摘要:
A process for the manufacture of ethylene polymers by homopolymerization and copolymerization of ethylene at pressures of from 500 to 5,000 bars and at from 50.degree. to 450.degree. C, with subsequent isolation of the polymers in high pressure product isolation zones and low pressure product isolation zones. The various parallel product isolation zones are at different temperatures, and the mean product residence times in the zones may be identical or different. Very different products, in amounts which can be chosen according to requirements, and with mutually independent polymer properties, can be obtained using only one high pressure polymerization system.
摘要:
Production of a homogeneous mixture of plastics materials in powder form by subjecting a molten inhomogeneous mixture of two or more plastics to a maximum shear velocity of from 10.sup.4 to 10.sup.8 sec.sup.-.sup.1 for from 10.sup..sup.-2 to 10.sup..sup.-6 seconds; the pulverulent mixtures obtained are used in rotary sintering and injection molding.
摘要:
A process for the manufacture of ethylene polymers by high pressure polymerization of ethylene, if desired mixed with other compounds copolymerizable with ethylene, and isolation of the reaction product in a multi-stage isolation zone. The molecular weight of the ethylene polymer can be varied by varying the temperature prevailing in the isolation zone. The isolation zone preferably consists of two stages, with a higher pressure prevailing in the first stage than in the second stage.
摘要:
Disclosed are citric acid fatty alcohol ester polyglycol ether sulfosuccinates of the general formula (1) ##STR1## and personal care products containing them, in which each R is the same or different and is H or -CH.sub.3 ; ##STR2## R.sup.2 is selected from the group consisting of ##STR3## acyl radicals having 8-22 carbon atoms, which radicals are optionally substituted and optionally contain one or more multiple bonds;R.sup.3 is an alkyl or acyl radical having 8-22 carbon atoms, which is optionally substituted and optionally contains multiple bonds;a and b, which are identical or different, are each 0-5, provided that the sum of (a+b) is at least 1;c is 0-15; andX.sup.+ is in each occurrence H.sup.+ or a cation.
摘要:
A process for the manufacture of ethylene polymers by high pressure polymerization of ethylene, if desired mixed with other compounds copolymerizable with ethylene, and isolation of the reaction product in a multi-stage isolation zone. The molecular weight of the ethylene polymer can be varied by varying the mean product residence time in the isolation zone. The isolation zone preferably consists of two stages, with a higher pressure prevailing in the first stage than in the second stage.
摘要:
Ethylene polymers are manufactured in a tubular reactor under high pressure and at high temperatures in the presence of polymerization initiators. The polymerization is carried out in two different zones of the reactor, a mixture of ethylene, oxygen and regulator being fed into the first zone and a co-initiator having a half-life temperature, measured in benzene, of above 140.degree. C being additionally fed into the second zone. The co-initiator may be a peroxide or a hydroperoxide. The melt index, or the haze and gloss of a film produced from the resulting ethylene polymer, can be varied advantageously through the choice of the co-initiator.
摘要:
Process for the manufacture of graft polymers from copolymers of ethylene with vinyl esters, acrylates or methacrylates by grafting an ethylenically unsaturated carboxylic acid thereto in the presence of a free-radical polymerization initiator. Homogeneous graft copolymers are obtained from which sheeting can be made. To this end, the unsaturated carboxylic acid is first caused to diffuse into the copolymer and the mixture is then extruded at temperatures above the crystallite melting point of the ethylene copolymer.
摘要:
Unsaturated carboxylic acids are grafted onto copolymers of ethylene and carboxylates. Carboxylic acid containing initiator is caused to diffuse into shaped elements of the copolymers, polymerization then being carried to completion by heating. The products exhibit no fish eyes and are highly suitable for sheet manufacture.
摘要:
Ethylene polymers are manufactured by polymerizing ethylene under high pressure at high temperatures in an autoclave reactor. The heat of reaction generated by the polymerization is removed, within the reactor, by a cooling system in which the cooling medium is ethylene; the pressure of the monomer in the cooling system should differ by from 0 to 200 bars from the pressure prevailing in the polymerization system, and the temperature of the monomer on entering the cooling system is at least 40.degree. C. lower than the temperature prevailing in the autoclave. The process permits an increase in the conversion achieved in the polymerization reaction.
摘要:
Ethylene polymers are produced at pressures between 1000 and 4000 atmospheres and temperatures of from 120.degree. to 300.degree. C in a reaction zone having an 1/d ratio of from 10:1 to 20:1 while shear forces act on the reaction mixture. The ethylene is fed continuously and radially to the reaction zone at a velocity of from 2 to 20 m/sec. The average residence time of the reaction mixture in the reaction zone is from 20 to 90 seconds. The products show a broad molecular weight distribution and are particularly advantageous for use as extruded coatings.