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公开(公告)号：US07858058B2
公开(公告)日：2010-12-28
申请号：US11666000
申请日：2005-10-18
申请人： Gerrald Bargeman , René Lodewijk Maria Demmer , Boris Kuzmanovic , Cornelis Elizabeth Johannus Van Lare , Mateo Jozef Jacques Mayer , Maarten André Irène Schutyser , Jan Barend Westerink
发明人： Gerrald Bargeman , René Lodewijk Maria Demmer , Boris Kuzmanovic , Cornelis Elizabeth Johannus Van Lare , Mateo Jozef Jacques Mayer , Maarten André Irène Schutyser , Jan Barend Westerink
IPC分类号： B01D61/00
CPC分类号： C01D3/14 , C01D3/16 , C01D5/00 , C01D7/00 , C02F1/44 , C02F1/442 , C02F1/52 , C02F1/66 , C02F9/00 , C02F2001/5218 , C02F2101/10 , C02F2101/16 , C02F2103/08 , Y02A20/131
摘要： The invention pertains to removing soluble alkali metal or ammonium salt of a divalent anion from brine comprising following steps: obtaining brine with NaCl-concentration between 150g/L and saturation in the presence or absense of a cyrstal growth inhibitor for NaCl(GCI-NaCl),or with NaCl concentration above saturation in the presence of a CGI-NaCl, said brine optionally comprising a crystal growth inhibitor for the alkali metal or ammonium salt of the divalent anion(CGI-DA); if necessary, acidify the solution to pH
摘要翻译： 本发明涉及从盐水中除去二价阴离子的可溶性碱金属盐或铵盐，包括以下步骤：在NaCl（GCI-NaCl）的硅藻土生长抑制剂的存在或不存在下，获得NaCl浓度在150g / L之间的饱和盐水， 或者在CGI-NaCl存在下NaCl浓度高于饱和，所述盐水任选地包含用于二价阴离子（CGI-DA）的碱金属或铵盐的晶体生长抑制剂; 如果需要，将溶液酸化至pH <11.5; 如果CGI-DA的浓度小于20mg / L，则加入CGI-DA获得至少20mg的CGI-DA / L; 对溶液进行膜过滤; 如果分离浓度的CGI-DA浓度小于20mg / L，则加入CGI-DA获得至少20mg CGI-DA / L; 结晶浓度; 除去二价阴离子的结晶的碱金属盐或铵盐。
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公开(公告)号：US20080169202A1
公开(公告)日：2008-07-17
申请号：US11884564
申请日：2006-02-13
申请人： Gerrald Bargeman , Rene Lodewijk Maria Demmer , Antoon Ten Kate , Boris Kuzmanovic , Cornelis Elizabeth Johannus Van Lare , Mateo Jozef Jacques Mayer , Maarten Andre Irene Schutyser , Jan Barend Westerink
发明人： Gerrald Bargeman , Rene Lodewijk Maria Demmer , Antoon Ten Kate , Boris Kuzmanovic , Cornelis Elizabeth Johannus Van Lare , Mateo Jozef Jacques Mayer , Maarten Andre Irene Schutyser , Jan Barend Westerink
IPC分类号： C25B1/26
CPC分类号： C01D3/14 , B01D61/027 , B01D61/04 , B01D2311/04 , B01D2311/06 , B01D2311/12 , B01D2311/25 , B01D2311/2684 , C01B7/03 , C01B11/14 , C25B1/26 , C25B1/265 , C25B15/08
摘要： The present invention relates to process to prepare a chlorine-containing compound using an aqueous salt solution containing at least 100 g/l of sodium chloride and a contaminating amount of polyvalent cations comprising the steps of (i) preparing an aqueous salt solution containing at least 100 g/l of sodium chloride and at least 0.01 ppm of polyvalent cations by dissolving a sodium chloride source in water, (ii) adding an effective amount of at least one positive retention enhancing component to the aqueous solution, (iii) subsequently subjecting the solution to a nanofiltration step, thereby separating the solution into a retentate which is enriched for polyvalent cations and a permeate which is the purified aqueous salt solution, (iv) reacting the chloride anions in the permeate to a chlorine- containing compound by an electrolysis step, and (v) recycling at least part of the retentate to dissolution step (i).
摘要翻译： 本发明涉及使用含有至少100g / l氯化钠和污染量的多价阳离子的盐水溶液制备含氯化合物的方法，包括以下步骤：（i）制备至少含有盐水溶液 通过将氯化钠源溶解在水中，将100g / l氯化钠和至少0.01ppm的多价阳离子，（ii）向该水溶液中加入有效量的至少一种阳性凝固促进组分，（iii） 溶液，从而将溶液分离成富含多价阳离子的保留物和作为纯化的盐水溶液的渗透物，（iv）通过电解步骤使渗透物中的氯阴离子与含氯化合物反应 ，和（v）将至少部分滞留物再循环到溶解步骤（i）中。
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公开(公告)号：US08038884B2
公开(公告)日：2011-10-18
申请号：US11884564
申请日：2006-02-13
申请人： Gerrald Bargeman , René Lodewijk Maria Demmer , Antoon Ten Kate , Boris Kuzmanovic , Cornelis Elizabeth Johannus Van Lare , Mateo Jozef Jacques Mayer , Maarten André Irène Schutyser , Jan Barend Westerink
发明人： Gerrald Bargeman , René Lodewijk Maria Demmer , Antoon Ten Kate , Boris Kuzmanovic , Cornelis Elizabeth Johannus Van Lare , Mateo Jozef Jacques Mayer , Maarten André Irène Schutyser , Jan Barend Westerink
CPC分类号： C01D3/14 , B01D61/027 , B01D61/04 , B01D2311/04 , B01D2311/06 , B01D2311/12 , B01D2311/25 , B01D2311/2684 , C01B7/03 , C01B11/14 , C25B1/26 , C25B1/265 , C25B15/08
摘要： The present invention relates to process to prepare a chlorine-containing compound using an aqueous salt solution containing at least 100 g/l of sodium chloride and a contaminating amount of polyvalent cations comprising the steps of (i) preparing an aqueous salt solution containing at least 100 g/l of sodium chloride and at least 0.01 ppm of polyvalent cations by dissolving a sodium chloride source in water, (ii) adding an effective amount of at least one positive retention enhancing component to the aqueous solution, (iii) subsequently subjecting the solution to a nanofiltration step, thereby separating the solution into a retentate which is enriched for polyvalent cations and a permeate which is the purified aqueous salt solution, (iv) reacting the chloride anions in the permeate to a chlorine-containing compound by an electrolysis step, and (v) recycling at least part of the retentate to dissolution step (i).
摘要翻译： 本发明涉及使用含有至少100g / l氯化钠和污染量的多价阳离子的盐水溶液制备含氯化合物的方法，包括以下步骤：（i）制备至少含有盐水溶液 通过将氯化钠源溶解在水中，将100g / l氯化钠和至少0.01ppm的多价阳离子，（ii）向该水溶液中加入有效量的至少一种阳性凝固促进组分，（iii） 溶液，从而将溶液分离成富含多价阳离子的保留物和作为纯化的盐水溶液的渗透物，（iv）通过电解步骤使渗透物中的氯阴离子与含氯化合物反应 ，和（v）将至少部分滞留物再循环到溶解步骤（i）中。
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公开(公告)号：US20060182808A1
公开(公告)日：2006-08-17
申请号：US10553211
申请日：2004-04-28
申请人： Wridzer Bakker , Robert Geertman , Marianne Reedijk , Jozef Baltussen , Gerrald Bargeman , Cornelis Van Lare
发明人： Wridzer Bakker , Robert Geertman , Marianne Reedijk , Jozef Baltussen , Gerrald Bargeman , Cornelis Van Lare
CPC分类号： B01D9/0063 , A61K9/14 , A61K9/1688 , A61K31/57 , B01D9/005 , C01D3/24 , C07J1/00 , C07J7/0005 , C07J7/0045
摘要： The present invention relates to a antisolvent solidification process wherein a liquid medium comprising at least one organic or inorganic compound which is to be solidified is forced through a membrane into one or more antisolvents, or wherein one or more antisolvents are forced through a membrane into a liquid medium comprising at least one organic or inorganic compound which is to be solidified, yielding a composition comprising solid particles comprising said organic and/or inorganic compound(s).
摘要翻译： 本发明涉及一种抗溶剂固化方法，其中包含至少一种待固化的有机或无机化合物的液体介质被迫通过膜进入一种或多种抗溶剂，或其中一种或多种抗溶剂被迫通过膜进入 包含至少一种待固化的有机或无机化合物的液体介质，产生包含所述有机和/或无机化合物的固体颗粒的组合物。
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公开(公告)号：US20050061149A1
公开(公告)日：2005-03-24
申请号：US10508970
申请日：2003-03-25
IPC分类号： B01D53/56 , B01D53/60 , B01D53/64 , B01D53/73 , B01D53/77 , B01D53/84 , B01D61/02 , B01D61/14 , B01D71/34 , B01D71/42 , B01D71/68 , B01D53/14
CPC分类号： B01D53/60 , B01D53/56 , B01D53/73 , B01D53/84 , B01D2251/90 , Y02A50/2344 , Y02A50/2358
摘要： The invention pertains to a method and an apparatus for removing a nitrogen oxide (NOx) from a gas by bringing the gas into contact with a scrub liquid in a scrubber for converting the nitrogen oxide into molecular nitrogen (N2), wherein the scrub liquid comprises a metal ion chelate and a biomass, after which at least a portion of the scrub liquid is subjected to a membrane separation process for separating at least part of the metal ion chelate, and the biomass and other solidified components, from dissolved components, wherein the membrane separation process comprises: a) filtering at least a portion of the scrub liquid using a first membrane capable of permeating the metal ion chelate to provide a first retentate liquid comprising the biomass and other solidified components, and a first permeate liquid comprising at least part of the metal ion chelate and dissolved components, and b) nanofiltering the first permeate liquid to give a second retentate liquid comprising the metal ion chelate and a second permeate liquid comprising dissolved components, and c) recycling at least part of the second retentate liquid to the scrubber.
摘要翻译： 本发明涉及一种通过使气体与洗涤器中的洗涤液接触以将氮氧化物转化为分子氮（N 2）而从气体中除去氮氧化物（NOx）的方法和装置，其中洗涤液包含 金属离子螯合物和生物质，之后至少部分洗涤液经受膜分离过程，用于从溶解的组分分离至少部分金属离子螯合物和生物质等固化组分，其中， 膜分离方法包括：a）使用能够渗透金属离子螯合物的第一膜过滤至少一部分洗涤液，以提供包含生物质和其它固化组分的第一渗余液，以及包含至少部分 的金属离子螯合物和溶解的组分，以及b）对第一渗透液进行纳滤，得到包含金属离子的第二滞留液 螯合物和包含溶解组分的第二渗透液体，和c）将至少部分第二滞留物液体再循环至洗涤器。
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6.发明授权Process for separating monochloroacetic acid and dichloroacetic acid via extractive distillation 有权通过萃取蒸馏分离一氯乙酸和二氯乙酸的方法公开(公告)号：US09073848B2
公开(公告)日：2015-07-07
申请号：US14126270
申请日：2012-03-13
申请人： Mark Theodorus Gerardus Jongmans , Johannes Josef Pragt , Gerrald Bargeman , Boelo Schuur , Jacobus Theodorus Josef Aaldering , André Banier De Haan , Melle Rinze Nieuwhof , Paul Verwer , Anton Alexandru Kiss , Antoon Jacob Berend Ten Kate , Cornelis Johannes Govardus Van Strien
发明人： Mark Theodorus Gerardus Jongmans , Johannes Josef Pragt , Gerrald Bargeman , Boelo Schuur , Jacobus Theodorus Josef Aaldering , André Banier De Haan , Melle Rinze Nieuwhof , Paul Verwer , Anton Alexandru Kiss , Antoon Jacob Berend Ten Kate , Cornelis Johannes Govardus Van Strien
摘要： The present invention pertains to a process for separating monochloroacetic acid and dichloroacetic acid from one another via extractive distillation, comprising the steps of (i) contacting a mixture comprising monochloroacetic acid and dichloroacetic acid with an extractive agent which is chemically stable and which has a BF3 affinity of between 65 kJ/mole and 110 kJ/mole, (ii) distilling the mixture to obtain a monochloroacetic acid stream and a stream comprising dichloroacetic acid and the extractive agent, and (iii) regenerating the extractive agent.
摘要翻译： 本发明涉及通过萃取蒸馏将一氯乙酸和二氯乙酸彼此分离的方法，包括以下步骤：（i）使包含一氯乙酸和二氯乙酸的混合物与化学稳定的萃取剂接触，并具有BF 3 65kJ / mol和110kJ /摩尔之间的亲和力，（ii）蒸馏混合物以获得一氯乙酸流和包含二氯乙酸和萃取剂的流，和（iii）再生提取剂。
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公开(公告)号：US20080056981A1
公开(公告)日：2008-03-06
申请号：US11666000
申请日：2005-10-18
申请人： Gerrald Bargeman , Rene Demmer , Boris Kuzmanovic , Cornelis Van Lare , Mateo Mayer , Maarten Schutyser , Jan Westerink
发明人： Gerrald Bargeman , Rene Demmer , Boris Kuzmanovic , Cornelis Van Lare , Mateo Mayer , Maarten Schutyser , Jan Westerink
IPC分类号： C01D3/06
CPC分类号： C01D3/14 , C01D3/16 , C01D5/00 , C01D7/00 , C02F1/44 , C02F1/442 , C02F1/52 , C02F1/66 , C02F9/00 , C02F2001/5218 , C02F2101/10 , C02F2101/16 , C02F2103/08 , Y02A20/131
摘要： The invention pertains to a method for at least partially removing soluble divalent anions from an aqueous divalent anion-containing brine solution comprising a crystal growth inhibitor (CGI) for the divalent anion, the method comprising the process steps: obtaining a sodium chloride concentration between 100 g/L and saturation in the presence or absence of a CGI for sodium chloride or a sodium chloride concentration above saturation in the presence of a CGI for sodium chloride, and acidifying the solution to a pH below 11.5; subjecting the solution to a membrane filtration step thereby separating the brine solution into a brine stream being supersaturated for the divalent anion (concentrate), and a brine stream being undersaturated for the divalent anion (permeate); subjecting the supersaturated brine stream comprising the crystal growth inhibitor for the divalent anion to a crystallization process, removing crystallized divalent anion; and optionally, recycling the overflow of the crystallizer to the brine solution for subjecting it again to the membrane filtration step.
摘要翻译： 本发明涉及从含二价阴离子的含水二价阴离子盐水溶液中至少部分除去可溶性二价阴离子的方法，该方法包括二价阴离子的结晶生长抑制剂（CGI），该方法包括以下步骤：获得100 在存在或不存在用于氯化钠的CGI或在氯化钠的CGI存在下高于饱和的氯化钠浓度的情况下的饱和度，并将溶液酸化至低于11.5的pH; 使溶液进行膜过滤步骤，从而将盐水溶液分离成用于二价阴离子（浓缩物）过饱和的盐水流，并且对于二价阴离子（渗透物）不饱和的盐水流; 将包含结晶生长抑制剂的过饱和盐水流作为二价阴离子进行结晶处理，除去结晶二价阴离子; 并且可选地，将结晶器的溢流器再循环到盐水溶液中，以再次使其进行膜过滤步骤。
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公开(公告)号：US20120232296A1
公开(公告)日：2012-09-13
申请号：US13481088
申请日：2012-05-25
申请人： Wridzer Jan Willem BAKKER , Robert Michael GEERTMAN , Marjanne Frederika REEDIJK , Jozef Johannes Maria BALTUSSEN , Gerrald BARGEMAN , Cornelis Elizabeth Johannus VAN LARE
发明人： Wridzer Jan Willem BAKKER , Robert Michael GEERTMAN , Marjanne Frederika REEDIJK , Jozef Johannes Maria BALTUSSEN , Gerrald BARGEMAN , Cornelis Elizabeth Johannus VAN LARE
CPC分类号： B01D9/0063 , A61K9/14 , A61K9/1688 , A61K31/57 , B01D9/005 , C01D3/24 , C07J1/00 , C07J7/0005 , C07J7/0045
摘要： The present invention relates to a antisolvent solidification process wherein a liquid medium comprising at least one organic or inorganic compound which is to be solidified is forced through a membrane into one or more antisolvents, or wherein one or more antisolvents are forced through a membrane into a liquid medium comprising at least one organic or inorganic compound which is to be solidified, yielding a composition comprising solid particles comprising said organic and/or inorganic compound(s).
摘要翻译： 本发明涉及一种抗溶剂固化方法，其中包含至少一种待固化的有机或无机化合物的液体介质被迫通过膜进入一种或多种抗溶剂，或其中一种或多种抗溶剂被迫通过膜进入 包含至少一种待固化的有机或无机化合物的液体介质，产生包含所述有机和/或无机化合物的固体颗粒的组合物。
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公开(公告)号：US20080185340A1
公开(公告)日：2008-08-07
申请号：US11884189
申请日：2006-02-13
申请人： Gerrald Bargeman , Rene Lodewijk Maria Demmer , Antoon Ten Kate , Boris Kuzmanovic , Cornelis Elizabeth Johannus Van Lare , Mateo Jozef Jacques Mayer , Maarten Andre Irene Schutyser , Jan Barend Westerink
发明人： Gerrald Bargeman , Rene Lodewijk Maria Demmer , Antoon Ten Kate , Boris Kuzmanovic , Cornelis Elizabeth Johannus Van Lare , Mateo Jozef Jacques Mayer , Maarten Andre Irene Schutyser , Jan Barend Westerink
摘要： The present invention relates to a process to prepare salt comprising the following steps: (i) preparing an aqueous salt solution containing at least 100 g/l of sodium chloride and at least 0.01 ppm of polyvalent cations by dissolving a sodium chloride source in industrial water, (ii) adding an effective amount of at least one positive retention enhancing component to the aqueous salt solution, (iii) subsequently subjecting the solution to a nanofiltration step, thereby separating the solution into a retentate which is enriched for the polyvalent cations and a permeate which is the purified aqueous salt solution, and (iv) concentrating the permeate to produce salt.
摘要翻译： 本发明涉及一种制备盐的方法，包括以下步骤：（i）通过将氯化钠源溶解在工业水中制备含有至少100g / l氯化钠和至少0.01ppm多价阳离子的盐水溶液 ，（ii）向所述盐水溶液中加入有效量的至少一种阳性滞留增强组分，（iii）随后使所述溶液经受纳滤过程，从而将所述溶液分离成富含多价阳离子的滞留物和 渗透物，其是纯化的盐水溶液，和（iv）浓缩渗透物以产生盐。
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公开(公告)号：US07405069B2
公开(公告)日：2008-07-29
申请号：US10508970
申请日：2003-03-25
IPC分类号： A61L9/01
CPC分类号： B01D53/60 , B01D53/56 , B01D53/73 , B01D53/84 , B01D2251/90 , Y02A50/2344 , Y02A50/2358
摘要： The invention pertains to a method and an apparatus for removing a nitrogen oxide (NOx) from a gas by bringing the gas into contact with a scrub liquid in a scrubber for converting the nitrogen oxide into molecular nitrogen (N2), wherein the scrub liquid comprises a metal ion chelate and a biomass, after which at least a portion of the scrub liquid is subjected to a membrane separation process for separating at least part of the metal ion chelate, and the biomass and other solidified components, from dissolved components, wherein the membrane separation process comprises: a) filtering at least a portion of the scrub liquid using a first membrane capable of permeating the metal ion chelate to provide a first retentate liquid comprising the biomass and other solidified components, and a first permeate liquid comprising at least part of the metal ion chelate and dissolved components, and b) nanofiltering the first permeate liquid to give a second retentate liquid comprising the metal ion chelate and a second permeate liquid comprising dissolved components, and c) recycling at least part of the second retentate liquid to the scrubber.
摘要翻译： 本发明涉及一种通过使气体与洗涤器中的洗涤液接触以将氮氧化物转化为分子氮而从气体中除去氮氧化物（NO x）的方法和装置（ N 2），其中所述洗涤液包含金属离子螯合物和生物质，然后将所述洗涤液的至少一部分进行膜分离过程以分离至少部分所述金属离子 螯合物和生物质和其它固化的组分，其中所述膜分离方法包括：a）使用能够渗透所述金属离子螯合物的第一膜过滤至少一部分所述洗涤液，以提供第一滞留物液体，其包含 生物质和其它固化组分，以及包含至少部分金属离子螯合物和溶解组分的第一渗透液，以及b）对第一渗透液进行纳滤，得到第二滞留液体com 赋予金属离子螯合物和包含溶解组分的第二渗透液，以及c）将至少部分第二滞留物液体再循环到洗涤器。
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