic anhydride by the partial oxidation of o-xylene, synthesis of benzaldehyde by the partial oxidation of toluene, synthesis of benzoic acid by the partial oxidation of toluene, synthesis of anisaldehyde by the partial oxidation of p-methoxy toluene, synthesis of propylene by the oxidative dehydrogenation of propane, synthesis of isobutene by the oxidative dehydrogenation of isobutane, synthesis of methyl formate by the oxidative dehydrogenation of methanol, and synthesis of acrylonitrile by the ammoxidation of propane.
摘要翻译： PCT No.PCT / JP96 / 01547 Sec。 371日期1997年1月29日 102（e）1997年1月29日PCT PCT 1996年6月7日PCT公布。 公开号WO96 / 41678 日期：1996年12月27日使用聚钒酸作为钒源可得到含钒催化剂。 含钒催化剂通过将除钒以外的催化剂组分或其前体与通过与质子型阳离子交换树脂离子交换偏钒酸水溶液并进行缩聚而形成的聚阴离子溶胶获得，并进行缩聚 干燥和/或煅烧该混合物。 这种含钒催化剂可以在温和的反应条件下充分发挥其催化活性，适用于各种反应，如通过邻二甲苯的部分氧化合成邻苯二甲酸酐，通过甲苯的部分氧化合成苯甲醛， 通过甲苯的部分氧化合成苯甲酸，通过对甲氧基甲苯的部分氧化合成茴香醛，通过丙烷的氧化脱氢合成丙烯，通过异丁烷的氧化脱氢合成异丁烯，通过甲酸甲酯合成甲酸甲酯 甲醇的氧化脱氢，丙烷的氨氧化合成丙烯腈。
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2.发明授权Lower alkane oxidative dehydrogenation catalysts and a process for producing olefins 失效低级烷烃氧化脱氢催化剂和烯烃生产方法公开(公告)号：US06756517B2
公开(公告)日：2004-06-29
申请号：US09895416
申请日：2001-07-02
IPC分类号： C07C5333
CPC分类号： C07C45/35 , B01J23/002 , B01J23/34 , B01J2523/00 , C07C5/48 , C07C45/33 , C07C45/34 , C07C51/252 , C07C2523/34 , Y02P20/52 , C07C11/02 , C07C47/22 , C07C57/04 , B01J2523/53 , B01J2523/72 , B01J2523/842 , B01J2523/51 , B01J2523/67 , B01J2523/56 , B01J2523/69 , B01J2523/17 , B01J2523/3712 , B01J2523/305 , B01J2523/12 , B01J2523/22 , B01J2523/62 , B01J2523/74 , B01J2523/55 , B01J2523/68 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/845
摘要： Lower alkenes of from 2 to 5 carbon atoms, such as propene, are produced by the vapor phase catalytic oxidative dehydrogenation of lower alkane, such as propane, using a mixed metal oxide catalyst of formula (1) as decribed, containing manganese and at least one additional metal as essential elements, e.g., Mn1Sb0.15Ox, Mn1P0.2Ox, Mn1S0.15W0.05Cr0.1Ox. The lower alkene may be further oxidatively dehydrogenated using a mixed metal oxide catalyst of formula (1), especially formula (2), as described, to produce a mixture of unsaturated aldehyde and unsaturated acid. The unsaturated aldehyde may be further oxidatively dehydrogenated in the vapor phase in the presence of mixed metal oxide catalyst of formula (1), especially formula (3).
摘要翻译： 通过低分子烷烃如丙烷的气相催化氧化脱氢，使用含有锰的至少一种式（1）的混合金属氧化物催化剂制备含2-5个碳原子的低级烯烃，如丙烯，至少 一种额外的金属作为必需元素，例如Mn1Sb0.15Ox，Mn1P0.2Ox，Mn1S0.15W0.05Cr0.1Ox。 可以使用如所述的式（1），特别是式（2）的混合金属氧化物催化剂进一步氧化降解烯烃，以产生不饱和醛和不饱和酸的混合物。 在式（1）的混合金属氧化物催化剂，特别是式（3）的存在下，不饱和醛可以在气相中进一步氧化脱氢。
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公开(公告)号：US06452021B1
公开(公告)日：2002-09-17
申请号：US09963402
申请日：2001-09-27
IPC分类号： C07D30777
CPC分类号： C07C51/235 , C07C63/307
摘要： The present invention has for its object to provide a production method of pyromellitic anhydride of high purity in good yield at low cost by catalytic gas-phase oxidation of a 2,4,5-trialkylbenzaldehyde with the aid of a suitable catalyst system. The present invention relates to a production method of pyromellitic anhydride comprising a step for catalytic gas-phase oxidation of a 2,4,5-trialkylbenzaldehyde with a molecular oxygen-containing gas in which said step for catalytic gas-phase oxidation is carried out in the presence of a catalyst such that a specific surface area of the catalytic active component thereof is not greater than 50 m2/g or in the presence of a catalyst containing vanadium as well as molybdenum and/or tungsten as a catalytic active component.
摘要翻译： 本发明的目的是通过合适的催化剂体系，通过2,4,5-三烷基苯甲醛的催化气相氧化，以低成本提供高纯度的均苯四酸酐的制备方法。 本发明涉及1,2,4,5-苯四酸酐的制备方法，其包括用含有分子氧的气体催化气相氧化2,4,5-三烷基苯甲醛的步骤，其中所述催化气相氧化步骤在存在下进行 的催化剂，使得其催化活性组分的比表面积不大于50m 2 / g，或者在含有钒的催化剂以及钼和/或钨作为催化活性组分的存在下。
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4.发明授权Method of catalyzing a gas phase reaction using an acid-base catalyst composed of vanadium pentoxide hydrate 失效使用由五氧化二钒水合物组成的酸碱催化剂催化气相反应的方法公开(公告)号：US06479710B2
公开(公告)日：2002-11-12
申请号：US09267396
申请日：1999-03-15
IPC分类号： C07C4100
CPC分类号： C01G31/02 , B01J23/22 , B01J23/8472 , B01J37/0018 , B01J37/033 , C01P2002/02 , C01P2002/20 , C01P2002/72 , C01P2002/78 , C01P2006/82
摘要： A solid acid-base catalyst contains vanadium pentoxide hydrate. Moreover, it is preferable that the vanadium pentoxide hydrate in the solid acid-base catalyst has a composition which is represented by the following general equation (1): V2O5.nH2O (1) (n: 0.1-3). Creation of the vanadium pentoxide hydrate was confirmed by measuring X-ray diffraction spectrum shown in FIG. 1. In accordance with the above arrangement, the solid acid-base catalyst can sufficiently display catalytic activity under mild conditions, and it can be suitably applied to various reactions, such as the syntheses of olefins or ethers through dehydration reactions of alcohols, the syntheses of aldehydes or ketones through dehydrogenation reactions of alcohols, hydrations and isomerization reactions of olefins, alkylations, esterifications, amidations, acetalizations, aminations, hydrogen shift reactions, aldol condensation reactions and polymerization reactions.
摘要翻译： 固体酸碱催化剂含有五氧化二钒水合物。 此外，固体酸 - 碱催化剂中的五氧化二钒水合物优选具有以下通式（1）表示的组成：（n：0.1-3）。五氧化二钒水合物的形成通过测定 图1所示的X射线衍射光谱。 根据上述配置，固体酸碱催化剂可以在温和条件下充分显示催化活性，可适用于各种反应，例如通过醇的脱水反应合成烯烃或醚，合成 通过醇的脱氢反应，烯烃的水合和异构化反应，烷基化，酯化，酰胺化，缩醛化，胺化，氢转移反应，醛醇缩合反应和聚合反应。
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5.发明授权公开(公告)号：US06281378B1
公开(公告)日：2001-08-28
申请号：US09586777
申请日：2000-06-05
IPC分类号： C07C25500
CPC分类号： C07C5/48 , B01J23/22 , C07C45/36 , C07C67/40 , C07C253/24 , C07C253/28 , Y02P20/52 , C07C47/575 , C07C47/54 , C07C69/06 , C07C255/50 , C07C255/08
摘要： Vanadium-containing catalysts are obtained by using polyvanadic acid as a source of vanadium. Vanadium-containing catalysts are obtained by mixing catalyst components other than vanadium, or their precursors, with a polyvanadic acid sol which is formed by ion-exchanging a metavanadic acid aqueous solution with a proton-type cation-exchange resin and performing polycondensation, and by drying and/or calcining the mixture. Such vanadium-containing catalysts can fully exhibit their catalytic activity under mild reaction conditions, and can be suitably used for various reactions, such as synthesis of phthalic anhydride by the partial oxidation of o-xylene, synthesis of benzaldehyde by the partial oxidation of toluene, synthesis of benzoic acid by the partial oxidation of toluene, synthesis of anisaldehyde by the partial oxidation of p-methoxy toluene, synthesis of propylene by the oxidative dehydrogenation of propane, synthesis of isobutene by the oxidative dehydrogenation of isobutane, synthesis of methyl formate by the oxidative dehydrogenation of methanol, and synthesis of acrylonitrile by the ammoxidation of propane.
摘要翻译： 通过使用聚阴离子作为钒源，得到含钒催化剂。 含钒催化剂通过将除钒以外的催化剂组分或其前体与通过与质子型阳离子交换树脂离子交换偏钒酸水溶液并进行缩聚而形成的聚阴离子溶胶获得，并进行缩聚 干燥和/或煅烧该混合物。 这种含钒催化剂可以在温和的反应条件下充分发挥其催化活性，适用于各种反应，如通过邻二甲苯的部分氧化合成邻苯二甲酸酐，通过甲苯的部分氧化合成苯甲醛， 通过甲苯的部分氧化合成苯甲酸，通过对甲氧基甲苯的部分氧化合成茴香醛，通过丙烷的氧化脱氢合成丙烯，通过异丁烷的氧化脱氢合成异丁烯，通过甲酸甲酯合成甲酸甲酯 甲醇的氧化脱氢，丙烷的氨氧化合成丙烯腈。
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6.发明授权Lower alkane oxidative dehydrogenation catalysts and a process for producing olefins 有权低级烷烃氧化脱氢催化剂和烯烃生产方法公开(公告)号：US06239325B1
公开(公告)日：2001-05-29
申请号：US09313658
申请日：1999-05-18
IPC分类号： C07C532
CPC分类号： B01J23/8885 , B01J23/30 , B01J23/888 , C07C5/48 , C07C2523/12 , C07C2523/18 , C07C2523/30 , C07C2523/31 , C07C11/02
摘要： The invention provides process for oxidative dehydrogenation of lower alkanes, by vapor phase oxidative dehydrogenation of C2-C5 lower alkanes in the presence of a catalyst and molecular oxygen to produce the corresponding olefins, in which the catalyst has a composition expressed by a general formula (1) below: A&agr;Sb&bgr;W&ggr;D&dgr;Ox (1) in which A is at least one metal selected from the group consisting of molybdenum and chromium; Sb is antimony; W is tungsten; O is oxygen; and D is at least one metal selected from the group consisting of V, Nb, Ta, Fe, Co, Ni, Cu, Ag, Zn, B, Tl, Sn, Pb, Te, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, La, Ce and Sm; &agr;, &bgr;, &ggr;, &dgr; and x denote atomic numbers of A, Sb, W, D and O, respectively, where when &agr;=1, &bgr;=0.5-10, &ggr;=0.1-10 and &dgr;=0-3; and x is a numerical value determined by the state of oxidation of those elements other than oxygen. When these catalysts are used in reactions for oxidizing and dehydrogenating C2-C5 alkanes with molecular oxygen in vapor phase, corresponding olefins can be produced at high yield.
摘要翻译： 本发明提供了在催化剂和分子氧的存在下，通过C2-C5低级烷烃的气相氧化脱氢制备低级烷烃的方法，以产生相应的烯烃，其中催化剂具有由通式（ 1）：其中A是选自钼和铬中的至少一种金属; 锑是锑; W是钨; O是氧; 并且D是选自V，Nb，Ta，Fe，Co，Ni，Cu，Ag，Zn，B，Tl，Sn，Pb，Te，Li，Na，K，Rb，Cs中的至少一种金属 ，Mg，Ca，Sr，Ba，La，Ce和Sm; α，β，γ，δ和x分别表示A，Sb，W，D和O的原子序数，其中α= 1，β= 0.5-10，γ= 0.1-10和δ= 0-3; x是由氧以外的元素的氧化状态确定的数值。当这些催化剂用于在气相中用分子氧氧化和脱氢C2-C5烷烃的反应中时，可以高产率生产相应的烯烃。
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公开(公告)号：US07683220B2
公开(公告)日：2010-03-23
申请号：US12225823
申请日：2007-03-27
IPC分类号： C07C45/32
CPC分类号： B01J27/182 , B01J21/08 , B01J27/16 , B01J27/1806 , B01J27/187 , B01J35/002 , B01J37/0201 , B01J37/03 , C07C45/52 , C07C47/22
摘要： There is provided a process for producing acrolein from glycerin, exhibiting a suppressed decrease in the yield of acrolein with time. In the process for producing acrolein by dehydrating glycerin in the presence of a catalyst containing a metal phosphate, one, or two or more, metal phosphates are used, which are selected from aluminum salts, zirconium salts, manganese salts, alkali metal salts (provided that the alkali metal is sodium, potassium, or cesium, and the ratio between the mole number (M) of the alkali metal and the mole number (P) of phosphoric acid (i.e., M/P ratio) in the metal phosphate is 2.0 or lower), alkali earth metal salts (provided that the ratio between the mole number (M) of the alkali earth metal and the mole number (P) of phosphoric acid (i.e., M/P ratio) in the metal phosphate is 1.0 or lower), and the like.
摘要翻译： 提供了一种从甘油制备丙烯醛的方法，随着时间的推移，丙烯醛的收率下降。 在含有金属磷酸盐，一种或两种以上的催化剂存在下，通过脱水甘油来制备丙烯醛的方法中，使用选自铝盐，锆盐，锰盐，碱金属盐的金属磷酸盐（提供 碱金属是钠，钾或铯，碱金属的摩尔数（M）与磷酸的摩尔数（P）之比（M / P比）在金属磷酸盐中的比例为2.0 或更低）碱土金属盐（条件是金属磷酸盐中碱土金属的摩尔数（M）与磷酸的摩尔数（P）之比（即M / P比）之比为1.0或 较低）等。
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8.发明申请PROCESS FOR PRODUCING ACRYLIC ACID, APPARATUS FOR PRODUCING ACRYLIC ACID, AND COMPOSITION FOR PRODUCING ACRYLIC ACID 审中-公开用于制备丙烯酸的方法，用于生产丙烯酸的装置和用于生产丙烯酸的组合物公开(公告)号：US20100069583A1
公开(公告)日：2010-03-18
申请号：US12312202
申请日：2007-09-20
CPC分类号： C07C45/82 , C07C45/52 , C07C51/252 , C07C47/22 , C07C57/04
摘要： There are provided a process, an apparatus, and an acrolein-containing composition, for producing acrylic acid from the acrolein-containing composition at a high yield. The process for producing acrylic acid includes a refinement step of removing phenol and/or 1-hydroxyacetone from an acrolein-containing composition and an oxidation step of oxidizing acrolein in the acrolein-containing composition after the refinement step to produce acrylic acid, and the apparatus to be used in the process includes a refiner to be used in the refinement step and an oxidation reactor for oxidizing acrolein to produce acrylic acid. The acrolein-containing composition is a composition having a (mass of phenol)/(mass of acrolein) ratio of 0.020 or lower and a (mass of 1-hydroxyacetone)/(mass of acrolein) ratio of 0.020 or lower.
摘要翻译： 提供了一种用于以高产率从含丙烯醛的组合物制备丙烯酸的方法，装置和含丙烯醛的组合物。 制备丙烯酸的方法包括从含丙烯醛的组合物中除去苯酚和/或1-羟基丙酮的精制步骤和在精制步骤之后在含丙烯醛的组合物中氧化丙烯醛以生产丙烯酸的氧化步骤，并且该装置 在该方法中使用的方法包括在精制步骤中使用的精制机和用于氧化丙烯醛以产生丙烯酸的氧化反应器。 含丙烯醛的组合物是具有（质量的苯酚）/（丙烯醛的质量）比为0.020以下和（质量的1-羟基丙酮）/（丙烯醛的质量）比为0.020以下的组合物。
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公开(公告)号：US20100010260A1
公开(公告)日：2010-01-14
申请号：US12312801
申请日：2007-11-28
IPC分类号： C07C51/16
CPC分类号： C07C51/23 , C07C51/235 , C07C51/377 , C07C57/04
摘要： The present invention provides a process for producing acrylic acid from glycerin with a catalyst having a prolonged life. In the process for producing acrylic acid from glycerin, a molar ratio of oxygen to glycerin in a raw material gas is set to be not lower than 0.8 and not higher than 20.
摘要翻译： 本发明提供了一种由具有延长使用寿命的催化剂由甘油生产丙烯酸的方法。 在由甘油生产丙烯酸的方法中，将原料气体中的氧与甘油的摩尔比设定为不低于0.8且不高于20。
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公开(公告)号：US08076509B2
公开(公告)日：2011-12-13
申请号：US12312801
申请日：2007-11-28
IPC分类号： C07C51/16
CPC分类号： C07C51/23 , C07C51/235 , C07C51/377 , C07C57/04
摘要： The present invention provides a process for producing acrylic acid from glycerin with a catalyst having a prolonged life. In the process for producing acrylic acid from glycerin, a molar ratio of oxygen to glycerin in a raw material gas is set to be not lower than 0.8 and not higher than 20.
摘要翻译： 本发明提供了一种由具有延长使用寿命的催化剂由甘油生产丙烯酸的方法。 在由甘油生产丙烯酸的方法中，将原料气体中的氧与甘油的摩尔比设定为不低于0.8且不高于20。
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