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公开(公告)号:US09187600B2
公开(公告)日:2015-11-17
申请号:US13286639
申请日:2011-11-01
IPC分类号: H01G4/18 , C08G73/10 , H01L51/00 , C09D179/08 , H01L51/50
CPC分类号: C08G73/101 , C08G73/1025 , C08G2261/92 , C09D179/08 , H01L51/006 , H01L51/5012
摘要: The present invention provides a process for the preparation of a transistor on a substrate, which transistor comprises a layer, which layer comprises polyimide B, which process comprises the steps of i) forming a layer comprising photocurable polyimide A by applying photocurable polyimide A on a layer of the transistor or on the substrate ii) irradiating the layer comprising photocurable polyimide A with light of a wavelength of >=360 nm in order to form the layer comprising polyimide B, and a transistor obtainable by that process.
摘要翻译: 本发明提供了一种在衬底上制备晶体管的方法,该晶体管包括一层,该层包括聚酰亚胺B,该层包括以下步骤:i)通过将光固化性聚酰亚胺A涂覆在 晶体管或衬底上的层; ii)为了形成包含聚酰亚胺B的层,以及可通过该方法获得的晶体管,将波长> = 360nm的光照射到包含可光固化聚酰亚胺A的层上。
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公开(公告)号:US08436208B2
公开(公告)日:2013-05-07
申请号:US12921176
申请日:2009-03-06
IPC分类号: C07C233/00 , C07C235/00 , C07C237/00 , C07C239/00
CPC分类号: C07D333/28 , C07D495/04 , C07D495/14 , C07F7/0814 , C07F9/6578 , C08G61/12 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/141 , C08G2261/3223 , C08G2261/3244 , C08G2261/3247 , C08G2261/364 , C08G2261/92 , H01L51/0036 , H01L51/0043 , H01L51/0094 , Y02E10/549
摘要: A process for the preparation of a substituted 2,2′-dithiophene is described, which process comprises the steps (a), (c) and optional steps (b) and (d): a reaction of a compound of the formula: with a suitable lithium organic compound, preferably Li-alkyl or Li-alkylamide; b) optional exchange of lithium against another metal selected from Mg1 Zn and Cu; c) reaction of the metallated intermediate obtained in step (a) or (b) with a suitable electrophil, which is CO2 or an aldehyde (addition reaction), or a compound Y′—R17 or Y′—R18-Z (substitution reaction), where R17 and R18 are as defined in claim 1; and optionally d) modification of the product obtained in step (c), e.g. by introducing one or more conjugating moieties Y ring closure between suitable monovalent residues R17, exchange or extension of functional groups or substituents such as addition to carbonyl or substitution of carbonyl in R17 or R18. The products, including or corresponding polymers, are excellent conducting materials
摘要翻译: 描述了制备取代的2,2'-二噻吩的方法,该方法包括步骤(a),(c)和任选步骤(b)和(d):下式化合物与 合适的锂有机化合物,优选为Li-烷基或Li-烷基酰胺; b)任选地将锂与另一种选自Mg1 Zn和Cu的金属交换; c)将步骤(a)或(b)中获得的金属化中间体与合适的亲电体(其为CO 2或醛(加成反应))或化合物Y'-R17或Y'-R18-Z(取代反应 ),其中R 17和R 18如权利要求1所定义; 和任选地d)修饰步骤(c)中获得的产物,例如, 通过在合适的单价残基R17之间引入一个或多个缀合部分Y闭环,官能团或取代基的交换或延伸,例如加成羰基或在R17或R18中取代羰基。 包括或相应的聚合物的产品是优良的导电材料
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公开(公告)号:US07723521B2
公开(公告)日:2010-05-25
申请号:US11919605
申请日:2006-05-03
IPC分类号: C07D471/02 , H01L21/02
CPC分类号: C09B5/028 , C07D471/06 , H01L51/0067 , H01L51/0069 , H01L51/0071 , H01L51/0072 , H01L51/0512 , H01L51/0541 , H01L51/5012 , Y10S428/93
摘要: A novel semiconductor device comprises an azaperylene organic semiconductor of the formula I wherein the substitutents are defined herein.
摘要翻译: 一种新颖的半导体器件包括式I的氮杂伯有机半导体,其中取代基在本文中定义。
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公开(公告)号:US20090302311A1
公开(公告)日:2009-12-10
申请号:US12308037
申请日:2007-06-20
申请人: Mathieu G.R. Turbiez , René Albert Johan Janssen , Martinus Maria Wienk , Hans Jürg Kirner , Mathias Düggeli , Bernd Tieke , Yu Zhu
发明人: Mathieu G.R. Turbiez , René Albert Johan Janssen , Martinus Maria Wienk , Hans Jürg Kirner , Mathias Düggeli , Bernd Tieke , Yu Zhu
摘要: The present invention relates to polymers comprising a repeating unit of the formula (I) and their use as organic semiconductor in organic devices, especially a diode, an organic field effect transistor and/or a solar cell, or a device containing a diode and/or an organic field effect transistor, and/or a solar cell. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).
摘要翻译: 本发明涉及包含式(I)的重复单元及其在有机器件,特别是二极管,有机场效应晶体管和/或太阳能电池中的有机半导体的用途的聚合物,或包含二极管和/ 或有机场效应晶体管,和/或太阳能电池。 根据本发明的聚合物在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外,当根据本发明的聚合物用于半导体器件或有机光伏(PV)器件时,可以观察到高的能量转换效率,优异的场效应迁移率,良好的导通/截止电流比和/或优异的稳定性 太阳能电池)。
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公开(公告)号:US09233930B2
公开(公告)日:2016-01-12
申请号:US13322506
申请日:2010-05-21
IPC分类号: C08G75/00 , C07D233/28 , C08G61/12 , H01L51/00 , H01L51/05
CPC分类号: H01L51/0094 , C07D233/28 , C07D495/04 , C07D513/14 , C07F7/0814 , C08F128/06 , C08G61/122 , C08G61/123 , C08G61/126 , C08G75/06 , C08G75/32 , C08G2261/3241 , C08G2261/3243 , C08G2261/3247 , C08G2261/414 , C08G2261/92 , C09B57/00 , H01L51/0003 , H01L51/0036 , H01L51/0043 , H01L51/0071 , H01L51/0074 , H01L51/0545 , H01L51/0558 , Y02E10/549
摘要: The present invention relates to novel compounds of the formula (I) wherein R1 and R1′ independently of each other are H or a substituent, halogen or SiR6R4R5; R2 and R2′ may be the same or different and are selected from C1-C25alkyl, C3-C12-cycloalkyl, C2-C25alkenyl, C2-C25alkynyl, C4-C25aryl, C5-C25alkylaryl or C5-C25aralkyl, each of which is unsubstituted or substituted, and under conditions as defined in claim 1, R2 and/or R2′ may also be halogen or hydrogen; X is a divalent linking group selected from formula (Ia) and formula (Ib); Y and Y′ independently are selected from formula (Ic), formula (Id), formula (Ie), formula (If), formula (Ig); n and p independently range from 0 to 6; where further symbols are as defined in claim 1, and to corresponding oligomers and (co)polymers. The compounds according to the invention are useful as semiconductors and have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.
摘要翻译: 本发明涉及式(I)的新化合物,其中R1和R1'彼此独立地为H或取代基,卤素或SiR6R4R5; R2和R2'可以相同或不同,并且选自C 1 -C 25烷基,C 3 -C 12 - 环烷基,C 2 -C 25烯基,C 2 -C 25炔基,C 4 -C 25芳基,C 5 -C 25烷基芳基或C 5 -C 25芳烷基,其各自为未取代的或 并且在如权利要求1所定义的条件下,R 2和/或R 2'也可以是卤素或氢; X是选自式(Ia)和式(Ib)的二价连接基团; Y和Y'独立地选自式(Ic),式(Id),式(Ie),式(If),式(Ig); n和p独立地为0至6; 其中符号如权利要求1中所定义,以及相应的低聚物和(共)聚合物。 根据本发明的化合物可用作半导体并且在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外,当根据本发明的聚合物用于有机场效应晶体管,有机光伏(太阳能电池)中时,可以观察到高效率的能量转换,优异的场效应迁移率,良好的开/关电流比和/或优异的稳定性 )和光电二极管。
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公开(公告)号:US20120097935A1
公开(公告)日:2012-04-26
申请号:US13322506
申请日:2010-05-21
IPC分类号: H01L51/30 , C07D495/14 , H01L51/40 , C08F230/06 , C08G75/32 , C07F7/10 , C08F130/08
CPC分类号: H01L51/0094 , C07D233/28 , C07D495/04 , C07D513/14 , C07F7/0814 , C08F128/06 , C08G61/122 , C08G61/123 , C08G61/126 , C08G75/06 , C08G75/32 , C08G2261/3241 , C08G2261/3243 , C08G2261/3247 , C08G2261/414 , C08G2261/92 , C09B57/00 , H01L51/0003 , H01L51/0036 , H01L51/0043 , H01L51/0071 , H01L51/0074 , H01L51/0545 , H01L51/0558 , Y02E10/549
摘要: The present invention relates to novel compounds of the formula (I) wherein R1 and R1′ independently of each other are H or a substituent, halogen or SiR6R4R5; R2 and R2′ may be the same or different and are selected from C1-C25alkyl, C3-C12-cycloalkyl, C2-C25alkenyl, C2-C25alkynyl, C4-C25aryl, C5-C25alkylaryl or C5-C25aralkyl, each of which is unsubstituted or substituted, and under conditions as defined in claim 1, R2 and/or R2′ may also be halogen or hydrogen; X is a divalent linking group selected from formula (Ia) and formula (Ib); Y and Y′ independently are selected from formula (Ic), formula (Id), formula (Ie), formula (If), formula (Ig); n and p independently range from 0 to 6; where further symbols are as defined in claim 1, and to corresponding oligomers and (co)polymers. The compounds according to the invention are useful as semiconductors and have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.
摘要翻译: 本发明涉及式(I)的新化合物,其中R1和R1'彼此独立地为H或取代基,卤素或SiR6R4R5; R2和R2'可以相同或不同,并且选自C 1 -C 25烷基,C 3 -C 12 - 环烷基,C 2 -C 25烯基,C 2 -C 25炔基,C 4 -C 25芳基,C 5 -C 25烷基芳基或C 5 -C 25芳烷基,其各自为未取代的或 并且在如权利要求1所定义的条件下,R 2和/或R 2'也可以是卤素或氢; X是选自式(Ia)和式(Ib)的二价连接基团; Y和Y'独立地选自式(Ic),式(Id),式(Ie),式(If),式(Ig); n和p独立地为0至6; 其中符号如权利要求1中所定义,以及相应的低聚物和(共)聚合物。 根据本发明的化合物可用作半导体并且在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外,当根据本发明的聚合物用于有机场效应晶体管,有机光伏(太阳能电池)中时,可以观察到高效率的能量转换,优异的场效应迁移率,良好的开/关电流比和/或优异的稳定性 )和光电二极管。
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公开(公告)号:US20120059140A1
公开(公告)日:2012-03-08
申请号:US13256943
申请日:2010-03-22
申请人: Pascal Hayoz , Olivier Frédéric Aebischer , Mathias Düggeli , Hans Jürg Kirner , Marta Fonrodona Turon
发明人: Pascal Hayoz , Olivier Frédéric Aebischer , Mathias Düggeli , Hans Jürg Kirner , Marta Fonrodona Turon
IPC分类号: C08G73/06 , H01L51/40 , C07D487/04
CPC分类号: H01L51/0036 , C07D487/04 , C07D519/00 , C08G61/124 , C08G61/126 , C08G2261/124 , C08G2261/1412 , C08G2261/18 , C08G2261/228 , C08G2261/3223 , C08G2261/3241 , C08G2261/3243 , C08G2261/334 , C08G2261/598 , C08G2261/91 , C08G2261/92 , C08G2261/94 , C08G2261/95 , C09B57/004 , C09B69/109 , H01B1/127 , H01L51/0003 , H01L51/0035 , H01L51/0043 , H01L51/0053 , H01L51/0558 , H01L51/42 , Y02E10/549
摘要: The present invention relates to polymers comprising one or more (repeating) unit(s) of the formula (I) which are characterized in that Ar1 and Ar1′ are independently of each other are an annulated (aromatic) heterocyclic ring system, containing at least one thiophene ring, which may be optionally substituted by one, or more groups, and their use as organic semiconductor in organic devices, especially in organic photovoltaics (solar cells) and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.
摘要翻译: 本发明涉及包含一种或多种式(I)的(重复)单元的聚合物,其特征在于Ar1和Ar1'彼此独立地为环状(芳族)杂环体系,至少含有 一个噻吩环,其可以任选地被一个或多个基团取代,并且它们在有机器件中的用途,特别是有机光伏(太阳能电池)和光电二极管中的有机半导体,或者在含有二极管和/或有机场的器件中 效应晶体管。 根据本发明的聚合物在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外,当根据本发明的聚合物用于有机场效应晶体管,有机光伏(太阳能电池)中时,可以观察到高效率的能量转换,优异的场效应迁移率,良好的开/关电流比和/或优异的稳定性 )和光电二极管。
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公开(公告)号:US20090299070A1
公开(公告)日:2009-12-03
申请号:US12086157
申请日:2006-12-04
申请人: Ulrich Berens , Frank Bienewald , Hans Jürg Kirner
发明人: Ulrich Berens , Frank Bienewald , Hans Jürg Kirner
IPC分类号: C07D471/04 , C07D495/04 , C07F7/10 , C07D487/04 , H01L51/40 , H01L51/30
CPC分类号: H01L51/0071 , C07D471/04 , C07D487/04 , C07D493/04 , C07D495/04 , C07D495/22 , C07D513/04 , C09B5/026 , C09B5/14 , C09B5/60 , C09B57/00 , C09B69/008 , H01L51/0058 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0074 , H01L51/0083 , H01L51/0094 , H01L51/0525 , H01L51/0545
摘要: The invention relates to a semiconductor device comprising a compound of the formula I and of the formula XXI, wherein the symbols have the meanings defined in the specification, to the novel compounds of the formula I and XXI and to the use of such a compound as an organic semiconductor for the preparation of an electronic device, and further compounds and devices, as well as other embodiments given in the specification.
摘要翻译: 本发明涉及一种半导体器件,其包含式I和式XXI的化合物,其中符号具有本说明书中定义的含义与式I和XXI的新型化合物以及使用这样的化合物 用于制备电子器件的有机半导体,以及本说明书中给出的其它化合物和器件以及其它实施方案。
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公开(公告)号:US07442838B2
公开(公告)日:2008-10-28
申请号:US11101860
申请日:2005-04-08
申请人: Paul Adriaan Van Der Schaaf , Franz Schwarzenbach , Hans Jürg Kirner , Martin Szelagiewicz , Claudia Marcolli , Andreas Burkhard
发明人: Paul Adriaan Van Der Schaaf , Franz Schwarzenbach , Hans Jürg Kirner , Martin Szelagiewicz , Claudia Marcolli , Andreas Burkhard
IPC分类号: C07C211/42
CPC分类号: A61K31/137 , A61K31/135 , C07C211/42 , C07C2602/10
摘要: Sertraline hydrochloride polymorphic form II is conveniently prepared by adding hydrogen chloride to solution of sertraline free amine in a ketone. In preferred processes, the solution of sertraline free amine seeded with some crystals of polymorphic form II and/or the solution is heated before addition of the hydrogen chloride.
摘要翻译: 盐酸舍曲林多晶型II通过将氯化氢加入酮中的舍曲林游离胺溶液方便地制备。 在优选的方法中,在加入氯化氢之前加入接种有多晶型II和/或溶液的一些晶体的舍曲林游离胺溶液。
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公开(公告)号:US07019161B2
公开(公告)日:2006-03-28
申请号:US10313041
申请日:2002-12-06
IPC分类号: C07C261/00 , C07C229/00 , C07C205/00
CPC分类号: C07C227/32 , C07B2200/07 , C07C227/34
摘要: The present invention relates to novel processes for the preparation of optically active 3-aminocarboxylic acids and their esters, in particular processes for the preparation of optically active compounds of the formula IA or IB as free bases or as acid addition salts thereof, in which the radicals are as defined in the description; in particular using the catalytic hydrogenation of olefinic precursors in the presence of platinum on alumina as a catalyst and the removal of chiral auxiliary groups from salt precursors; and novel process sections in the route for their synthesis, and processes for the preparation of biologically, in particular pharmacologically, active compounds, which comprise the novel processes.
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