公开(公告)号：US08247358B2

公开(公告)日：2012-08-21

申请号：US12587039

申请日：2009-10-01

Applicant: Gordon H. Lee ,  Kevin A. Chinn

Inventor： Gordon H. Lee ,  Kevin A. Chinn

IPC: C10M111/04 ,  C10G71/00

CPC classification number: C10M111/04 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2205/0285 ,  C10M2205/173 ,  C10M2207/2825 ,  C10M2229/02 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/024 ,  C10N2230/02 ,  C10N2230/68 ,  C10N2230/74 ,  C10N2240/04

Abstract: The invention relates to oil compositions containing metallocene catalyzed high viscosity index polyalphaolefins (HVI-PAO). In one embodiment the oil formulation comprises a metallocene catalyzed HVI-PAO with a viscosity greater than 125 cSt kv 100° C. and a viscosity index greater than 100, a second base stock with a viscosity of at least 2 cSt kv 100° C. and less than 60 cSt kv 100° C. wherein the second base stock is at least 60 cSt kv 100° C. less than the metallocene HVI-PAO, an ester with a viscosity of at least 2 and less than 6, the ester comprising more than 10 weight percent and less than 30 weight percent of the oil formulation, the oil formulation having a viscosity index of greater than 195. The use of metallocene catalyzed HVI-PAOs in a bimodal blend provides advantages in improved shear stability, and other properties related to shear stability.

Abstract translation: 本发明涉及含有茂金属催化的高粘度指数聚α-烯烃（HVI-PAO）的油组合物。 在一个实施方案中，油配方包含粘度大于125cSt kv 100℃，粘度指数大于100的茂金属催化的HVI-PAO，粘度至少为2cSt kv 100℃的第二种基础油。 并且小于60cSt kv 100℃，其中第二基础原料比金属茂HVI-PAO至少60cSt kv 100℃，粘度至少为2且小于6的酯，所述酯包含 大于10重量％且小于30重量％的油配方，油配方具有大于195的粘度指数。在双峰共混物中使用茂金属催化的HVI-PAO提供改进的剪切稳定性和其它性能的优点 与剪切稳定性有关。

公开(公告)号：US08748361B2

公开(公告)日：2014-06-10

申请号：US11995118

申请日：2006-06-02

Applicant: Margaret May-Som Wu ,  Lisa Saunders Baugh ,  Jo Ann Marie Canich ,  Chia Shian Chee ,  Mark Paul Hagemeister ,  Andrew Jackson ,  Peijun Jiang ,  Gordon H. Lee ,  Frederick Yip-Kwai Lo ,  Steven P. Rucker ,  Shakeel Tirmizi ,  John F. Walzer, Jr. ,  Norman Yang

Inventor： Margaret May-Som Wu ,  Lisa Saunders Baugh ,  Jo Ann Marie Canich ,  Chia Shian Chee ,  Mark Paul Hagemeister ,  Andrew Jackson ,  Peijun Jiang ,  Gordon H. Lee ,  Frederick Yip-Kwai Lo ,  Steven P. Rucker ,  Shakeel Tirmizi ,  John F. Walzer, Jr. ,  Norman Yang

IPC: C10L1/16

CPC classification number: C07C11/02 ,  C07C2/02 ,  C07C2/34 ,  C07C5/05 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/14 ,  C08F110/14 ,  C08F210/04 ,  C08F210/14 ,  C10M107/10 ,  C10M143/08 ,  C10M2205/026 ,  C10M2205/0265 ,  C10M2205/028 ,  C10M2205/0285 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2220/025 ,  C10N2220/026 ,  C10N2220/028 ,  C10N2220/033 ,  C10N2270/00 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/20 ,  C08F2500/02

Abstract: This invention relates to a polyalpha-olefin (and hydrogenated analogs thereof) comprising more than 50 mole % of one or more C5 to C24 alpha-olefin monomers where the polyalpha-olefin has: a) 40 mole % or more of mm triads, b) a Bromine number of Y or greater, where Y is equal to 89.92*(V)′°5863, where V is the Kinematic Viscosity of the polyalpha-olefin measured at 100° C. in cSt, and c) 1,2 disubstituted olefins present at 7 mole % or more, preferably having Z mole % or more of units represented by the formula: where j, k and m are each, independently, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, or 22, n is an integer from 1 to 350, and where Z=8.420*Log(V)−4.048, where V is the kinematic viscosity of the polyalpha-olefin measured at 1000 C in cSt This invention also relates to process to produce such polyalpha-olefins.

Abstract translation: 本发明涉及包含大于50摩尔％的一种或多种C 5〜C 24α-烯烃单体的聚α-烯烃（及其氢化类似物），其中聚α-烯烃具有：a）40摩尔％以上的mm三单元组，b ）Y或更大的溴数，其中Y等于89.92 *（V）'°5863，其中V是在100℃下在cSt中测量的聚α-烯烃的运动粘度，c）1,2二取代 存在7摩尔％以上的烯烃，优选具有Z摩尔％以上的由下式表示的单元：其中j，k和m各自独立地为3，4，5，6，7，8，9，10， 11，12，13，14，15，16，17，18，19，20，21或22，n为1〜350的整数，Z = 8.420 * Log（V）-4.048，其中V为 在1000℃下测量的聚α-烯烃的运动粘度在cSt中本发明还涉及生产这种聚α-烯烃的方法。

公开(公告)号：US08476205B2

公开(公告)日：2013-07-02

申请号：US12587040

申请日：2009-10-01

Applicant: Gordon H. Lee ,  Kevin J. Kelly ,  Marcia G. Rogers ,  Kevin A. Chinn

Inventor： Gordon H. Lee ,  Kevin J. Kelly ,  Marcia G. Rogers ,  Kevin A. Chinn

IPC: C10M129/72 ,  C10M107/02

CPC classification number: C10M111/04 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2205/0285 ,  C10M2205/173 ,  C10M2207/2825 ,  C10M2229/02 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/024 ,  C10N2230/02 ,  C10N2230/68 ,  C10N2230/74 ,  C10N2240/04

Abstract: The invention relates to oil compositions containing chromium catalyzed high viscosity index polyalphaolefins (HVI-PAO). In one embodiment the oil formulation comprises a chromium catalyzed HVI-PAO with a viscosity greater than 125 cSt kv 100° C. and a viscosity index greater than 100, a second base stock with a viscosity of at least 2 cSt kv 100° C. and less than 60 cSt kv 100° C. wherein the second base stock is at least 120 cSt kv 100° C. less than the chromium HVI-PAO, an ester with a viscosity of at least 2 and less than 6, the ester chosen from the group consisting of monoester, di-octyl sebacate and any combination thereof comprising more than 10 weight percent and less than 30 weight percent of the oil formulation, the oil formulation having a viscosity index of greater than 180.

Abstract translation: 本发明涉及含铬催化的高粘度指数聚α-烯烃（HVI-PAO）的油组合物。 在一个实施方案中，油配方包含粘度大于125cSt kv 100℃，粘度指数大于100的铬催化的HVI-PAO，粘度至少为2cSt kv 100℃的第二种基础油。 并且小于60cSt kv 100℃，其中第二基础原料比CVI至少为120cSt kv 100℃，低于铬HVI-PAO，粘度至少为2且小于6的酯，所选择的酯 来自由单酯，癸二酸二辛酯及其任何组合组成的组，其包含大于10重量％且小于30重量％的油配方，该油配方具有大于180的粘度指数。

公开(公告)号：US20100105589A1

公开(公告)日：2010-04-29

申请号：US12587040

申请日：2009-10-01

Applicant: Gordon H. Lee ,  Kevin J. Kelly ,  Marcia G. Rogers ,  Kevin A. Chinn

Inventor： Gordon H. Lee ,  Kevin J. Kelly ,  Marcia G. Rogers ,  Kevin A. Chinn

IPC: C10M169/00

CPC classification number: C10M111/04 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2205/0285 ,  C10M2205/173 ,  C10M2207/2825 ,  C10M2229/02 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/024 ,  C10N2230/02 ,  C10N2230/68 ,  C10N2230/74 ,  C10N2240/04

Abstract: The invention relates to oil compositions containing chromium catalyzed high viscosity index polyalphaolefins (HVI-PAO). In one embodiment the oil formulation comprises a chromium catalyzed HVI-PAO with a viscosity greater than 125 cSt kv 100° C. and a viscosity index greater than 100, a second base stock with a viscosity of at least 2 cSt kv 100° C. and less than 60 cSt kv 100° C. wherein the second base stock is at least 120 cSt kv 100° C. less than the chromium HVI-PAO, an ester with a viscosity of at least 2 and less than 6, the ester chosen from the group consisting of monoester, di-octyl sebacate and any combination thereof comprising more than 10 weight percent and less than 30 weight percent of the oil formulation, the oil formulation having a viscosity index of greater than 180.

Abstract translation: 本发明涉及含铬催化的高粘度指数聚α-烯烃（HVI-PAO）的油组合物。 在一个实施方案中，油配方包含粘度大于125cSt kv 100℃，粘度指数大于100的铬催化的HVI-PAO，粘度至少为2cSt kv 100℃的第二种基础油。 并且小于60cSt kv 100℃，其中第二基础原料比CVI至少为120cSt kv 100℃，低于铬HVI-PAO，粘度至少为2且小于6的酯，所选择的酯 来自由单酯，癸二酸二辛酯及其任何组合组成的组，其包含大于10重量％且小于30重量％的油配方，该油配方具有大于180的粘度指数。

公开(公告)号：US20120302478A1

公开(公告)日：2012-11-29

申请号：US13117684

申请日：2011-05-27

Applicant: Evelyn N. Drake ,  James T. Carey ,  Suzzy C. Ho ,  Gordon H. Lee ,  Martin N. Webster

Inventor： Evelyn N. Drake ,  James T. Carey ,  Suzzy C. Ho ,  Gordon H. Lee ,  Martin N. Webster

IPC: C10M129/72 ,  C10M129/68

CPC classification number: C10M169/04 ,  C10M177/00 ,  C10M2205/0285 ,  C10M2207/30 ,  C10M2207/301 ,  C10M2209/109 ,  C10N2230/58 ,  C10N2250/02 ,  C10N2270/00

Abstract: This invention provides a method for producing a lubricant composition that is comprised of a continuous phase and a discontinuous phase. The method involves mixing together high viscosity ester, ether or combination thereof, and polar diluent or solvent, to produce a solution. The solution is then added to a low viscosity Group IV base oil to produce a discontinuous phase dispersed throughout a continuous phase.

Abstract translation: 本发明提供一种由连续相和不连续相组成的润滑剂组合物的制造方法。 该方法包括将高粘度酯，醚或其组合以及极性稀释剂或溶剂混合在一起以产生溶液。 然后将溶液加入到低粘度的IV族基础油中以产生分散在连续相中的不连续相。

公开(公告)号：US20100087349A1

公开(公告)日：2010-04-08

申请号：US12587039

申请日：2009-10-01

Applicant: Gordon H. Lee ,  Kevin A. Chinn

Inventor： Gordon H. Lee ,  Kevin A. Chinn

IPC: C10M129/72

CPC classification number: C10M111/04 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2205/0285 ,  C10M2205/173 ,  C10M2207/2825 ,  C10M2229/02 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/024 ,  C10N2230/02 ,  C10N2230/68 ,  C10N2230/74 ,  C10N2240/04

Abstract: The invention relates to oil compositions containing metallocene catalyzed high viscosity index polyalphaolefins (HVI-PAO). In one embodiment the oil formulation comprises a metallocene catalyzed HVI-PAO with a viscosity greater than 125 cSt kv 100° C. and a viscosity index greater than 100, a second base stock with a viscosity of at least 2 cSt kv 100° C. and less than 60 cSt kv 100° C. wherein the second base stock is at least 60 cSt kv 100° C. less than the metallocene HVI-PAO, an ester with a viscosity of at least 2 and less than 6, the ester comprising more than 10 weight percent and less than 30 weight percent of the oil formulation, the oil formulation having a viscosity index of greater than 195. The use of metallocene catalyzed HVI-PAOs in a bimodal blend provides advantages in improved shear stability, and other properties related to shear stability.

Abstract translation: 本发明涉及含有茂金属催化的高粘度指数聚α-烯烃（HVI-PAO）的油组合物。 在一个实施方案中，油配方包含粘度大于125cSt kv 100℃，粘度指数大于100的茂金属催化的HVI-PAO，粘度至少为2cSt kv 100℃的第二种基础油。 并且小于60cSt kv 100℃，其中第二基础原料比金属茂HVI-PAO至少60cSt kv 100℃，粘度至少为2且小于6的酯，所述酯包含 大于10重量％且小于30重量％的油配方，油配方具有大于195的粘度指数。在双峰共混物中使用茂金属催化的HVI-PAO提供改进的剪切稳定性和其它性能的优点 与剪切稳定性有关。

公开(公告)号：US20090005279A1

公开(公告)日：2009-01-01

申请号：US11995118

申请日：2006-06-02

Applicant: Margaret May-Som Wu ,  Lisa Saunders Baugh ,  Jo Ann Canich ,  Chia Shian Chee ,  Mark Paul Hagemeister ,  Andrew Jackson ,  Peijun Jiang ,  Gordon H. Lee ,  Frederick Yip-Kwai Lo ,  Steven P. Rucker ,  Shakeel Tirmizi ,  John F. Walzer, JR. ,  Norman Yang

Inventor： Margaret May-Som Wu ,  Lisa Saunders Baugh ,  Jo Ann Canich ,  Chia Shian Chee ,  Mark Paul Hagemeister ,  Andrew Jackson ,  Peijun Jiang ,  Gordon H. Lee ,  Frederick Yip-Kwai Lo ,  Steven P. Rucker ,  Shakeel Tirmizi ,  John F. Walzer, JR. ,  Norman Yang

IPC: C10L1/20 ,  C08F114/14 ,  C08F4/42 ,  C10L1/16

CPC classification number: C07C11/02 ,  C07C2/02 ,  C07C2/34 ,  C07C5/05 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/14 ,  C08F110/14 ,  C08F210/04 ,  C08F210/14 ,  C10M107/10 ,  C10M143/08 ,  C10M2205/026 ,  C10M2205/0265 ,  C10M2205/028 ,  C10M2205/0285 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2220/025 ,  C10N2220/026 ,  C10N2220/028 ,  C10N2220/033 ,  C10N2270/00 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/20 ,  C08F2500/02

Abstract: This invention relates to a polyalpha-olefin (and hydrogenated analogs thereof) comprising more than 50 mole % of one or more C5 to C24 alpha-olefin monomers where the polyalpha-olefin has: a) 40 mole % or more of mm triads, b) a Bromine number of Y or greater, where Y is equal to 89.92*(V)′°5863, where V is the Kinematic Viscosity of the polyalpha-olefin measured at 100° C. in cSt, and c) 1,2 disubstituted olefins present at 7 mole % or more, preferably having Z mole % or more of units represented by the formula: where j, k and m are each, independently, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, or 22, n is an integer from 1 to 350, and where Z=8.420*Log(V)−4.048, where V is the kinematic viscosity of the polyalpha-olefin measured at 1000 C in cSt This invention also relates to process to produce such polyalpha-olefins.

Abstract translation: 本发明涉及包含大于50摩尔％的一种或多种C 5〜C 24α-烯烃单体的聚α-烯烃（及其氢化类似物），其中聚α-烯烃具有：a）40摩尔％以上的mm三单元组，b ）Y或更大的溴数，其中Y等于89.92 *（V）'°5863，其中V是在100℃下在cSt中测量的聚α-烯烃的运动粘度，c）1,2二取代 存在7摩尔％以上的烯烃，优选具有Z摩尔％以上的由下式表示的单元：其中j，k和m各自独立地为3，4，5，6，7，8，9，10， 11，12，13，14，15，16，17，18，19，20，21或22，n为1〜350的整数，Z = 8.420 * Log（V）-4.048，其中V为 在1000℃下测量的聚α-烯烃的运动粘度在cSt中本发明还涉及生产这种聚α-烯烃的方法。